Earth Sciences Commons^™

Geotraces And Beyond: Studies Of Trace Elements In Coastal And Open Ocean Waters With An Emphasis On The Effects Of Oxygen Depletion And Hydrothermal Plumes, Peng Ho

Dissertations

We investigated various dissolved trace element (dTE) distributions in two distinct areas: the coastal northern Gulf of Mexico and the eastern tropical Pacific Ocean.

A multi-year (2007‒2011) chemical time series of eight stations in the western Mississippi Sound (MS) and northwestern Mississippi Bight (MB) was undertaken to examine the factors affecting chemical distributions in this dynamic region. Key findings include the frequent development of bottom water hypoxia in MB during late spring-summer, the likely contribution of submarine groundwater discharge (SGD) to the material flows, and observation of effects of episodic events including tropical storms and the opening of the Bonnet …

Managing Herbicide Resistance: Listening To The Perspectives Of Practitioners. Procedures For Conducting Listening Sessions And An Evaluation Of The Process, Jill Schroeder, Michael Barrett, David R. Shaw, Amy B. Asmus, Harold Coble, David Ervin, Raymond A. Jussaume Jr., Micheal D. K. Owen, Ian Burke, Cody F. Creech, A. Stanley Culpepper, William S. Curran, Darrin M. Dodds, Todd A. Gaines, Jeffrey L. Gunsolus, Bradley D. Hanson, Prashant Jha, Annie E. Klodd, Andrew R. Kniss, Ramon G. Leon, Sandra Mcdonald, Don W. Morishita, Brian J. Schutte, Christy L. Sprague, Phillip W. Stahlman, Larry E. Steckel, Mark J. Vangessel

Plant and Soil Sciences Faculty Publications

Seven half-day regional listening sessions were held between December 2016 and April 2017 with groups of diverse stakeholders on the issues and potential solutions for herbicide-resistance management. The objective of the listening sessions was to connect with stakeholders and hear their challenges and recommendations for addressing herbicide resistance. The coordinating team hired Strategic Conservation Solutions, LLC, to facilitate all the sessions. They and the coordinating team used in-person meetings, teleconferences, and email to communicate and coordinate the activities leading up to each regional listening session. The agenda was the same across all sessions and included small-group discussions followed by reporting …

Characterizing Polychlorinated Biphenyl Degradation Potential In Surface Water Bacteria From Rio Grande Valley, Texas Reservoirs, Alisha M. Janiga

Theses and Dissertations

The Donna Reservoir in Donna, Texas is contaminated with polychlorinated biphenyl (PCB) pollution. This reviews the current understanding of PCBs and investigate the potential of PCB degradation by native bacteria communities in the Donna Reservoir. The metabolic diversity, biphenyl tolerance, bphA1 presence were tested on surface water samples from the Donna Reservoir. The Ecoplate data suggest that the communities have a diverse metabolic capacity and the degree of plant life may interact with carbon type metabolism but not the rate of growth. Biphenyl growth curves showed that all the samples from the Donna Reservoir are tolerant to the average PCB …

Improvement Of Soil Structure Through Organic Crop Management, Conservation Tillage And Grass-Clover Ley, Viviana Loaiza Puerta, Engil Isadora Pujol Pereira, Raphaël Wittwer, Marcel G. A. Van Der Heijden, Johan Six

School of Earth, Environmental, & Marine Sciences Faculty Publications

Highlights

• Organic crop management combined with reduced tillage improved soil structure.
• The ley period improved soil structure for conventional intensive tillage.
• The ley period increased total carbon in organic crop management at 0–6 cm soil depth.

Abstract

Conventional intensive tillage is a widespread soil management practice that controls weeds and promotes nutrient mineralization at the expense of a degraded soil structure and soil carbon (C) loss. Alternative soil management practices such as no tillage, reduced tillage and temporary leys, however, can minimize the negative effects of intensive tillage on soil structure. To improve understanding of these management practices on …

Warning Confidence And Perceptions Of Lava Flow Hazard Diversion Strategies At Kīlauea And Mauna Loa Volcanoes, Hawai‘I, Ashleigh Reeves

Electronic Theses and Dissertations

The 2014-15 lava flow crisis at Kīlauea volcano, Hawai‘i and post-September 2015 elevated unrest at adjacent Mauna Loa volcano provided opportunities to assess households’ psychological and behavioral responses to different levels of volcanic activity. Weused the Protective Action Decision Model to examine stakeholder perceptions and confidence in warnings, in addition toattitudes toward lava flow mitigation strategies, such as diversion by berms and bombing, and people’s acceptance of additional risk to personal property in exchange for protecting important elements of their community, such as schools, major roads, electrical substation, and shopping centers. Respondents’ confidence in events important in decision-making during emergencies …

Sequence Stratigraphy Of Campanian-Maastrichtian Strata In Eastern Alabama, David Simmons

Master's Theses

Eastern Alabama is an area of interest due to the transition from the Gulf Coastal Plain to the Atlantic Coastal Plain. Coastal Plain investigations have been sparse compared to research conducted in the oil rich areas down dip in the Gulf of Mexico. A sequence stratigraphic framework using the T-R cycle methodology of Embry (2002) has been established by integrating surface and subsurface lithologic data with biostratigraphic zonations into Petra ®. High sedimentation from the ancestral Chattahoochee River and lower relative sea-level formed an additional depositional sequence within the Santonian-Campanian aged Blufftown Formation in eastern Alabama. The sequence is approximately …

Mapping Lower Austin Chalk Secondary Porosity Using Modern 3-D Seismic And Well Log Methods In Zavala County, Texas, David Kilcoyne

Graduate Theses and Dissertations

Establishing fracture distribution and porosity trends is key to successful well design in a majority of unconventional plays. The Austin Chalk has historically been referred to as an unpredictable producer due to high fracture concentration and lateral variation in stratigraphy, however recent drilling activity targeting the lower Austin Chalk has been very successful. The Upper Cretaceous Austin Chalk (AC) and underlying Eagle Ford (EF) units are considered by many to act as a single hydrocarbon system, with communication between these two units largely through expulsion or dewatering fractures, extensional faults or along the AC/EF unconformity. Total porosity for the Eagle …

The Occurrence Of The Greta Sandstone, Frio Formation (Late Oligocene), Texas Gulf Coastal Plain, Sean C. Kincade

Graduate Theses and Dissertations

The Greta sandstone is an informal lithostratigraphic unit of the upper Frio Formation (Oligocene) that occurs across the Texas Gulf Coastal Plain. The Greta sandstone has been known to geologists since it was first drilled in the 1930’s, yet there has been very little research into this un-depleted and overlooked reservoir. This study provides insights into the lateral distribution and reservoir facies of the Greta sandstone. The unit represents an aggradational to transgressive barrier sandstone package grading up to mud-rich open marine inner shelf deposits. The interval is easily recognizable in well logs based on its strong SP and Gamma-ray …

Kinetic Processes And Stable Isotopes In Cave Dripwaters As Indicators Of Winter Severity, Vasile Ersek, Bogdan P. Onac, Aurel Perșoiu

School of Geosciences Faculty and Staff Publications

We examine how the stable isotope composition of meteoric water is transmitted through soil and epikarst to dripwaters in a cave in western Romania. δ²H and δ¹⁸O in precipitation at this site are influenced by temperature and moisture sources (Atlantic and Mediterranean), with lower δ¹⁸O in winter and higher in summer. The stable isotope composition of cave dripwaters mimics this seasonal pattern of low and high δ¹⁸O, but the onset and end of freezing conditions in the winter season are marked by sharp transitions in the isotopic signature of cave dripwaters of …

The Geotraces Intermediate Data Product 2017, Reiner Schlitzer, Robert F. Anderson, Elena Masferrer Dodas, Maeve Lohan, Walter Geibert, Alessandro Tagliabue, Andrew Bowie, Gregory A. Cutter, Peter N. Sedwick, Bettina Sohst

OES Faculty Publications

The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and …

Dissolution Rates Of Allophane, Fe-Allophane, And Hisingerite And Implications For Aqueous Alteration On Mars And In Potential Returned Martian Samples, S. J. Ralston

UNLV Theses, Dissertations, Professional Papers, and Capstones

Recent measurements from Mars document X-ray amorphous/nano-crystalline materials in multiple locations across the planet. However, despite their prevalence, little is known about these materials or what their presence implies for the history of Mars. The amorphous component of the martian soil in Gale Crater has an X-ray diffraction pattern that can be partially fit with allophane (approximately Al2O3•(SiO2)1.3-2•(H2O)2.5-3), as well as low-temperature water release consistent with allophane. The chemical data from Gale Crater suggest that other silicate phases similar to allophane, such as Fe-substituted allophane (here, approximately (Fe2O3)0.01(Al2O3)0.99(SiO2)2•3H2O) and hisingerite (approximately Fe3+2Si2O5(OH)4•(H2O)), may also be present. In order to investigate …

Thermobarometry Of The Moine And Sgurr Beag Thrust Sheets, Northern Scotland, Sarah E. Mazza, Calvin Mako, Richard D. Law, Mark J. Caddick, Maarten Krabbendam, John Cottle

Geosciences: Faculty Publications

In the Caledonides of northern Scotland temperatures of metamorphism (Tm) and deformation (Td) progressively increase structurally up section in the Moine thrust sheet at the foreland edge of the Scandian (mid Silurian) orogenic wedge. However, the thermal history of the structurally overlying, more hinterland positioned thrust sheets is less well known. This study focuses on determining Td and Tm for both the central/upper part of the Moine thrust sheet and the lower part of the overlying Sgurr Beag thrust sheets in the middle of the Northern Highlands Terrane. Preserved microstructures and quartz c-axis fabric opening angles in the Moine and …

Mitigating Accumulation Of Aeolian Dust Particles On Solar Power Generator Panels Without Water, Sanjana Das

UNLV Theses, Dissertations, Professional Papers, and Capstones

Accumulation of dust on solar panels poses a serious problem as it can significantly reduce light absorption and electrical energy output. Several factors affect the dust accumulation such as location, dust properties, wind velocity, system orientation, ambient temperature, humidity, and panel surface properties. Experimental and theoretical studies show that short circuit current and maximum power output of photovoltaic panels reduce approximately linearly with dust concentration. Incidentally, the locations with higher solar energy concentrations are also arid or semi-arid regions with higher dust concentrations. In order to avoid loss in power output, most PV installations perform periodic panel cleaning with water. …

Testing An Improved Method For Estimating The Unsaturated Hydraulic Conductivity Of Moderately Dry Soils, Sara Gedo

UNLV Theses, Dissertations, Professional Papers, and Capstones

Prediction of water movement in the vadose zone requires knowledge of either the unsaturated hydraulic conductivity, K(θ), or the hydraulic diffusivity, D(θ), of the soil as a function of the moisture content. However, both K(θ) and D(θ) are difficult to obtain for moderately dry soils because the tests are time consuming and expensive. In order to address this issue, Globus and Gee (1995) developed a “heat pipe” method that allowed for the direct estimation of D(θ) and K(θ) for moderately dry soils on relatively short time scales. They proposed that exposing a sealed horizontal soil column to a steady thermal …

Coastal Wetland Dynamics Under Sea-Level Rise And Wetland Restoration In The Northern Gulf Of Mexico Using Bayesian Multilevel Models And A Web Tool, Tyler Hardy

Master's Theses

There is currently a lack of modeling framework to predict how relative sea-level rise (SLR), combined with restoration activities, affects landscapes of coastal wetlands with uncertainties accounted for at the entire northern Gulf of Mexico (NGOM). I developed such a modeling framework – Bayesian multi-level models to study the spatial pattern of wetland loss in the NGOM, driven by relative RSLR, vegetation productivity, tidal range, coastal slope, and wave height – all interacting with river-borne sediment availability, indicated by hydrological regimes. These interactions have not been comprehensively investigated before. I further modified this model to assess the efficacy of restoration …

Projected Trends In Climate Extremes In The Passaic River Basin Based On Bias-Corrected And Spatially Downscaled Global Climate Model Simulations, Archana Prasad

Theses, Dissertations and Culminating Projects

Global Climate Models (GCMs) are increasingly becoming useful tools for predicting future climatic changes. These GCMs typically employ large spatial scales while municipalities may experience varied impacts at the local level. By downscaling and bias-correcting GCM outputs, more accurate predictions concerning specific regions can be made. The Multivariate Adaptive Constructed Analogs (MACA) models provide daily precipitation and temperature information for point localities by modifying coarse resolution data from GCMs to a higher spatial resolution. In this study, trends in climate extremes over the Passaic River Basin (PRB) between 1981-2005 are estimated based on three MACA models (bcc-csm1-1m, CCSM4, and MRI-CGCM3). …

Estimating Watershed Mercury Contribution To Lake Fort Smith State Park, Arkansas, Usa, William Miles Harmon

Graduate Theses and Dissertations

Mercury contamination associated with human activities poses global human health and environmental risks. A fish-consumption advisory has been in effect at Lake Fort Smith in central west Arkansas for more than a decade due to observed methylmercury concentrations in fish tissue. Lake Fort Smith is an important municipal drinking water supply and recreational resource. Water samples from the majority contributing tributary stream, Frog Bayou creek, were collected periodically, under differing hydrologic conditions in order to quantify the allochthonous mercury load delivered to the lake. Temperature, specific conductance, and turbidity data were collected and used to estimate dissolved organic carbon, methylmercury …

Quantifying Carbon Dioxide Fluxes In The Air And Water In Blowing Springs Cave, Arkansas, Holly Young

Graduate Theses and Dissertations

Prior work has shown that the concentration of carbon dioxide (CO2) within cave atmospheres is a function of cave airflow patterns. The dynamics of CO2 within karst systems are of increasing interest as they can control periods of precipitation or dissolution in speleothems and influence potential interpretations of paleoclimate records. Similarly, CO2 is an important driver of speleogenesis, and air-water CO2 dynamics can control patterns of cave passage evolution. Karst also plays an uncertain role in the global carbon cycle and understanding CO2 dynamics within karst systems will aid the development of carbon budgets. Here, a monitoring station was deployed …

Seismic Facies Mapping For Source Rock Distribution Of The Rakopi Formation In Deep-Water Taranaki Basin, New Zealand, Sidney W. Mahanay

Graduate Theses and Dissertations

The Taranaki Basin is located off the coast of the north island of New Zealand and is currently the only producing basin in New Zealand. Hydrocarbon accumulation in the Tui, Maari, and Maui fields is sourced to the Late Cretaceous and Paleogene units. Exploration of these units has extended from the continental shelf of the Taranaki Basin into the deep-water to the northwest. The Romney 3D survey and Romney–1 well are some the first public exploration projects to supply data from this area. The objective of this study is to estimate source rock quality and distribution of the Rakopi Formation …

Comparative Microbial Community Dynamics In A Karst Aquifer System And Proximal Surface Stream In Northwest Arkansas, Josue Rodriguez

Graduate Theses and Dissertations

Northwest Arkansas has well-developed karst systems, with numerous sinking streams and springs. Karst conduits make it easy for contaminants to enter groundwater systems, degrading the water quality and destroying fragile karst ecosystems. With the increase of urbanization, potential threats in the form of fecal contamination may prove to be more of a problem. The purpose of this research is to compare the difference between microbial communities within two different settings, a karst aquifer and a surface stream. The microbial communities within Blowing Spring Cave and Little Sugar Creek were detected and identified in water and sediment samples. Samples were also …

Flow Regime Influences On Stream And Riparian Soil Carbon Dynamics In The Ozark Highlands And Boston Mountains Of Arkansas, Allyn Dodd

Graduate Theses and Dissertations

The natural flow regime exerts primacy over lotic ecosystem patterns and processes. However, little work has examined the influence of flow regime on instream and riparian carbon (C) dynamics in minimally-impacted, temperate forested systems. To date, most research efforts have focused on characterizing C movement and transformations across biomes and land use categories; however, flow regime represents an overlooked, finer level of detail that may drive differences in ecosystem function. My dissertation objective was to measure C fixation and movement within and across multiple environmental spheres (e.g. within stream channels, between stream surfaces and the atmosphere, and from riparian soils …

Stratigraphic Evaluation Of The St. Joe-Boone Boundary Interval, Kinderhookian-Osagean Series, Lower Mississippian System, Tri-State Region, Southern Midcontinent, Forrest Dalton Mcfarlin

Graduate Theses and Dissertations

The Lower Mississippian interval comprises a single, third-order, eustatic cycle subdivided lithostratigraphically into the St. Joe Limestone (Hopkins 1893) and overlying Boone Formation (Branner 1891, Simonds 1891) with type areas in northern Arkansas. Coeval, homotaxial limestones occur in adjacent southwestern Missouri and northeastern Oklahoma. Missouri formation names for the St. Joe interval are recognized in Arkansas as members (ascending order): Bachelor, Compton, Northview, Pierson. The Boone interval in Missouri is represented by the (ascending order): Reeds Spring, Elsey, Burlington-Keokuk undifferentiated, but utilization of those names in Arkansas is problematic. in northern Arkansas, the Boone Formation is subdivided into informal lower …

Seismic Structure Near The Mariana Trench And Deep Earthquake Triggering In The Tonga Flat Slab, Chen Cai

Arts & Sciences Graduate Student Theses and Dissertations

This dissertation utilizes multiple techniques of earthquake location and seismic tomography to investigate deep seismicity in the Tonga flat slab region and the upper mantle structure of the Mariana subduction zone. I study the rupture property and aftershock distributions of the largest earthquake ever recorded in the Tonga flat slab region, defined by scattered seismicity and velocity anomalies. These, along with background seismicity, regional 3-D seismic velocity model and tectonic reconstructions of relict Vitiaz subduction zone, suggest the earthquakes are occurring in the final portion of the slab subducted at the now inactive Vitiaz trench. The associated Coulomb stress change …

Spatial And Temporal Trends Of Mining-Related Lead-Zinc Sediment Contamination, Galena River Watershed, Sw Wisconsin-Nw Illinois, Dylan Alexander King

Graduate Theses/Dissertations

Alluvial sediments within the Galena River Watershed were severely contaminated with heavy metals by historical zinc (Zn) and lead (Pb) mining operations during the early 1800s until 1979. Since the mines closed, there have been efforts to remediate on-site mine waste. However, the effectiveness of these efforts to reduce metal concentrations in stream sediments is unknown. This study compares present-day (2017) contamination trends in the Galena River Watershed to trends reported 25 years ago. A total of 415 sediment/soil samples were collected and analyzed using X-ray florescence spectrometry to determine sediment metal concentrations. The highest concentrations of zinc measured were …

Nutrient Transport And Storage In A Karst Spring-Reservoir System During Baseflow, Missouri Ozarks, Heather A. Moule

Graduate Theses/Dissertations

Urban and agricultural land uses are important sources of nitrogen and phosphorus which, if in excess, can cause eutrophication in lakes and rivers. There have been few studies of nutrient transport and storage in karst spring and reservoir connected stream systems draining the Missouri Ozarks. This study aims to link the baseflow nutrient contributions of Sanders Spring to downstream reservoir outflow and the Headwaters South Dry Sac River Watershed in Springfield, Missouri. Water samples were collected seasonally and analyzed for total nitrogen (TN), total phosphorus (TP), and several other water quality parameters. Discharge was also monitored to calculate water and …

Plant And Microbial Responses To Repeated Cu(Oh)2 Nanopesticide Exposures Under Different Fertilization Levels In An Agro-Ecosystem, Marie Simonin, Benjamin P. Colman, Weiyi Tang, Jonathan D. Judy, Steven M. Anderson, Christina M. Bergemann, Jennifer D. Rocca, Jason M. Unrine, Nicolas Cassar, Emily S. Bernhardt

Plant and Soil Sciences Faculty Publications

The environmental fate and potential impacts of nanopesticides on agroecosystems under realistic agricultural conditions are poorly understood. As a result, the benefits and risks of these novel formulations compared to the conventional products are currently unclear. Here, we examined the effects of repeated realistic exposures of the Cu(OH)₂ nanopesticide, Kocide 3000, on simulated agricultural pastureland in an outdoor mesocosm experiment over 1 year. The Kocide applications were performed alongside three different mineral fertilization levels (Ambient, Low, and High) to assess the environmental impacts of this nanopesticide under low-input or conventional farming scenarios. The effects of Kocide over time were …

Holocene Formation History Of Mud Depocenters On The Continental Shelf In The Gulf Of Cadiz, Southwestern Spain, Mary Lee King

Electronic Theses and Dissertations

Holocene mud accumulation on the continental shelf in northern Gulf of Cadiz, from the Guadalquivir River to the Tinto-Odiel Estuary, is described as two types of mud depocenters (MDCs): a sheet-like prodelta and mud belt. Despite a substantial number of investigations of this continental shelf (Somoza et al., 1997; Hernández-Molina et al., 2000; Lobo et al., 2001; synthesis: Lobo et al., 2015), information on Holocene sediment facies and a robust stratigraphic age model remained unestablished (Lobo et al., 2002; and Lobo and Ridente, 2014). Objectives of this study are to describe the dynamics of MDC formation in a chrono- and …

Hardbottom Characterization And Relationship To The Geologic Framework In Long Bay, South Carolina, Cathryn J. Wheaton

Electronic Theses and Dissertations

Hardbottom seafloor is a common element among sediment-starved portions of the inner continental shelf along the U.S. Atlantic margin. These areas are characterized by indurated sediment surfaces that are heavily altered by biological and physical processes. Long Bay, in northeastern South Carolina, offers ideal environmental conditions for hardbottom exposure with only patchy Holocene sand deposits, interspersed with extensive hardbottom areas. Here we use high-resolution multibeam bathymetry, CHIRP subbottom profiling and electrical resistivity data, along with surficial sediment samples, hardbottom thin sections, and water column radioisotope (radon-222) analysis to investigate the origin and geologic framework of a region of hardbottom seafloor …

The Efficacy Of Raw Malangali Kaolin Clay In The Adsorptive Removal Of Cadmium And Cobalt Ions From Water, Nyemaga Masanje Malima, Esther Hellen Lugwisha, Alinanuswe Simon Mwakaboko

Tanzania Journal of Science

The suitability of raw Malangali kaolin (RMK) clay for the removal of cadmium and cobalt ions from water was investigated using a batch technique whereas the characterization of adsorbent material was performed by XRD, XRF, ATR-FTIR and N2 physisorption techniques. Various experimental parameters were tested for the effectiveness of RMK in removing heavy metals whereby quantitative determination of both Cd2+ and Co2+ ions has shown that, the factors such as adsorbent particle size, solution pH, contact time, adsorbent dose as well as initial metal ion concentration had significant effects on the adsorption processes. The equilibrium data described by Langmuir and …

Dynamics Of Magma Recharge And Mixing At Mount Hood Volcano, Oregon -- Insights From Enclave-Bearing Lavas, Molly Kathryn Ellowitz

Dissertations and Theses

Magma recharge events and subsequent mixing processes are understood to precede volcanic eruptions. Textural evidence of intrusion of hot, mafic magma into a cooler, rheologically locked silicic magma is commonplace. Solidified "blobs" of injected magma, called enclaves, are evidence of magma mixing, but the petrological and mechanical conditions during their formation are debated. Mount Hood, Oregon consistently erupts andesite bearing compositionally similar enclaves. These enclaves are evidence of mingling and mixing of two magmas. However, due to the compositional similarity between enclave and host lava (e.g. ~1-5 wt.% difference in SiO₂), it is unclear whether the preserved enclaves …