Earth Sciences Commons^™

Modeling Potential Chemical Environments: Implications For Astrobiology, Brian Craig Szenay

USF Tampa Graduate Theses and Dissertations

Modeling chemical environments is an important step to understanding the diversity of prebiotic systems that may have formed on the early earth or potentially can occur on other worlds. By using the modern Earth as a test case, these models predict scenarios with systems more conducive to the formation of the organic molecules that are important to life. Here we use the equilibrium thermodynamic modeling program HSC Chem to investigate prebiotic environments. This program uses the raw material that the user inputs into the system in order to calculate the change in amounts of chemical species forming as a function …

Morphological Changes Associated With Tropical Storm Debby In The Vicinity Of Two Tidal Inlets, John's Pass And Blind Pass, West-Central Florida, Andrew Brownell

USF Tampa Graduate Theses and Dissertations

Tropical Storm Debby affected the Gulf coast of Florida in late June, 2012. The storm's southerly approach temporarily reversed the annual net southward longshore sediment transport. The energetic conditions associated with Tropical Storm Debby can be seen in the wind, wave and tidal measurements taken from both onshore and offshore weather stations around the dual tidal inlets system of John's Pass and Blind Pass, approximately 25 kilometers north of the mouth of Tampa Bay. The energetic and persistent southerly forcing, in addition to higher storm induced water levels and wave heights, resulted in atypical beach erosion and sediment deposition on …

Distinguishing Processes That Induce Temporal Beach Profile Changes Using Principal Component Analysis: A Case Study At Long Key, West-Central Florida, Denise Marie Davis

USF Tampa Graduate Theses and Dissertations

The heavily developed Long Key is located in Pinellas County in west-central Florida. The structured Blind Pass at the north end of the barrier island interrupts the southward longshore sediment transport, resulting in severe and chronic beach erosion along the northern portion of the island. Frequent beach nourishments were conducted to mitigate the erosion. In this study, the performance of the most recent beach nourishment in 2010 is quantified through time-series beach profile surveys. Over the 34-month period, the nourished northern portion of the island, Upham Beach, lost up to 330 m3/m of sand, with a landward shoreline retreat of …

Hypogene Speleogenesis In The Cerna River Basin, Sw Romania: A Sedimentological, Mineralogical, And Stable Isotopic Approach, Cristina Montana Puscas

USF Tampa Graduate Theses and Dissertations

Ever since it was identified as a speleogenetic process in the Guadalupe Mountains of New Mexico, USA, hypogene speleogenesis has become the focus of numerous research projects aimed at discerning between classical epigene caves and sulfuric acid or thermal caves. The first distinguishing characteristics that were recognized for hypogene caves were passage and cave morphology. The following step was the identification of rare minerals, specific for processes associated to hypogene speleogenesis. One other important step was the recognition of the importance of stable isotopes - mainly of S - in tracing the source of S and the chemical processes affecting …

Unusual Patterns Of Seismicity During Eruptive And Non-Eruptive Periods At The Persistently Restless Telica Volcano, Nicaragua, Melanie Rodgers

USF Tampa Graduate Theses and Dissertations

Telica Volcano, Nicaragua, is a persistently restless volcano with high rates of seismicity that can vary from less than ten events to over a thousand events per day. Low-frequency (LF) events dominate the seismic catalogue and seismicity rates at Telica show little clear correlation with periods of eruption. As such, traditional methods of forecasting of volcanic activity based on increases in seismicity and recognition of LF activity are not applicable. A single seismic station has been operating at Telica since 1993, and in 2010 we installed a broadband seismic and continuous GPS network (TESAND network) at Telica. In this study …

Stable Isotopes And Trace Elements In Tooth Enamel Bioapatite: Effects Of Diagenesis And Pretreatment On Primary Paleoecological Information, Jessica Norman Wilson

USF Tampa Graduate Theses and Dissertations

The geochemical analysis of bioapatite in vertebrate skeletal tissues is an important tool used to obtain ecological information from fossil animals. An important consideration when conducting stable isotope and trace element analyses is obtaining biogenic information that has been unaffected by diagenetic processes.

A two-step pretreatment procedure is commonly used remove diagenetically altered material by removing organic material, via an oxidation reaction with H2O2 or NaOCl, and secondary carbonate, via dissolution in dilute acetic acid, from bioapatite. While much work has been done to determine the efficacy of the pretreatment process, little research has been conducted to determine the potential …

Appropriate Terminology For Karst-Like Phenomena: The Problem With ‘Pseudokarst’, Rolan S. Eberhard, Chris Sharples

International Journal of Speleology

The practice of referring to certain morphologically karst-like phenomena as ‘pseudokarst’ is problematic, because it ignores basic principles of sound classification, logical naming conventions and accepted geomorphic classifications and terminology. These problems have compounded the difficulty in establishing an accepted classification of ‘pseudokarst’ types. The practice embodies a karst-centric perspective which should be avoided in favour of using conventional geomorphic terminology for non-karstic features. We illustrate this by providing existing conventional terms for many ‘pseudokarst’ types reported in the literature.

Book Review: Speleothem Science: From Process To Past Environments, Giovanni Zanchetta

International Journal of Speleology

Ian J. Fairchild and Andy Baker.
Speleothem Science: From Process to Past Environments
Wiley Blackwell, 2012. Hardcover, 450 p.,
ISBN-10: 1405196203, ISBN-13: 978-1405196208, €57

Optimized Correlation Of Geophysical And Geotechnical Methods In Sinkhole Investigations: Emphasizing On Spatial Variations In West-Central Florida, Henok Gidey Kiflu

USF Tampa Graduate Theses and Dissertations

Abstract

Sinkholes and sinkhole-related features in West-Central Florida (WCF) are commonly identified using geotechnical investigations such as standard penetration test (SPT) borings and geophysical methods such as ground penetrating radar (GPR) and electrical resistivity tomography (ERT). Geophysical investigation results can be used to locate drilling and field testing sites while geotechnical investigation can be used to ground truth geophysical results. Both methods can yield complementary information. Geotechnical investigations give important information about the type of soil, groundwater level and presence of low-density soils or voids at the test location, while geophysical investigations like GPR surveys have better spatial coverage and …

Impacts Of The Anomalous Mississippi River Discharge And Diversions On Phytoplankton Blooming In Northeastern Gulf Of Mexico, Brendan O'Connor

USF Tampa Graduate Theses and Dissertations

On April 20, 2010 a tragic explosion aboard the Deepwater Horizon (DWH) drilling rig marked the beginning of one of the worst environmental disasters in history. For 87 days oil and gas were released into the Gulf of Mexico. In August 2010, anomalous phytoplankton activity was identified in the Northeastern Gulf of Mexico, using the Fluorescence Line Height (FLH) ocean color product. The FLH anomaly was bound by approximately 30-28 degrees North and 90 and 86 degrees West and there was a suggestion that this anomaly may have occurred due to the presence of oil. This study was designed to …

Deciphering Deposits: Using Ground Penetrating Radar And Numerical Modeling To Characterize The Emplacement Mechanisms And Associated Energetics Of Scoria Cone Eruption And Construction, Leah Michelle Courtland

USF Tampa Graduate Theses and Dissertations

Our understanding of tephra depositional processes is significantly improved by high-resolution ground-penetrating radar (GPR) data collected at Cerro Negro volcano, Nicaragua. The data reveal three depositional regimes: (1) a near-vent region on the cone itself, where 10 GPR radargrams collected on the western flank show quantifiable differences between facies formed from low energy normal Strombolian and higher energy violent Strombolian processes, indicating imaging of scoria cone deposits may be useful in distinguishing eruptive style in older cones where the proximal to distal tephra blanket has eroded away; (2) a proximal zone in which horizons identified in crosswind profiles collected at …

Ecology Of The Late Neogene Extinctions: Perspectives From The Plio-Pleistocene Of Florida, Shubhabrata Paul

USF Tampa Graduate Theses and Dissertations

The ecological impact of past extinction events is one of the central issues in paleobiology. In face of present environmental changes, a better understanding of past extinctions will enable us to identify the magnitude of biodiversity crises and their underlying processes. The Late Neogene was a time of extraordinary climatic reorganization, including Northern Hemisphere glaciation, the rise of the Central American Isthmus, and associated changes in environmental conditions. Therefore, the Late Neogene extinctions of marine molluscs of South Florida present an ideal platform to examine the interaction between environmental changes and biotic response. In the present study, three different aspects …

The Extent Of Phosporus Redox Chemistry In West Central Florida Waters, Jacqueline Marie Sampson

USF Tampa Graduate Theses and Dissertations

Phosphorus (P) has long been acknowledged as a vital nutrient for living organisms and is a key factor responsible for the fresh water eutrophication. Our understanding of the phosphorus cycle has been limited by: (1) the common assumption that all P in the environment occurs primarily as phosphates and (2) by the limited analytical methods available to identify P speciation. In an attempt to understand the distribution and chemistry of phosphorus within a freshwater system we must be able to identify individual P species. To this end, we used a coupled High Performance Liquid Chromatograph (HPLC) - Inductively Coupled Plasma …

World Karst Reviews

International Journal of Speleology

No abstract provided.

Cave Ventilation Is Influenced By Variations In The Co2-Dependent Virtual Temperature, Enrique P. Sánchez-Cañete, Penélope Serrano-Ortiz, Francisco Domingo, Andrew S. Kowalski

International Journal of Speleology

Dynamics and drivers of ventilation in caves are of growing interest for different fields of science. Accumulated CO₂ in caves can be exchanged with the atmosphere, modifying the internal CO₂ content, affecting stalagmite growth rates, deteriorating rupestrian paintings or creating new minerals. Current estimates of cave ventilation neglect the role of high CO₂ concentrations in determining air density – approximated via the virtual temperature (T_v) –, affecting buoyancy and therefore the release or storage of CO₂. Here we try to improve knowledge and understanding of cave ventilation through the use of T …

Natural And Anthropogenic Factors Which Influence Aerosol Distribution In Ingleborough Show Cave, Uk, Andrew C. Smith B.S.C, Peter M. Wynn, Philip A. Barker Professor

International Journal of Speleology

Monitoring in Ingleborough Show Cave (N. Yorkshire, UK) reveals the influence of tourism and cave management techniques on different parameters of the cave atmosphere. Exploratory aerosol monitoring identified a 0.015 ± 0.03 mg/m³ (≈70%) reduction in airborne particulates within the first 75 meters of cave passage and two major aerosol sources within this artificially ventilated show cave. Autogenic aerosol production was identified close to active stream ways (increases of

Table Of Contents

International Journal of Speleology

No abstract provided.

Book Review: Trevor Shaw And Alenka Čuk Slovene Caves & Karst, Pictured 1545-1914, Arrigo A. Cigna

International Journal of Speleology

Trevor Shaw and Alenka Čuk.
Slovene Caves & Karst, pictured 1545-1914
Založba ZRC, Ljubljana, 2012.
ISBN 978-961-254-369-3, 230 p. 200x290, 258 b/w and colour illustrations, paper cover, € 25.00

Full Issue 42(2)

International Journal of Speleology

All articles in Volume 42 Issue 2. Does not include cover image.

Full Issue 42(1)

International Journal of Speleology

All articles in Volume 42 Issue 1. Does not include cover image.

Mixing Of Water In A Carbonate Aquifer, Southern Italy, Analysed Through Stable Isotope Investigations, Emma Petrella, Fulvio Celico

International Journal of Speleology

Mixing of water was analysed in a carbonate aquifer, southern Italy, through stable isotope investigations (¹⁸O,δ²H). The input signal (rainwater) was compared with the isotopic content of a 35-meter groundwater vertical profile, over a 1-year period. Within the studied aquifer, recharge and flow are diffuse in a well-connected fissure network.

At the test site, the comparison between input and groundwater isotopic signals illustrates that no efficient mixing takes place in the whole unsaturated zone, between the fresh infiltration water and the stored water.

When analysing the stable isotopes composition of groundwater, significant variations were observed above …

Front Cover

International Journal of Speleology

No abstract provided.

The Use Of Passive Seismological Imaging In Speleogenetic Studies; An Example From Kanaan Cave, Lebanon, Carole Nehme, Christophe Voisin, Armand Mariscal, Pierre-Charles Gérard, Cécile Cornou, Badr Jabbour-Gédéon, Samer Amhaz, Nancy Salloum, Nada Badaro-Saliba, Jocelyne Adjizian-Gérard, Jean-Jacques Delannoy

International Journal of Speleology

Among many parameters that control the evolution of caves stands the volume of unconsolidated clay sediments generally produced by the alteration of the calcareous rocks. Here we introduce the use of a passive seismological imaging technique to investigate the clay deposits and estimate its total volume in a cave. Applied for the first time for speleogenesis studies, the HVSR (Horizontal / Vertical Spectral Ration) is a geophysical technique that can help better interpret cave geomorphology. We apply seismological spectral techniques (H/V ratio) on ambient noise vibrations to derive the clay volume, as well as its shape. This technique applied on …

Variances In Airflows During Different Ventilation Modes In A Dynamic U-Shaped Cave, Jiří Faimon, Marek Lang

International Journal of Speleology

Airflow dynamics were studied in Císařská Cave (Moravian Karst, Czech Republic) under different seasonal conditions. The dependence of airflows on the difference between external and cave temperatures is nonlinear and roughly obeys the Darcy-Weisbach equation. The upward airflows were found to be systematically higher than the downward airflows under comparable driving forces. The principle reason is nonlinearity between air temperature and air density. U-shaped cave geometry magnifies this effect by feedback between external temperature and airflow driving forces. Whereas this feedback is positive during the upward airflow ventilation mode, it is negative during the downward airflow mode. To discuss the …

A Model For The Formation Of Layered Soda-Straw Stalactites, Bence Paul, Russell Drysdale, Helen Green, Jon Woodhead, John Hellstrom, Rolan Eberhard

International Journal of Speleology

Climate records based upon instrumental data such as rainfall measurements are usually only available for approximately the last 150 years at most. To fully investigate decadal-scale climate variation, however, these records must be extended by the use of climate proxies. Soda-straw stalactites (straws) are a previously under-utilised potential source of such data. In this contribution we investigate the structure and formation of straws and look at some issues that may affect the reliability of straw-based palaeoclimate records. We use laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) trace element analysis to document surface contamination features that have the potential to obscure annual …

Book Review: Water In Karst: Management, Vulnerability, And Restoration, Arthur N. Palmer

International Journal of Speleology

Neven Kresic.
Water in Karst: Management, Vulnerability, and Restoration
New York, McGraw-Hill, 2013. ISBN 978-0-07-175333.3, 19×24 cm, 736 p. + 14 p. of color plates, hardbound,
US $125 (also available as e-book)

Front Cover

International Journal of Speleology

No abstract provided.

Table Of Contents

International Journal of Speleology

No abstract provided.

World Karst Reviews

International Journal of Speleology

No abstract provided.

Editorial, Jo De Waele

International Journal of Speleology

No abstract provided.