Earth Sciences Commons^™

Geochemical Modeling Of Solubility And Speciation Of Uranium, Neptunium, And Plutonium, Zhongbo Yu, Yuyu Lin, Karen Johannesson, Amy J. Smiecinski, Klaus J. Stetzenbach

Publications (YM)

The purpose of this study is to model the solubility, speciation, and transport of three actinides: uranium (U), neptunium (Np), and plutonium (Pu) by a geochemical modeling tool under possible repository environmental conditions upon waste package failure. The dissolution concentration of three actinides in the waste package, their aqueous speciation after dissolving in the unsaturated zone (UZ), and transport processes in the saturated zone (SZ) along the groundwater flow path at Yucca Mountain (YM) are simulated by geochemical modeling calculations using PHREEQC. This model report was prepared in fulfillment of Groundwater Characterization at Yucca Mountain, Task II: Surface Complexation and …

Groundwater Characterization At Yucca Mountain Task 2: Surface Complexation And Solid Phase Sorption, Kenneth Czerwinski, Anthony Hechanova, Amy J. Smiecinski

Publications (YM)

The purpose and scope of this report is to present an overview of the experiments, methods, results, and conclusions from research performed for the project “Groundwater Characterization at Yucca Mountain Task 2: Surface Complexation and Solid Phase Dissolution”. The impact of surface complexation, alteration phase formation, and solution competition with metal ions on the solubility and speciation of actinide elements (U, Pu, Np) will be examined. In particular the role of iron (as Fe2+ and Fe3+) and silicate (as SO3 2-) concentrations on speciation, solubility, sorption, and secondary phase formation of actinides will be investigated. While a large body of …

Risk Perception, Warning Systems And Evacuation Plans For Volcanic Hazards, Matt Davis, David Johnston, Julia Becker

Collected Faculty Scholarship

No abstract provided.

The Microbial Community Structure In Petroleum-Contaminated Sediments Corresponds To Geophysical Signatures, Jonathan P. Allen, Estella A. Atekwana, Eliot A. Atekwana, Joseph W. Duris, D. Dale Werkema, Silvia Rossbach

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The interdependence between geoelectrical signatures at underground petroleum plumes and the structures of subsurface microbial communities was investigated. For sediments contaminated with light non-aqueous-phase liquids, anomalous high conductivity values have been observed. Vertical changes in the geoelectrical properties of the sediments were concomitant with significant changes in the microbial community structures as determined by the construction and evaluation of 16S rRNA gene libraries. DNA sequencing of clones from four 16S rRNA gene libraries from different depths of a contaminated field site and two libraries from an uncontaminated background site revealed spatial heterogeneity in the microbial community structures. Correspondence analysis showed …

Quaternary Evolution Of The Colorado River At Lees Ferry, Arizona, William Scott Cragun

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

A well-exposed suite of Colorado River fill terraces preserved at Lees Ferry records the oscillating history of this major river superimposed on its overall downcutting of the Colorado Plateau. Detailed mapping, sedimentology, cross-sectional surveys, and the use of two geochronometers have been used in order to establish a detailed chronostratigraphy for the area. Eight distinct deposits have been identified along the Colorado River (Ml -M7, and S3), and four deposits have been identified along the Paria River (Pl -P4).

Geochronology of six of these deposits using optically stimulated luminescence and cosmogenic ¹⁰Be exposure techniques indicates a long-term average bedrock …

Does The Southern Farmington Canyon Complex Record A Late Archean/Early Proterozoic Accretionary Complex?, Kyle C. Andreasen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Farmington Canyon Complex, situated along the Wasatch front in northern Utah, has been the target for many studies. The FCC has been interpreted to be a passive margin sedimentary wedge. Previous studies have yielded isotopic ages that broadly support an Archean age of formation, and a prominent mid-proterozoic amphibolite grade metamorphic event.

Based on this study, a new interpretation for the FCC is presented. Field relations and whole-rock geochemistry as well as recent advances in understanding Archean crustal processes have resulted in the FCC to be considered as an accretionary complex that formed along the SW margin of the …

Late Cambrian (Steptoean) Sedimentation And Responses To Sea-Level Change Along The Northeastern Laurentian Margin: Insights From Carbon Isotope Stratigraphy, Bosiljka Glumac, Laurel E. Mutti

Geosciences: Faculty Publications

Carbon isotopes are applied as tools for stratigraphic correlation of poorly fossiliferous Upper Cambrian carbonate strata in the northern U.S. Appalachians. Upper Cambrian (Steptoean) marine carbonate rocks record a significant global positive carbon isotope excursion (δ 13C = +4‰-5‰ Vienna Peedee belemnite [VPDB]), the timing of which is well documented in fossiliferous sections elsewhere. The Steptoean excursion peaks at a sea-level lowstand that produced the Sauk II-Sauk III sequence boundary on the North American craton. In this study, this excursion is documented for the first time in the northern U.S. Appalachians in poorly exposed limestone debris flow and olistolith deposits …

Big Fences Do Not Make Good Neighbors, David J. Keeling

Earth, Environmental, and Atmospheric Sciences Faculty Publications

No abstract provided.

Ua66 2007 Student Awards Ceremony, Wku Ogden College Of Science & Engineering

WKU Administration Documents

Program recognizing Ogden College students with brief list of activities for each student.

Climatic And Structural Controls On The Geomorphology Of Wadi Sana, Highland Southern Yemen, Joshua Michael Anderson

USF Tampa Graduate Theses and Dissertations

Middle Holocene climate change forced significant environmental response and influenced human activities throughout southern Arabia. Climate models and proxy data indicate that climate along the southern Arabian peninsula changed from a moist phase, spanning the early to middle Holocene, to an arid phase, which persisted for the last ca. 5,000 years. A weakening and southward shift of the Southwest Indian Monsoon System, forced by northern hemisphere insolation variations in the precession band and/or glacial boundary conditions, is suggested as the mechanism for the abrupt shift to more arid conditions. Geoarchaeological evidence suggests that agriculture was more widespread and evolved alongside …

Influence Of Evapotranspiration On Patterns Of Ground-Water Conductivity In Small Basins, Ana Jiménez

USF Tampa Graduate Theses and Dissertations

Ground-water conductivity data were obtained from shallow wells in a 12 km2 stream-basin along a 400 m transect, extending from the divide to the stream. The stream, Pringle Branch, is a second-order perennial stream in Hillsborough County, Florida. The shallow stratigraphy consists of 2-3 m of fine sand over a layer of clayey silt and silty clay. Vegetation cover includes grasses on the upper and middle slope, and riparian woodlands on the foot slope and floodplain. Precipitation is about 1.3 m per year. Shallow ground-water conductivity is about 50 uS/cm at the divide. It increases moderately along the mid slope, …

Hikorocodium Endo Is Not An Alga But An Inozoid Sponge, J. Keith Rigby, Baba Senowbari-Daryan

Faculty Publications

The genus Hikorocodium, with the type species Hikorocodium elegantae from the Permian of Japan, was described originally as a codiacean alga by Endo. It is not a codiacean alga but an inozoid sponge of the family Preperonidellidae. Several fossils described later by Endo and other authors as H. elegantae should be assigned to different inozoid sponge taxa. Specimens of H. fertiliz, described by Endo from the Jurassic of Japan, are also sponge fragments. The taxonomic positions of H. transversum Endo and H. kuramotoi Nakamura, as sponges or

Observer Bias In Anuran Call Surveys, Aaron Lotz, Craig R. Allen

United States Geological Survey: Staff Publications

Amphibian monitoring programs rarely question the quality of data obtained by observers and often ignore observer bias. In order to test for bias in amphibian call surveys, we sampled 29 clusters of wetlands from the Rainwater Basin, Nebraska, USA, totaling 228 functionally connected wetlands. Sampling consisted of 3-minute stops where volunteers recorded species heard and made digital recordings. Based on 627 samples, we examined 3 types of observer bias: omission, false inclusion (commission), and incorrect identification. Misidentification rates ranged from 4.2% to 18.3%. Relatively high and unquantified error rates can negatively affect the ability of monitoring programs to accurately detect …

Episodic Tremor And Slip In The Pacific Northwest, Kenneth C. Creager, Timothy I. Melbourne

Geological Sciences Faculty Scholarship

Every 14 months the Pacific Northwest experiences slow slip on a fault that is the equivalent of about a magnitude 6.5 earthquake. While a typical earthquake of this magnitude happens in less than 10 seconds, the duration of these slip events is two to several weeks. The most recent event occurred from January 14 through February 1, 2007.

Geophysical Monitoring Probes And Their Applications To Some Hydrogeological Problems, Laura Smart

Dissertations

Geophysical monitoring probes were constructed to monitor the vertical changes of water content and ion concentration in the subsurface. These devices contain electrodes for resistivity measurements and thermistors for temperature measurements. They are designed to monitor the resistivity and temperature of the saturated zone, the transition zone, and the vadose zone near a groundwater/surface water interface. Additional installations at the site include four monitoring wells and four Time Domain Reflectometry (TDR) access tubes, each paired with the geophysical probe installations. Pole-Pole resistivity measurements with an a-spacing of 5 cm are made using a CR1000 Campbell Scientific, Inc. datalogger. Automated data …

Sequence Stratigraphic Controls On Synsedimentary Cementation And Preservation Of Dinosaur Tracks: Example From The Lower Cretaceous, (Upper Albian) Dakota Formation, Southeastern Nebraska, U.S.A., Preston Lee Phillips Jr., Greg A. Ludvigson, R. Matthew Joeckel, Luis A. González, Robert L. Brenner, Brian J. Witzke

Department of Earth and Atmospheric Sciences: Faculty Publications

A thin cemented sandstone bed in the Upper Albian Dakota Formation of southeastern Nebraska contains the first dinosaur tracks to be described from the state. Of equal importance to the tracks are stable-isotope (C, O) analyses of cements in the track bed, especially in the context of data derived from generally correlative strata (sandstones and sphaerosiderite-bearing paleosols) in the region. These data provide the framework for interpretations of paleoenvironmental conditions, as well as a novel approach to understanding mechanisms of terrestrial vertebrate track preservation.

High minus-cement-porosity (> 47%) and low grain-to-grain contacts (~2.5) in the track bed indicate early (pre-compaction) …

Hydrogeochemical Evolution Of Arsenic Along Groundwater Flow Paths: Linking Aqueous And Solid Phase Arsenic Speciation, Shama Haque

Earth & Environmental Sciences Dissertations - Archive

The central hypothesis of this Doctoral research work is that changes occurring along groundwater flow paths that accompany chemical weathering and oxidation-reduction reactions catalyze both arsenic (As) mobilization from, and capture by, minerals via adsorption/desorption and/or mineral dissolution/precipitation reactions. This central hypothesis is addressed by (i) quantifying concentrations and speciation of As, and ancillary geochemical parameters, including a number of redox sensitive parameters in groundwater samples collected along flow paths, and (ii) determining solid phase speciation of As in aquifer sediment samples, with specific emphasis on the labile (i.e., surface exchangeable) and non-labile As fractions (e.g., precipitated with Fe oxides). …

Droughtscape, Spring 2007, National Drought Mitigation Center

DroughtScape: Quarterly Newsletter of the National Drought Mitigation Center (2007–2023)

2007 Spring Drought Outlook & Winter Summary

VegDRI Expands to 15 States, Refines Views

DroughtScape

State Spotlight: Utah

International Panel Foresees Drought as Part of Climate Change

NIDIS Portal Advancing

Unlv Magazine, Grace Russell, Gian Galassi, Shane Bevell, Karyn S. Hollingsworth, Jennifer Lawson, Lori Bachand, Cate Weeks, Erin O'Donnell, Peter Starkweather

UNLV Magazine

No abstract provided.

Late Pleistocene Climate Variability And Chemical Weathering In The Goriganga, Higher Central Himalaya, North India, Steven Paul Beukema

Dissertations

Relict lacustrine deposits in the Higher Central Himalaya, India, provide a rich repository of paleoclimate information for the period 16 ka to 11 ka. Stable isotope analysis of deposits near the village of Burfu shows the hydrologic balance between glacial meltwater and monsoon precipitation as source waters for the lake. During the period from 15.5 ka to 14 ka the Burfu lake was largely fed by melting glaciers. A warming event correlated to glacial Meltwater Pulse 1a indicates a sudden increase in carbonate weathering in the region accompanied by a gradual decrease in the ratio of glacial meltwater/monsoon precipitation feeding …

Seagrass-Mediated Carbonate Dissolution And Early Diagenesis In Bahamas Bank Sediments, Xinping Hu

OES Theses and Dissertations

This dissertation presents the results of studies examining the role that seagrasses play in carbonate dissolution and early diagenesis of Bahamas Bank sediments. Three aspects of this problem are addressed: (1) stable carbon isotopes as an indicator of early diagenesis of carbonates, using results of a field study; (2) carbonate dissolution stoichiometry and carbonate reprecipitation, using the results from closed-system sediment incubation studies; (3) carbonate dissolution and reprecipitation across the broader Bahamas Bank. In Chapter II, I examined δ¹³C in the dissolved inorganic carbon (DIC) of sediments with various degrees of seagrass densities. In low seagrass density and …

The Observation, Modeling, And Retrieval Of Bio-Optical Properties For Coastal Waters Of The Southern Chesapeake Bay, Xiaoju Pan

OES Theses and Dissertations

The primary purpose of this study was to develop an inverse method to retrieve the inherent optical properties (IOPs) and biogeochemical parameters (e.g. chlorophyll a concentration and salinity) appropriate to monitor the water quality and biogeochemical processes from remote sensing of the coastal waters in the southern Chesapeake Bay and coastal Mid-Atlantic Bight region (MAB) dominated by Case 2 waters. For this purpose, knowledge of the relationship between remote sensing reflectance (R_rs) and IOPs and the effect from bottom reflectance on R_rs, is required.

A substantial investigation of IOPs has been conducted for the coastal …

Stratigraphy And Organic Carbon Contents Of Glacial Deposits In The City Of Portage, Michigan, U.S.A., Nathaniel A. Barnes

Masters Theses

The objectives of this study are to characterize the stratigraphy of the glacial drift in an area located in Portage, Michigan using four complete rotasonic cores, and to determine the variation of organic carbon content in the drift that may explain the high iron concentrations in the groundwater typically obtained in moderate to deep wells in southwestern Michigan. The four cores were characterized in detail in terms of lithology, textural and statistical analyses, gamma ray logging, S¹³C variation and organic carbon analyses. Clay minerals were characterized using X-ray diffraction analysis.

Results of this study identified two main diamicton …

Effects Of Elevated Atmospheric Co2 On Root Dynamics, Biomass And Architecture In A Scrub-Oak Ecosystem At Kennedy Space Center, Florida, Daniel Benjamin Stover

Biological Sciences Theses & Dissertations

A major gap in whole-plant ecology lies with our understanding of root system growth, function and distribution. Large belowground structures, in addition to fine roots, are of particular interest because of their role in carbon sequestration. Non-destructive methods, including ground-penetrating radar (GPR) and minirhizotron observation tubes, were used to investigate effects of elevated CO₂ on root biomass, dynamics (productivity, mortality, and turnover), root persistence and architecture in a fire dominated scrub-oak ecosystem. Open-top chambers have been exposed to elevated atmospheric CO₂ for the past eleven years at Kennedy Space Center, Florida. No significant sustained CO₂ treatment effects …

Downstream Pathway Activation In Cultured Hepatocytes Following Treatment With Francisella Tularensis, Nicole Wakefield

Undergraduate Theses and Capstone Projects

Francisella tularensis, the intracellular pathogen that causes tularemia, was investigated to determine how it infects and replicates within mammalian hepatocytes. To date, it has been shown that hepatocytes can be infected by F. tularensis and that this causes considerable change in the protein phosphorylation state of several vital signaling molecules within the host cell. Protein kinase pathways can be mapped as signatures of infection. Hepatocytes tend to be susceptible to infection by F. tularensis, thus stimulating internal signaling. The Francisella strains used were selected with the goal of producing a model that can be used to elucidate the cell signaling …

Identification And Catalog Of Holocene And Late Pleistocene Chiropteran Fossils From Hamilton County, Tn, Ashley Miller

Honors Theses

Caves play an essential role in our understanding of the Pleistocene Epoch. Caves represent the largest percentage of known North American Pleistocene faunas (Kurten and Anderson, 1980). These unique environments provide stable erosion free conditions that allow fossils to remain preserved for thousands, if not millions, of years (Corgan, 1996; Schubert et al., 2003). The fossil remains found in caves can help paleontologists document biogeographic and evolutionary patterns in a great variety of organisms (Schubert et al., 2003). Many fossils found in cave deposits only date to the Holocene (Schubert et al., 2003). These fossils localities are rarely studied by …

Frequency Of Sublethal Injury In A Deepwater Ophiuroid, Ophiacantha Bidentata, An Important Component Of Western Atlantic Lophelia Reef Communities, R. Allen Brooks, Martha S. Nizinski, Steve W. Ross, Kenneth J. Sulak

United States Geological Survey: Staff Publications

The occurrence and relative abundance of tissue (arm) regeneration in the ophiuroid, Ophiacantha bidentata (Retzius), was examined in individuals collected primarily among colonies of the deep-water coral Lophelia pertusa off the southeastern United States. Seven deep-water coral sites (384–756 m), located between Cape Lookout, NC, and Cape Canaveral, FL, were sampled in June 2004 using a manned submersible. The presence of regenerative tissue was evaluated by visual inspection of each individual ophiuroid, and the proportion of regenerating arms per individual was examined relative to size of individual, geographic location, and depth of collection. Ophiacantha bidentata, the dominant brittle star collected, …

Frequency-Dependent Attenuation Analysis Of Ground-Penetrating Radar Data, John H. Bradford

CGISS Publications and Presentations

In the early 1990s, it was established empirically that, in many materials, ground-penetrating radar (GPR) attenuation is approximately linear with frequency over the bandwidth of a typical pulse. Further, a frequency-independent Q* parameter characterizes the slope of the band-limited attenuation versus frequency curve. Here, I derive the band-limited Q* function from a first-order Taylor expansion of the attenuation coefficient. This approach provides a basis for computing Q* from any arbitrary dielectric permittivity model. For Cole-Cole relaxation, I find good correlation between the first-order Q* approximation and Q* computed from linear fits to the attenuation coefficient …

Evidence For Prehistoric Coseismic Folding Along The Tsaotun Segment Of The Chelungpu Fault Near Nan-Tou, Taiwan, Ashley R. Streig, Charles M. Rubin, Wen-Shan Chen, Long-Shen Lee, Stephen C. Thompson, Chris Madden, Shih-Ting Lu

All Faculty Scholarship for the College of the Sciences

Taiwan's 1999 M_w 7.6 earthquake generated over 85 km surface rupture along the Chelungpu thrust fault. Paleoseismic studies at the Shi‐Jia site near Nantou city, reveal folding as the predominant form of deformation. Stratigraphic relations across the 1999 fold scarp show the style and degree of deformation caused by the penultimate event is similar to observed 1999 deformation. A boring transect across the fold scarp provides additional evidence of an earlier earthquake. Investigations at the Shi‐Jia site revealed three prehistoric events; accelerator mass spectrometry (AMS) radiocarbon ages indicate that the penultimate earthquake occurred between 1160 and 1440 A.D. Paleoseismic …

Particulate Organic Carbon Fluxes Along Upwelling‐Dominated Continental Margins: Rates And Mechanisms, Robert Thunell, Claudia R. Benitez-Nelson, Ramon Varela, Yrene Astor, Frank Muller‐Karger

Faculty Publications

[1] Time series sediment trap samples were used to examine the rates and mechanisms of particulate organic carbon (POC) flux at three continental margin locations, Santa Barbara Basin, Cariaco Basin, and Guaymas Basin, marked by seasonal upwelling and high primary production. The mean POC flux in Santa Barbara Basin (0.096 g m−2 d−1) is nearly twice that of Cariaco Basin and 4 times higher than that in Guaymas Basin, with all three sites having POC fluxes significantly higher than the open ocean average (0.007 g m−2 d−1). In Cariaco Basin, the only site with available primary production numbers, there is …