Earth Sciences Commons^™

Surface Complexation Modeling Of Cr(Vi) Absorption On Mineral Assemblages, Ann M. Gilchrist

Masters Theses

Hexavalent chromium (Cr(VI)) is a waste product of many anthropogenic processes. Because it is highly mobile, the improper disposal of Cr(VI) has caused widespread contamination. Because reduction and adsorption reactions may reduce the bioavailability and mobility of Cr(VI) in environmental systems, a better understanding of Cr(VI) adsorption behavior will improve remediation efforts.

Subsurfaces and soils are heterogeneous, however most studies focus on single sorbate/sorbent interactions to develop surface complexation models (SCM) for prediction of heavy metal adsorption. Theoretically, combining the SCMsdeveloped for single sorbate/sorbent systems should yield accurate predictions of adsorption in more complex systems (i.e., the component additivity approach …

Wettability Alteration Of Sandstone By Chemical Treatments, Yanling Wang, Li Ma, Baojun Bai, Guancheng Jiang, Jiafeng Jin, Zengbao Wang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Liquid condensation in the reservoir near a wellbore may kill gas production in gas-condensate reservoirs when pressure drops lower than the dew point. It is clear from investigations reported in the literature that gas production could be improved by altering the rock wettability from liquid-wetness to gas-wetness. In this paper, three different fluorosurfactants FG1105, FC911, and FG40 were evaluated for altering the wettability of sandstone rocks from liquid-wetting to gas-wetting using contact angle measurement. The results showed that FG40 provided the best wettability alteration effect with a concentration of 0.3% and FC911 at the concentration of 0.3%.

Formation, Deformation, And Incision Of Colorado River Terraces Upstream Of Moab, Utah, Andrew P. Jochems

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The history of rivers is laid down as sediment in all landscapes, typically as a function of climate, geologic structures, and/or changes in sea level. When a river abandons its floodplain, this sediment collectively constitutes a landform called a fluvial terrace. Terraces are used to unlock prior characteristics of a river flowing through a given area at both local and regional scales. Dating terrace sediment allows comparison to known changes in climate and geologic deformation, two significant controls on the hydraulics of rivers and the deposition of their sediment loads.

The importance of terraces lies in their utility as markers …

A Geomechanical Study Of The Mississippian Boone Formation, Karen Nicole Mason Buckland

Graduate Theses and Dissertations

The Boone Formation in northwest Arkansas is a chert-limestone sequence analogous to the subsurface Mississippi Lime reservoir in parts of Oklahoma and Kansas. It has low permeability and produces via horizontal drilling and hydraulic fracturing. The response to stimulation by fracturing is dependent on the quantity of chert in the area. Chert nodules and laterally extensive chert layers in the sequence are variable. Locally, cm- to dm-scale chert bedding is continuous and comprises up to 50% of the outcrop. Elsewhere, the chert is nodular and intermittent.

Samples collected from representative outcrops spanning the thickness and aerial extent of the formation …

The Application Of Geographic Information Technology And Ground-Penetrating Radar In The Study Of The Evolution Of The Charles River Basin, Lars E. Anderas

Graduate Masters Theses

A two-part study was conducted on the evolution of the shoreline of the Charles River basin on a city-wide scale as well as in finer detail in Magazine Beach Park, along the Cambridge shore of the river. Both parts of the study utilized geographic information technology (GIT) to integrate and analyze data from modern and historical sources, including maps, digital elevation models (DEMs), and orthographic and oblique photography. The city-scale portion of the study produced estimates of the total area of new land made within the study area since Boston's founding in 1630, 14.3 km², of which 6.5 …

Paleoecology Of Late Pleistocene Megaherbivores: Stable Isotope Reconstruction Of Environment, Climate, And Response, Aubrey Mae Bonde

UNLV Theses, Dissertations, Professional Papers, and Capstones

Late Pleistocene megaherbivore communities of the Pacific and Mountain West states of California and Nevada are under-analyzed in regard to ecological function (diet, mobility, niche partitioning, and range of ecological tolerance). Stable isotope analysis is a powerful tool that is known to recover primary paleodiet and paleoenvironmental information from biogenic materials, such as enamel and dentin. This dissertation explores the use of carbon and oxygen stable isotopes in Late Pleistocene (40-10 Ka) megaherbivore teeth to gain a better understanding of inter- and intra-specific behavior and reconstruct Late Pleistocene ecosystems of California and Nevada. Radiocarbon dates exist for most of the …

Landslides Of Nebraska, Duane A. Eversoll

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

Insights Into The Timing, Origin, And Deformation Of The Highland Mountains Gneiss Dome In Southwestern Montana, Usa, Lane Markes Boyer

Graduate Theses and Dissertations

The Highland Mountains of southwestern Montana offer a unique view of the Archean igneous and metamorphic rocks within the Great Falls tectonic zone (GFTZ). A Paleoproterozoic structural gneiss dome has been interpreted in the southern extent of the Highland Mountains. The ∼ 130km² of exhumed metamorphic rocks and gneiss dome exposed in the Highland Mountains are the primary focus of this research. The formation of the Highland Mountains gneiss dome is proposed to be directly related to a northwest-side down detachment (the Steels Pass shear zone) that formed during terrane collision along the GFTZ. The field investigation determined foliation …

Analysis Of Tripolitic Chert In The Boone Formation (Lower Mississippian, Osagean), Northwest Arkansas And Southwestern Missouri, Paul Marchand Minor

Graduate Theses and Dissertations

The Boone Formation in northwest Arkansas and southwestern Missouri exposes a nearly complete sequence of Lower Mississippian chert-bearing carbonates deposited by a single 3rd order transgression and regression. An abundant amount of chert that has replaced limestone highlights the Boone, but little is understood about the timing and development of chert in Lower Mississippian carbonates. Interpretation of the diagenetic history of the chert, in particular tripolite, has significant implications beyond the outcrop. Determining the origin, timing, and extent of tripolitic chert in the Lower Mississippian System improves reservoir characterization in subsurface petroleum reservoirs in the mid-continent that are laterally equivalent …

Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins

Graduate Theses and Dissertations

The Edwards aquifer is one of the major regional karst aquifers in the United States, with an average withdrawal of 950 million liters per day (L/d). This investigation focuses on the connection between the Uvalde pool and the San Antonio pool of the Edwards aquifer, known as the Knippa Gap, west of the San Antonio metropolitan area in Uvalde County. This is a major zone of recharge to the Edwards aquifer and is approximately 6.4 km wide. The Knippa Gap is bounded by northeast trending faults of the Balcones Fault Zone (BFZ) on the north (specifically the Cooks and Trio …

Updated Pressure And Temperature Determinations For The Metapelites Of The Western Hudson Highlands, Ny, Eric W. Sonnenwald

Theses, Dissertations and Culminating Projects

Pelitic sedimentary material was deposited along the eastern margin of North America in the Mesoproterozoic (~1300-1200 Ma) in an active continental arc basin setting and was subsequently metamorphosed during the Ottawan Orogeny (~1080-1030 Ma) as a part of a closing ocean basin between two continents (Volkert and Drake, 1999). The resulting metapelitic gneisses now exposed in the western Hudson Highlands in Harriman State Park, New York were analyzed to determine the sedimentary protolith and the peak metamorphic pressure-temperature (P-T) conditions during the Ottawan Orogeny that affected this region during the final assembly of Rodinia. The protolith, a clay-bearing arkosic sandstone, …

Population Dynamics Of Pseudo-Nitzschia Species (Bacillariophyceae) In The Near Shore Waters Of Dar Es Salaam, Tanzania, Charles Lugomela

Tanzania Journal of Science

The genus Pseudo-nitzschia is a chain-forming diatom comprising about 30 species some of which are known to produce domoic acid (DA) that causes amnesic shellfish poisoning (ASP). The current study aimed at assessing the population dynamics of Pseudo-nitzschia in the near shore waters of Dar es Salaam. Samples were collected between August 2008 and July 2009 from two stations. The first station was located in the open waters off Mbudya Island and the second was located at a point in-between Kunduchi and Mbudya Island. Three Pseudo-nitzschia species, i.e., Pseudo-nitzschia pungens, Pseudo-nitzschia seriata and Pseudo-nitzschia cuspidata were encountered with Pseudo-nitzschia pungens …

U.S. Drought Monitor, July 30, 2013, Brian Fuchs

United States Agricultural Commodities in Drought Archive

Drought map of U.S. for July 30, 2013 (7/30/13) plus: U.S. crop areas experiencing drought (map), Approximate percentage of crop located in drought, by state (bar graph), Percent of crop area located in drought, past 52 weeks (line graph) for: Corn, Soybeans, Hay, Cattle, Winter wheat.

My Geological Connection Between Minnesota And Western Australia, Larry E. Davis

The Compass: Earth Science Journal of Sigma Gamma Epsilon

Even though the flora and fauna of Minnesota and Western Australia are vastly different, there are some similarities in the geology. This essay illustrates the author’s geological connection between Minnesota, USA and Western Australia.

The Coffee Sands: A Cretaceous Beach Deposit In The Mississippi Embayment Of Western Tennessee, Jennifer Martin, Lara Homsey

The Compass: Earth Science Journal of Sigma Gamma Epsilon

The Coffee Sands represent a beach deposited associated with a vast network of rivers draining the highlands of the Pascola Arch to the west along the margin of the Mississippi Embayment of the Cretaceous Interior Seaway in western Tennessee. The Coffee Sands occur only as ephemeral, discontinuous deposits capping ridges within the Western Highland Rim in western Tennessee and Kentucky. This paper describes an outcrop of the Coffee Sands along U.S. Hwy 140 just east of Buchanan, TN.

P-T Constraints Of Orthogneiss, Metapelites, And Ultra-Mafic Lenses Located In The Virgin Mountains Of Northwestern Arizona, Bryan R. Nielson, Brady M. Nielson, Andrew Schroeder, Mark R. Colberg

The Compass: Earth Science Journal of Sigma Gamma Epsilon

The Virgin Mountains, located in northwestern Arizona, host a variety of different geologic features. Many workers have focused on Tertiary extension within the mountain range, but little work has been done on the Paleo-Proterozoic basement rocks. Tertiary extension has exposed 1.73 – 1.80 Ga basement material that exhibits intense shear deformation and evidence of high temperature/high pressure and possibly ultra-high pressure metamorphism. These rocks are well exposed throughout Elbow and Lime Kiln Canyons, which are located east and south of Mesquite, Nevada. Some exposures enclose ultra-mafic lenses containing pyroxene/spinel pseudomorphs after garnet. These features suggest decompression through the garnet-spinel transition. …

Microbial Ecology, Nitrogen, And Nitrous Oxide Trends In Marginal Soils Used For Cellulosic Biofuel Production In Eastern Nebraska, Carla M. Ahlschwede

School of Natural Resources: Dissertations, Theses, and Student Research

There is a growing demand for diverse biofuels in the United States. Potential feedstocks for cellulosic ethanol include corn (Zea mays, L.) stover and switchgrass (Panicum virgatum, L). Lands used to provide for corn production can provide some cellulosic feedstock through corn stover, but crop residue removal can have negative impacts on soil quality. Furthermore, arable land must supply both fuel and food. To meet both demands, lands considered marginal for row-crop production will likely be used to produce dedicated bioenergy crops such as switchgrass. Marginal lands are typically placed in conservation programs because they are prone …

Incision History Of Glenwood Canyon, Colorado, Usa, From The Uranium-Series Analyses Of Water-Table Speleothems, Victor J. Polyak, Harvey R. Duchene, Donald G. Davis, Arthur N. Palmer, Margaret V. Palmer, Yemane Asmerom

International Journal of Speleology

Uranium-series analyses of water-table-type speleothems from Glenwood Cavern and “cavelets” near the town of Glenwood Springs, Colorado, USA, yield incision rates of the Colorado River in Glenwood Canyon for the last ~1.4 My. The incision rates, calculated from dating cave mammillary and cave folia calcite situated 65 and 90 m above the Colorado River, are 174 ± 30 m/My for the last 0.46 My and 144 ± 30 m/My for the last 0.62 My, respectively. These are consistent with incision rates determined from nearby volcanic deposits. In contrast, δ²³⁴U model ages (1.39 ± 0.25 My; 1.36 ± 0.25 …

Characterization Of The Shallow Subsurface Geohydrology Of The Ni-Les'tun Unit On The Bandon Marsh National Wildlife Refuge, Christopher Madison Beard

Dissertations and Theses

The Bandon Marsh is a large marsh restoration project located in southwest Oregon. The land has been previously used for dairy farms and much of the marsh was used for cattle grazing. The goal of the restoration is to recreate a natural habitat for shorebirds and fish. The purpose of this thesis is to gather and analyze data on the geology of the marsh and both ground and surface water quality to evaluate its ability to support biology.

The US Fish and Wildlife Service began restoration on the Bandon marsh in 2005. Research on the Ni-les'tun Unit began in that …

Accelerated Thermokarst Formation In The Mcmurdo Dry Valleys, Antarctica, Joseph S. Levy, Andrew G. Fountain, James L. Dickson, James W. Head, Marianne Okal, David R. Marchant, Jaclyn Watters

Geology Faculty Publications and Presentations

Thermokarst is a land surface lowered and disrupted by melting ground ice. Thermokarst is a major driver of landscape change in the Arctic, but has been considered to be a minor process in Antarctica. Here, we use ground-based and airborne LiDAR coupled with timelapse imaging and meteorological data to show that 1) thermokarst formation has accelerated in Garwood Valley, Antarctica; 2) the rate of thermokarst erosion is presently,10 times the average Holocene rate; and 3) the increased rate of thermokarst formation is driven most strongly by increasing insolation and sediment/albedo feedbacks. This suggests that sediment enhancement of insolation-driven melting may …

U.S. Drought Monitor, July 23, 2013, Richard R. Heim Jr.

United States Agricultural Commodities in Drought Archive

Drought map of the United States for July 23, 2013 (7/23/13) plus: United States crop areas experiencing drought (map), an approximate percentage of crop located in drought by state (bar graph), and the percentage of crop area located in drought during the past 52 weeks (line graph) for corn, soybeans, hay, cattle, and winter wheat.

Grounding Zone Processes: Ice Mechanics And Margin Lakes, Kamb Ice Stream And Whillans Ice Stream, West Antarctica, Mason Joseph Fried

Dissertations and Theses

The lateral "corners" where Kamb and Whillans Ice Streams (KIS and WIS) discharge into the Ross Ice Shelf share common geometries and ice mechanical settings. At both corners of the now-stagnant KIS outlet, shear margins of apparently different ages confine regions with a relatively flat, smooth surface expression. These features are called the "Duckfoot" on the northern, right-lateral side and the "Goosefoot" on the other. It has been suggested, on evidence found in ice internal layers, that the flat ice terrains on KIS were afloat in the recent past, at a time when the ice stream grounding line was upstream …

Arsenic Mobility And Compositional Variability In High-Silica Ash Flow Tuffs, Courtney Beth Young Savoie

Dissertations and Theses

Volcanic rocks typically have only low to moderate arsenic concentrations, none-the-less, elevated levels of arsenic in ground waters have been associated with pyroclastic and volcaniclastic rocks and sediments in many parts of the world. The potential for arsenic leaching from these deposits is particularly problematic as they often comprise important water-bearing units in volcanic terrains. However, the role that chemical and mineralogical variations play in controlling the occurrence and mobility of arsenic from pyroclastic rocks is largely unexplored.

This study uses chemical and X-ray diffraction data to characterize and classify 49 samples of ash-flow tuffs, and 11 samples of tuffaceous …

A Lover And A Fighter: The Genome Sequence Of An Entomopathogenic Nematode Heterorhabditis Bacteriophora, Xiaodong Bai, Byron J. Adams, Todd A. Ciche, Sandra Clifton, Randy Gaugler, Kwi-Suk Kim, Parwinder Grewal

School of Earth, Environmental, & Marine Sciences Faculty Publications

Heterorhabditis bacteriophora are entomopathogenic nematodes that have evolved a mutualism with Photorhabdus luminescens bacteria to function as highly virulent insect pathogens. The nematode provides a safe harbor for intestinal symbionts in soil and delivers the symbiotic bacteria into the insect blood. The symbiont provides virulence and toxins, metabolites essential for nematode reproduction, and antibiotic preservation of the insect cadaver. Approximately half of the 21,250 putative protein coding genes identified in the 77 Mbp high quality draft H. bacteriophora genome sequence were novel proteins of unknown function lacking homologs in Caenorhabditis elegans or any other sequenced organisms. Similarly, 317 of the …

Selecting Surrogate Endpoints For Estimating Pesticide Effects On Avian Reproductive Success, Richard S. Bennett, Matthew A. Etterson

United States Environmental Protection Agency: Publications

A Markov chain nest productivity model (MCnest) has been developed for projecting the effects of a specific pesticide‐use scenario on the annual reproductive success of avian species of concern. A critical element in MCnest is the use of surrogate endpoints, defined as measured endpoints from avian toxicity tests that represent specific types of effects possible in field populations at specific phases of a nesting attempt. In this article, we discuss the attributes of surrogate endpoints and provide guidance for selecting surrogates from existing avian laboratory tests as well as other possible sources.We also discuss some of the assumptions and uncertainties …

Exposure And Effects Of Perfluoroalkyl Substances In Tree Swallows Nesting In Minnesota And Wisconsin, Usa, Christine M. Custer, Thomas W. Custer, Paul M. Dummer, Matthew A. Etterson, Wayne E. Thogmartin, Qian Wu, Kurunthachalam Kannan, Annette Trowbridge, Patrick C. Mckann

United States Environmental Protection Agency: Publications

The exposure and effects of perfluoroalkyl substances (PFASs) were studied at eight locations in Minnesota and Wisconsin between 2007 and 2011 using tree swallows (Tachycineta bicolor). Concentrations of PFASs were quantified as were reproductive success end points. The sample egg method was used wherein an egg sample is collected, and the hatching success of the remaining eggs in the nest is assessed. The association between PFAS exposure and reproductive success was assessed by site comparisons, logistic regression analysis, and multistate modeling, a technique not previously used in this context. There was a negative association between concentrations of perfluorooctane …

Exposure And Effects Of Perfluoroalkyl Substances In Tree Swallows Nesting In Minnesota And Wisconsin, Usa, Christine M. Custer, Thomas W. Custer, Paul M. Dummer, Matthew A. Etterson, Wayne E. Thogmartin, Qian Wu, Kurunthachalam Kannan, Annette Trowbridge, Patrick C. Mckann

United States Environmental Protection Agency: Publications

The exposure and effects of perfluoroalkyl substances (PFASs) were studied at eight locations in Minnesota and Wisconsin between 2007 and 2011 using tree swallows (Tachycineta bicolor). Concentrations of PFASs were quantified as were reproductive success end points. The sample egg method was used wherein an egg sample is collected, and the hatching success of the remaining eggs in the nest is assessed. The association between PFAS exposure and reproductive success was assessed by site comparisons, logistic regression analysis, and multistate modeling, a technique not previously used in this context. There was a negative association between concentrations of perfluorooctane …

U.S. Drought Monitor, July 16, 2013, Richard R. Heim Jr.

United States Agricultural Commodities in Drought Archive

Drought map of the United States for July 16, 2013 (7/16/13) plus: United States crop areas experiencing drought (map), an approximate percentage of crop located in drought by state (bar graph), and the percentage of crop area located in drought during the past 52 weeks (line graph) for corn, soybeans, hay, cattle, and winter wheat.

The Impact Of Nitrogen Contamination And River Modification On A Mississippi River Floodplain Lake, Indu Karthic, Richard B. Brugam Ph.D., William A. Retzlaff, Kevin Johnson

SIUE Faculty Research, Scholarship, and Creative Activity

Anthropogenic nitrogen contamination has increased in ecosystems around the world (frequently termed the “nitrogen cascade”). Coke production for steel manufacturing is often overlooked as a source of nitrogen to natural ecosystems. We examined sediment cores from a Horseshoe Lake, a floodplain lake located just East of St. Louis Missouri (USA) to test whether a coking plant effluent could be traced using stable isotopes of nitrogen and diatom microfossils. The distribution of δ¹⁵N values in surface sediment samples from the lake shows the highest values near the coking plant effluent. Analysis stable isotopes of nitrogen from sediment cores using …

Using Airborne Ku-Band Altimeter Waveforms To Investigate Winter Accumulation And Glacier Facies On Austfonna, Svalbard, Robert L. Hawley, Ola Brandt, Thorben Dunse, Jon Ove Hagen, Veit Helm, Jack Kohler, Kirsty Langley, Eirik Malnes, Kjell-Arild Hogda

Dartmouth Scholarship

Winter balance is an important metric for assessing the change on glaciers and ice caps, yet measuring it using ground-based techniques can be challenging. We use the European Space Agency prototype Airborne SAR/Interferometric Radar Altimeter System (ASIRAS) to extract snow depths from the received altimeter waveforms over Austfonna ice cap, Svalbard. Additionally, we attempt to distinguish the long-term firn area from other glacier facies. We validate our results using snow depth and glacier facies characterizations determined from ground-based radar profiles, snow pits and a multi-look satellite synthetic aperture radar image. We show that the depth of the winter snowpack can …