Earth Sciences Commons^™

Sulfate Sources In Groundwater From An Agricultural Area Central Illinois, Christabel I. Obi

Theses and Dissertations

Increasing sulfate (SO₄^2-) concentrations in the water environment, corresponding with increases in urbanization and industrialization, are a rising global concern. Over 250 mg/L, sulfate threatens human health and ecosystems. Elevated concentrations influence carbonate rock weathering, contributing to the evolution of the global carbon cycle. Knowledge of sulfate sources, whether natural or anthropogenic, is essential for understanding sulfate transport and fate in groundwater. This study investigates SO₄^2- origin and transport in groundwater in an area dominated by agricultural land use in Mclean County, Illinois. Specifically, we explored these questions: 1) Do sulfate concentrations change with groundwater …

Investigating Heterogeneity Of Hydraulic Conductivity And Its Influence On Groundwater Flow Dynamics Within A Saturated Riparian Buffer In Central Illinois, Joseph L. Awuku

Theses and Dissertations

The use of Saturated Riparian Buffers (SRBs) in agricultural settings as a means of reducing contamination of surface water and groundwater resources has gained popularity due to their trapping ability and solute removal (nutrient recycling) capacity. In light of SRB’s nutrient-trapping and removal ability, numerous studies have been conducted to characterize the effectiveness of SRBs. However, most studies on SRBs have paid minimal attention to heterogeneity of hydraulic conductivity (K) and groundwater flow dynamics within SRBs. This study investigated the heterogeneity in horizontal K and estimated the vertical groundwater-specific discharge (q_v) between the upper weathered and its …

Exploring Nitrate Reduction In A Saturated Riparian Buffer Through A Three-Dimensional Reactive Contaminant Transport Model In An Agricultural Area, Mcclean County Central Illinois, Franklin O. Ijigade

Theses and Dissertations

Saturated Riparian Buffers (SRBs) are engineered systems designed to remove nitrate and other pollutants from subsurface agricultural drainage water before it reaches a stream. This study utilizes a high-resolution coupled flow and reactive transport model to explore nitrate reduction and transformation in an SRB in glacial sediment. The influence of material heterogeneity on nitrate reduction and the effectiveness of the SRB was investigated. The study was conducted in an SRB located next to and receiving tile drainage water that ultimately drains into a 3^rd order stream (T3 stream) in central Illinois, USA. A three-dimensional steady groundwater flow model was …

Application Of Floating Wetlands To Improve Urban Stream Quality, Daniel Chukwunonso Chukwudi

Theses and Dissertations

Urban streams, impacted by urbanization, often exhibit degraded water quality due to elevated nutrient levels, a phenomenon known as urban stream syndrome. This study evaluates the effectiveness of a floating wetland (FW) system in reducing nitrate as nitrogen (NO₃-N) and phosphate (PO₄³⁻) concentrations in a side canal of the Chicago River’s North Branch, adjacent to Goose Island, Chicago, IL, from 2018 to 2023. Using a five-year dataset, including new sampling from May to December 2023, the research addresses two questions: (1) Do FWs lower NO₃-N and PO₄³⁻ concentrations in urban streams? and (2) Do FWs exhibit seasonal differences in nutrient …

Geomorphic Evolution Of St. Augustine Inlet, St. Johns County, Florida, Kristen Becker

Theses and Dissertations

Tidal inlets interrupt longshore sediment transport, influencing adjacent beach morphology and allowing the exchange of water and sediment between the open oceans and protected back barrier bay. Inlets evolve through a combination of natural processes and are highly dynamic zones where sediment exchanges cause shifting shoreline positions nearby and create new morphological features. Barrier islands/beaches that are close in proximity to inlets evolve and are an important natural feature that dissipates wave energy and protects inland areas. Both natural and anthropogenic processes that affect barrier islands will be investigated during this study, including storm activity, waves, wind, water level, and …

Algal Community Investigations: Present Day To Year-2100 For Mississippi Lakes And The Western Mississippi Sound, Emma Madison Tucker

Theses and Dissertations

Algae play a key role in the aquatic environment as primary producers; however, they can form harmful algal blooms that are detrimental to the aquatic environment, people, and even the economy. It is generally believed that climate change will influence future algal blooms. The first study estimated algae community in three freshwater locations in Mississippi, Desoto Lake, White’s Creek Lake, and Columbus Lake, and one saline location, Western Mississippi Sound, using modern and new tools of the autonomous surface vessel, FlowCam, and EcoTaxa. From those results and leading into the second study was the application of four climate scenarios on …

Implementing Organic Fertilization Practices To Improve Aloe Vera Growth And Soil Health In The Lower Rio Grande Valley, Isaiah Edward Jaramillo

Theses and Dissertations

Aloe vera (L.) (Aloe) Burm. f., is valued for its applications across the cosmetic, medicinal, and food industries due to its leaf gel. In the aloe industry, the extraction of gel from leaves generates significant quantities of organic waste, which presents an opportunity to repurpose this material as an amendment in aloe cultivation. While Aloe is renowned for its resilience, understanding the feasibility of using these organic shavings as a soil fertility amendment in aloe production is critical. This research aims to identify sustainable fertilization methods for Aloe that can maintain and/or improve crop yield while enhancing soil health. This …

A Nursery Study Of The Interplay Between Soil Texture, Rooting Space, And Nurse Plants On Seedling Growth And Root Development In Woody Species Of Tamaulipan Thornscrub, Lance I. Santos

Theses and Dissertations

Reforestation attempts in semi-arid regions are plagued with seedling mortality. Blanket greenhouse practices may not be optimal, in addition, commensalism interactions between nurse plants are considered. To better understand the effects of soil texture and nurse plant interactions on growth and drought tolerance, two experiments were developed. For soil texture, Border palo verde seedlings were grown in different-sized plant bands with three soil types. To observe the effects of nurse plants, an experiment using guayacan, was developed using Texas Ebony, as a leguminous nurse plant. Plants were also exposed to a drought experiment. The results suggest that some soil textures …

Engaging Students In The Scientific Process: An Examination Of Active Learning Strategies In Introductory Geoscience Labs, Meryssa Piper

Theses and Dissertations

High-quality instruction of introductory geoscience courses entices students to major in geoscience fields and ensures undergraduate students have opportunities to learn and apply scientific information and practices. Prior studies indicate that active learning strategies in higher education settings can increase student knowledge and interest. This dissertation explores the integration of two active learning strategies in introductory geoscience laboratory courses: inquiry and gamification The first study housed in Chapter 2 investigates the level of inquiry used in introductory geoscience lab activities across the United States. Through a comprehensive analysis of these activities, this chapter assesses: (1) the degree to which instructor …

The Fifth Element In Three Dimensions: Boron Systematics Along And Across The Aleutian Volcanic Arc, Owen Jensen

Theses and Dissertations

This study uses abundances and isotope ratios of the fluid-mobile element boron (B) to better understand the role of fluids in volcanism at the Aleutian arc in Alaska. In volcanic rocks from the Aleutian volcanic front, patterns in B abundance and isotope ratios (δ11B) point to three endmembers: a sediment melt, a slab interior melt, and a slab-top melt. Most lavas from the eastern Aleutian Islands have δ11B of -2 to +5‰, similar to Aleutian sediment. Hence, sediment is likely to be the dominant B source in the Aleutian Island samples. In lavas from the western Aleutian seafloor, high δ11B …

Temporal Dynamics Of Coastal Sediment Characteristics: A Comparative Study On Pre- And Post-2004 Tsunami Event Along The Nagoor - Poompuhar Stretch, Tamil Nadu, Yamini S

Theses and Dissertations

Tsunamis represent some of the most devastating natural events for coastal regions, as exemplified by the 26th December 2004 Great Indonesian Earthquake triggered a massive tsunami across the Bay of Bengal and Indian Ocean, causing extensive destruction in various countries, including India. This study addresses a significant gap in the literature by focusing on the detailed sedimentological aspects of coastal dynamics. Specifically, it examines the pre-tsunami (December 2004), post-tsunami (January 2005), and recent (December 2022) sediment characteristics along a 35 km stretch of the Coromandel coast from Poompuhar to Nagoor.

Eight stations were selected for sampling: Poompuhar, Chinnankudi, Kuttyandiyur, Chandrapadi, …

Deconvolving Provenance Signatures Of Pliocene-Pleistocene Coastal Loess Deposits Along The Atlantic Margin Of Argentina, Will Robert Quanrud

Theses and Dissertations

Dust derived from southern South America provides critical nutrients for autotropic marine biota in the South Atlantic Ocean, such that fluxes of wind-blown sediment may ultimately affect the concentration of atmospheric CO2. Expansive sand, silt, and loess deposits are exposed in Central Argentina, recording millions of years of eolian processes; however, the provenance and transport pathways of this dust remains unclear. Coastal loess deposits ranging in age from Pliocene to upper Pleistocene are present along the Atlantic margin of Argentina and provide information on sediment transport pathways for the last 4 million years. Nine samples of loess were collected and …

Investigating Arctic Ocean Freshwater Content And Circulation In A Changing Climate, Emma Louise Hoffman

Theses and Dissertations

The Arctic Ocean is unique among the world’s oceans, characterized by its cold temperatures, salinity-driven vertical structure, and shallow shelf seas. It has warmed intensely since the 1980s at rates exceeding the global average. This Arctic Amplification drives variability in sea ice and salinity, affecting local circulation and exchange with other basins, leading to global changes in oceanic and atmospheric circulation and the biosphere. This thesis explores changing dynamics in the Arctic Ocean, in particular connecting modeled changes in liquid freshwater content (FWC) and its pathways with major ocean circulation patterns, atmospheric drivers, and large-scale climatic changes.

This research combines …

New Techniques For Studying Ocean Eddy Dynamics In The Arabian Sea And The Gulf Of Mexico, Paul Andrew Ernst

Theses and Dissertations

Coherent vortices known as eddies are ubiquitous throughout the world’s oceans and are responsible for modulating regional climates via the transfer of heat, momentum, and salt. Two regions where eddies are particularly prominent are the Arabian Sea (AS) and the Gulf of Mexico (GoM). This dissertation advances the study of eddies in these regions by developing and employing new techniques in conjunction with remotely sensed data and high-resolution ocean models. These models focus particularly on lesser-studied eddy components at the subsurface and the submesoscale (below 25 km in radius).

The first component of this dissertation focuses on the Lakshadweep High …

Assessing Multi-Annual Phytoplankton Community Compositions And Biomass Across Tidal Creek And Open Water Estuarine Habitats In South Carolina, Shannon Elizabeth Powers

Theses and Dissertations

The urbanization of coastal environments in recent decades has caused an accelerating increase in nutrient-rich runoff from the landscape. The presence of these excess nutrients in the aquatic environment can result in degradation of water quality and harmful algal blooms. In South Carolina (SC), coastal development continues to threaten the resiliency of salt marsh estuaries, especially in combination with other stressors like climate change and sea level rise. Estuaries are important nurseries and habitats for fisheries and ecotourism. The South Carolina Estuarine and Coastal Assessment Program (SCECAP) is an ongoing monitoring program that assesses the habitat condition along the coast …

Offshore Detachment Of The Winyah Bay Plume Through Ekman Dynamics Under Upwelling Conditions, Isabella Moore

Theses and Dissertations

ABSTRACT River plumes play a crucial role in coastal ecosystems by influencing land-ocean interactions, primary production, water quality, and ocean circulation. This study presents observations of a buoyant river plume off Winyah Bay, South Carolina (USA), conducted in 2020 and 2021. Observations comprised CTD casts and shipborne ADCP profiles as well as near surface flow measurements from a floating platform and microstructure profiles in uprising mode. This research focuses on the offshore transport of the buoyant water through Ekman dynamics under upwelling-favorable conditions. Under varying wind forcing and stratification scenarios, the Winyah Bay plume either remains near the coast or …

Ecological Effects On Greenhouse Gas Emissions In Vegetated Estuarine Soils Of The Lower Laguna Madre, David R. De La Garza

Theses and Dissertations

Coastal wetlands are important ecosystems that provide numerous ecosystem services including erosion control, habitat for fauna, and carbon sequestration. Notably, coastal wetlands are producers of greenhouse gases (GHGs) but are able to store significant amounts of carbon relative to their surface area. Mangrove forests are amongst the most effective ecosystems for carbon sequestration. Soil emits (GHGs) containing carbon (such as carbon dioxide (CO2) and methane (CH4)), which are produced by organic matter decomposition and soil organic carbon mineralization, and both are an important component of the global carbon cycle. Soil emissions may be affected by a variety of factors including …

Calibration And Use Of The Transparency Tube As An Estimate Of Turbidity: An Analysis Of Factors Controlling Light Attenuation In Estuarine Waters, Makenna Leigh Thompson

Theses and Dissertations

The transparency tube is low-cost, portable, and easy to use to measure the transparency or clarity of the water. Filling the tube with water creates a small-scale water column where water will be slowly drained out of the bottom until the Secchi disk at the bottom of the tube is visible from the top opening, and the depth of the remaining water in the tube is recorded in centimeters. Unlike traditional Secchi disk measurements, the advantage of this instrument is that sampling depth in highly turbid waters is possible with a centimeter scale resolution. Transparency tube measurement, through careful calibrations, …

The Olmsted Fault, Southernmost Illinois: A Key To Understanding Seismic Hazard In The Northern New Madrid Seismic Zone, Christopher E. Bexfield

Theses and Dissertations

The northernmost extent of the New Madrid seismic zone in the central USA has been investigated using an integrated approach involving both compressional-wave (P) and horizontally polarized-wave (SH) seismic reflection and regional and dedicated borehole geophysical information in order to assess seismic hazard and risk. Our study area, centered around southernmost Illinois and western Kentucky, USA, represents an area of concentrated facilities (e.g., lock and dam sites and chemical plants on the Ohio River near its confluence with the Mississippi River) as well as an area of high potential soil amplification due to earthquake shaking. Integrated high-resolution seismic reflection profiles …

Soil Carbon Sequestration Efforts In Arid And Semi-Arid Climates Under Conservation Agriculture And Reforestation, Samantha Lynn Colunga

Theses and Dissertations

Soil organic carbon (SOC) plays a vital role in the global carbon cycle and aids in climate change mitigation. However, deforestation and intensive agricultural practices threaten topsoil and carbon (C) pools through soil disturbances releasing vast amounts of carbon dioxide (CO2) by enhancing the decomposition of organic materials. Degraded soils typically lack stable aggregates, nutrient and water retention, and overall low fertility. In arid and semi-arid regions, soils are in an even more dire situation, as low precipitation and high temperatures slow down the accumulation of SOC. This thesis has two objectives: 1) to evaluate whether conservation tillage practices increase …

Towards Machine Learning-Based Control Of Autonomous Vehicles In Solar Panel Cleaning Systems, Farima Hajiahmadi

Theses and Dissertations

This thesis presents a machine learning (ML)-based approach for the intelligent control of Autonomous Vehicles (AVs) utilized in solar panel cleaning systems, aiming to mitigate challenges arising from uncertainties, disturbances, and dynamic environments. Solar panels, predominantly situated in dedicated lands for solar energy production (e.g., agricultural solar farms), are susceptible to dust and debris accumulation, leading to diminished energy absorption. Instead of labor-intensive manual cleaning, robotic cleaners offer a viable solution. AVs equipped to transport and precisely position these cleaning robots are indispensable for efficient navigation among solar panel arrays. However, environmental obstacles (e.g., rough terrain), variations in solar panel …

Determining Hydraulic Characteristics In Close Proximity Of Hymenocallis Coronaria Within The Flint River Basin, Georgia, Sarah K. Tash

Theses and Dissertations

Emergent macrophytes in river systems occupy a narrow habitat for optimal survival. Each plant species adapts to a set of conditions that meets the physiological requirements to grow and reproduce. The influence of hydraulic characteristics on plant morphology is significant within fluvial systems. Macrophytes must be able to withstand swift flowing water and changes in water surface levels in order to compete with other plant species for limited habitat availability. In addition, emergent macrophytes require water levels to be low enough to allow the reproductive portion of plants to remain above water during certain times of the year. Hymenocallis coronaria …

Morphological And Structural Characterization Of Shortening Landforms On Mars, Leta Mccullough

Theses and Dissertations

The lithosphere of Mars accommodates shortening through folding and faulting, producing landforms qualitatively categorized as wrinkle ridges or lobate scarps. However, we lack a deep understanding of the morphological differences between these landforms. This study aimed to develop a quantitative model for shortening landform classification based on surface morphology and subsurface architecture. We developed this model by mapping 100 landforms in a GIS, recording parameters for each landform. We conducted a Discriminant Function Analysis (DFA) using these morphometrics. This DFA produced a predictive linear function for categorizing wrinkle ridges and lobate scarps. We then modeled the subsurface structural geology of …

Understanding The Role Of The Jet Streams And Gulf Stream Eddies On The Northwest Atlantic Marine Heatwaves, Lydia Rose Duncan Sims

Theses and Dissertations

The Northwest (NW) Atlantic is one of the fastest warming regions in the global ocean and in the recent decade has experienced several extreme temperature events. These extreme anomalous temperature events are known as Marine Heatwaves (MHWs), which are forced by a variety of physical processes that affect the heat source and sink of the water column. These MHWs have been increasing globally in duration and frequency due to anthropogenic warming, and have increased ecological damage seen in mass mortality events of economically viable species. Within the NW Atlantic, several key processes encourage the formation of MHWs, such as the …

Changes In Paleobiodiversity Across The K-Pg Boundary In Oktibbeha County, Mississippi, Joshua Broussard

Theses and Dissertations

Evidence of the Cretaceous-Paleogene (K-Pg) extinction can be seen across the Mississippi Embayment, however research examining the K-Pg boundary in the state of Mississippi is lacking. The objective of this study addresses how macrofauna changed across the K-Pg boundary in Oktibbeha County, Mississippi and subsequent comparison to other Early Paleogene and Late Cretaceous benthic marine macrofaunal localities. Comparison included previously collected material as well as specimens collected during this study in order to reconstruct the biological community living on the seafloor in the earliest Paleocene Mississippi Embayment. The primary fauna present after the K-Pg extinction was mainly composed of small …

Trace Metal Analysis Of Pond Sediments To Measure Deposition From A Coal-Fired Power Plant In Ackerman Mississippi, Charles Bills

Theses and Dissertations

Trace element sediment pollution due to coal power plants have been reported in many countries. In this study, pond sediment samples collected from locations around a coal fired power plant in Ackerman, MS, were evaluated for their trace element concentration and pollution status. The samples were collected at two depths to study changes in element accumulation over time. The samples were digested and the elements, As, Cd, Cr, Cu, Pb, Hg, and Zn were analyzed using ICP-MS. Results were then compared to known background concentrations as well as sediment quality guidelines and pollution thresholds. The sample locations downwind of the …

Nitrous Oxide Cycling In The Eastern Tropical North Pacific Oxygen Deficient Zone From Concentrations, Stable Isotopes And Isotopomers, Margaret Ann Gaspar

Theses and Dissertations

Nitrous oxide (N₂O) is a potent greenhouse gas and ozone depleting substance. It is estimated that the ocean accounts for about one third of total atmospheric emissions, which mostly occur in Oxygen Deficient Zones (ODZs) connected to coastal upwelling regions. Modeling efforts and high-resolution datasets are starting to provide a clearer picture of global marine N₂O fluxes, spatiotemporal variability, and the impacts of submesoscale processes on N₂O distributions. We measured nitrous oxide concentrations, stable isotope ratios and isotopomers at 7 open ocean stations along a transect crossing the Eastern Tropical North Pacific ODZ as …

Groundwater Flow And Salt Marsh Migration: The Forest/Marsh Boundary, Camille Rossiello

Theses and Dissertations

Salt marshes migrate landward in response to sea level rise, but the rate of this migration is not constant and can be influenced by pulse disturbances. Long term observations at Sapelo Island, Georgia, show that salt marsh migration has occurred during droughts, but the mechanism for this migration is unclear. Drought is thought to influence salt marsh migration by reducing fresh groundwater discharge from the upland. Rising sea level also encroaches on the upland, which could cause movement of the freshwater lens inland. A two-dimensional numerical model was built to simulate groundwater flow and solute transport based on the Marsh …

Hf Radar: Shining A Light On Ocean Currents, Douglas Cahl

Theses and Dissertations

High Frequency (HF) radar systems are commonly used to estimate surface ocean currents over the coastal ocean. Their range depends on their operational frequency and low frequency systems (≤ 10 MHz) can reach distances up to 200 km from the coastline. These systems are used to estimate surface currents by measuring the phase speed of wind-driven waves and comparing the measured speed with that expected theoretically; deviations from the theoretical still-water phase speed are attributed to ocean surface currents. Although HF radar systems are considered a mature technology and the accuracy of the radar-derived surface current estimates is well studied, …

Development And Evaluation Of An Automated Tactical Tillage Tool To Control Weeds In Row-Crop Production Systems, Grace Mccormick Friday

Theses and Dissertations

Weed control is an integral part of a successful overall production strategy in row- cropping systems and has the potential to reduce or eliminate yield losses that negatively affect profitability. Timely and correctly selected herbicide applications are the major keys for effective weed control in a majority of instances. However, there are negative factors that contribute to ineffectiveness and weed escape issues that currently lack viable options for management. Sparsely populated late-season weeds that emerge after lay-by herbicide applications and weeds that have become tolerant and resistant to traditional herbicide chemistries are of greatest concern. Historically, these weeds would have …