Earth Sciences Commons^™

Desorption Of Bisphenol-A (Bpa) And Regeneration Of Bpa-Spent Granular Activated Carbon Using Ultrasonic Irradiation And Organic Solvent Extraction, Chao Zhou, Naiyun Gao, Ruoyu Li, Yang Deng

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Desorption of bisphenol-A (BPA) from granular activated carbon (GAC) by ultrapure water and regeneration of BPA-spent GAC using ultrasonic irradiation and organic solvent extraction are investigated in this paper. The results showed that the pseudo-second-order kinetic model more appropriately described the BPA desorption pattern, and BPA desorption well followed the classical Arrhenius equation at a temperature range of 288–308 K with an activation energy of −56.47 kJ mol−1. Desorption rates of BPA were significantly favored by increasing acoustic intensity within a range of 17–100 W at 20 kHz frequency. Certain fraction of methanol or ethanol, particularly methanol, in the extraction …

Interplay Of Porous Media And Fracture Stimulation In Sedimentary Enhanced Geothermal Systems : Red River Formation, Williston Basin, North Dakota, Caitlyn M. Hartig

Theses and Dissertations

Fracture stimulated enhanced geothermal systems (EGS) can be installed in both crystalline rocks and sedimentary basins. The Red River Formation (Ordovician), which lies between 3.6 and 4.2 km depth in the Williston Basin, is a viable site for installation of sedimentary EGS (SEGS). SEGS is possible there because temperatures in the formation surpass 140° Celsius and the permeability is 0.1-38 mD; fracture stimulation can be utilized to improve performance. The main objectives of this project were 1) to determine the spatial variation of the intrinsic properties of the Red River Formation across the study area, and 2) to understand the …

Seismic Structural Investigation And Reservoir Characterization Of The Moki Formation In Maar Field, Taranaki Basin, New Zealand, Mohammed Dhaifallah M Alotaibi

Masters Theses

"The Maari Field is a large oil field located in the southern part of the Taranaki Basin, New Zealand. The field is bounded by two major structures, the Eastern Mobile Belt and Western Stable Platform. The Maari Field produces 40,000 BOPD (Barrels of Oil per Day) from five wells from reservoirs in the Moki Formation. The Miocene Moki Formation was deposited as part of the Wai-iti Group and consists of sandstone interbedded with siltstone and claystone. The sandstone of the Moki Formation is characterized by a submarine fan. It is distributed along the southern and central Taranaki shelf. Three-dimensional seismic …

Heavy Metal Uptake By Four Plant Species: Radish, Indian Mustard, Corn, And Soybean., Oluwasogo Bolaji Alonge

Graduate Theses, Dissertations, and Problem Reports (ETD)

Metal contaminated soils are a problem throughout the world. Because metals accumulate in the food chain they have been linked to adverse human and ecosystem health. One promising approach to remediating metal contaminated soils is phytoremediation but success has been limited by an incomplete understanding of the factors that control metal uptake by plants, including the effects when more than one contaminant metal is present in the system. Metal contaminated soil for this study was collected from near Spelter in Harrison County WV, the site of a former zinc smelting site that has contaminated residential soils and stream sediments with …

Magnetic Susceptibility Of North American Ordovician Epicontinental Seas: Spatial Variability And Sandbian-Katian Boundary Correlation, Thomas J. Schramm

LSU Doctoral Dissertations

Magnetic susceptibility (χ) has gained increased usage as a stratigraphic correlation tool. This project evaluates the utility of a χ correlation tool, including its shortcomings, and attempts its integration with other datasets. The Upper Ordovician of eastern North America represent the stratigraphic interval in which these experiments were conducted. 4566 samples were collected for the purposes of this study, and χ was measured on 3345 of the samples. This project includes three major facets, 1) the spatial variability of χ, 2) correlation of Sandbian-Katian boundary interval strata in eastern North America using χ, and 3) utility of χ for interpreting …

Interpretation Of Geochemical Signatures From Modern Carbonate Springs To The Rock Record, Benjamin Maas

LSU Doctoral Dissertations

Despite the importance of carbonate aquifers as reservoirs of oil, of water, and of carbon dioxide, questions remain about the diagenetic processes that enhance porosity and permeability. Some of the questions are: 1) what are the water-rock interactions that control the geochemistry of spring waters; 2) are the geochemical signatures of saline-fresh water mixing zones preserved in the carbonate rock record; and 3) how much carbon dioxide outgases along spring runs? To address these questions, two field sites, one in Oklahoma (the site of an active saline-fresh water mixing zone) and the other in Colorado, the location of a former …

Using Trace Fossils To Determine The Role Of Oceanic Anoxic Event Ii On The Cretaceous Western Interior Seaway Paleoenvironment, Jacob Frederick Grosskopf

LSU Doctoral Dissertations

Did well-oxygenated benthic conditions exist in all parts of the Cretaceous Western Interior Seaway (CWIS) during the deposition of Bed 63 at the onset Oceanic Anoxic Event II (OAE II), as suggested by findings from two cores from the central portion of the CWIS? This problem was approached by categorizing the bioturbation that is prevalent through Bed 63 into oxygen-related ichnofabrics (ORI) in order to describe benthic oxygen conditions. These data were collected from outcrop and core among seven different sites along West–East and North–South transects that traversed portions of the CWIS with differing depositional settings and proximities to the …

Improving Processing By Adaption To Conditional Geostatistical Simulation Of Block Compositions, R. Tolosana-Delgado, Ute A. Mueller, K. G. Van Den Boogaart, C. Ward, J. Gutzmer

Research outputs 2014 to 2021

Exploitation of an ore deposit can be optimized by adapting the beneficiation processes to the properties of individual ore blocks. This can involve switching in and out certain treatment steps, or setting their controlling parameters. Optimizing this set of decisions requires the full conditional distribution of all relevant physical parameters and chemical attributes of the feed, including concentration of value elements and abundance of penalty elements. As a first step towards adaptive processing, the mapping of adaptive decisions is explored based on the composition, in value and penalty elements, of the selective mining units. Conditional distributions at block support are …

Boundaries Of Governance: Social Responsibility In Mining In Western Australia, Gemma L. Broderick

Theses: Doctorates and Masters

This research investigated the boundaries of governance of social responsibility in three multinational mining organisations based in Perth, Western Australia. The mining industry has economic, environmental and social impacts, both positive and negative. While most of the attention of the media and supporters in government seems to focus on the positive impacts, a growing concern regarding the social implications of mining is clearly evident in public discourse and the academic literature. In response to public concern, the mining industry has adopted terms such as ‘sustainability’, ‘sustainable development’, ‘social licence to operate’ and ‘social responsibility’. Such phrases are widely used in …

Wedge Failure Analysis Of Anchored Rock Slopes Subjected To Surcharge And Seismic Loads, Yan Kou

Theses: Doctorates and Masters

Slope stability in mining and civil engineering projects is always a problem of great concern. Because the rock mass behavior is significantly governed by the presence of joints or other discontinuities, several types of slope failure, such as plane failure, wedge failure, toppling failure, buckling failure and circular failure, are often observed. The present work focuses on the study of the wedge failure, which occurs as sliding of a mass of rock on two intersecting planes, generally discontinuity planes.

Recently, the factor of safety of rock slopes against the wedge failure has been studied in a number of investigations under …

Patterns And Processes Of Salt Efflorescences In The Mcmurdo Region, Antarctica, Kelsey M. Bisson, Kathleen A. Welch, Susan A. Welch, Julia Meyer Sheets, W. Berry Lyons, Joseph S. Levy, Andrew G. Fountain

Geology Faculty Publications and Presentations

Evaporite salts are abundant around the McMurdo region, Antarctica (~78°S) due to very low precipitation, low relative humidity, and limited overland flow. Hygroscopic salts in the McMurdo Dry Valleys (MDVs) are preferentially formed in locations where liquid water is present in the austral summer, including along ephemeral streams, ice-covered lake boundaries, or shallow groundwater tracks. In this study, we collected salts from the Miers, Garwood, and Taylor Valleys on the Antarctic continent, as well as around McMurdo Station on Ross Island in close proximity to water sources with the goal of understanding salt geochemistry in relationship to the hydrology of …

Sinuous Rhizoliths Mimic Invertebrate Trace Fossils On Upper Pleistocene Caliche Surfaces, San Salvador Island, Bahamas, H. Allen Curran

Geosciences: Faculty Publications

The Pleistocene–Holocene boundary on islands of the Bahama Archipelago is typically marked by a calichified paleosol horizon that formed on exposed limestone surfaces during lowered sea level of the Last Glacial. On the north coast of San Salvador, an extensive laminar caliche surface is present west of Singer Bar Point. Formed on Upper Pleistocene (Eemian) carbonate eolianite and overlain by Holocene eolianite, this surface bears numerous and distinctive large, sinuous structures typically preserved in half relief, and with sharp, parallel ridge-like edges that slope inward to form a smooth, medial ‘trough’ having widths mostly between 1 and 3 cm. Individual …