Earth Sciences Commons^™

Rates Of Diagenesis Of Tropical Insectivorous Bat Guano Accumulations: Implications For Potential Paleoenvironmental Reconstruction, Donald A. Mcfarlane, Joyce Lundberg

International Journal of Speleology

Cave guano deposits are increasingly being recognized as valuable repositories of paleo-climatic and paleo-environmental information. However, that value is constrained by rates of guano decomposition, and these rates have not been previously well-studied. Here we show that field and laboratory studies of deep insectivorous bat guano sequences in the caves of Borneo demonstrate the extreme dependence of decomposition rate on guano water content. Under tropical conditions, moist guanos exhibit decomposition coefficients (k) values of ~ 0.01, implying the loss of most of the organic content on decadal timescales. Under similar temperatures but drier conditions, k values drop to …

Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág

International Journal of Speleology

Clumped isotope measurements of carbonates and stable isotope analyses of water trapped in fluid inclusions are both promising techniques to determine carbonate formation temperatures. Cave-hosted carbonate deposits (speleothems) are excellent targets for such studies, but kinetic fractionations and diagenetic influences frequently deteriorate the temperature data obtained from these methods. However, subaqueous carbonate deposits may provide reliable data, as kinetic fractionations are less significant in underwater environments. In this study, subaqueous speleothems, whose formation temperatures were directly measured in the water, were investigated. Additionally, temperatures calculated from the oxygen isotope fractionations between calcite and fluid inclusion-hosted water were compared with clumped …

Agriculture Against The Wall: Barriers And Opportunities For Agroecological Transitions In California’S Industrial Agricultural Landscapes, Estelí Jiménez-Soto, Madeleine Fairbairn, Joji Muramoto, Carol Shennan

School of Geosciences Faculty and Staff Publications

Agroecology emphasizes a shift from low diversity, high chemical input farming to more biodiverse agroecosystems cultivated in conjunction with natural ecosystem processes and embedded in socially just relationships. Yet achieving such agroecological transitions presents enormous challenges in industrial agricultural landscapes dominated by consolidation and overproduction. We examine both the challenges and the opportunities for agroecological transition in one particular industrial agricultural context: the fumigant-dependent strawberry production of California’s Central Coast. We do so by exploring adoption of Anaerobic Soil Disinfestation (ASD), an agroecological alternative to fumigation which has shown considerable promise but has been historically underutilized. Building on previously identified …

Evidence That Ericoid Mycorrhizal Shrubs Can Outcompete Ectomycorrhizal Trees For Nitrogen In Tannin-Rich Litter, Kai C. Rains, Caroline Bledsoe, Tamara E. Kraus, Nina Wurzburger

School of Geosciences Faculty and Staff Publications

Mycorrhizal associations of trees play a key role in ecosystem biogeochemistry, yet we know relatively little about the nutrient acquisition strategies of ericoid mycorrhizal (ErM) shrubs, despite their prevalence in forest understories. ErM shrubs tend to produce litter with high concentrations of polyphenols, which form decay-resistant complexes with organic nitrogen (N). Some ErM fungi appear capable of producing a diverse suite of extracellular enzymes, but it is unclear whether this enables ErM shrubs to acquire the N from their own litter, and whether this ability is greater than that of ectomycorrhizal (EcM) trees, with which they commonly co-occur. Here, we …

Uav-Based Wetland Monitoring: Multispectral And Lidar Fusion With Random Forest Classification, Robert Van Alphen, Kai C. Rains, Mel Rodgers, Rocco Malservisi, Timothy H. Dixon

School of Geosciences Faculty and Staff Publications

As sea levels rise and temperatures increase, vegetation communities in tropical and sub-tropical coastal areas will be stressed; some will migrate northward and inland. The transition from coastal marshes and scrub–shrubs to woody mangroves is a fundamental change to coastal community structure and species composition. However, this transition will likely be episodic, complicating monitoring efforts, as mangrove advances are countered by dieback from increasingly impactful storms. Coastal habitat monitoring has traditionally been conducted through satellite and ground-based surveys. Here we investigate the use of UAV-LiDAR (unoccupied aerial vehicle–light detection and ranging) and multispectral photogrammetry to study a Florida coastal wetland. …

Climate Monitoring In The Caumont Cave And Quarry System (Northern France) Reveal Near Oxygen Isotopic Equilibrium Conditions For Carbonate Deposition, Ingrid Bejarano-Arias, Carole Nehme, Sebastian Breitenbach, Hanno Meyer, Sevasti Modestou, Damase Mouralis

International Journal of Speleology

The study of modern cave deposits forming under near isotopic equilibrium conditions can potentially help disentangle the processes influencing the oxygen isotope system and suitability of stalagmites as archives of past hydrological or thermal changes. We used cave monitoring to evaluate the impact of kinetic isotope fractionation and assess the conditions under which modern cave carbonates form in the Caumont cave and quarry system, located in Normandy, northwest France. Over 20 months, we collected climatological data, dripwater, and modern carbonate samples at 2–4-week intervals at three different stations inside the Caumont cave and quarry system. We find highly stable (10.4 …

Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti

International Journal of Speleology

A new sub-type of folia named “reverse pseudo-gour” has been observed and described in the Nerja Cave, southern Spain. It consists of fairly vertical, thin barriers (about 5 mm high and 2 mm thick) that develop on the underside of a sub-horizontal surface (shelfstone) and grow in the opposite direction to normal gours (rimstone dams), generating sinuous shapes. Their mineral composition is essentially calcium carbonate, although globular aggregates composed of clay and phosphate minerals have also been identified. The genesis and evolution of these reverse pseudo-gours occur just at the air-water interface and are controlled by (1) the sub-horizontality of …

Determining The P-Wave Velocity Structure In The Near-Surface Of Nw Miami, Florida, Using Quarry Blasts, Elham Moslemi

USF Tampa Graduate Theses and Dissertations

The fact that Florida is an earthquake-free region has caused seismologists to pay less attention to it. Few earthquakes in this state mean it is not a usual practice to study the propagation of seismic waves. However, utilizing data from quarry blasts, we studied wave propagation in this region. The primary objective of the project is to investigate the near-surface P-wave velocity structure and factors that may affect it. We also analyzed the amplitude of signals versus distance and blast size. A network of up to 10 Raspberry Shake instruments around the NW Miami-Lakes mining area was deployed where four …

Investigating Mobility In The Northern Balkans During The Fifth Millenium Bc Through Strontium Analysis Of Human Tooth Enamel, Aurélien Tafani

USF Tampa Graduate Theses and Dissertations

This research investigates how individual mobility among ancient populations in Romania during the Eneolithic, between 5000 and 4000 BC, may be related to the spread of the material culture known as Kodjadermen-Gumelniţa-Karonovo VI (KGK VI) that extended over most of southern Romania and Bulgaria. This work seeks to combine results on individual mobility with other lines of archaeological evidence to provide a better understanding of the social context and kinship relationships that were in place when these events took place.

Strontium isotopic analyses were performed on 130 individuals from two sites located in the southern Romania: 49 from Sultana and …

Examining Paleoshorelines In The Eastern Gulf Of Mexico: Insights On Sea Level History And Potential Areas Of Interest For Habitat Management, Catalina Rubiano

USF Tampa Graduate Theses and Dissertations

An inventory of multibeam bathymetry containing relict drowned and lithified paleoshorelines has been compiled and analyzed in the first ever shelf-wide investigation of paleo sea level indicators on the west Florida shelf (WFS). On the largest scale, the WFS is a wide and gently sloping terrain that is characterized by a carbonate-rich sediment regime. This framework coupled with the region’s tectonic stability provided a setting in which sea level changes since ~ 20 ka have been recorded to a remarkable degree of resolution in the form of paleoshorelines which formed at sea level and were subsequently drowned and preserved in …

Water Chemistry Variability In Peacock Springs Cave System And Spring Basin: Impacts On Continuous Monitoring Of Karst Aquifers, Mahnoor Kamal

USF Tampa Graduate Theses and Dissertations

The Upper Floridan Aquifer (UFA) is a highly transmissive and heterogeneous karst aquifer that makes it acutely susceptible to pollution. Rapid and extensive water quality changes in nutrients at springs draining the UFA have prompted intensive monitoring at several priority springs, including continuous and discrete water quality sampling. Springs, however, are a discrete discharge point of an often-expansive phreatic cave network that can intersect different land uses and thus drain distinct geographic areas of a springshed. The extensive network contains convergent passages from deep and shallow aquifer regions and may contribute to varying water chemistry across passages resulting in water …

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …

Understanding Controls On Spring Hydrographs In An Eogenetic Karst Aquifer In North-Central Florida, Ryan Almeqhem

USF Tampa Graduate Theses and Dissertations

Florida has one of the largest karst aquifers in the United States, with a significant portion of its water resources originating from the eogenetic karst system in north central Florida. Despite the importance of this system, eogenetic karst still needs to be studied compared to telogenetic karst. The hydrological behavior of karst aquifers is complex, with numerous factors influencing the timing, magnitude, and shape of spring hydrographs. One hypothesis, by Florea and Vacher (2006), suggests that matrix permeability is the primary control of spring hydrographs in karst systems. However, this thesis challenges this hypothesis by presenting evidence that the recharge …

Mining Multibeam Transit Data For Deep Ocean Polymetallic Nodules: Case Study In Se Pacific Ocean, Mark E. Mussett

USF Tampa Graduate Theses and Dissertations

Occurrences of nodules on the seafloor represent benthic habitats and present potential deposits of economically important metals. Better understanding their extent throughout Earth’s oceans will aid in resource management and determining different factors which influence their formative factors and respective local characteristics. Multibeam bathymetry and backscatter data, along with auxiliary data suggest an area of seafloor near the Foundation Seamount chain in the southern Pacific Ocean, centered around -36.84° latitude, -119.75° longitude, contains a previously uncharted polymetallic nodule occurrence. Our analysis of Simrad EM12 DUAL (12 kHz) multibeam data, collected during a 1997 transit, shows an area of strong backscatter …

Book Review: Australian Caves And Karst Systems, John Webb, Susan White, Garry K. Smith, Jo De Waele

International Journal of Speleology

No abstract provided.

Seasonal Dynamics Of Karst Surface Dissolution Based On A Limestone Tables Experiment (Slovak Karst), Alena Gessert, Zdenko Hochmuth

International Journal of Speleology

Chemical denudation in karst is the basic process of karst relief formation. However, it is influenced by many factors of varying intensity that depend on the climatic conditions and characteristics of each given location. Based on measurable results of weight loss of limestone tablets, we monitored the intensity of chemical denudation in two areas of the Slovak Karst, Silica Plateau and Jasov Plateau that are situated in the most developed karst plateau region of Slovakia. Both experimental sites are similar in terms of geographical conditions, thus comparable between them. In each locality, we placed three sets of standardized tablets at …

Paleokarst Coastal Caves At Torricelle Hills (Lessini Mountains, Venetian Prealps, Italy), Guido Gonzato, Enrico Borghi, Roberto Chignola, Nereo Preto, Guido Rossi

International Journal of Speleology

This paper describes a set of paleokarst caves at Torricelle Hills near Verona (Southern Alps, Italy.) At this locality, erosional surfaces and paleokarst cavities show that sedimentation of late Paleogene neritic limestones was interrupted by subaerial exposure. Karst features developed during a phase of marine regression that started after the early Oligocene and ended in the mid Miocene. These caves were originally completely filled by iron oxides- and hydrated oxides-rich paleosol sediments (ochre) that, for centuries, have been mined for pigments. Mining activity emptied the caves, leaving the voids and related shapes mostly intact; as a result, the original morphologies …

An Attempt To Identify Source Areas Of Clastic Deposits From Selected Caves Of The Prokletije Mountains (Montenegro): A Mineralogical And U-Series Geochemistry Approach, Ditta Kicińska, Jacek Pawlak, Jacek Stienss

International Journal of Speleology

The Prokletije Mountains/Albanian Alps are the highest part of the Dinaric Mountains. Paradoxically, these mountains and their cave areas remain among the most enigmatic in Europe, having only recently become subjects of scientific research and cave exploration. This paper focuses on the Kolata and Greben massifs, where the highest, and thus the oldest, cave systems are located. Through the analysis of heavy mineral composition, the apatite-tourmaline index, and cluster analysis for mineralogical composition and uranium isotopic data, it becomes possible to identify the source areas for the cave clastic deposits. It also allow to distinguish multiple paleoflow directions, each corresponding …

Predictive Modeling Of Cave Entrance Locations: Relationships Between Surface And Subsurface Morphology, William Blitch, Adia R. Sovie, Benjamin W. Tobin

International Journal of Speleology

Cave entrances directly connect the surface and subsurface geomorphology in karst landscapes. Understanding the spatial distribution of these features can help identify areas on the landscape that are critical to flow in the karst groundwater system. Sinkholes and springs are major locations of inflow and outflow from the groundwater system, respectively, however not all sinkholes and springs are equally connected to the main conduit system. Predicting where on the landscape zones of high connectivity exist is a challenge because cave entrances are difficult to detect and imperfectly documented. Wildlife research has a similar issue of understanding the complexities of where …

Flow Generation And Propagation From Headwater Wetlands To Downstream Waters, Leanne Marie Stepchinski

USF Tampa Graduate Theses and Dissertations

Headwater wetlands are connected to one another and to downstream waters by dynamic hydrologic flowpaths, functioning as integrated hydrologic networks at the watershed scale. Headwater wetlands perform a variety of hydrologic lag, sink, and source functions, including flow generation and propagation, thereby contributing to the natural flow regimes of downgradient waters. The functions of individual wetlands and their contributions to hydrologic connectivity and subsequently to the natural flow regime have been widely studied and are well understood. Comparatively, the functions and hydrologic connectivity within wetland complexes as a whole and their collective subsequent contributions to the natural flow regime of …

Detection Of Subsidence In West-Central Florida Using Persistent Scatterer Interferometry And Near-Surface Geophysics, Tonian R. Robinson

USF Tampa Graduate Theses and Dissertations

This dissertation consists of three studies that employ Persistent Scatterer Interferometry (PSI, also known as PSInSAR) to better understand how subsidence in west-central Florida relates to underlying geological processes. In the first study, near-surface geophysical methods (Ground Penetrating Radar (GPR) and Electrical Resistivity (ERT)), terrestrial remote sensing applications (Light Detection and Ranging (LiDAR) and Structure from Motion (SfM)), and PSI were used to monitor the spatial and temporal behaviors of a suspected growing sinkhole in the Sandhill Boyscout Reservation, Hernando County, Florida. The survey area was located within and around a topographic low assumed to be the surface of the …

Ice-Core Reveals Flavors Of Hydroclimate Extremes In The American Southwest, Laura Calabrò

USF Tampa Graduate Theses and Dissertations

A small number of caves and lava tubes worldwide host perennial ice deposits, which occur at elevations well below those of mountain glaciers and in areas outside the permafrost climatic belt, where no surface glaciation exists. These settings make any of the ice deposits in caves or lava tubes particularly susceptible to the current warming trend, leading to the imminent loss of some untapped cryospheric paleoenvironmental archives.

The present work is the result of a paleoclimate study based on ice deposits accumulated within lava tubes in El Malpais National Monument (ELMA, western New Mexico). The ice cores span from 7,000 …

Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett

USF Tampa Graduate Theses and Dissertations

A method for gas chromatography tandem mass spectrometry (GC-MS/MS) in selected reaction monitoring (SRM) mode has been optimized to quantify 250 compounds of a variety of compound classes such as polycyclic aromatic hydrocarbons (PAHs), oxidized PAHs, organochlorinated pesticides, polychlorinated biphenyls, biomarkers (hopanes, steranes, tri-aromatic steroids, and fecal sterols), aliphatic hydrocarbons, and plastic additives. This method was validated based on available QA/QC standards using several environmental samples, both sediment and biota, and standard reference materials. This contaminant-focused method can be used as a forensic geochemistry tool to evaluate oil contamination and other contaminant histories in future research studies. When applied to …

Applications Of Seismic And Geodetic Data To Earthquake Hazard Research, Mahsa Afra

USF Tampa Graduate Theses and Dissertations

Being a part of a seismically active zone, including large and crowded cities such asTehran, Qazvin and Semnan, Central Alborz experiences many local earthquakes. Knowl- edge of crustal velocity structure in this area is thus necessary considering its economical and political importance, a large concentration of population, and relatively poor construc- tion practice which increases the earthquake risks in this region. In second chapter of this thesis, we aim at obtaining the 3D crustal velocity structure of the Central Alborz region in northern Iran using local earthquake tomography. We also validate anomalies inferred from our velocity model using an independent …

Preliminary Data Of Potentially Hazardous Radon Concentrations In Modrič Cave (Croatia), Robert Lončarić, Vanja Radolić, Maša Surić, Igor Miklavčić, Matea Šatalić, Dalibor Paar, Lukrecija Obšivač

International Journal of Speleology

Instigated by relatively high cave-air CO₂ concentrations in Modrič Cave (Croatia) recorded for the purpose of speleothem-based paleoclimate research, we established preliminary monitoring of radon (²²²Rn) concentrations within the cave for a 4.5-year period (2018–2022). As radioactive geogenic gas, radon, which often correlates with cave-air CO₂ concentrations, presents a potential health hazard in cases of longer exposure time in high concentration conditions. Since the Modrič Cave is open to tourists and long-term scientific research has been performed within, a safety assessment for radon concentrations was essential. The integrated measurements of radon concentrations were performed by passive …

Geoarchaeology Of Estuarine Seascapes In Tampa Bay, Florida., Kendal R. Jackson

USF Tampa Graduate Theses and Dissertations

This dissertation investigates the geological, ecological, and archaeological histories of Tampa Bay, Florida’s largest open-water estuary system. Previous geoscientific and archaeological work has studied the evolution of Florida’s estuaries as ‘pre-anthropogenic’ ecosystems and conceptualized Indigenous maritime societies as mostly passive inhabitants of dynamic ‘natural’ environments. Further, the environmental legacies of more recent, industrial-scale estuary modification attending Florida’s 20th-century population boom have been understudied—leading to popular and scientific confusion about historical conditions. The work composing this dissertation research seeks to reconceptualize Tampa Bay as a complex mosaic of cultural seascapes that have been variously altered and modified by human societies across …

4d Flow Pattern Of The Longest Cave In The Eastern Alps (Schönberg-Höhlensystem, Totes Gebirge), Lukas Plan, Eva Kaminsky, Pauline Oberender, Clemens Tenreiter, Maximilian Wimmer

International Journal of Speleology

The Schönberg-Höhlensystem (SBH) is not only the longest cave system in the Eastern Alps (length 156 km, depth 1061 m), but a significant proportion of the passages have developed on or just below two surfaces that dip 1.7° to the NE. These so-called "speleogenetic phases" are rarely developed in caves of the Northern Calcareous Alps and have not yet been confirmed by detailed morphological mapping. Furthermore, the deep parts of the cave offer the possibility to study the active epiphreatic zone for a distance of 1.6 km. Detailed morphological mapping shows that the main level at about 1500 m a.s.l. …

A Seismic Investigation Of Uturuncu Volcano And The Lazufre Volcanic Complex, Heather L. Mcfarlin

USF Tampa Graduate Theses and Dissertations

The following dissertation is a study of three seismological techniques used to determine the geophysical properties of two large, inflating magma bodies in the upper crust in South America: one under Uturuncu volcano and one beneath Lastarria and Cordon del Azufre volcanoes. First, I use the method of teleseismic receiver functions to image the top and bottom of the magma body beneath Uturuncu volcano. Depths to the top of this body vary between 6 and 12 km below sea level, while depths to the bottom vary between 13 and 22 km below sea level, with the thickness ranging from 6 …

Lithium And Lithium Isotope Behavior During High Temperature Solid/Fluid Exchanges: Examples From Iceland And The Izu-Bonin Forearc, Alex Maruszczak

USF Tampa Graduate Theses and Dissertations

The development of a method for lithium isotopic measurement was developed using a quadrupole, single-collector ICP-MS. Measured precision was ±1.00‰ 2σ over a 15-month period based on measurements of international rock standards. A 1-hour leach using cold, HCl was sufficient to remove alteration-related Li in minimally to moderately altered seafloor basalts. Measurements on the Holocene ages lavas from the neovolcanic zones of Iceland suggest no systematic Li isotopic variability among the differing Icelandic sources. Felsic samples from Hekla and Pumice contain elevated Li contents of >18ug/g while the tholeiitic and alkaline basalts are <8ug/g Li. Most of the island lies around MORB values of ~+3 to +5‰ with the exception of Western Volcanic Zone samples that show evidence for seawater inputs. The RN-17 drillcore, which penetrates >3000m through a hydrothermal system in the …

Land Use/Land Cover Uncertainty Analysis Using Hydrological Modeling In The Northern Watershed Of Lake Okeechobee, Andres Lora Santos

USF Tampa Graduate Theses and Dissertations

Over the past 150 years, Florida has undergone a major land-form transformation, transitioning from a natural to a primarily built environment. The state's population has grown exponentially, from less than 50,000 residents in the 1850s to approximately 22 million residents today. This population growth has led to significant changes in land use, including urbanization, mining, and agriculture. This trend is expected to continue, with projections indicating an increase in urbanization across the state. 2070 land use/land cover projections were used as input for the Watershed Assessment Model (WAM) to analyze the potential impact of these changes on flow, total nitrogen …