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Articles 31 - 60 of 339
Full-Text Articles in Earth Sciences
Struvite Effects On Greenhouse Gas Emissions From Flood- And Furrow-Irrigated Rice In The Greenhouse, Chandler Arel
Struvite Effects On Greenhouse Gas Emissions From Flood- And Furrow-Irrigated Rice In The Greenhouse, Chandler Arel
Graduate Theses and Dissertations
Over time, as the influences of climate-change and declining, mineable, global phosphorus (P) reserves begin to impact agricultural production systems, alternative fertilizer sources and management practices, such as struvite (MgNH4PO4 · 6H2O) and furrow-irrigation, will be necessary to accommodate nutrient and water demands. The precipitation and use of struvite as a fertilizer-P source could reduce environmental damages caused by nutrient-rich wastewater streams, supplement domestic P supply, and improve the sustainability of flood-, and furrow-irrigated rice production by reducing greenhouse gas emissions. The study of struvite from both chemical and electrochemical precipitation processes is well documented, …
Cover-Crop Effects On Near-Surface Soil Properties Over Time In The Lower Mississippi River Valley, Cooper Fanning
Cover-Crop Effects On Near-Surface Soil Properties Over Time In The Lower Mississippi River Valley, Cooper Fanning
Graduate Theses and Dissertations
Human population growth and climate change are present stressors that continue to put pressure on current agricultural production systems, where typical row-crop agricultural practices can negatively impact soil health. Extensive use of cover crops (CC) to increase soil health remains widely unrealized. Soil health in Arkansas is a major concern for sustaining agricultural output, therefore research into CC implementation across Arkansas to maintain or improve soil health is needed. The objective of this study was to evaluate the effects of CC (i.e., with and without CC) across various physical, hydraulic, biological, and chemical soil indicators in the Lower Mississippi River …
Controls On The Development Of Hummocky Topography On Debris-Covered Glaciers, Ryan M. Strickland
Controls On The Development Of Hummocky Topography On Debris-Covered Glaciers, Ryan M. Strickland
Graduate Theses and Dissertations
Rock debris covers many glaciers in Earth’s highest mountains and the debris impacts glacier response to changes in climate. Interactions between debris, drainage, glacier dynamics, and climate produce contrasts in melt rates that cause debris-covered glaciers to develop complex, hummocky topography. Contrasts in melt rate produce thousands of hills–hummocks–and depressions. Ponds and ice cliffs often form in the depressions. Although ponds and ice cliffs occupy only a small fraction of the surface, they account for nearly half of glacier melt. Understanding the processes that control the development of hummocky topography is key to predicting the evolution of debris-covered glaciers. In …
Temporal Trends And Dental Metric Variation In The Macaca Sylvanus Lineage, Cristina Stan
Temporal Trends And Dental Metric Variation In The Macaca Sylvanus Lineage, Cristina Stan
Graduate Theses and Dissertations
The extensive collection of fossil macaques from Europe, spanning from the Late Miocene to the Late Pleistocene period, is believed to be of the species Macaca sylvanus. However, there has been a prolonged discussion regarding the classification of these specimens into a single taxonomic group as the existing dental sample exhibits a large amount of morphological and metric variation. Specifically, researchers have attempted to identify multiple subspecies based on chronological data of the paleontological locality and, secondly, based on dental metric variation. In this study, I assess temporal trends in the fossil record of Macaca sylvanus and compare overall variation …
Geochemical Analysis Of Basement Rock As A Potential Metal Source In Mississippi Valley-Type Ores, Southern Midcontinent U.S.A., Mackenzie Moorhead
Geochemical Analysis Of Basement Rock As A Potential Metal Source In Mississippi Valley-Type Ores, Southern Midcontinent U.S.A., Mackenzie Moorhead
Graduate Theses and Dissertations
Mississippi Valley-Type (MVT) ores are epigenetic, sedimentary hydrothermal base metal deposits that exist worldwide with type localities in the midcontinent United States. These Permian-aged sulfide ores represent an extraordinary concentration of economic metals, Pb and Zn. Ore deposits occur in vast districts that have a rich mining history. The Pb and Zn from these deposits account for 24% of worldwide reserves. The geologic processes responsible for MVT ore genesis are not fully understood, especially the sourcing of ore constituents. In the midcontinent, the Ouachita Orogeny expelled saline hydrothermal brines in response to high rates of subsidence. These fluids migrated through …
Determining The Climatic Effects Of The Central Atlantic Magmatic Province Across The End Triassic Mass Extinction In The Elliot Formation, Southern Africa, Danielle Elizabeth Oberg
Determining The Climatic Effects Of The Central Atlantic Magmatic Province Across The End Triassic Mass Extinction In The Elliot Formation, Southern Africa, Danielle Elizabeth Oberg
Graduate Theses and Dissertations
Understanding the intricate relation between carbon-cycle perturbations, climate change, and biodiversity stability is crucial in the face of ongoing anthropogenic greenhouse-gas emissions. This thesis explores the impacts of rapid climate change induced by carbon-cycle perturbations and their potential repercussions on global climate. Large igneous provinces, particularly the Central Atlantic Magmatic Province, offer a lens through which to examine the nexus of volcanic activity, mass extinctions, and climate change. The emplacement of Central Atlantic Magmatic Province, covering vast regions across continents, emitted substantial amounts of carbon dioxide, profoundly impacting global climate and ecosystems. The end-Triassic Mass Extinction, attributed to Central Atlantic …
Geomorphic Analysis Of The Lower Arkansas River, Usa, Matthew Edwards
Geomorphic Analysis Of The Lower Arkansas River, Usa, Matthew Edwards
Graduate Theses and Dissertations
The Arkansas River is one of several large and important river systems stretching from the Rocky Mountains to the Mississippi River. It meanders across the Great Plains for ~1000 km before plunging into a mountain-bound valley, confined by the Ozarks to the north and Ouachitas to the south. The geologic history of the Arkansas River is poorly understood and crudely constrained to sometime between ~60 Ma and 100 Ka. Questions remain concerning its path(s), potential integration of the upper and lower sections, and overall history. The combination of knickpoint and chi (χ) mapping, tributary grain size analysis, tensile strength testing, …
Environmental And Agronomic Evaluation Of Struvite In Rice Production Systems, Diego Della Lunga
Environmental And Agronomic Evaluation Of Struvite In Rice Production Systems, Diego Della Lunga
Graduate Theses and Dissertations
Furrow-irrigation constitutes an alternative water regime that has been increasingly adopted in Arkansas. Among the management of nutrients in furrow-irrigated systems, phosphorus (P) represents a substantial challenge. The environmental sustainability of rice (Oryza sativa) production systems needs to be evaluated across different water regimes and fertilizer-P sources. Therefore, the objectives of the following studies were to: i) evaluate season-long carbon dioxide (CO2) and methane (CH4) emissions and global warming potential (GWP) under different tillage treatments [i.e., conventional tillage (CT) and no-tillage (NT)] and at different site positions (i.e., up-, mid-, down-slope) along the predominant slope of a production-scale, furrow-irrigated rice …
Tree-Ring Reconstruction Of Ouachita River Streamflow, Keaton Cade Jenkins-Joyce
Tree-Ring Reconstruction Of Ouachita River Streamflow, Keaton Cade Jenkins-Joyce
Graduate Theses and Dissertations
The Ouachita River drains the Ouachita Mountains and Upper Coastal Plain in Arkansas and Louisiana. The Ouachita River is used for navigation, power generation, recreation, water supply, and wastewater treatment. The river has been prone to low flows during drought and extreme flooding, which were principal justifications for the construction of three large multipurpose dams on the stream. It is likely that the use of the Ouachita River will be stressed by future population growth, economic expansion, and climate change. For this study, tree-ring chronologies from various locations in and near the Ouachita River drainage basin were used to reconstruct …
Shallow Groundwater Distributions And Changes With Sea Level Rise In Seattle, Washington, Taylor L. Watson
Shallow Groundwater Distributions And Changes With Sea Level Rise In Seattle, Washington, Taylor L. Watson
Graduate Theses and Dissertations
Sea level rise (SLR) associated hazards, such as coastal flooding and erosion, are pressing issues of great concern for coastal communities across the globe. Shallow and emergent groundwater can contribute to groundwater hazards such as flooding, landslides, or damage to shallow infrastructure. This study investigates the shallow groundwater within Seattle, Washington, and projects how it will respond to SLR using interpolation and numerical groundwater modeling methods. Then, a geologic modeling method is presented as a preliminary investigation of heterogeneity and anisotropy within the aquifer system. In the results for the present-day interpolation, ~6 % of the coastal buffer –the total …
Geochemistry Of Metal-Rich Black Shales And Their Genetic Relationship To Mississippi Valley-Type Pb-Zn Ore Deposits, Midcontinent U.S., Noah S. Morris
Geochemistry Of Metal-Rich Black Shales And Their Genetic Relationship To Mississippi Valley-Type Pb-Zn Ore Deposits, Midcontinent U.S., Noah S. Morris
Graduate Theses and Dissertations
The formation of Mississippi Valley-type (MVT) lead-zinc (Pb-Zn) ores is complex, involving an interaction of tectonic compression, hydrothermal fluid migration, and geochemical processes within the subsurface. Fundamental questions regarding this interaction remain unclear, including the source(s) of the Pb and Zn ions that make up the ores. A genetic link between black shales and MVT ores has been thought to exist because of (1) the presence of mature hydrocarbon and brine fluid inclusions within many MVT ores, (2) the association of the hydrothermal fluids that are linked to MVT ore formation with organic compounds and oil-like droplets, and (3) the …
Modeling The Peak Ground Acceleration And Assessing The Economic Loss And Casualty Due To Potential Earthquakes Of Various Magnitudes In The New Madrid Seismic Zone, Mahmud Afroz
Graduate Theses and Dissertations
The New Madrid Seismic Zone (NMSZ) is one of the active tectonic zones capable of producing big earthquakes in the southcentral USA. The objective of this study was to assess the economic losses and casualties that might be caused by various magnitudes of seismic events in the NMSZ. The manifestation is the estimation for each magnitude which is using the Peak Ground Acceleration (PGA) that might occur during an earthquake. It is calculated using an attenuation function that correlates the intensity of local ground movement, the earthquake magnitude, and the distance from its epicenter. The assessment of casualties was conducted …
The Spatial And Temporal Distribution Of Large Rock Blocks And Control On Landscape Evolution In The Ozarks, Chelsea Moran
The Spatial And Temporal Distribution Of Large Rock Blocks And Control On Landscape Evolution In The Ozarks, Chelsea Moran
Graduate Theses and Dissertations
Geologists often use landscape form to infer landscape processes through time. While climate and tectonics shape geomorphic form, the potential range of spatial or temporal scales that can shape any specific landscape can render landscape process-form based hypotheses too general for consideration. Contributions by mathematical modeling have helped bridge the gap between inferring processes from form, notably in how sediment transport dynamics shape hillslopes. However, few models encapsulate the movement of large rock blocks ( >2 meters across) and their potential impact as hillslope sediment transport disruptors. The Upper Buffalo River watershed (BRW) in the Ozarks of northern Arkansas has …
Geospatial Analysis Of Weathering And Recession On Architectural Limestone At The 1891 Powerhouse/Icehouse In Eureka Springs, Arkansas, Stuart Bruce Wright
Geospatial Analysis Of Weathering And Recession On Architectural Limestone At The 1891 Powerhouse/Icehouse In Eureka Springs, Arkansas, Stuart Bruce Wright
Graduate Theses and Dissertations
The objective of this study of the architectural limestone of the 1891 Powerhouse/Icehouse in Eureka Springs, Arkansas was to analyze the environmental factors that influenced the deterioration and surface recession of this historical stone structure. The focus of this research was to examine and establish a baseline study that may assist in future monitoring and documentation of this historic limestone structure on stone weathering. A replicable methodology was specifically created toward this baseline research in hopes that it represented a solid baseline study. Observations and data analyses revealed the relationship between the architectural limestone building structure and the dominating recession …
Maximum Depositional Age Analysis Using Paired La-Icp-Ms And Ca-Id-Tims Detrital Zircon U-Pb Geochronology, Benjamin L. Howard
Maximum Depositional Age Analysis Using Paired La-Icp-Ms And Ca-Id-Tims Detrital Zircon U-Pb Geochronology, Benjamin L. Howard
Graduate Theses and Dissertations
The “law of detrital zircons” states that a sedimentary unit cannot be older than its youngest detrital zircon. The youngest U-Pb date(s) from detrital zircon may thus be used to infer a given sedimentary deposit’s maximum depositional age (MDA). MDAs may be calculated in various ways using dates from zircon U-Pb geochronology. Common dating methods used for U-Pb geochronology are laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS), a low- and high-resolution instrument type, respectively. Chapter 2 will systematically compare paired LA-ICP-MS and CA-ID-TIMS dates from the same zircon grains to assess the agreement …
Verification Of Astm Centrifugation Equations For Soil Suction Determination, Esteban Maclein Miranda Pinzon
Verification Of Astm Centrifugation Equations For Soil Suction Determination, Esteban Maclein Miranda Pinzon
Graduate Theses and Dissertations
The unit correction constant (B) in the ASTM D6836 standard needs to be evaluated. The B-value was proposed to be 0.00548 instead of 0.00553. This apparent discrepancy led to an investigation comparing the predicted and measured suction values for high air entry (HAE) ceramic disks. A Beckman-Coulter Model J6-MI six-bay centrifuge and a WP4C Dewpoint Potentiameter were used in the testing program. HAE ceramic disks rated with bubbling pressures of 3-bar and 5-bar were used as analogue soil specimens. The HAE ceramic disks were spun in the small-scale centrifuge to apply prescribed suction amounts and then placed in the WP4C …
Constraining High Temperature Deformation And Metamorphism In The Southern Wet Mountains, Colorado, Usa: Implications For The Regional Extent Of The Picuris Orogeny, Sarah Morse
Graduate Theses and Dissertations
The Wet Mountains of Colorado are underlain by exhumed Proterozoic metamorphic rock that lies north of the recently identified 1.46 to 1.40 Ga Picuris orogen in northern New Mexico. The Picuris orogen is inferred to have formed in response to a Mesoproterozoic (ca. 1.49-1.40 Ga) contractional to transpressional event extrapolated to be regional in extent. It has been proposed that the Picuris orogen composes the westernmost tectonic segment of the Pinware-Baraboo-Picuris orogen that formed along an evolving convergent margin that becomes younger from northeast to southwest. This study is focused on the record of high temperature deformation, metamorphism, and plutonism …
Short-Term Response In Soil Health To Management Practices Within Large- And Small-Scale Cropping Systems In Arkansas, Torri Holder
Short-Term Response In Soil Health To Management Practices Within Large- And Small-Scale Cropping Systems In Arkansas, Torri Holder
Graduate Theses and Dissertations
Improving soil health is a growing area of interest within large- and small-scale agricultural systems in Arkansas as producers face increasing input costs, increased awareness of variability and intensity in extreme weather events, decreasing resource availability, and suboptimal productivity related to environmental degradation. Practices aimed at improving soil health such as cover cropping and the use of organic amendments are increasingly recommended and adopted; however, research on optimal management in the Mid-South is lacking. Two studies were conducted to evaluate the effectiveness of soil health management under both small- and large-scale farming operations in Arkansas. The objective of the small-scale …
Nutrient Responses To Hippuric Acid In Sheep Urine Applied To Pasture Soil Cores, Ethan Avery Collins
Nutrient Responses To Hippuric Acid In Sheep Urine Applied To Pasture Soil Cores, Ethan Avery Collins
Graduate Theses and Dissertations
Hippuric acid is a breakdown product of tannins, which bind with proteins in the animal rumen and slow down protein metabolism, thus increasing nitrogen (N) retention in the animal. Increased hippuric acid concentration in bovine and ovine urine applied to soil may decrease rates of nitrification, denitrification, and nitrous oxide fluxes in pasture soils. Additionally, condensed tannins have increased rates of carbon mineralization when incorporated in humus and leaf litter. To evaluate effects of hippuric acid concentration, treatments of urine from sheep fed a tannin-supplemented diet, synthetic urine, or urea controls were applied to intact soil cores seeded with crabgrass …
Runoff Water Quality And Crop Growth As Affected By Wastewater-Derived Struvite, Machaela Morrison
Runoff Water Quality And Crop Growth As Affected By Wastewater-Derived Struvite, Machaela Morrison
Graduate Theses and Dissertations
Mined phosphate rock, used to produce phosphorus (P) fertilizers, is a finite resource. Struvite (MgNH4PO4 • 6H2O) that has been synthetically produced from a stock solution of known P and nitrogen (N) concentrations has been shown to be an effective, alternative fertilizer-P source for various crops. However, little is known about the runoff-water-quality implications from and the crop response to soil application of struvite created from an actual municipal wastewater source. This study consisted of two objectives: i) to evaluate the effects of soil [i.e., Creldon (Oxyaquic Fragiudalf), Dapue (Fluventic Hapludoll), Roxana (Typic Udifluvent), and Calloway (Aquic Fraglossudalf) series], fertilizer-P …
Chemostratigraphic And Paleoclimatic Studies Of Cloverly Formation, Northern Wyoming, U.S.A, Queen Amarachi Kalu
Chemostratigraphic And Paleoclimatic Studies Of Cloverly Formation, Northern Wyoming, U.S.A, Queen Amarachi Kalu
Graduate Theses and Dissertations
The Early – Late Cretaceous transition in Western North America recorded a period of rapid climatic and tectonic change in Earth’s history. Major climate events associated with large igneous province eruptions caused several instances of ocean anoxic events (OAE) and perturbations to the global carbon (C) – cycle. These perturbations to the global C-cycle are observed in the bulk organic C record of both marine and terrestrial deposits and can be used to correlate units across major depositional basins. Major efforts are being made to generate time-constrained palaeontologic and paleoclimate information from the North American Cordilleran foreland basin and C-isotope …
Evaluation Of Hydrogeochemical Characteristics Of San Joaquin, Tulare, And Mojave Aquifers, Southern California, Maedeh Hassanvand
Evaluation Of Hydrogeochemical Characteristics Of San Joaquin, Tulare, And Mojave Aquifers, Southern California, Maedeh Hassanvand
Graduate Theses and Dissertations
Before making attempts to enhance and manage the quality of water, a thorough understanding of these processes is necessary since the chemical quality of groundwater is impacted by a number of linked processes. This would be more important in arid and semiarid regions like the southern part of California where more rely on groundwater for agriculture and drinking water uses than the other states. As a result, fundamental knowledge of the governing processes of groundwater chemistry is required for effective water resource management. Thus, this study is primarily concerned with three aspects in Mojave, Tulare, and San Joaquin aquifers: The …
Effects Of Land Use On Soil Microbial Communities In Tropical Montane Forests Of Malaysian Borneo, Yang Kai Tang
Effects Of Land Use On Soil Microbial Communities In Tropical Montane Forests Of Malaysian Borneo, Yang Kai Tang
Graduate Theses and Dissertations
Land use, such as logging and forest conversion to agriculture, can modify soil physicochemical and biological properties, and affect soil health. To understand how land use change can impact soil properties and canopy structure, we used a land use gradient in Malaysian Borneo consisting of six sites, including old growth forests, mixed forests, and agriculture fields. Specifically, we aimed to answer the following questions: (1) How do soil physicochemical properties vary across land use types? (2) Does bacterial diversity and composition vary across different land use types? (3) Does fungal diversity and composition vary across different land use types? We …
An Age, Size, And Climate Response Study Of Old Growth Shortleaf Pine In The Mccurtain County Wilderness Area, Oklahoma, Nicholas Cancalosi-Dean
An Age, Size, And Climate Response Study Of Old Growth Shortleaf Pine In The Mccurtain County Wilderness Area, Oklahoma, Nicholas Cancalosi-Dean
Graduate Theses and Dissertations
Increment cores were extracted from 483 trees distributed over 21 semi-randomly sampled 0.1-hectare plots on three distinct landscape positions in the McCurtain County Wilderness Area (MCWA), a 57 square kilometer tract of uncut shortleaf pine in southeastern Oklahoma. Forty additional cores were taken off plot from older-appearing trees. All sampled trees were shortleaf pine (Pinus echinata) with a diameter at breast height (DBH) of at least 10 cm. Hardwoods were not included in the size and age analyses. The study site chosen for the sampling was made up of four parallel east-west trending ridges near North Linson Creek, making up …
The Terroir Of Swiss Cheese: A Temporal And Geomorphological Investigation Of The Martian Co2 Sublimation Pits, Racine D. Cleveland
The Terroir Of Swiss Cheese: A Temporal And Geomorphological Investigation Of The Martian Co2 Sublimation Pits, Racine D. Cleveland
Graduate Theses and Dissertations
Observations by NASA Mars Global Surveyor showed evidence of rough topography on the South Pole of Mars. The topography is the result of CO2 sublimation processes that occur through the changing seasons on the red planet. These sublimation areas are known to scientists as Swiss Cheese Features (SCF). SCF are erosional degradation pits that have been studied for over two decades. Studies show that these SCF increase in area over time, but these values are collected by hand on a per feature basis. Models for the pit evolution have also played a part in understanding these SCF. This work is …
Flood Hazard And Risk Analyses In The Republic Of Panama: A Case Study From The Juan Diaz River Watershed In Panama City, Virgilio De Jesus Quintero
Flood Hazard And Risk Analyses In The Republic Of Panama: A Case Study From The Juan Diaz River Watershed In Panama City, Virgilio De Jesus Quintero
Graduate Theses and Dissertations
Flooding is the natural hazard with most occurrences in Panama. Its frequency and magnitude have increased over the years. This dissertation analyzes Panama’s flood activity in order to better understand flood hazards, the current evolution of Panamanian perceptions of flood risk, and the incorporation of indigenous knowledge used to mitigate flood hazards. The first chapter developed a baseline of past and current flood inventory in Panama, which required the use of flood historical data, thematic cartography, and Geographic Information Science (GIS). This chapter shows Panama has experienced floods in varying degrees. Through the spatial and temporal distribution of floods from …
Nitrogen Use Efficiency Of Pretassel Nitrogen Applications In Corn, Robyn Brittlee Mulloy
Nitrogen Use Efficiency Of Pretassel Nitrogen Applications In Corn, Robyn Brittlee Mulloy
Graduate Theses and Dissertations
Corn (Zea mays L.) production continues to be a critical component of row-crop production systems within Arkansas and is seeing a resurgence in recent years. Nitrogen (N) is critical for corn growth and is often one of the single largest input costs associated with corn production. Research objectives for this study were to determine the nitrogen use efficiency (NUE) of late season N applications as influenced by sidedress N rate and timing of pretassel application and to quantify the nutrient uptake and partitioning in modern era corn hybrids within a furrow-irrigated production system. Research was conducted at the Milo J. …
Nitrogen Management In Rice Under Suboptimal Soil Conditions, Payton Suzanne Rhea
Nitrogen Management In Rice Under Suboptimal Soil Conditions, Payton Suzanne Rhea
Graduate Theses and Dissertations
In Mid-South rice (Oryza sativa, L.) production, nitrogen (N) fertilizer management for pureline varieties is most often recommended as a single preflood (SPF) or two-way split (2WS) application in a direct-seeded, delayed-flood system. Most of the N fertilizer is typically applied at the four- to six-leaf stage onto dry soil, and the second application, if necessary, into the floodwater during early reproductive growth stages (referred to as midseason). Environmental factors frequently prohibit growers from applying early N fertilizer under optimal dry soil conditions. A study was conducted to determine the best N fertilization management practices to utilize in rice when …
Orbital Mapping Of Seasonal And Yearly Changes In Co2 And Water Ice On The Southern Polar Cap Of Mars, Victoria Michell Ann Karnes
Orbital Mapping Of Seasonal And Yearly Changes In Co2 And Water Ice On The Southern Polar Cap Of Mars, Victoria Michell Ann Karnes
Graduate Theses and Dissertations
This research exhibits a new foundation for the rates of change in CO2 and water ice on the southern polar cap of Mars, where the annual precipitation cycles are known to fluctuate seasonally between the north and south pole, based on observations from the Compact Reconnaissance Imaging Spectrometer (CRISM). The conventional belief is that both CO2 ice and water ice on the southern polar cap condenses and evaporates over the course of a Martian year (MY), condensing during the Martian spring and summer and evaporating during the Martian fall and winter. With this theory in mind, CO2 and water ice …
The Binding Of The Micronutrient Transition Metals To The Alkylation Products Of Chemical Warfare Agent, Sulfur Mustard, And Thiols, Potentially Giving New Understanding To Physiological Effects Of Exposure And Increased Toxicity, Colin O'Donnell
Graduate Theses and Dissertations
Model compounds, 3,6,9-trithaiundecane-1,11-dicarboxylic acid (TTDPA), 2,5,8-trithianonane-1,9-dicarboxylic acid (TTDAA), and 1,11-diamide-3,6,9-trithiaundecane (TTDAce), closely related to the adducts formed by cysteine alkylation of the chemical weapon, sulfur mustard, were synthesized. It is shown that TTDPA forms complexes with key metal micronutrients: copper, nickel, cobalt, manganese, and zinc. Though the strength of binding to TTDPA varies, the complexes in many cases precipitate from solution. All metals produced a visible precipitate upon interaction with TTDPA under the conditions tested, however only Cu2+, Mn2+, and Zn2+ produced enough to be measured. The mass of formed precipitate seemed to peak at an equimolar ratio of TTDPA …