Earth Sciences Commons^™

Effects Of Plant Uptake And Micro-Topography On Chloride Transport In Arid Soils, Wenming Nie

UNLV Theses, Dissertations, Professional Papers, and Capstones

Chloride concentration profiles to depths of 1 m were evaluated on a young alluvial fan in Eldorado Valley, NV. It was found that chloride beneath plant canopies were 11 to 222 times higher than adjacent (1 - 2 m away) bare soil locations. Two-dimensional numerical simulations using HYDRUS 2D/3D model were used to further explore the impact of plants on chloride transport. The simulation results indicated that lateral flow driven by root uptake concentrated chloride toward root zones, leading to the accumulation of chloride under plant canopies. Results also suggest that locally micro-topography can have a substantial impact on chloride …

Geoelectrical Response Of Surfactant Solutions In A Quartzitic Sand Analog Aquifer, Meghan Therese Magill

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this project, the resistivity and phase shift of ten surfactant aqueous solutions in a sand matrix were measured using spectral induced polarization (SIP). In addition, specific conductivity, pH, dissolved oxygen, and dielectric constant measurements of the solutions were also evaluated. The frequency range assessed was 0.091-12000Hz. The surfactants, which are typically used in the remediation of tetrachloroethylene, were Aerosol MA 80-I, Dowfax 8390, and Steol CS-330. The surfactants were mixed into solutions of both deionized and tap water at varying concentrations and injected into a closed system of silica sand. The surfactant treatments altered resistivity, specific conductivity, and pH …

Provenance Of The Miocene-Pliocene Muddy Creek Formation Near Mesquite, Nevada, Steven Wayne Forrester

UNLV Theses, Dissertations, Professional Papers, and Capstones

The provenance, stratigraphy, and depositional history of the Miocene-Pliocene Muddy Creek Formation (MCF) in southern Nevada are poorly studied and poorly constrained. Previous studies of the MCF have concluded that the formation consists of lacustrine, eolian, and fluvial deposits. Currently the age of deposition is loosely constrained between 8.5 and 4.1 Ma. This study documents the evolution of one portion of the eastern extent of the MCF and determines its provenance and depositional history at Flat Top and Mormon Mesas in Nevada; and near Beaver Dam and Littlefield, Arizona.

This study intended to determine whether the MCF was deposited by …

Predicting The Effect Of Wetland Restoration On Phosphorus Retention, Northwest Minnesota, Ryan J. Whittaker

Theses and Dissertations

Water quality in the Red River Valley and downstream in Lake Winnipeg has been diminishing due to excess nutrients from agriculture. One method to reduce nutrient loading to surface water is to create or restore wetlands in agricultural areas that drain cropped fields. It is commonly believed that wetlands improve water quality, but research has shown that restoring wetlands can actually release phosphorus (P) into solution. Reducing conditions caused by soil flooding can release Fe-bound P, since ferrous Fe is more soluble than ferric Fe. Little is known concerning how the soils in the Red River Valley will be affected …

The ‘Benchmark Glacier’ Concept – Does It Work? Lessons From The North Cascade Range, Usa, Andrew G. Fountain, Matthew J. Hoffman, Frank Granshaw, Jon L. Riedel

Geology Faculty Publications and Presentations

Benchmark glaciers were established in many alpine areas during the 1960s as part of the International Hydrological Decade to represent ‘typical’ mass and energy processes on glaciers in different climatic regions around the world. These glaciers have received new interest in the past decade because they are used to infer the contribution of alpine glacier wastage to global sea-level rise. We compare South Cascade Glacier, the benchmark glacier for the northwest contiguous USA, and four other secondary glaciers, against the topographic, area and mass changes of 321 glaciers in the surrounding region. Results show that South Cascade Glacier is unusually …

Carbon Dioxide Flooding Induced Geochemical Changes In A Saline Carbonate Aquifer, Alyssa Boock

Theses and Dissertations

Carbon dioxide (CO2) has been injected into depleted oil reservoirs for enhanced oil recovery for several decades. Injection of CO2 into geologic formations in the Williston Basin is currently under consideration for long-term CO2 storage to reduce anthropogenic CO2 emissions to the atmosphere. The Madison Group in the North Dakota Williston Basin provides the greatest potential for geologic sequestration in either deep saline aquifers or depleted oil reservoirs. Little is known about the geochemical reactions that take place when supercritical carbon dioxide is injected into deep saline aquifers at geologic conditions similar to those found in potential sequestration units of …

Investigating The Impact Of Microbial Interactions With Geologic Media On Geophysical Properties, Caroline A. Davis

Doctoral Dissertations

"The goals of this study were to investigate the effect of: (1) microbial metabolic byproducts, microbial growth, and biofilm formation on the low frequency electrical properties of porous media, (2) biofilm formation on acoustic wave properties, and (3) the natural electrical (self-potential) signatures associated with an in-situ biological permeable reactive barrier (PRB). The results suggest: (1) increases in electrolytic conductivity are consistent with increased concentrations of organic acids and biosurfactants; (2) mineral weathering promoted by organic acids causes increases in electrolytic conductivity, concomitant with increases in major cation concentrations; (3) interfacial conductivity generally parallels microbial cell concentrations and biofilm formation; …

Biodegradation Of Fuel Oxygenates In Northeastern United States Aquifers With An Analysis Of Underground Storage Tank Leaks, Gordon Hinshalwood

Dissertations, Theses, and Capstone Projects

During the past decade the application of monitored natural attenuation has become one of the predominant technologies used in the remediation of gasoline spills impacting subsurface soils and groundwater. The success of this method has depended, for the most part, on the biodegradation of those gasoline constituents that dissolve into groundwater and transport with the groundwater most readily.

One of the most mobile components of gasoline formulations during the past 20 years has been methyl tertiary butyl ether (MTBE), which has traditionally been viewed in both the scientific and the regulatory communities as relatively recalcitrant to biodegradation. However, cases of …

Export Of Terrestrial Dissolved Organic Matter Along A River To Ocean Transect Of The Lower Chesapeake Bay Investigated By Advanced Analytical Techniques, Rachel Leigh Sleighter

Chemistry & Biochemistry Theses & Dissertations

Ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) has proved essential for the complete separation of the thousands of peaks present in natural organic matter (NOM), a complex assemblage of organic molecules present in water, soils, and sediments. An improved understanding of its composition is crucial to understand how pollutants interact with NOM and how NOM cycles through global carbon cycles.

Optimizing the acquisition and handling of the FTICR mass spectra is the first step to obtaining high quality data. A simple method to internally calibrate the peaks in the complex spectra, using naturally present fatty …

Does The Mg/Ca In Foraminifera Tests Provide A Reliable Temperature Proxy?, Sarah Clark, Figen Mekik

Student Summer Scholars Manuscripts

The Mg/Ca in foraminifera shells is commonly used as a proxy to estimate ocean temperatures in Earth’s past. However, studies have shown that both dissolution and salinity influence the Mg/Ca in shells of tropical foraminifera, which can cause paleotemperature estimates to be inaccurate. We measured Mg/Ca in shells of Globigernoides ruber and Globigerinoides sacculifer from core tops in the eastern equatorial Pacific. We compared our results with global core top data, which paleotemperature equations have been calibrated and published. We find that Mg/Ca values range greatly at the same surface ocean temperature. We also find that salinity and dissolution do …

Paleogeographic Reconstructuion Of The St. Lawrence Promontory, Western Newfoundland, John Stefan Allen

University of Kentucky Doctoral Dissertations

Neoproterozoic-Early Cambrian continental rifting related to the breakup of the supercontinent Rodinia framed the continental margin of eastern Laurentia and the departing cratons around the opening Iapetus Ocean. The result of continental extension was the production of a zig-zag set of promontories and embayments on the eastern Laurentian margin defined by northeast-trending rift segments offset by northwesttrending transform faults.

The St. Lawrence promontory defines the Laurentian margin in western Newfoundland. There, Neoproterozoic-Carboniferous clastic, volcanic, and carbonate successions record protracted continental rifting and passive-margin thermal subsidence followed by destruction of the margin during the early, middle, and late Paleozoic Appalachian orogenic …

Long-Period Ground Motions In The Upper Mississippi Embayment From Finite-Fault, Finite-Difference Simulations, Kenneth A. Macpherson

University of Kentucky Doctoral Dissertations

A 3D velocity model and 3D wave propagation code have been employed to simulate long-period ground motions in the upper Mississippi embayment. This region is exposed to seismic hazard in the form of large earthquakes in the New Madrid seismic zone and observational data are sparse, making simulation a valuable tool for predicting the effects of large events. These simulations were undertaken in order to estimate ground-motion characteristics and to investigate the influence of the 3D embayment structure and finite-fault mechanics. There are three primary fault zones in the New Madrid seismic zone, each of which was likely associated with …

Ultraviolet Radiation Sensitivity In Cave Bacteria: Evidence Of Adaptation To The Subsurface?, Jessica R. Snider, Caitlin Goin, Robert V. Miller, Penelope J. Boston, Diana E. Northup

International Journal of Speleology

We hypothesize that a reduced capacity to withstand or repair cellular damage from ultraviolet radiation may be present in cave-adapted microorganisms that never experience such conditions. However, a small number of previous studies have shown that some subsurface bacteria do not show greater sensitivity to ultraviolet radiation (UVR) than surface bacteria. To estimate UVR sensitivity in cave bacteria, bacterial isolates were collected from Carlsbad Cavern, New Mexico, U.S.A., and percent survival following exposure to various UVC and UVA radiation doses was determined. Cave bacteria from Left Hand Tunnel in Carlsbad Cavern and surface bacteria from soil and rocks above Carlsbad …

Matrix Geochemistry And Phytophthora Occurrence On Reforested Mine Lands In Appalachia, Kathryn M. Ward

University of Kentucky Master's Theses

At the Bent Mountain surface mine, Pike County, Kentucky, a study has been ongoing since 2005 to assess the influence of various types of loose-graded mine spoils on water quality and forest establishment. Six research plots consist of two replicates of brown weathered sandstone, gray unweathered sandstone, and mixed brown sandstone, gray sandstone, and shale that were emplaced according to Forestry Reclamation Approach criteria. A series of analyses was initiated in 2007 to examine influence of spoil matrix composition on sulfate and carbonate geochemistry of infiltrated waters, as well as to investigate the occurrence of Phytophthora, a group of …

Variation In C/P Ratios In Devonian-Mississippian Marine Shales: Testing The Productivity-Anoxia Feedback Model, Brian T. Scott

University of Kentucky Master's Theses

Carbon/phosphorus ratios for late Devonian-early Mississippian marine black shales along a transect from the Illinois Basin, across the Cumberland Saddle, and into the Appalachian Basin were evaluated to assess the role of productivity in organic carbon accumulation. Phosphorus is a key limiting nutrient for biological productivity in marine environments and may be regenerated preferentially relative to organic carbon, the amount of regeneration possibly being related to bottom-water anoxia. A positive feed-back mechanism (more specifically, productivity-anoxia feedback or PAF) has been proposed between water-column anoxia, high benthic regeneration of phosphorus, and marine productivity. This regeneration of phosphorus under anoxic conditions and …

Use Of Surface Geophysical Techniques To Locate A Karst Conduit In The Cane Run - Royal Spring Basin, Kentucky, Ganesh N. Tripathi

University of Kentucky Master's Theses

Groundwater flow in karst terrains is difficult to map because it can be concentrated through conduits that do not necessarily coincide with the surface features. We applied electrical resistivity (ER) and self-potential (SP) techniques at three sites to locate an inferred trunk conduit feeding a major spring in the Inner Bluegrass region of Kentucky. Royal Spring is the primary water supply for the city of Georgetown; the upper part of its basin coincides with the Cane Run watershed. ER and SP profiles were perpendicular to the inferred trunk conduit orientation. ER profiles (972 m total length) were measured using a …

Bedrock Mapping Of The Winchendon (1:25,000) Quadrangle (Ma-Nh): Evidence For Discontinous Deformation Along The Bronson Hill-Central Maine Boundary Zone, Timothy M. O'Brien

University of Kentucky Master's Theses

Bedrock geology of the Winchendon quadrangle is divided into two zones based on structures and lithology. The eastern zone consists of tightly folded Silurian Rangeley and Paxton metasediments and pegmatites. Planar, NNE-SSW striking, W dipping foliations are characterized by alternating phyllosilicate-rich and leucosome layers. Fold axes of tight to isoclinal upright and recumbent folding are parallel to SSW-NNE shallowly plunging sillimanite, quartz and muscovite lineations. In the western zone Rangeley schists were intruded by Devonian Hardwick and Coys Hill and Fitzwilliam plutons. Planar NNE-SSW striking foliations dip shallowly to steeply west. Fold axes of tight-to-isoclinal asymmetric to recumbent folds plunge …

Structural Geology Of The Transylvania Fault Zone In Bedford County, Pennsylvania, Elizabeth Lauren Dodson

University of Kentucky Master's Theses

Transverse zones cross strike of thrust-belt structures as large-scale alignments of cross-strike structures. The Transylvania fault zone is a set of discontinuous right-lateral transverse faults striking at about 270º across Appalachian thrust-belt structures along 40º N latitude in Pennsylvania. Near Everett, Pennsylvania, the Breezewood fault terminates with the Ashcom thrust fault. The Everett Gap fault terminates westward with the Hartley thrust fault. Farther west, the Bedford fault extends westward to terminate against the Wills Mountain thrust fault. The rocks, deformed during the Alleghanian orogeny, are semi-independently deformed on opposite sides of the transverse fault, indicating fault movement during folding and …

Magma In A Beaker: Analog Experiments With Water And Various Salts Or Sugar For Teaching Igneous Petrology, John B. Brady

Geosciences: Faculty Publications

Solutions of water and a salt or sugar make excellent experimental analog magmas for teaching concepts of igneous petrology because of the comparatively low temperatures involved, the simplicity of the apparatus needed, and the responsiveness of familiar chemical systems. Boiling of these aqueous solutions on a hot plate can be used to increase the concentration of a dissolved salt or sugar to levels that may be predicted by steam-saturation curves. Sufficiently concentrated solutions will crystallize, partially or completely, upon cooling to room temperature. Binary temperature–composition phase diagrams for H₂O and KCl, NaCl, MgCl₂, CaCl₂, …