Earth Sciences Commons^™

Examination Of The Role Of Macropores And Subsurface Drainage In The Delivery Of Nitrogen Trioxide-Nitrogen To A Small First-Order Agricultural Stream In Southern Ontario, Abraham House

Theses and Dissertations (Comprehensive)

Agricultural practices may result in nitrate losses, diminished surface water quality and widespread groundwater aquifer contamination. Many works have identified preferential flow through macropores as an important feature that may increase nitrate losses. Subsurface drainage collectors may intercept preferential flow and indicate changing unsaturated/saturated processes. Antecedent conditions are important in determining runoff response. It is unclear how tile drains modify the antecedent soil moisture regime and water tables in near stream areas. Vegetated riparian buffer zones found beetween agricultural fields and watercourses may attenuate nitrate in shallow groundwater pathways. However, little work recognizes the close proximity of buffer strips and …

Modeling The Bull Run River-Reservoir System, Scott A. Wells

Civil and Environmental Engineering Faculty Publications and Presentations

The City of Portland, Water Bureau currently operates 2 Bull Run reservoirs, Reservoir #2 and Reservoir #1 as a water supply source in the Bull Run watershed shown in Figure 1 and Figure 2. The Water Bureau wants to operate their water supply system in order to meet both water supply objectives and fish habitat objectives downstream of the Bull Run reservoirs in Bull Run River. In addition, a third Bull Run reservoir has been proposed as an additional water supply source. This reservoir also may be used to meet water supply and fish habitat objectives in Bull Run River. …

Nitrogen Isotopic Composition Of Pore Water Ammonium, Blake Ridge, Site 997, Odp Leg 164, Walter S. Borowski, Charles K. Paull

EKU Faculty and Staff Scholarship

Ammonium (NH4 +) concentration profiles in piston-core sediments of the Carolina Rise and Blake Ridge generally have linear concentration profiles within the sulfate reduction zone (Borowski, 1998). Deep Sea Drilling Project (DSDP) Site 533, located on the Blake Ridge, also displayed a linear ammonium concentration profile through the sulfate reduction zone and the profile linearity continues into the upper methanogenic zone to a depth of ~200 meters below seafloor (mbsf), where the first methane gas hydrates probably occur (Jenden and Gieskes, 1983; Kvenvolden and Barnard, 1983). Sediments from the Ocean Drilling Program (ODP) Leg 164 deep holes (Sites 994, 995, …

Significance Of Anaerobic Methane Oxidation In Methane-Rich Sediments Overlying The Blake Ridge Gas Hydrates, Walter S. Borowski, Tori M. Hoehler, Mark J. Alperin, Namcy M. Rodriguez, Charles K. Paull

EKU Faculty and Staff Scholarship

A unique set of geochemical pore-water data, characterizing the sulfate reduction and uppermost methanogenic zones, has been collected at the Blake Ridge (offshore southeastern North America) from Ocean Drilling Program (ODP) Leg 164 cores and piston cores. The δ13 C values of dissolved CO2(Σ CO2) are as 13 C-depleted as –37.7‰ PDB (Site 995) at the sulfate-methane interface, reflecting a substantial contribution of isotopically light carbon from methane. Although the geochemical system is complex and difficult to fully quantify, we use two methods to constrain and illustrate the intensity of anaerobic methane oxidation in Blake Ridge sediments. An estimate using …

Geologic Map Of The Lima 30' X 60' Quadrangle, Southwest Montana, J. D. Lonn, B. Skipp, E. T. Ruppel, Susanne U. Janecke, W. J. Perry, J. W. Sears, M. J. Bartholomew, M. C. Stickney, W. J. Fritz, H. A. Hurlow, R. C. Thomas

Geosciences Faculty Publications

No abstract provided.

Verification Of The Causes Of Glaciations And Sea Level Changes Using The Records Of Calcite Speleothems, Y. Shopov, D. Stoykova, L. Tsankov, M. Sanabria, J. Lundberg, L. Georgiev, P. Forti, D. Georgieva

International Journal of Speleology

The luminescence of calcite speleothems displays an exponential dependence on soil temperature unless there is a dense cover of forest over the cave to dampen it. This relationship is determined primarily by the strength of solar visible and infrared radiation. It is suggested that, as a consequence, the microzonal variations of luminescence often found in speleothems can be used as a proxy index of Solar Insolation. The luminescence solar insolation proxy record of a speleothem from Jewel Cave, South Dakota, USA, was found to display millenial and centennial cycles in the record. It exhibits a rapid increase in solar insolation …

Iron And Manganese In The Ross Sea, Antarctica: Seasonal Iron Limitation In Antarctic Shelf Waters, Peter N. Sedwick, Giacomo R. Ditullio, Denis J. Mackey

OES Faculty Publications

Dissolved iron and manganese and total dissolvable iron were measured in water column samples from the Polynya Region of the southern Ross Sea in cruises in Nov.-Dec. 1994 (spring 1994) and Dec. 1995 to Jan. 1996 (summer 1995). Iron and manganese addition bottle incubation experiments were also performed on these cruises to assess the nutritional sufficiency of ambient iron and manganese concentrations for phytoplankton growth. Generally high dissolved iron concentrations (>0.5 nM) and relatively complex iron and manganese vertical profiles were obtained in spring 1994 vs. summer 1995. Dissolved iron concentrations in the upper water column averaged 1.0 nM …

Spatial And Temporal Patterns Of Fluvial Suspended Sediment Yield From Eastern North America, Catherine Treena Conrad

Theses and Dissertations (Comprehensive)

A knowledge of spatial and temporal patterns of sediment yields and an understanding of the factors that determine those patterns have theoretical, environmental and socio-economic significance. To assess the change in sediment yields (in both space and time) a data base of 193 river gauging sites spanning the eastern provinces of Canada and eastern United States was compiled. The original source of the data was the United States Geological Survey data base (obtained from a Hydrosphere Data Inc. cd-rom) and Environment Canada (HYDAT) data base, which included stream discharge, sediment loads and basin areas, with record lengths of one year …

Dolomitization And Dolomite Neomorphism: Trenton And Black River Limestones (Middle Ordovician) Northern Indiana, U.S.A., M. I N Chan, Jay M. Gregg, Kevin L. Shelton

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The Trenton and Black River Limestones are dolomitized extensively along the axis of the Kankakee Arch in Indiana, with the proportion of dolomite decreasing to the south and southeast of the arch. Planar and nonplanar dolomite replacement textures and rhombic (type 1) and saddle (type 2) void-filling dolomite cements are present. Three stages of dolomitization, involving different fluids, are inferred on the basis of petrographic and geochemical characteristics of the dolomites. Nonferroan planar dolomite has relatively high δ18O values (-1.8 to -6.1‰ PDB) and has ⁸⁷Sr/⁸⁶Sr ratios (0.70833 to 0.70856) that overlap those of Middle Ordovician seawater. …

Civilian Conservation Corps Rubble And Masonry Dams And Gully Morphology In Northeastern Iowa, Timothy Robert Beerman

Dissertations and Theses @ UNI

The Civilian Conservation Corps (CCC) was created in 1933 in an effort to help solve the problems associated with the lack of jobs for young men, the nations dwindling natural resources, and problems associated with soil erosion. The CCC's work in Iowa was primarily in the areas of reforestation and erosion control. Company 1749 of Cresco, Iowa stands out as an example of how the CCC worked to halt erosion. As a part of their erosion-control strategy, Company 1749 built a large number of rubble and masonry dams on gullies. These dams were designed to trap sediments and prevent further …

Air-Ground Temperature Exchange, William L. Schmidt

Theses and Dissertations

Most borehole paleoclimate studies have been based on the assumption that the exchange of temperature between the air and ground surface remains constant. However, secular changes in boundary-layer factors can generate anomalous ground temperatures. This dissertation is an investigation of factors that cause separation of air and ground temperatures on a seasonal to inter-annual time scale, including snow cover duration, latent energy of ground freezing, daily sunlight, precipitation, and vegetation.

Continual records of surface air and near-surface ground temperatures from five sites in North Dakota show similar trends in seasonal air-ground temperature separation. Statistical regressions of mean annual ground temperatures …

Detecting The Cause Of Acidification At A Seasonal Wetland On The Swan Coastal Plain, Western Australia, Through Laboratory And Field Mesocosm Experiments, Kelli O'Neill

Theses : Honours

Acidification (pH< 4.5) was detected at Lake Jandabup, a shallow, seasonal wetland on the Swan Coastal Plain. Western Australia. Concern has been raised because populations of invertebrate species have declined or disappeared since acidification, potentially compromising the status of the lake as a nature reserve. The Jake bed is underlain with pyrite (feS₂), which oxidises when dry producing sulfates, hydrogen ions and ferrous iron. Being seasonal, Lake Jandabup would be expected to be naturally acidic, but the more recent trend has been a prolonged (> 1 year) and extreme acidification (pH < 4.0). This study endeavoured to explain why the Jake may have undergone an acidic change, why it may have recovered and whether it will happen again. It was hypothesised that the acidification may have been caused by prolonged drying of the lake causing excessive oxidation of pyrite which produced more acid than the wetland could neutralise through buffering. The hypothesis was tested through laboratory and field experiments. The laboratory experiment involved taking intact sediment cores from around the lake, drying them for various lengths of time, and measuring pH, sulfate, total iron, total alkalinity and total aridity upon rehydration. Dried sediment from diatomaceous earth under Fe(OH)₃ precipitate gave the lowest pH of less than 4.0. High sulfates, low alkalinity and low pH were interrelated. While drying in its own right produced low pH, generally there was no significant difference between drying times for release of selected variables. The field experiment involved the establishment of small in situ mesocosms to test for the effects …

The Use Of Stable Isotopic Signatures Of Marine Biota To Map Sewage Effluent Disposed Into The Marine Environment, Adam Gartner

Theses : Honours

Recent work indicates that nitrogen stable isotopic signatures of aquatic biota can be used to link nutrient inputs in the marine environment to terrestrial sources. While this technique of tracing nutrients has been shown to be effective in environments that are not nutrient limited, it has not been proved that this method is effective in oligotrophic environments. This study examined whether nitrogen stable isotopic signatures of marine biota can be used to trace the distribution of sewage effluent in highly mixed, nitrogen limited waters, by examining the δ¹⁵N values of marine biota situated close to and distant from …

Identification Of Wetland Plant Hydrotypes On The Swan Coastal Plain Western Australia, Robyn Loomes

Theses : Honours

The hydrology of 19 Swan Coastal Plain wetlands was described in relation to its influence on the composition and stn1cturc of wetland vegetation. Sixty species were identified as ‘wetland’ plants. The water depth ranges, or hydrological envelopes, of these species were determined and species grouped together based on the water regimes they experienced. Descriptions of wetland hydrology suggested that the surface and groundwater levels of the majority of study wetlands had declined in both the short (3-5 years) and long-term (20-50 years). Wetlands belonging to the Bibra Suite did not follow this trend as surface water levels either increased or …

The Long-Term Viability Of A Zero-Valent Iron Permeable Reactive Barrier, Stuart Cowburn

Dissertations and Theses

Zero-valent iron permeable reactive barriers (PRB's) hold significant potential as a tool for groundwater remediation. Uncertainties remain, however, as to the effective lifetime of Fe⁰ barrier technology under full-scale operational conditions. Potential limits on barrier lifetime include reductions in permeability due to clogging by precipitates and oxidation of all Fe⁰ prior to the exhaustion of the contaminant source.

A 46 m long, 0.6 m wide, and 7.3 m deep Fe⁰ PRB was installed at the US Coast Guard Support Center, Elizabeth City, NC, in June 1996. The barrier was designed to remediate groundwater principally contaminated with Cr(VI) …

Carbonate Deposition And Sequence Stratigraphy Of The Terminal Cambrian Grand Cycle In The Southern Appalachians, U.S.A, Bosiljka Glumac, Kenneth R. Walker

Geosciences: Faculty Publications

The cessation of shale and carbonate deposition of the Conasauga Group grand cycles (Middle to Upper Cambrian) and the establishment of the widespread peritidal carbonate deposition of the Knox Group (Upper Cambrian to Lower Ordovician) represent a prominent change in sedimentation along the early Paleozoic passive continental margin in the southern Appalachians. To evaluate the causes for this change, this study focuses on the Maynardville Formation, which is the uppermost carbonate unit of the Conasauga Group. The Maynardville consists of: (1) a lower subtidal faciès succession, which is underlain by the Nolichucky Shale and resembles the rest of the Conasauga …

Small-Scale Variability Of Groundwater-Lake Interaction At Shingobee Lake, Minnesota, Hans F. Kishel

Theses and Dissertations

Groundwater discharge is an important contributor to the water budget of a lake. The variability of hydraulic parameters of lake and groundwater systems causes difficulties in estimating the contribution of groundwater to a lake water budget. This study attempts to show that amount of variability for a small portion of the lake and shore (8 x 15 meter section, starting approximately five meters from shore and extending nine meters into the lake).

Piezometers were installed at a depth of one half and one meter in nests at 70 locations in the rectangular study site. Water levels were collected from the …

Characterization Of Hyporheic Zone Processes Of A Northern Prairie Stream, David B. Rush

Theses and Dissertations

A hyporheic zone occurs beneath and adjacent to streams where surface water and groundwater mix. This zone is known to be a reservoir for solutes and a habitat for interstitial organisms. Hyporheic zone boundaries in the Tongue River, North Dakota, were investigated through examination of the physicochemical and biological gradients present in the stream channel and bank sediments. The effects of cattle grazing at the streamside interface of the riparian zone were also examined at two locations to determine land use impacts on the hyporheic zone.

Electrical conductivity (EC) and ammonium gradients were observed beneath the stream channel via nests …

Determination Of Thermal Maturity And Organic Matter Type By Principal Components Analysis Of The Distributions Of Polycyclic Aromatic Compounds, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The thermal maturity and organofacies sensitivity of polycyclic aromatic compound (PAC) distributions was explored by examination of the aromatic fractions of solvent extracts from a diverse set of 53 shales, coals and kerogen macerals which have undergone either natural or artificial maturation and which represent all three principal sedimentary organic matter (OM) types. Systematic changes with maturation were observed in the following groups of isomers: tri- and tetramethylnaphthalenes, methyl- and dimethylphenanthrenes, methyl- and dimethyldibenzothiophenes, methylpyrenes, and methylchrysenes. The maturity differences were quantified by mathematical ratios of the relative concentrations of the more thermally stable isomers to the less stable, on …

Tributaries To West Antarctic Ice Streams: Characteristics Deduced From Numerical Modelling Of Ice Flow, Christina L. Hulbe, Ian R. Joughin, David L. Morse, R. A. Bindschadler

Geology Faculty Publications and Presentations

A network of relatively fast-flowing tributaries in the catchment basins of the West Antarctic ice streams transport ice from the inland reservoir to the heads of the ice streams. Branches of the network follow valleys in basal topography, but not all valleys contain tributaries. We investigate the circumstances favoring tributary flow upstream of Ice Streams D and E, using a combination of observation and numerical modelling. No consistent pattern emerges. The transition from tributary to ice-stream flow occurs smoothly along the main tributary feeding into the onset of Ice Stream D, with ice thickness being relatively more important upstream, and …

Revised Glacial Margins And Wisconsin Meltwater Paleoflood Hydrology In Slippery Rock Creek Basin, Central Western Pennsylvania, Gary John D'Urso

Graduate Theses, Dissertations, and Problem Reports (ETD)

Glacial margins mapped in Slippery Rock Creek basin during the 1950s are problematic. The number of sedimentological, mineralogical, petrological, and textural analyses used to distinguish glacial drifts in the southern portion of the basin were inadequate to resolve the margins. Furthermore, misidentification of man-made deposits as glacial drift led to erroneous interpretations regarding the extent and character of pre-Wisconsin glacial deposits, and appears to have influenced subsequent soil mapping. Canadian Shield erratic weathering was the primary tool used in this study to re-investigate the glacial margins. Erratics display one of three distinctive weathering rinds, so glacial deposits can be differentiated …

Révision De Quelques Hypothèses Sur Le Creusement Karstique, Jacques Choppy

International Journal of Speleology

Quite often, as we know better karst phenomena and the evolution of the karst environment, several hypotheses on speleogenesis appeared to be flimsy. Some of these hypotheses, concerning processes playing a part in the creation of karst forms, exceed the limits of their field. Others suggest hydraulic mechanisms, and interventions of geological or geographical factors likely to be questioned. Hypotheses relating to the evolution of karst, as well as the classification of karst types, suffer from the lack of an analytical approach. However, some of these hypotheses still have an important place in the current vision of speleologists and karstologists.

The Link Between Climate Warming And Break-Up Of Ice Shelves In The Antarctic Peninsula, Ted A. Scambos, Christina L. Hulbe, Mark A. Fahnestock, Jennifer Bohlander

Geology Faculty Publications and Presentations

A review of in situ and remote-sensing data covering the ice shelves of the Antarctic Peninsula provides a series of characteristics closely associated with rapid shelf retreat: deeply embayed ice fronts; calving of myriad small elongate bergs in punctuated events; increasing flow speed; and the presence of melt ponds on the ice-shelf surface in the vicinity of the break-ups. As climate has warmed in the Antarctic Peninsula region, melt-season duration and the extent of ponding have increased. Most break-up events have occurred during longer melt seasons, suggesting that meltwater itself, not just warming, is responsible. Regions that show melting without …

Development, Management And Economy Of Show Caves, Arrigo A. Cigna, Ezio Burri

International Journal of Speleology

The problems concerning the development of show caves are here considered by taking into account different aspects of the problem. A procedure to carry out an Environmental Impact Assessment (EIA) has been established in the last decade and it is now currently applied. Such an assessment starts with a pre-operational phase to obtain sufficient information on the undisturbed status of a cave to be developed into a show cave. Successively a programme for its development is established with the scope to optimise the intervention on the cave at the condition that its basic environmental parameters are not irreversibly modified. The …

The Influence Of Cave Tourism On Co2 And Temperature In Baiyun Cave, Hebei, China, Linhua Song, Wei Xiaoning, Liang Fuyuan

International Journal of Speleology

Baiyun Cave in Hebei Province is one of the main show caves in North China. The speleothem landscape is wonderful, but strongly weathered. In order to set up the relationship between visitor flow and CO₂ content and temperature, these parameters were measured at observation sites No. 1 and No. 2 in the tourist peak period of May Day Holiday from May 1 to May 7, 2000. and general tourist season August and October, 2000. The results show that visitor flow strongly affects the fluctuations of cave CO₂ content and temperature, that the cave topography and dimensions affect the …

Is It Always Dark In Caves?, Giovanni Badino

International Journal of Speleology

Underground natural sources of visible light are considered. The main light producer is Cerenkov radiation emitted in air, water and rock by cosmic ray muons, that depends, in a complex way, on shape of mountain and of caves. In general the illumination increases linearly with the cavity dimensions. Other light sources are from secondary processes generated by radioactive decays in rock from minerals luminescence. The natural light fluxes in caves are in general easy to detect but are not used from underground life.