Earth Sciences Commons^™

Carbon And Nitrogen Stable Isotopes In Organic Matter From Lake Chalco, Mexico: A Record Of Quaternary Hydrology And Climate Change, Kristin Slezak Pearthree

Earth and Planetary Sciences ETDs

Sediment cores from Lake Chalco, central Mexico, were analyzed to reconstruct paleoclimate in the neotropics. This study employs total organic carbon, organic carbon-organic nitrogen ratios, carbon and nitrogen stable isotope ratios of organic matter (OM), and lithology to reconstruct changes in lake level and productivity. During Marine Isotope Stage 3 (~42-29 ka) bulk OM d¹³C and d¹⁵N results suggest the lake experienced strong evaporation and high pH due to warm temperatures and moderate precipitation. Large amounts of terrestrial C3 plant matter were deposited during the Last Glacial Maximum (~22-19 ka), suggesting a swampy environment resulting from …

Architecture And Evolution Of The Peace Vallis Distributive Fluvial System, Gale Crater, Mars, Zachary E. Gallegos

Earth and Planetary Sciences ETDs

The Peace Vallis alluvial fan, located within Gale crater on the planet Mars, is a distributive fluvial system indicating a wet climate in Mars’ past. The Mars Science Laboratory rover instrument ChemCam, with the high-resolution Remote Micro-imager, was utilized to remotely explore the Peace Vallis alluvial fan and surrounding areas area. The Peace Vallis imaging campaigns 1 and 2, led by Dr. Horton Newsom and Zachary Gallegos respectively, acquired 20 distinct rover observations with a total of 243 individual images to investigate the fan. Using visual interpretation of the images and GIS techniques, this study interprets the processes and products …

Constraining The Oxygen Values Of The Late Cretaceous Western Interior Seaway Using Marine Bivalves, Camille H. Dwyer

Earth and Planetary Sciences ETDs

The Western Interior Seaway (WIS) remains an oceanographic enigma, including its circulation, similarity to the open ocean, and the fidelity of geochemical proxies to reconstruct paleoenvironments. Across the late Campanian and early Maastrichtian I test whether: 1) the WIS had unique δ¹⁸O_VPDB compared to other marine settings, 2) increasing oceanographic restriction changed the stable isotope composition, and 3) biases, e.g., taxonomy or diagenesis, influenced stable isotope compositions. Results indicate distinct δ¹⁸O_VPDB in the WIS compared to other marine settings. δ¹⁸O_VPDB values were stable through time, suggesting insignificant oceanographic restriction and a …

Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla

Earth and Planetary Sciences ETDs

The Jemez River, a tributary of the Rio Grande in north-central New Mexico, receives thermal water input from the geofluids of the Valles Caldera, an active, high-temperature, liquid-dominated geothermal system. We focus on a ∼50-km portion of the northern Jemez River. This research extends previous decadal work (Crossey et al., in prep., 2013) on major chemistry in the river by characterizing the response of 16 trace elements to geochemical contributions from geothermal waters (McCauley, Spence, Soda Dam, and Jemez Springs springs and San Ysidro mineral waters), an area with copious hydrothermal degassing (Hummingbird), and two major tributaries (Rio San Antonio …

An Estimation Of Lower Tropospheric Mixing Derived From Inverse Modeling Of Boundary Layer Water Vapor Isotopologues On Graciosa Island, Azores, Jacquelyn M. Delp

Earth and Planetary Sciences ETDs

Recent studies have shown water vapor isotopologues to be sensitive tracers of mixing processes that govern low-cloud feedback in climate models. In this study, we develop an inverse model (MBL Mix inverse model) that uses one year of isotope and humidity observations from Graciosa Island, Azores to estimate mixing for four seasons. We show the dry end-member of the model, the lower free troposphere (LFT), can be represented using Rayleigh fractionation. Isotope observations from Graciosa Island are compared to other field locations to discuss controls on isotopic variability other than mixing. Output from the MBL Mix inverse model shows the …

Evaluating Future Reservoir Storage In The Rio Grande Using Normalized Climate Projections And A Water Balance Model, Nolan T. Townsend

Earth and Planetary Sciences ETDs

We develop and implement new tools for assessing the future of surface water supplies in downstream reaches of the Rio Grande, for which Elephant Butte Reservoir is the major storage reservoir. First, a normalization procedure is developed to adjust natural Rio Grande streamflows simulated by dynamical models in downstream reaches. The normalization accounts for upstream anthropogenic impairments to flow that are not considered in the model, thereby yielding downstream flows closer to observed values and more appropriate for use in assessments of future flows in downstream reaches. The normalization is applied to assess the potential effects of climate change on …

Early Mississippian Ocean Anoxia Triggering Organic Carbon Burial And Enhancing Late Paleozoic Ice Age Onset: Evidence From Uranium Isotopes Of Marine Limestones, Keyi Cheng

Earth and Planetary Sciences ETDs

The Early Mississippian (Tournaisian) positive δ¹³C excursion (or TICE) is one of the largest recorded in the Phanerozoic and the organic carbon (OC) burial associated with its development is hypothesized to have driven global cooling and increased glaciation. We are testing the hypothesis that expanded ocean euxinia/anoxia drove widespread OC burial and the TICE and we are testing this hypothesis using uranium isotopes (δ²³⁸U) of Lower Mississippian marine limestones from southern Nevada as a global seawater redox proxy.

δ²³⁸U trends record a prominent mid-Tournaisian negative excursion (~0.30‰ magnitude) lasting ~1 My. The lack of …

An Estimation Of Lower Tropospheric Mixing Derived From Inverse Modeling Of Boundary Layer Water Vapor Isotopologues On Graciosa Island, Azores, Jacquelyn M. Delp

Earth and Planetary Sciences ETDs

Recent studies have shown water vapor isotopologues to be sensitive tracers of mixing processes that govern low-cloud feedback in climate models. In this study, we develop an inverse model (MBL Mix inverse model) that uses one year of isotope and humidity observations from Graciosa Island, Azores to estimate mixing for four seasons. We show the dry end-member of the model, the lower free troposphere (LFT), can be represented using Rayleigh fractionation. Isotope observations from Graciosa Island are compared to other field locations to discuss controls on isotopic variability other than mixing. Output from the MBL Mix inverse model shows the …

Observed And Projected Snowmelt Runoff In The Upper Rio Grande In A Changing Climate, Nels R. Bjarke

Earth and Planetary Sciences ETDs

As climate has warmed over the past half century, the strength of the covariance between interannual snowpack and streamflow anomalies in the Rio Grande headwaters has decreased. This change has caused an amplification of errors in seasonal streamflow forecasts using traditional statistical forecasting methods, based on the diminishing correlation between peak snow water equivalent (SWE) and subsequent snowmelt runoff. Therefore, at a time when water resources in south-western North America are becoming scarcer, water supply forecasters need to develop prediction schemes that account for the dynamic nature of the relationship between precipitation, temperature, snowpack and streamflow. We quantify temporal changes …

Fluid Transport In Porous Media For Engineering Applications, Eric M. Benner

Chemical and Biological Engineering ETDs

This doctoral dissertation presents three topics in modeling fluid transport through porous media used in engineering applications. The results provide insights into the design of fuel cell components, catalyst and drug delivery particles, and aluminum- based materials. Analytical and computational methods are utilized for the modeling of the systems of interest. Theoretical analysis of capillary-driven transport in porous media show that both geometric and evaporation effects significantly change the time dependent behavior of liquid imbibition and give a steady state flux into the medium. The evaporation–capillary number is significant in determining the time-dependent behavior of capillary flows in porous media. …

Irrigation Forbearance In The Middle Rio Grande: Using Remote Sensing To Improve Investments, Trevor Birt

Water Resources Professional Project Reports

In extremely dry years when there is a high premium on surface water, irrigation forbearance agreements help water managers maintain riparian health, fish populations, and ensure water delivery to downstream users. In order for these programs to maximize their effectiveness and limit their impact on agricultural communities, water managers should seek the highest return on investment - or the highest amount of water per acre entered into forbearance. This may be accomplished by assessing the water requirements of fields and then grouping by conveyance lateral, to target the highest among them as good forbearance participants. Unfortunately, irrigation measurement in the …

Melt Inclusions And Their Application - New Perspective On The Subsurface Architecture Of Cerro Negro Volcano, Nicaragua, John M. Hamilton

Earth and Planetary Sciences ETDs

Volatiles are the drivers of volcanic eruptions and monitoring and measurement in quiescent times are the key in determining when unrest within a volcanic system is beginning leading to possible cataclysms. Previous studies have focused on direct measurements from volcanic plumes or fumaroles, however, this study proposes the use of melt inclusions from tephra to determine volatile contents from the 1992 eruption of Cerro Negro Volcano, Nicaragua. The analysis of melt inclusions adds a new technique to the volatile analytical toolbox and can help to determine volatile contents from past eruptions and their subsequent evolution within a volcanic system.

Though …

Northeastern China 4.2ka Database, Louis A. Scuderi, Xiaoping Yamg, Samantha Ascoli, Hongwei Li

Paleoclimate Datasets

The Hunshandake Sandy Lands of northeastern China, currently a semiarid lightly vegetated region, were characterized by perennial lakes and forest stands in the early and middle Holocene. Well-developed dark grassland-type paleosols (mollisols) at the southern edge of the Hunshandake OSL-dated to between 6.93 +0.61 and 4.27 +0.38 ka along with lacustrine sands at higher elevations that date to between 5.7 +0.3 and 5.2 +0.2 ka and thick gray lacustrine sediments suggest a wetter climate. Between 4.2 and 3.8 ka, the region experienced extreme drying that was exacerbated by lake overflow drainage and sapping that depleted the groundwater table. The region …

How To Celebrate 24 New Year's Eves In A Single Year!, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

New Year's Eve 2018 reaches me on Jeju Island, South Korea, in the East China Sea. While I had spent New Year's Eve 2017 in Galapagos Islands, in the Pacific. We can celebrate 24 New Year's Eves in a single year, moving to the West – for example in an orbital spacecraft - (in the reverse sense of Earth's rotation around its axis) at a faster angular speed than Earth's rotation, jumping from one time-zone to another, and starting from the International Date Line. { In this paper we are referring to the solar day, hence to the angular speed …

Mineralogy, Petrology, And Geochemistry Of The Unique Silica-Rich Ungrouped Achondrite Northwest Africa 11575, Mya Ann Habermann

Earth and Planetary Sciences ETDs

We report here on a unique, newly discovered, silica-rich ungrouped achondrite Northwest Africa 11575 (NWA 11575). NWA 11575 is one of four known silica-rich ungrouped achondrites, presenting evidence for igneous processes resulting in evolved compositions early in the history of the solar system. It is unique from the other silica-rich ungrouped achondrites in that it has pyroxene compositional trends matching those of lunar samples and martian meteorites; contains quartz and potassium feldspar; and contains oxygen, hydrogen, and chromium isotopes that are similar to those of LL chondrites. Together, these four silica-rich ungrouped achondrites provide evidence for evolved compositions resulting from …

Insights Into Fluid-Rock Interactions On The Cv3 Carbonaceous Chondrite Asteroid: The Complex Record In The Allende-Like Cv3 Chondrite, Nwa 2364., Jessica Marie Johnson

Earth and Planetary Sciences ETDs

The two subgroups of the CV3 chondrites, oxidized and reduced, contain primitive solar system materials that provide many insights into early solar system processes. Both subgroups record significant evidence of secondary alteration that has modified their primary characteristics. In this work, we have studied the petrography, mineralogy, and oxygen isotopic composition of the NWA 2364 CV3_OxA chondrite and a large lithic inclusion using SEM, electron microprobe, FIB/TEM, and laser fluorination oxygen isotope analyses in order to characterize their alteration histories in detail. The NWA 2364 host and lithic inclusion consist of chondrules, Calcium-Aluminum-rich Inclusions (CAIs), and fine-grained matrix. In …

Widespread, Prolonged Microbial Limestone Deposition And Large, Rapid Sulfur Isotope Excursions: A New Perspective On The Early Triassic From The Western U.S., Brad M. Jeffrey

Earth and Planetary Sciences ETDs

The Early Triassic records a ~5 My period of marine biological recovery following the end-Permian mass extinction (EPME, ~252 My). Global oceans were characterized by warm sea-surface temperatures (SSTs), widespread anoxia, and major perturbations to the carbon cycle, the collective result of repeated massive Siberian Traps eruptions and associated global climate feedbacks. Globally widespread microbial deposits (stromatolites, thrombolites) developed in shallow marine environments. Several marine isotope records (C, O, S, U) indicate repeated, large-magnitude shifts related to paleoceanographic events during the recovery of marine ecosystems following the EPME.

Chapter 1 describes and interprets a widespread (~400 km along strike) Smithian …

Sedimentology And Stratigraphy Of Core Stl14: An Early Pleistocene-To-Present Paleoclimate Archive From Stoneman Lake, Arizona, Spencer Staley

Earth and Planetary Sciences ETDs

An 80 m lacustrine sediment core (STL14) from Stoneman Lake, Coconino County, Arizona, contains a sedimentary sequence of at least 1.5 million years, chronicling the complete history of basin infill and recording an extensive and high-resolution archive of climatic and hydrologic fluctuations. Lake levels in this small, internally-drained catchment are sensitive to changes in regional hydrologic balance. Consistent groundwater inflow, even during regionally dry episodes in the lake’s history, has prevented complete desiccation of the lake and sustained continuous lacustrine deposition except for one soil horizon. Multiproxy analysis of sedimentological indicators including lithofacies, color, wet bulk density, magnetic susceptibility, preliminary …

Mantle-To-Surface Neotectonic Connections In The San Juan Mountains Documented By 3he/4he, Co2 Flux Meaurements, And Hydrochemical Analysis Of The Geothermal System Near Rico, Colorado, Benjamin D. Holt

Earth and Planetary Sciences ETDs

This project investigates the controls on geothermal fluids and their conduit systems which may account for high mantle helium components of geothermal fluids in intracratonic continental regions. The field laboratory is the western San Juan Mountains of southwestern Colorado where the structural setting and hydrochemistry of carbonic springs suggest potential connections among surface hot springs, fault networks, CO2 degassing, significant geothermal potential, young volcanic and plutonic rocks (< 7 Ma), and low-velocity upper mantle. The Rico Hot Springs have the highest mantle volatile component of any spring in Colorado with air-corrected values of 3He/4He = 5.88 RA indicating 73% mantle helium component. This near-MORB mantle helium value at Rico indicates that volatiles degassing from the mantle must be rapidly transmitted into the groundwater system along deep-seated faults such that accumulation of 4He from radiogenic crust has not swamped mantle-derived primordial 3He. Geologic features that are important for volatile transport and spring chemistry controls include a complex conduit system and fault network involving the Precambrian-cored Rico Dome, ~4 Ma intrusive rocks at Calico Peak and Priest Gulch, and a low-velocity upper mantle. Therefore, Rico and the surrounding region is a natural laboratory for studying geothermal fluid and mantle volatile pathways. Additional noble gas analyses and hydrochemistry data were gathered from regional springs and modeled via chemical geothermometers. New noble gas measurements from this study, paired with literature values, reveal highest air corrected 3He/4He at Rico (4.09-5.88 RA), Dunton (3.11-4.54 RA), Geyser Warm Spring (3.39 RA), and Paradise Warm Spring (2.72 RA). Water volume is dominated by meteoric fluids as shown by stable isotope data but hydrochemistry indicates high TDS, high CO2, and high He come from a geothermal fluid endmember. Variable mixing and water-rock interactions are processes that can explain chemistry variations between spatially proximal springs. CO2 flux measurements (up to 36.2 g/m2/hr) vary across structural features and demonstrate that the faults act as pathways for CO2 flux suggesting ongoing degassing. Overall, we find that local high mantle helium signature is localized directly above regions of lowest upper mantle velocity in the San Juan mantle anomaly and is derived from neotectonic mantle melts in those regions.

Use Of Sodium Dithionite For Groundwater Restoration Following Uranium In-Situ Recovery Mining At The Smith Ranch-Highalnd Site In Wyoming, Rose J. Harris

Earth and Planetary Sciences ETDs

Uranium in-situ recovery (ISR) is a subsurface aqueous mining technique used to extract uranium from sandstone roll-front deposits. After ISR mining, groundwater restoration is conducted to decrease concentrations of residual U(VI) and other contaminants leftover in the groundwater. Sodium dithionite, a strong chemical reductant, is being tested for use in groundwater restoration following uranium ISR at the Smith Ranch-Highland site in Wyoming. Sodium dithionite has been used to remediate chromium plumes by creating an in-situ permeable reactive barrier, but there has been no work using sodium dithionite for groundwater restoration following uranium ISR mining.

Laboratory batch and column experiments, and …

Post-Impact Light Vapor Incorporation During Lunar Formation Based On Triple Oxygen Isotopes, Erick J. Cano

Earth and Planetary Sciences ETDs

Initial triple oxygen isotope analyses of lunar samples showed them to be indistinguishable from Earth, which led to numerous papers aimed at explaining the similarities. Recent high-precision analyses suggested either a subtle enrichment in Δ'¹⁷O or virtually no difference between the Earth and Moon. Herein we expand on previous studies by correlating the triple oxygen isotope measurements with different lunar lithologies. We show that these data can be explained by mixing between a light vapor phase, generated during the Giant Impact, and the residual material from the proto-lunar impactor ‘Theia’. There is a general decrease in Δ'^{17 …}

Radionuclides In Rainwater And Their Impact On Background Radiation, Damien M. Milazzo

Earth and Planetary Sciences ETDs

Radioactive waste has accrued throughout the continental United States and in the Oceans surrounding the country. Significant quantities of the waste are poorly documented regarding their location and the radioisotopes contained in the waste. Locating the waste is not an easy matter, as its locations are not well documented, and its method of disposal may be covered with plants, soils, and sediments. A common tool used to locate the waste is a gamma spectrometer, which measure the gamma emissions spectrum of radionuclides. The effectiveness of this tool when utilized to locate gamma emitting waste may be reduced due to the …

Are The Oxygen Isotope Values Of The Late Cretaceous Western Interior Seaway Different From The Open Ocean?, Camille H. Dwyer, Corinne Myers, Viorel Atudorei

Shared Knowledge Conference

The Western Interior Seaway (WIS) was a North American epicontinental sea that was connected to the open ocean through the passage of the northern Boreal Sea and the southern Tethys Sea from the early Albian (~113 million years ago) to the early Paleogene (~65 million years ago). The WIS began to recced and lost its connection to the southern Tethys Sea in the late Campanian (~72 million years ago). In the early Paleogene, the WIS dried up completely. The oxygen isotopic composition (δ18O) of benthic bivalves was measured from the upper Campanian and lower Maastrichtian (75 million years ago to …

Assessing Water Policy Implications Of The Changing Agriculture In New Mexico, Trevor A. Birt

Shared Knowledge Conference

Agriculture is the dominant water sector in New Mexico, responsible for more than 80% of water withdrawals in 2015 (USGS 2018). Water policy needs to be extremely adaptive and informed to meet the needs of not only farmers, but cities, industry and riparian uses. Since 1840, the U.S. Department of Agriculture (USDA) has conducted census surveys assessing all levels of agriculture. These data are physically published at the county, state, and national level on a 5-year cycle, detailing various material counts such as acreage, yields, and water usage, as well as socioeconomic estimates of farm costs, revenues, and hired workers. …

Natural Trace Element Salinization Of The Jemez River, New Mexico By Geothermal Springs And Major Tributaries, Jon K. Golla, Laura J. Crossey, Abdul-Mehdi S. Ali, Karl E. Karlstrom

Shared Knowledge Conference

The Jemez River (JR), a tributary of the Rio Grande, is in north-central New Mexico within the Jemez Mountains, which houses the active, high-temperature (≤ 300 oC), liquid-dominated Valles Caldera geothermal system (VC). This work focuses on the northern portion of the JR, spanning a reach from the East Fork JR to the town of San Ysidro. Previous decadal work during low-flow or baseflow conditions (~10-20 cfs) has identified and characterized significant major-solute contributions from two outflow expressions of the VC, Soda Dam Springs and Jemez Hot Springs, and two major tributaries, Rio San Antonio and Rio Guadalupe. There is …

Crustal Seismic Anisotropy Of The Ruby Mountains Core Complex And Surrounding Northern Basin And Range, Justin T. Wilgus

Earth and Planetary Sciences ETDs

Metamorphic core complexes (MCC) are distinctive uplifts that expose deeply exhumed and deformed crustal rocks due to localized extensional deformation. Consequently, their detailed structure provide a window into deep crustal mechanics. The North American Cordillera contains numerous MCC, one of which is the Ruby Mountains core complex (RMCC) located in the highly extended northern Basin and Range. To constrain the extent to which anisotropy below the RMCC deviates from the regional Basin and Range average and test the depth dependence of crustal anisotropy we conduct a radial anisotropy investigation below the RMCC and surrounding northern Basin and Range. Data from …

Comparison Of Methodologies Of Using Colorimetry To Detect Low Concentrations Of Bromide As A Hydrologic Tracer, Emily Wolf

Water Resources Professional Project Reports

The objective of this research was to compare colorimetric methods for measuring low concentrations of bromide in natural waters. The bromide ion has long been used as a tracer to study hydrodynamic processes and properties. Its conservative nature makes it ideal as a tracer. Bromide is almost entirely immune to loss from a solution via adsorption on rocks and sediments, or reaction with other solutes present in the water. Using three methodologies to use colorimetry in the detection of bromide, I analyzed samples taken from the Gila River, Jemez Creek, and the Rio Grande after injections of sodium bromide were …

To Rebate Or Not To Rebate: The Influences And Deterrents For Residential Customers To Participate In Water Authority Rebates, Meagan Virginia Oldham

Water Resources Professional Project Reports

The depletion of aquifers and reduced surface water flows are a growing concern for water managers. Educational outreach and incentives to promote conservation have been a growing trend over the past couple of decades in the arid Southwestern United States, including Albuquerque, New Mexico. Rebates for the installation of water efficient appliances and xeric landscape conversions are a couple of ways that water authorities incentivize their residential consumers to do their part at home to conserve water. This study involves a survey sent to a random sample of 2,215 Albuquerque Bernalillo County Water Utility Authority residential customers, with a 31% …

Dense-Array Teleseismic Imaging Of The Southern Albuquerque Basin, Tori S. Finlay

Earth and Planetary Sciences ETDs

The southern Albuquerque basin is a complex area of high extension, multiple orogenies, and ongoing uplift from a midcrustal magma body in which geophysical coverage is sparse. In this thesis, I capitalize on recent innovations in dense-array processing techniques to create virtual source reflection profiles from five teleseismic events during the deployment of the Sevilleta array. The Sevilleta array consisted of ~800 vertical component nodes with ~300 m spacing deployed for 10 days in February of 2015. Virtual source reflection profiles are created by using the free surface of the earth as a virtual seismic source, yielding profiles that mimic …

Mainland Southeast Asia In The Longue Durée: A Zooarchaeological Test Of The "Broad Spectrum Revolution" In Northern Thailand, Cyler Norman Conrad

Anthropology ETDs

In northern Thailand, previous zooarchaeological research suggests that hunter-gatherers consumed a broad diversity of animal resources during the Pleistocene-Holocene transition and afterwards (Gorman 1971a). This is a pattern characteristic of Kent Flannery’s (1969) “broad spectrum revolution” hypothesis. Based primarily on presence and absence evidence, faunal assemblages in northern Thailand typically include species of mammals, reptiles, birds, fish and shellfish, suggesting that prehistoric foragers consumed a wide range of taxa within this mainland Southeast Asian tropical environment. Although zooarchaeological analyses commonly identify this pattern within prehistoric cave and rockshelter sites, past investigations have 1) not attempted to formally test Flannery’s hypothesis, …