Earth Sciences Commons^™

A Time Series Of Water Column Distributions And Sinking Particle Flux Of Pseudo-Nitzschia And Domoic Acid In The Santa Barbara Basin, California, Blaire P. Umhau, Claudia R. Benitez-Nelson, Clarissa R. Anderson, Kelly Mccabe, Christopher Burrell

Faculty Publications

Water column bulk Pseudo-nitzschia abundance and the dissolved and particulate domoic acid (DA) concentrations were measured in the Santa Barbara Basin (SBB), California from 2009–2013 and compared to bulk Pseudo-nitzschia cell abundance and DA concentrations and fluxes in sediment traps moored at 147 m and 509 m. Pseudo-nitzschia abundance throughout the study period was spatially and temporally heterogeneous (L⁻¹ to 3.8 × 10⁶ cells L⁻¹, avg. 2 × 10⁵ ± 5 × 10⁵ cells L⁻¹) and did not correspond with upwelling conditions or the total DA (tDA) concentration, which was also spatially …

The Neiumatic Shake Table: A New Tool, Elisabet M. Head, John Papiewski

Faculty Research and Creative Activities Symposium

No abstract provided.

Proceedings Of The First Annual Symposium On The Wright State Woods, College Of Science And Mathematics, College Of Liberal Arts

1st Annual Wright State Woods Symposium

The proceeding of the Woods Symposium held at Wright State University and sponsored by the College of Science and Mathematics and the College of Liberal Arts.

The Utility Of The Conductivity Mass-Balance Method For Base Flow Separation In Rivers And Streams, Darline Alegria Lott

USF Tampa Graduate Theses and Dissertations

Freshwater for ecosystems, drinking water, and water for various businesses are important resources and those resources are rapidly diminishing globally due to drought and overuse. In order to manage the availability of water for all concerned, good estimates of base flow (groundwater) is required. Base flow, a component of streamflow, is deduced by separating a stream hydrograph into two components, base flow and runoff. There are several techniques used to perform base flow separation; however two techniques are used in this study, chemical mass-balance and analytical methods. This dissertation explains how an analytical technique was derived from a mass-balance method, …

Evolution Of Noble Gas And Water Isotopes Along The Regional Groundwater Flow Path Of The Konya Closed Basin, Turkey, N. Nur Ozyurt, C. Serdar Bayari

International Journal of Speleology

Noble gas and water isotope compositions of regional groundwater were investigated along two transects in the Konya Closed Basin (KCB) of central Turkey. According to the ³He/⁴He versus Ne/He plot of samples, crust (up to 86%) and mantle (up to 26%) appear to be the primary and secondary sources of dissolved He in groundwater, respectively. After the beginning of both transects where the flow domain is confined, both ³He and ⁴He accumulate steadily in groundwater. Thereafter, the intermediate recharge from the surface in the unconfined part of regional flow system disrupts the steady accumulation trend …

Interpreting The Origin And Evolution Of ‘Karst’ Features From A Siliceous Hydrothermal Terrane: A Case Study From The Upper Geyser Basin In Yellowstone National Park, Usa, Kevin W. Blackwood, Lainee A. Sanders, Stacy I. Gantt-Blackwood

International Journal of Speleology

The Upper Geyser Basin in Yellowstone National Park occurs over a siliceous hydrothermal terrane containing numerous hot springs and geysers. The pool and vent-conduit geometries of these hydrothermal features share a resemblance to conventional karst features known from other rock types, suggesting karst processes could be responsible for their origin and/or evolution. Hypogene speleogenesis is a cave-forming process in which the formation of caves is decoupled from and occurs independently of surface recharge. The geologic setting for hypogene speleogenesis typically occurs at the distal end of regional groundwater systems wherein the hydrogeology is manifested by ascending fluids and/or by geochemical …

The Contribution Of Atmospheric Particulate Matter To The Formation Of Cx3r-Type Disinfection By-Products In Rainwater During Chlorination, Mengtian Hou, Wenhai Chu, Feifei Wang, Yang Deng, Naiyun Gao, Di Zhang

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Atmospheric particulate matter (PM) can be scavenged by rainfall and contribute dissolved organic matter (DOM) to rainwater. Rainwater may serve as a part or the whole of drinking water sources, leading to the introduction of PM-derived DOM into drinking water. However, little information is available on the role of PM-derived DOM as a remarkable precursor of CX3R-type disinfection by-products (DBPs) in rainwater. In this study, samples were collected from ten occurrences of rainfall in Shanghai and batch experiments were executed to explore the contribution of PM-derived DOM to CX3R-type DBP formation in rainwater and to further understand some of unknowns …

Martian Magmatism From Plume Metasomatized Mantle, James M. D. Day, Kimberly T. Tait, Arya Udry, Frédéric Moynier, Yang Liu, Clive R. Neal

Geoscience Faculty Research

Direct analysis of the composition of Mars is possible through delivery of meteorites to Earth. Martian meteorites include ∼165 to 2400 Ma shergottites, originating from depleted to enriched mantle sources, and ∼1340 Ma nakhlites and chassignites, formed by low degree partial melting of a depleted mantle source. To date, no unified model has been proposed to explain the petrogenesis of these distinct rock types, despite their importance for understanding the formation and evolution of Mars. Here we report a coherent geochemical dataset for shergottites, nakhlites and chassignites revealing fundamental differences in sources. Shergottites have lower Nb/Y at a given Zr/Y …

Assessing The Cooling Effects Of Urban Vegetation On Urban Heat Mitigation In Selected U.S. Cities, Qiuyan Yu

USF Tampa Graduate Theses and Dissertations

Urban Heat Island (UHI) is a growing problem worldwide. Mitigation of UHI is necessary for cities to adapt to climate change and enhance sustainable development at a city scale. Cooling cities with urban vegetation management is a sustainable solution for urban heat mitigation. Urban vegetation influences urban microclimate through the shading effect, surface roughness, and evapotranspiration. The differences in horizontal and vertical structures of urban vegetation determine the shading effect, surface roughness, and evapotranspiration. Enhancing the cooling effect of urban vegetation requires a comprehensive understanding of how vegetation structure affects UHI. The effects of horizontal structure on land surface temperature …

Post-Impact Light Vapor Incorporation During Lunar Formation Based On Triple Oxygen Isotopes, Erick J. Cano

Earth and Planetary Sciences ETDs

Initial triple oxygen isotope analyses of lunar samples showed them to be indistinguishable from Earth, which led to numerous papers aimed at explaining the similarities. Recent high-precision analyses suggested either a subtle enrichment in Δ'¹⁷O or virtually no difference between the Earth and Moon. Herein we expand on previous studies by correlating the triple oxygen isotope measurements with different lunar lithologies. We show that these data can be explained by mixing between a light vapor phase, generated during the Giant Impact, and the residual material from the proto-lunar impactor ‘Theia’. There is a general decrease in Δ'^{17 …}

Mantle-To-Surface Neotectonic Connections In The San Juan Mountains Documented By 3he/4he, Co2 Flux Meaurements, And Hydrochemical Analysis Of The Geothermal System Near Rico, Colorado, Benjamin D. Holt

Earth and Planetary Sciences ETDs

This project investigates the controls on geothermal fluids and their conduit systems which may account for high mantle helium components of geothermal fluids in intracratonic continental regions. The field laboratory is the western San Juan Mountains of southwestern Colorado where the structural setting and hydrochemistry of carbonic springs suggest potential connections among surface hot springs, fault networks, CO2 degassing, significant geothermal potential, young volcanic and plutonic rocks (< 7 Ma), and low-velocity upper mantle. The Rico Hot Springs have the highest mantle volatile component of any spring in Colorado with air-corrected values of 3He/4He = 5.88 RA indicating 73% mantle helium component. This near-MORB mantle helium value at Rico indicates that volatiles degassing from the mantle must be rapidly transmitted into the groundwater system along deep-seated faults such that accumulation of 4He from radiogenic crust has not swamped mantle-derived primordial 3He. Geologic features that are important for volatile transport and spring chemistry controls include a complex conduit system and fault network involving the Precambrian-cored Rico Dome, ~4 Ma intrusive rocks at Calico Peak and Priest Gulch, and a low-velocity upper mantle. Therefore, Rico and the surrounding region is a natural laboratory for studying geothermal fluid and mantle volatile pathways. Additional noble gas analyses and hydrochemistry data were gathered from regional springs and modeled via chemical geothermometers. New noble gas measurements from this study, paired with literature values, reveal highest air corrected 3He/4He at Rico (4.09-5.88 RA), Dunton (3.11-4.54 RA), Geyser Warm Spring (3.39 RA), and Paradise Warm Spring (2.72 RA). Water volume is dominated by meteoric fluids as shown by stable isotope data but hydrochemistry indicates high TDS, high CO2, and high He come from a geothermal fluid endmember. Variable mixing and water-rock interactions are processes that can explain chemistry variations between spatially proximal springs. CO2 flux measurements (up to 36.2 g/m2/hr) vary across structural features and demonstrate that the faults act as pathways for CO2 flux suggesting ongoing degassing. Overall, we find that local high mantle helium signature is localized directly above regions of lowest upper mantle velocity in the San Juan mantle anomaly and is derived from neotectonic mantle melts in those regions.

Use Of Sodium Dithionite For Groundwater Restoration Following Uranium In-Situ Recovery Mining At The Smith Ranch-Highalnd Site In Wyoming, Rose J. Harris

Earth and Planetary Sciences ETDs

Uranium in-situ recovery (ISR) is a subsurface aqueous mining technique used to extract uranium from sandstone roll-front deposits. After ISR mining, groundwater restoration is conducted to decrease concentrations of residual U(VI) and other contaminants leftover in the groundwater. Sodium dithionite, a strong chemical reductant, is being tested for use in groundwater restoration following uranium ISR at the Smith Ranch-Highland site in Wyoming. Sodium dithionite has been used to remediate chromium plumes by creating an in-situ permeable reactive barrier, but there has been no work using sodium dithionite for groundwater restoration following uranium ISR mining.

Laboratory batch and column experiments, and …

Sedimentology And Stratigraphy Of Core Stl14: An Early Pleistocene-To-Present Paleoclimate Archive From Stoneman Lake, Arizona, Spencer Staley

Earth and Planetary Sciences ETDs

An 80 m lacustrine sediment core (STL14) from Stoneman Lake, Coconino County, Arizona, contains a sedimentary sequence of at least 1.5 million years, chronicling the complete history of basin infill and recording an extensive and high-resolution archive of climatic and hydrologic fluctuations. Lake levels in this small, internally-drained catchment are sensitive to changes in regional hydrologic balance. Consistent groundwater inflow, even during regionally dry episodes in the lake’s history, has prevented complete desiccation of the lake and sustained continuous lacustrine deposition except for one soil horizon. Multiproxy analysis of sedimentological indicators including lithofacies, color, wet bulk density, magnetic susceptibility, preliminary …

Can The Desiccation Of Great Salt Lake Be Stopped?, Wayne A. Wurtsbaugh, Craig Miller, Sarah E. Null, R. Justin Derose, Peter Wilcock

Watershed Sciences Faculty Publications

Great Salt Lake is a terminal lake, with its watershed in the Wasatch and Uinta Mountains of Utah, Wyoming and Idaho. Like all terminal lakes, the water inflows are balanced only by evaporative loss from its surface—when inflows decrease the lake shrinks until evaporation matches that inflow.

Radionuclides In Rainwater And Their Impact On Background Radiation, Damien M. Milazzo

Earth and Planetary Sciences ETDs

Radioactive waste has accrued throughout the continental United States and in the Oceans surrounding the country. Significant quantities of the waste are poorly documented regarding their location and the radioisotopes contained in the waste. Locating the waste is not an easy matter, as its locations are not well documented, and its method of disposal may be covered with plants, soils, and sediments. A common tool used to locate the waste is a gamma spectrometer, which measure the gamma emissions spectrum of radionuclides. The effectiveness of this tool when utilized to locate gamma emitting waste may be reduced due to the …

Optical Remote Sensing Of Oil Spills In The Gulf Of Mexico, Shaojie Sun

USF Tampa Graduate Theses and Dissertations

Assessment of oil spills in the ocean using passive remote sensing (i.e., reflected sun light) faces two challenges: detect oil presence/absence and quantify oil volume. While the optical properties of oil allow it to be differentiated from the surrounding marine environment, sun glint can facilitate oil presence/absence detection because the oil-water spatial contrast is enhanced due to wave dampening. However, sun glint also modulates the magnitude and shape of the spectral reflectance of surface oil. In addition to this difficulty, the most critical challenge is how to quantify oil volume (or thickness) through remote sensing. To date, such quantifications have …

Water, Energy, And Carbon Footprints Of Bioethanol From The U.S. And Brazil, Mesfin Mekonnen, Thiago L. Romanelli, Chittaranjan Ray, Arjen Y. Hoekstra, Adam Liska, Christopher M. U. Neale

Adam Liska Papers

Driven by biofuel policies, which aim to reduce greenhouse gas (GHG) emissions and increase domestic energy supply, global production and consumption of bioethanol have doubled between 2007 and 2016, with rapid growth in corn-based bioethanol in the U.S. and sugar cane-based bioethanol in Brazil. Advances in crop yields, energy use efficiency in fertilizer production, biomass-to-ethanol conversion rates, and energy efficiency in ethanol production have improved the energy balance and GHG emission reduction potential of bioethanol. In the current study, the water, energy, and carbon footprints of bioethanol from corn in the U.S. and sugar cane in Brazil were assessed. The …

Enhancement Of Rainfall-Triggered Shallow Landslide Hazard Assessment At Regional And Site Scales Using Remote Sensing And Slope Stability Analysis Coupled With Infiltration Modeling, Thilanki Maneesha Dahigamuwa Rajaguru Mudiyanselage

USF Tampa Graduate Theses and Dissertations

Landslides cause significant damage to property and human lives throughout the world. Rainfall is the most common triggering factor for the occurrence of landslides. This dissertation presents two novel methodologies for assessment of rainfall-triggered shallow landslide hazard. The first method focuses on using remotely sensed soil moisture and soil surface properties in developing a framework for real-time regional scale landslide hazard assessment while the second method is a deterministic approach to landslide hazard assessment of the specific sites identified during first assessment. In the latter approach, landslide inducing transient seepage in soil during rainfall and its effect on slope stability …

The Fate Of Sulfur During Melting And Crystallization: Implications For Sulfur Transfer From Mantle To The Crust-Atmosphere System, Shuo Ding

Sustainability Seminar Series

Sulfur (S) is one of the most abundant volatiles; one that has a fundamental impact on various magmatic processes, from the mantle to the Earth’s surface. Ocean island basalts (OIB) are one of the critical probes for understanding the chemical, lithological and thermal variations in the Earth’s mantle. Therefore, S abundances of primary OIB that sample peridotite partial melts, as well as deeply recycled components, can provide a better understanding of the long-term S cycle on Earth. In this study, we developed a model to describe the behavior of sulfide and copper (Cu) during decompression melting of the mantle by …

Reduced Carbon Use Efficiency And Increased Microbial Turnover With Soil Warming, Jianwei Li, Gangsheng Wang, Melanie A. Mayes, Steven D. Allison, Serita D. Frey, Zheng Shi, Xiao-Ming Hu, Yiqi Luo, Jerry M. Melillo

Agricultural and Environmental Sciences Faculty Research

Global soil carbon (C) stocks are expected to decline with warming, and changes in microbial processes are key to this projection. However, warming responses of critical microbial parameters such as carbon use efficiency (CUE) and biomass turnover (rB) are not well understood. Here, we determine these parameters using a probabilistic inversion approach that integrates a microbial-enzyme model with 22 years of carbon cycling measurements at Harvard Forest. We find that increasing temperature reduces CUE but increases rB, and that two decades of soil warming increases the temperature sensitivities of CUE and rB. These temperature sensitivities, which are derived from decades-long …

Alpine Ice Evidence Of A Three-Fold Increase In Atmospheric Iodine Deposition Since 1950 In Europe Due To Increasing Oceanic Emissions, Michel Legrand, Joseph R. Mcconnell, Susanne Preunkert, Monica M. Arienzo, Nathan Chellman, Kelly E. Gleason, Tomás Sherwen, Mat J. Evans, Lucy J. Carpenter

Environmental Science and Management Faculty Publications and Presentations

Iodine is an important nutrient and a significant sink of tropospheric ozone, a climate-forcing gas and air pollutant. Ozone interacts with seawater iodide, leading to volatile inorganic iodine release that likely represents the largest source of atmospheric iodine. Increasing ozone concentrations since the preindustrial period imply that iodine chemistry and its associated ozone destruction is now substantially more active. However, the lack of historical observations of ozone and iodine means that such estimates rely primarily on model calculations. Here we use seasonally resolved records from an Alpine ice core to investigate 20th century changes in atmospheric iodine. After carefully considering …

Modulation Of Auxin And Cytokinin Responses By Early Steps Of The Phenylpropanoid Pathway, Jasmina Kurepa, Timothy E. Shull, Sumudu S. Karunadasa, Jan A. Smalle

Plant and Soil Sciences Faculty Publications

Background: The phenylpropanoid pathway is responsible for the synthesis of numerous compounds important for plant growth and responses to the environment. In the first committed step of phenylpropanoid biosynthesis, the enzyme phenylalanine ammonia-lyase (PAL) deaminates L-phenylalanine into trans-cinnamic acid that is then converted into p-coumaric acid by cinnamate-4-hydroxylase (C4H). Recent studies showed that the Kelch repeat F-box (KFB) protein family of ubiquitin ligases control phenylpropanoid biosynthesis by promoting the proteolysis of PAL. However, this ubiquitin ligase family, alternatively named Kiss Me Deadly (KMD), was also implicated in cytokinin signaling as it was shown to promote the degradation of …

Reduced Carbon Use Efficiency And Increased Microbial Turnover With Soil Warming, Jianwei Li, Gangsheng Wang, Melanie A. Mayes, Steven D. Allison, Serita D. Frey, Zheng Shi, Xiao-Ming Hu, Yiqi Luo, Jerry M. Melillo

Faculty Publications

Global soil carbon (C) stocks are expected to decline with warming, and changes in microbial processes are key to this projection. However, warming responses of critical microbial parameters such as carbon use efficiency (CUE) and biomass turnover (rB) are not well understood. Here, we determine these parameters using a probabilistic inversion approach that integrates a microbial-enzyme model with 22 years of carbon cycling measurements at Harvard Forest. We find that increasing temperature reduces CUE but increases rB, and that two decades of soil warming increases the temperature sensitivities of CUE and rB. These temperature sensitivities, which are derived from decades-long …

Spatial Variation In Throughfall, Soil, And Plant Water Isotopes In A Temperate Forest, Gregory R. Goldsmith, Scott T. Allen, Sabine Braun, Nadine Engbersen, Clara Romero González-Quijano, James W. Kirchner, Rolf T. W. Siegwolf

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Studies of stable isotopes of water in the environment have been fundamental to advancing our understanding of how water moves through the soil‐plant‐atmosphere continuum; however, much of this research focuses on how water isotopes vary in time, rather than in space. We examined the spatial variation in the δ¹⁸O and δ²H of throughfall and bulk soil water, as well as branch xylem and bulk leaf water of Picea abies (Norway Spruce) and Fagus sylvatica (Beech), in a 1 ha forest plot in the northern Alps of Switzerland. Means and ranges of water isotope ratios varied considerably …

A Review Of Fractals In Karst, Eulogio Pardo-Igúzquiza, Peter A. Dowd, Juan J. Durán, Pedro Robledo-Ardila

International Journal of Speleology

Many features of a karst massif can either be modelled using fractal geometry or have a fractal distribution. For the exokarst, typical examples include the geometry of the landscape and the spatial location and size-distribution of karst depressions. Typical examples for the endokarst are the geometry of the three-dimensional network of karst conduits and the length-distribution of caves. In addition, the hydrogeological parameters of the karst massif, such as hydraulic conductivity, and karst spring hydrographs may also exhibit fractal behaviour. In this work we review the karst features that exhibit fractal behaviour, we review the literature in which they are …

Evaluation Of The Weak Constraint Data Assimilation Approach For Estimating Turbulent Heat Fluxes At Six Sites, Xinlei He, Tongren Xu, Sayed M. Bateni, C.M.U. Neale, Thomas Auligne, Shaomin Liu, Kaicun Wang, Kebiao Mao, Yunjun Yao

Daugherty Water for Food Global Institute: Faculty Publications

A number of studies have estimated turbulent heat fluxes by assimilating sequences of land surface temperature (LST) observations into the strong constraint-variational data assimilation (SC-VDA) approaches. The SC-VDA approaches do not account for the structural model errors and uncertainties in the micrometeorological variables. In contrast to the SC-VDA approaches, the WC-VDA approach (the so-called weak constraint-VDA) accounts for the effects of structural and model errors by adding a model error term. In this study, the WC-VDA approach is tested at six study sites with different climatic and vegetative conditions. Its performance is also compared with that of SC-VDA at the …

Variations Of Soil Qualities In Urban And Rural Areas, Gabby Barnes, Iin Handayani, Steve Still

Posters-at-the-Capitol

The purpose of this study was to evaluate the variations of soil characteristics under different management practices in rural soils versus urban soils. In this study, soil samples from rural areas in Kentucky were collected from a woodland plot, a no-till plot, and a tilled plot. The soil samples from the rural were taken from two depths in order to better evaluate the effect of tillage on the soil. A shallow depth of 0-7cm and a deep depth of 7-15cm were used. Soil samples were also taken from urban plots in Memphis, TN. The sampled plots included were an animal …

Are The Oxygen Isotope Values Of The Late Cretaceous Western Interior Seaway Different From The Open Ocean?, Camille H. Dwyer, Corinne Myers, Viorel Atudorei

Shared Knowledge Conference

The Western Interior Seaway (WIS) was a North American epicontinental sea that was connected to the open ocean through the passage of the northern Boreal Sea and the southern Tethys Sea from the early Albian (~113 million years ago) to the early Paleogene (~65 million years ago). The WIS began to recced and lost its connection to the southern Tethys Sea in the late Campanian (~72 million years ago). In the early Paleogene, the WIS dried up completely. The oxygen isotopic composition (δ18O) of benthic bivalves was measured from the upper Campanian and lower Maastrichtian (75 million years ago to …

Assessing Water Policy Implications Of The Changing Agriculture In New Mexico, Trevor A. Birt

Shared Knowledge Conference

Agriculture is the dominant water sector in New Mexico, responsible for more than 80% of water withdrawals in 2015 (USGS 2018). Water policy needs to be extremely adaptive and informed to meet the needs of not only farmers, but cities, industry and riparian uses. Since 1840, the U.S. Department of Agriculture (USDA) has conducted census surveys assessing all levels of agriculture. These data are physically published at the county, state, and national level on a 5-year cycle, detailing various material counts such as acreage, yields, and water usage, as well as socioeconomic estimates of farm costs, revenues, and hired workers. …

Natural Trace Element Salinization Of The Jemez River, New Mexico By Geothermal Springs And Major Tributaries, Jon K. Golla, Laura J. Crossey, Abdul-Mehdi S. Ali, Karl E. Karlstrom

Shared Knowledge Conference

The Jemez River (JR), a tributary of the Rio Grande, is in north-central New Mexico within the Jemez Mountains, which houses the active, high-temperature (≤ 300 oC), liquid-dominated Valles Caldera geothermal system (VC). This work focuses on the northern portion of the JR, spanning a reach from the East Fork JR to the town of San Ysidro. Previous decadal work during low-flow or baseflow conditions (~10-20 cfs) has identified and characterized significant major-solute contributions from two outflow expressions of the VC, Soda Dam Springs and Jemez Hot Springs, and two major tributaries, Rio San Antonio and Rio Guadalupe. There is …