Earth Sciences Commons^™

Improving The Efficiency Of Fall Applied N With Cover Crops, Corey Lacey

Theses and Dissertations

Nitrate loss studies in Midwestern tile-drained fields have found that fall applied nitrogen (N) resulted in elevated nitrate concentrations in tile water during both the corn and soybean year of a 2 year rotation. The effectiveness of cover crops to reduce nitrate leaching when N is spring applied has been well demonstrated, however there is a dearth of knowledge on the ability of cover crops to reduce nitrate leaching in a system where N is fall applied. Thus, the objectives of this research were to (i) investigate the efficacy of winter cover crops to reduce nitrate leaching from fall applied …

A Bond Valence-Based Force Field: A Multi-Body Approach, Matthew Harris Davis

Theses and Dissertations

The typical form for a molecular mechanics force field consists of a foundation of pair-wise terms to describe bonded and non-bonded atomic interactions, with multi-body correction terms to deal with the limitations of pair-wise terms. I present here the first attempts of a molecular mechanics model that is founded on multi-body terms, which are based on the Bond Valence Model (Brown, 2002) and recent developments in the Vectorial Bond Valence Model (Bickmore et al., 2013a; Harvey et al., 2006). I calibrated these models on pressure vs. energy curves for a set of SiO2 polymorphs. The average deviation for the best-fit …

Exploring Connections Between A Very Large Volume Ignimbrite And An Intracaldera Pluton: Intrusions Related To The Oligocene Wah Wah Springs Tuff, Western Us, Chloe Noelle Skidmore

Theses and Dissertations

The Wah Wah Springs Tuff and the Wah Wah Springs Intrusive Granodiorite Porphyry(Wah Wah Springs Intrusion) both originated from the Indian Peak caldera complex, which wasa major focus of explosive silicic activity in the middle Cenozoic Great Basin ignimbrite flareup. This caldera formed 30.0 Ma when an estimated 5,900 km3 of crystal-rich dacitic magma erupted to create the Wah Wah Springs Tuff. The Wah Wah Springs Intrusion later intruded the tuff, causing resurgence of the caldera. Field, modal, and geochemical evidence suggest the tuff and intrusion are cogenetic. The mineral assemblages of the two rocks are similar: both include similar …

Facies And Reservoir Characterization Of The Permian White Rim Sandstone, Black Box Dolomite, And Black Dragon Member Of The Triassic Moenkopi Formation For Co2 Storage And Sequestration At Woodside Field, East-Central Utah, Walter Andrew Harston

Theses and Dissertations

Geologic sequestration of anthropogenic carbon dioxide (CO2) greenhouse gas emissions is an engineering solution that potentially reduces CO2 emissions released into the atmosphere thereby limiting their effect on climate change. This study focuses on Woodside field as a potential storage and sequestration site for CO2 emissions. The Woodside field is positioned on a doubly plunging, asymmetrical anticline on the northeast flank of the San Rafael Swell. Particular focus will be placed on the Permian White Rim Sandstone, Black Box Dolomite and Black Dragon Member of the Triassic Moenkopi Formation as the reservoir/seal system to store and sequester CO2 at Woodside …

Toward A Better Understanding Of Recent Warming Of The Central West Antarctic Ice Sheet From Shallow Firn Cores, Jessica Williams

Theses and Dissertations

Previous studies have shown significant warming through the 1990s in the West Antarctic Ice Sheet (WAIS); but the records used in those studies end in early 2000, preventing trend analysis into the latest decade. Fourteen new snowpits and firn cores were collected in 2010 and 2011, which have been combined with previous cores to extend the isotopic records over WAIS. Significance of these isotopic patterns across WAIS was determined and is used to re-evaluate the warming of the West Antarctic interior over recent decades. We find that isotopic records longer than 50 years are needed to assess climate trends due …

Energy Metrics For State Government Buildings, Trevor Michael

Theses and Dissertations

Measuring true progress towards energy conservation goals requires the accurate reporting and accounting of energy consumption. An accurate energy metrics framework is also a critical element for verifiable Greenhouse Gas Inventories. Energy conservation in government can reduce expenditures on energy costs leaving more funds available for public services. In addition to monetary savings, conserving energy can help to promote energy security, air quality, and a reduction of carbon footprint. With energy consumption/GHG inventories recently produced at the Federal level, state and local governments are beginning to also produce their own energy metrics systems.

In recent years, many states have passed …

Climate Change Effects On Vibrio Bacteria In The Winyah Bay Estuary And The Projected Spread Of Vibrio Under Future Climatic Scenarios., Reem Deeb

Theses and Dissertations

While there are several studies on the distribution ofVibrio vulnificusandVibrio parahaemolyticusin estuarine waters around the world, there is little information on the distribution of both organisms in South Carolina waters. Monthly sampling of surface and bottom water from 9 sites in Winyah Bay was conducted over the period April-October 2012. Both organisms were enumerated on CHROMagarVibriomedia. TheVibriocounts obtained were mainly less than 20 Colony Forming Units (CFU)/ml which is typical for what was found elsewhere along the coast of the Carolinas. TheVibrio vulnificuscounts were the highest when salinity ranged between 5 ppt and 20 ppt.Vibrio parahaemolyticusdid not show a clear …

Thermal History Of Nearly Metamict Zircon Of The Taza-Guercif Basin (Morocco) Revealed Using Scanning Electron Microscope High-Density Fission-Track Dating, Tyler Michael Izykowski

Theses and Dissertations

Northwest Africa provides unique insight into a wide range of geologic processes throughout a vast portion of Earth's history. Moroccan geology in particular can provide valuable insight, from the formations of West Africa through the Eburnian orogeny (~2000 Ma), Gondwana during the Pan-African orogeny (~900-500 Ma), and Pangaea by means of the Hercynian (Variscan) orogeny (~400-300 Ma), to more recent crustal and climatic events, such as the Messinian salinity crisis (5.96-5.33 Ma). However, the current lack of western literature regarding this region presents a significant obstacle in understanding the aforementioned processes. Herein, I employ a new technique in zircon fission-track …

Identifying Values And Benefits Of Congaree National Park, Maka Bitsadze

Theses and Dissertations

Protected areas are important tools for the conservation of biological diversity. They also support a wide range of ecosystem services and provide economic, cultural and social values and benefits. Many values and benefits of protected areas are poorly understood and greatly under-valued by decision-makers, the business sector, and the general public. Accordingly, identification and assessment of values and benefits of protected areas has been increasingly promoted during recent years.

This research investigates values and benefits of Congaree National Park and provides guidance for the further economic valuation of identified values and benefits. While the ecological significance of Congaree National Park …

Geophysical Investigation And Assessment Of The Rye Patch Known Geothermal Resource Area, Rye Patch, Nevada, Mark Richmond Mcdonald

Theses and Dissertations

A gravity and ground-based magnetic survey was conducted at the Rye Patch Known Geothermal Resource Area located at Rye Patch, Nevada. The purpose of the study was to attempt to further delineate the geothermal reservoir and/or to identify potential drilling targets. The survey consisted of collecting data at 264 new stations to augment data from 203 stations collected in 2008. Information from previous seismic, aeromagnetic and geochemical investigations was also examined and incorporated. Filtering methods including removal of a polynomial trend surface and wavelength filtering were utilized on the gravity data to remove the strong regional overprint caused by the …

Correcting Heat Flow Data In The United States To Account For Climate Change, Godswill Njoku

Theses and Dissertations

Heat flow measurements may require correction for both recent warming and post-glacial warming signals. Warming during the last century can be detected in borehole temperature profiles. Both climate warming signals during the past century and post-glacial warming signals during the past 10 millennia are greatest near the surface and diminish with depth.

Both atmospheric data and borehole temperature data show that recent warming varies systematically with latitude along a north-south transect in the United States. The systematic increase with latitude from +0.7 oC at 41.6oN to +2.3 oC at 49oN during the last century is consistent with the prediction that …

The Effects Of Mean Sea Level And Tidal Amplitude On Ground Water Discharge And Pore-Water Salinity Distribution Along A Forest/Marsh Boundary, North Inlet, Sc, John Bradley Peurifoy

Theses and Dissertations

Advective groundwater flow in salt marshes is an important mechanism through which nutrients are exported to adjacent coastal waters. Groundwater flow also influences the distribution of pore-water salinity in the subsurface marsh, which affects botanical zonation, nutrient transport, and primary productivity. Recent idealized marsh island simulations have suggested that increases in tidal amplitude result in increased groundwater discharge, and that the elevation of MWL relative to the marsh platform is inversely related to groundwater discharge. These simulations were only representative of marsh islands (as opposed to forest-marsh boundaries) and relied on simulated tides and MWL position. The results were not …

Tidal Flux Of Trace Metals And Rare Earth Elements In A Barrier Island Salt Marsh, Ryan Antle

Theses and Dissertations

Barrier island salt marshes are known as sources of nutrients to the coastal ocean but it is unclear whether they are also sources or sinks of trace metals in regards to coastal waters. Salt marshes are characterized by steep redox and biogeochemical gradients, which constantly fluctuate as a result of tidal pumping. While several studies have examined metal budgets between terrestrial fresh water, estuarine subterranean fluids, and coastal saline waters, there is little data regarding fluid chemistry for metals in salt water estuaries in the absence of fresh water input. This study investigated a back barrier salt marsh on Cabretta …

Tectonics Of The South Georgia Rift, David Michael Heffner

Theses and Dissertations

Triassic rifting of the supercontinent Pangea left behind numerous basins on what is now the eastern North American margin. The South Georgia Rift (SGR) was thought to be the best preserved of these basins having been capped by thick basalt flows of the Central Atlantic Magmatic Province (CAMP) and later buried beneath the Cretaceous and younger Coastal Plain. Because it is buried beneath the Coastal Plain, the SGR is only known through sparse drilling and geophysical methods. Despite this limited dataset, the SGR is the only one of the eastern North American Triassic basins known to overlie the ancient Alleghanian …

Subsurface Imaging And Petrophysical Analysis Of The South Georgia Rift Basin, South Carolina, Olusoga Martins Akintunde

Theses and Dissertations

The Triassic-Jurassic South Georgia Rift (SGR) basin, buried beneath Coastal Plain sediments of southern South Carolina, southeastern Georgia, western Florida, and southern Alabama, consists of an assemblage of continental rift deposits (popularly called red beds), and mafic igneous rocks (basalt flows and diabase sills). The red beds are capped by basalts and/or diabase sills, and constitute the target for supercritical CO2 storage as part of a Department of Energy funded project to study feasibility for safe and long-term sequestration. This study addresses key stratigraphic, structural and petrophysical issues critical to determine subsurface suitability for CO2 storage as well as improved …

Amplitude Vs. Offset Effects On Gas Hydrates At Woolsey Mound, Gulf Of Mexico, Walter R. Anderson

Theses and Dissertations

Due to the estimated massive quantities of natural methane hydrates, they represent one of the largest sources of future alternative energy on Earth. Methane hydrates have been found in the shallow sub-seafloor of the Northern Gulf of Mexico where the water depth is in excess of ~900 m. Mississippi Canyon Block 118 has been chosen by the Gulf of Mexico Hydrates Research Consortium to be the site of a multi-sensor, multi-discipline sea-floor observatory for gas hydrate research. First evidence for gas hydrates at MC 118 was observed at Woolsey Mound. Subsurface evidence for gas hydrates has subsequently been substantiated by …

Volcanic And Tectonic Processes Along Anomalous Mid-Ocean Ridges, Julia Kathryn Howell

Theses and Dissertations

The morphological and structural characteristics of the global spreading ridge system are systematically related to spreading rate and magma supply (e.g. Macdonald, 1982). Because intermediate spreading-rate ridges (ISRs) spreading between 60 and 80 mm/yr have characteristics of both fast and slow spreading ridges, they are ideal environments to study the differences controlling upper crustal accretion. We examine the distribution of seamounts along spreading ridges to understand the relationship between seamount volcanism and axial morphology along four ISRs: the Juan de Fuca Ridge (JdFR), the Galápagos Spreading Centers (GSC), the Southeast Indian Ridge (SEIR), and the Eastern Lau Spreading Centers (ELSC). …

Benthic Boundary Layer Processes: Bedform Evolution And Bottom Turbulence, Timothy Robert Nelson

Theses and Dissertations

Bedform roughness, caused by ripples on the seabed, plays an important role in controlling sediment dynamics in the nearshore region. In this dissertation, the temporal and spatial evolution of ripples from two field sites located in the South Atlantic Bight, offshore Long Bay, SC and Georgia are used to relate wave-induced ripple geometry (wavelength and orientation) to near bed directional wave velocities. 2-D spectral analysis techniques were developed to automate detection of ripple wavelength, direction, and irregularity. This analysis showed that magnitude, direction, and duration of wave forcing controls ripple geometry and irregularity. During highly energetic events, ripple geometry changes …

Drought Indices In Decision-Making Process Of Drought Management, Ekaterina Negodyaeva Altman

Theses and Dissertations

Drought indices are one of the most important elements of an effective drought monitoring and early warning system. They help to characterize drought and guide appropriate responses to reduce drought impacts. Drought indicators are more useful than raw data in decision-making process, even though each index has specific use and limited by its strengths and weaknesses. The literature review showed the evaluation of drought conditions by decision-makers as an important issue, but so far no research has been done to understand how decision-makers use diverse and often conflicting values of drought indices to make drought declarations. This research studies how …

Geochemical Source Components In Seafloor Lavas In The Aleutian Back-Arc, Max Thomas Siegrist

Theses and Dissertations

Whole-rock compositions of seafloor lavas are used to constrain the processes and source characteristics contributing to the formation of geochemically distinctive, primitive magma types located in the Aleutian back-arc. Samples were dredged primarily from small volcanic cones on the seafloor, located between the emergent volcanoes and in the back-arc up to 60 km from the volcanic front. Compositions vary from basalt to dacite, with 48-70 % SiO₂ and 4-13 % MgO. Nearly 30% of the samples are primitive, with Mg/Mg+Fe >0.60. Most primitive samples are basalts, which fall into two groups, based on minor and trace element abundances. Low/med-K …

Hydraulic Fracturing Design For Horizontal Wells In The Bakken Formation, Williston Basin, Hadi Jabbari

Theses and Dissertations

Unconventional hydrocarbon reservoirs have proved to be challenging in terms of reservoir characterization, predicting production potential, estimating ultimate recovery, and optimizing hydraulic fracture stimulations. The methods by which these resources are extracted use progressive, or unconventional, technologies. Today, through the use of hydraulic fracturing and horizontal drilling, extraordinary amounts of oil and natural gas from deep shale formations across the United States and around the world are being safely produced.

Performing a hydraulic fracture design requires modeling of fracture propagation and tracking the fluid front in the created fracture. In this dissertation, the roles of all effective parameters and properties …

Lithological And Sequence Stratigraphic Examination Of The Madison Group Marker Beds, Eastern Williston Basin Margin, North Dakota, Troy Jd. Skitt

Theses and Dissertations

The Frobisher-Alida interval consists of eight log-defined subintervals or “beds” within the Mississippian upper Mission Canyon and lower Charles Formations of the Madison Group in the Williston Basin. The subintervals are composed of predominantly evaporite and carbonate lithologies, and include in descending order: 1) Midale, 2) Rival, 3) Bluell, 4) Sherwood, 5) Mohall, 6) Glenburn, 7) Wayne, and 8) Landa. The top of the lower six subintervals are separated by thin but areal extensive log-defined markers of contrasting lithologies and include in descending order: 1) State A, 2) Sherwood Argillaceous Marker (S.A.M.), 3) K-1, 4) K-2, 5) K-3, and 6) …

Research About Low Permeability Measurement, Jun He

Theses and Dissertations

Petroleum exploration and production from shale formations have gained great attention throughout the world in the last decade. Producing the hydrocarbons from shale is challenging because of the low porosity and permeability. It is imperative to investigate permeability of the shale formations in order to better understand the performance of wells that are producing hydrocarbons from shale. Permeability is also one of key parameters in modeling fluids flow in matrix in reservoir simulation. Due to the low or very low permeability, the measurement of permeability is time consuming and expensive. These factors often limited the ability to perform permeability measurement …

Geomechanics And Elastic Anisotropy Of The Bakken Formation, Williston Basin, Mehdi Ostadhassan

Theses and Dissertations

Many of the earth’s rocks exhibit anisotropic characteristics. Anisotropy is particularly common in many sedimentary rocks, such as shales. Anisotropy is defined as the spatial alignment of mineral grains, layers, fractures and stresses which causes elastic wave velocity and other elastic properties to vary with direction. There are two types of anisotropy: intrinsic and stress-induced. Intrinsic anisotropy is caused by beddings, microstructures or aligned fractures formed during deposition. Stress-induced anisotropy is caused by strain associated with external stresses. Intrinsic anisotropy originates in the absence of external stresses, while stress-induced anisotropy results from tectonic and overburden stresses. The style of earth …

Insights Into The Early Transgressive History Of Lake Bonneville From Stratigraphic Investigation Of Pilot Valley Playa, Ut/Nv, Usa, Kevin A. Rey

Theses and Dissertations

Multiple shallow sediment cores were obtained from Pilot Valley playa, a sub-basin located in the northwestern Bonneville basin. Analysis of stratigraphy, ostracodes, mineralogy, chemistry, total inorganic carbon (TIC), total organic carbon (TOC), and stable isotopes were performed to better place these sediments into proper context with respect to the Lake Bonneville cycle. Results showed Pilot Valley playa contains a nearly full sequence of Lake Bonneville deep-water marl in addition to sediments deposited before and after the Lake Bonneville cycle. Within the marl is a sequence of organic rich algal laminated marl correlated with the Stansbury oscillation. Four 14C ages ranging …

The Role Of Case-Hardening In The Development And Preservation Of Narrow, Vertical-Walled Canyons In Adršpach-Teplice, Czech Republic, Shawn Austin Wiggins

Theses and Dissertations

The geomorphology at Adršpach-Teplice, Czech Republic is dominated by vertical-walled, fracture-controlled features including slot canyons, gorges and pillars. Surfaces of canyon walls in Adršpach are case-hardened and more resistant to erosion than the bulk of the sandstone, which appears to be fundamental to the formation and preservation of canyons. Core and whole rock samples from Adršpach-Teplice were analyzed in thin section, including SEM analysis with cathodo luminescence. XRF and XRD analyses indicated that silica case-hardened surfaces are chemically and mineralogically similar to the rock interior, while iron case-hardened surfaces have an increase in iron present at the surface as the …

Demographic And Genetic Consequences Of Small Population Size In Remnant Populations Of Arabis Georgiana Harper (Georgia Rockcress), Alicia M. Garcia

Theses and Dissertations

The goal of this thesis is to provide a greater scientific understanding of the demographic and genetic consequences of small population size in remnant populations of Arabis georgiana Harper (Georgia Rockcress). Specifically, 1 ) traits associated with phenological progression, fitness and reproductive success were compared between naturally occurring "native" plants and plants grown ex situ and subsequently restored to one of the largest remaining populations of A. georgiana, and 2) a preliminary analysis of population genetic structure in remnant populations across the species' range was performed. In addition to updating census information on remnant populations of A. georgiana, chapter one …

Discriminant Analysis Of Xrf Data From Sandstones Of Like Facies And Appearance: A Method For Identifying A Regional Unconformity, Paleotopography,And Diagenetic Histories, Stephen Paul Phillips

Theses and Dissertations

The placement of an unconformable surface within a stratal succession affects the interpreted thickness of units and sequences in contact with that surface. Unit thickness influences the interpretation of basin subsidence, paleotopography, diagenesis, and depositional style. Accurate placement of an unconformity results in true formational thicknesses for formations associated with that unconformity. True thicknesses aid in producing more precise surface to subsurface correlations, isopach maps, and paleogeographic maps. An unconformity may be difficult to identify in the stratal succession due to similar rocks above and below the unconformity and the presence of multiple candidate surfaces. Using statistical discriminant analysis of …

Self-Organizing Fluid Flow Patterns In Crystalline Rock: Theoretical Approach To The Hydrothermal Systems In The Middle Fork Of The Boise River, Scott A. Himes

Theses and Dissertations

The thermal springs along the Middle Fork of the Boise River (MFBR) within the Atlanta lobe of the Idaho batholith discharge in discrete locations that appear to be part of self-organizing flow systems. Infiltrating water flows through Basin and Range fractures to depth where it is heated and ultimately discharged at the intersection of trans-Challis oriented faults along the MFBR. Isotopic compositions of the thermal waters have a linear trend with elevation suggesting that the recharge locations are near each thermal spring and the hydrothermal system is not one large interconnected system, but rather multiple individual hydrothermal systems. Water chemically …

Geologic Map Of The Deer Point Quadrangle, Garfield County, Utah, Nicholaus D. Driscoll

Theses and Dissertations

A new geologic map of the Deer Point 7.5' quadrangle located in the southern region of Capitol Reef National Park in south-central Utah provides stratigraphic and structural detail not previously available. The Deer Point quadrangle was mapped at a scale of 1:24,000 and is the fourth geologic map completed at this scale in Capitol Reef National Park. Twelve Quaternary units and eighteen bedrock formations and members are exposed in the Deer Point quadrangle. Bedrock formations range in age from Triassic to Cretaceous. The details not available on previous geologic maps include: four alluvial terrace units, two lacustrine units, two mass …