Earth Sciences Commons^™

Nitrogen Management In Rice Under Suboptimal Soil Conditions, Payton Suzanne Rhea

Graduate Theses and Dissertations

In Mid-South rice (Oryza sativa, L.) production, nitrogen (N) fertilizer management for pureline varieties is most often recommended as a single preflood (SPF) or two-way split (2WS) application in a direct-seeded, delayed-flood system. Most of the N fertilizer is typically applied at the four- to six-leaf stage onto dry soil, and the second application, if necessary, into the floodwater during early reproductive growth stages (referred to as midseason). Environmental factors frequently prohibit growers from applying early N fertilizer under optimal dry soil conditions. A study was conducted to determine the best N fertilization management practices to utilize in rice when …

The Binding Of The Micronutrient Transition Metals To The Alkylation Products Of Chemical Warfare Agent, Sulfur Mustard, And Thiols, Potentially Giving New Understanding To Physiological Effects Of Exposure And Increased Toxicity, Colin O'Donnell

Graduate Theses and Dissertations

Model compounds, 3,6,9-trithaiundecane-1,11-dicarboxylic acid (TTDPA), 2,5,8-trithianonane-1,9-dicarboxylic acid (TTDAA), and 1,11-diamide-3,6,9-trithiaundecane (TTDAce), closely related to the adducts formed by cysteine alkylation of the chemical weapon, sulfur mustard, were synthesized. It is shown that TTDPA forms complexes with key metal micronutrients: copper, nickel, cobalt, manganese, and zinc. Though the strength of binding to TTDPA varies, the complexes in many cases precipitate from solution. All metals produced a visible precipitate upon interaction with TTDPA under the conditions tested, however only Cu2+, Mn2+, and Zn2+ produced enough to be measured. The mass of formed precipitate seemed to peak at an equimolar ratio of TTDPA …

Diagnosing Excess Nitrogen In Rice Using Post-Season Tissue Samples, Kyle Hoegenauer

Graduate Theses and Dissertations

Proper nitrogen (N) management in rice production can be difficult to achieve without the aid of tools such as soil and tissue tests. There are no tests currently available to rice producers that determine whether N has been managed properly throughout the season or that detect instances of over fertilization. Rice stalk samples were collected from N response trials within 3 days of harvest from the primary Arkansas rice growing region in 2016-2018. Stalk samples were analyzed for N concentration through a KCl extraction and spectrofluorometric quantification. Samples analyzed with leaf material intact contained statistically different N concentrations than samples …

Delineating Field Variation Using Apparent Electrical Conductivity In An Ozark Highlands Agroforestry System, Shane Reid Ylagan

Graduate Theses and Dissertations

Little to no work has been conducted assessing field variability using repeated electromagnetic induction (EMI) apparent electrical conductivity (ECa) surveys in agroforestry (AF) systems within regions similar to the Ozark Highlands. The objectives of this thesis were to identify i) spatiotemporal ECa variability; ii) ECa-derived soil management zones (SMZs); iii) correlations among EMI-ECa and in-situ, sentential-site soil properties; iv) whether fewer, EMI-ECa surveys could be conducted to capture similar ECa variance as mid-monthly EMI-ECa surveys; v) correlations between ECa and forage yield, tree growth, and terrain attributes based on plant (forage and tree) species, and fertility treatments, and ECa-derived SMZs, …

Recovery Of Soil Microbial Diversity And Functions Along A Tropical Montane Forest Disturbance Gradient, Renee Sniegocki, Jessica B. Moon, Abigail L. Rutrough, Jude Gireneus, Jaya Seelan Sathiya Seelan, Michael C. Farmer, David C. Weindorf, Kusum Naithani

Biological Sciences Faculty Publications and Presentations

Logging and forest conversion are occurring at alarming rates in tropical forests. These disturbances alter soil microbial community structure and functions. While direct links between changes in soil properties, such as pH and microbial community structure are well established, the indirect effects of logging and forest conversion on soil microbial community structure and functions are poorly understood. We used a space-for-time substitution to investigate the changes in soil microbial diversity and functions across a forest recovery gradient in the tropical montane forests of northern Borneo. We used surface (top 5 cm) soil to assess soil physicochemical and microbial (next-generation DNA …

Development Of Deep Shear Wave Velocity Profiles And An Approach To Generate Site Signature Consistent Pseudo Shear Wave Velocity Profiles In The Mississippi Embayment, Ashraf Kamal Himel

Graduate Theses and Dissertations

This dissertation details the development of a surface wave method (SWM) technique to generate deep shear wave velocity profiles (VS profiles), applying this technique at 24 sites across the Mississippi embayment and developing an approach to generate pseudo site signature consistent VS profiles from velocity functions and fundamental frequency. In the presented SWM technique, active and passive source surface wave measurements are inverted along with fundamental frequency to develop a site signature consistent VS profile. Multiple transformation methods, including MSPAC, HRFK and FK are used to resolve experimental dispersion data from surface wave measurements. SWM VS profile at the Central …

Examining The Expression Patterns Of Desulfotalea Psychrophila Dsrab Operon And Pit At Subfreezing Temperatures And Different Concentrations Of Sulfate Salts As A Model For Mars And Icy Worlds Survival And Colonization, Sergio Luis Mosquera Mora

Graduate Theses and Dissertations

Since ancient times, Humanity has been fascinated with the idea of what lies beyond the borders of our planet. Fortunately, the combined efforts of many nations have made it possible to send unmanned spacecraft to orbit planets located close to Earth. These missions have the principal goal to collect data that could help us understand the basic environmental conditions that persist on those planets, or for evidence of past or present life. Equally important, landers and rovers have been successfully deployed to start the in-situ exploration of many planets of the Solar System. Among them, Mars has been extensively studied …

Evaluation Of Factors That Contribute To Injury To Quizalofop-Resistant Rice From Quizalofop Applied Postemergence, Navdeep Godara

Graduate Theses and Dissertations

Quizalofop-resistant rice technology allows for over-the-top applications of quizalofop, an acetyl-coenzyme A carboxylase-inhibiting herbicide. However, quizalofop caused significant injury to quizalofop-resistant rice in some Arkansas fields during the first year of commercialization. Experiments evaluated the effect of early-season soil moisture and nitrogen availability; pre-exposure to low rates of glyphosate and imazethapyr; planting date; and environmental conditions including, soil moisture content, air temperature, and light intensity on quizalofop-resistant rice tolerance to quizalofop applications. All experiments assessed sequential quizalofop applications made to 2-leaf followed by 5-leaf stage of rice. Sequential quizalofop applications alone and with surface irrigation or nitrogen application at the …

A Comparison Of Relict And Active Terrestrial Patterned Ground As An Analog For Mars, John Paul Knightly Jr.

Graduate Theses and Dissertations

Patterned ground is a ubiquitous landform in periglacial regions of Earth and is also present across the mid to high latitudes of Mars. The association of terrestrial patterned ground to the presence of subsurface water ice in the form of permafrost that develops a seasonal ‘wet’ active layer during the summer thaw prompted further investigation of patterned ground on Mars. The Phoenix spacecraft was sent to the surface of the north polar plains of Mars to investigate an area of patterned ground where water ice was predicted to occur. The confirmation of subsurface water ice at the Phoenix landing site …

A Cross-Scale Nexus: Microbial Functional Genes In Tandem With Molecular-Level Nitrogen Fluxes And Implications For Field-Scale Biogeochemical Processes, Srusti Maddala

Graduate Theses and Dissertations

Nitrogen (N) biogeochemical cycling entails close networking between soil nutrients, plant species and resulting microbial communities, and abiotic factors such as temperature, moisture, and pH. To better understand transformations of N in soil microsites, which are known to be rich in N-cycling behavior, the microdialysis technique was employed to generate in situ data on temporal alterations of N during wetting-drying conditions in both the field and laboratory. The objectives were to 1) determine the lifespan of the microdialysis technique in field conditions, 2) evaluate the ability of the method to yield N fluxes that would be differential between the two …

Optimization Techniques For Soil Organic Carbon Prediction Using Mid-Infrared Spectroscopy, Minerva J. Dorantes

Graduate Theses and Dissertations

Resource-efficient techniques for accurate soil carbon estimation are necessary to satisfy the increasing demand for spatiotemporal data. In the last thirty years, mid-infrared (MIR) soil spectroscopy has developed as an accurate, rapid, cost-effective, and non-destructive technique for soil organic carbon (SOC) analysis. In soil spectroscopy, a calibration model relates spectral data to a corresponding measured soil property and is subsequently used to predict this value from new spectral data. Various optimization techniques have been used to improve the statistical performance of calibrations; however, there is little consensus on the conditions that make these techniques effective. The objectives of this research …

Structural Interpretation Of An Alkaline-Carbonatite Complex Using Gravity And Magnetic Methods At Magnet Cove, Arkansas, Chelsea Morgan Amaral

Graduate Theses and Dissertations

The Magnet Cove alkaline-carbonatite complex in the Ouachita Mountains of south-central Arkansas could be a valuable resource for rare earth elements, though it has not yet been thoroughly studied using geophysical methods, and existing geophysical models simplify its diverse nature. Prior to this study, the subsurface structure and extent of the Magnet Cove complex was poorly understood and, in general, the process of emplacement of alkaline carbonatite complexes worldwide is also not fully understood. The Magnet Cove complex hosts an extensive variety of rare rock types and mineral resources that contrast significantly to the sedimentary rocks into which they have …

Evaluation Of Carbon Isotopic Chemostratigraphy Of The Cedar Mountain Formation Of Utah, Clayton Forster

Graduate Theses and Dissertations

The Lower Cretaceous rocks of Utah preserve the origin of a multitude of dinosaur taxa, spread of angiosperms on the North American continent, and evolution of marsupial and eutherian mammals. However, the timing of deposition of these rocks is not well understood and must be determined to understand climatic controls on these biological events. Estimates of the age of the Cedar Mountain Formation and its constituent members range from Late Jurassic to early Late Cretaceous. Understanding the timing of deposition of the Cedar Mountain Formation is critical to dinosaurian and associated taxa studies as well as paleoclimate reconstructions from within …

Understanding Martian Salts And Their Implications For Liquid Water, Rachel Slank

Graduate Theses and Dissertations

Water is one of the key components for life as we know it. The existence of salts on Mars has been a large contributing factor to the possibility of habitability, due to their ability to allow liquid water to remain stable at colder temperatures. Salts, including perchlorates, chlorates, and chlorides, have been detected by multiple landers, rovers, and orbiters, and are now believed to be ubiquitous on Mars. One of the pathways to liquid brine solutions is through deliquescence. Deliquescence is the transition from a solid salt crystal into an aqueous solution when exposed to a humid atmosphere. This research …

Arkansas Corn And Grain Sorghum Research Studies 2021, Victor Ford, Jason Kelley, Nathan Mckinney Ii

Arkansas Agricultural Experiment Station Research Series

The 2021 edition of the Arkansas Corn and Grain Sorghum Research Studies Series includes research results on topics pertaining to corn and grain sorghum production, including weed, disease, and insect management; economics; sustainability; irrigation; post-harvest drying; soil fertility; mycotoxins; cover crop management; and research verification program results. Our objective is to capture and broadly distribute the results of research projects funded by the Arkansas Corn and Grain Sorghum Board. The intended audience includes producers and their advisors, current investigators, and future researchers. The Series serves as a citable archive of research results.

Machine Learning Applied To A Modern-Pleistocene Petrographic Data Set: The Global Prediction Of Sand Modal Composition (Gloprsm) Model, J. Isaac Johnson, Glenn R. Sharman, Eugene Szymanski, Xiao Huang

Geosciences Faculty Publications and Presentations

Petrography has long been used as a tool to decipher the sedimentary provenance of sand and sandstone based on relative proportions of detrital grain types. However, there is not yet a predictive framework that constrains the relationship between sand grain composition and the factors that influence it, including bedrock lithology, elevation, slope, basin area, precipitation, and temperature. We used a globally extensive modal point-count data set of 3,522 Pleistocene to modern sand samples to train an inline series of random forest meta-estimators to predict relative abundances of quartz (Q), feldspar (F), and lithic (L) grain types and eight subcompositions. The …

Rodent Dental Microwear Texture Analysis As A Proxy For Fine-Scale Paleoenvironment Reconstruction, Jenny H. E. Burgman

Graduate Theses and Dissertations

Dental microwear texture analysis (DMTA) of fossil fauna has become a valuable tool for dietary inference and paleoenvironment reconstruction. Most of this work has utilized larger taxa with larger home ranges. These studies may result in broader-scale habitat inferences that could mask the details of complex mosaic habitats. Rodent DMTA offers an opportunity to work at finer spatial scales because most species have smaller home ranges. Rodents are also keystone species within their ecosystems, abundant, ubiquitous, and found in many fossil deposits. These attributes make them excellent proxies for environmental reconstructions. However, the application of DMTA to rodents remains relatively …

Temporal Changes In Surface Water Availability: Patterns Of Seasonal Shift On Water Stress In The Conterminous Us Under A Changing Climate, Quinn Montana

Graduate Theses and Dissertations

The argument could be made that there is nothing more valuable on the planet than water. Our lives depend upon it. Climate change is already having an impact on the United States (US) and water stress will be one of the problems we increasingly face in coming decades. Regional research has shown that one or another part of the conterminous US (CONUS) is expected to experience an annual deficit or a surplus in runoff. Further studies have looked at changing patterns over the CONUS as a whole. Other research has focused on a particular season. This work addresses a gap …

Wayne E. Sabbe Arkansas Soil Fertility Studies 2021, Nathan A. Slaton

Arkansas Agricultural Experiment Station Research Series

Rapid technological changes in crop management and production require that the research efforts be presented in an expeditious manner. The contributions of soil fertility and fertilizers are major production factors in all Arkansas crops. The studies described within will allow producers to compare their practices with the university’s research efforts. Additionally, soil-test data and fertilizer sales are presented to allow comparisons among years, crops, and other areas within Arkansas.

The Effect Of Changing Land Use On Streamflow Statistics And Flood Flows Across Select Gages In Northwest Arkansas, Timothy Mcmullen

Civil Engineering Undergraduate Honors Theses

Since 1901, heavy rainfall events have increased in the United States in both intensity and frequency, and population in the United States has increased, resulting in significant land use changes. Both of these trends could explain an increase in observed flood magnitude and frequency. In order to determine if a relationship exists between land use/land cover and changing stream flows in northwest Arkansas, this study analyzed temporal changes in various flow statistics for fourteen stream gages and compared the rates of change in flow statistics from gages on streams with watersheds that have varying land uses, i.e. urban, agricultural, and …

A Geochemical And Mineralogical Evaluation Of The Mona Lisa Turquoise Mine, Polk County, Arkansas, Alexander Arai Goodsuhm

Graduate Theses and Dissertations

The presence of turquoise in Arkansas has long been disputed by geologists and gem collectors. Despite the prevalence of other phosphate minerals in Arkansas, such as planerite, wavellite, and variscite, the absence of an obvious copper (Cu) source required for turquoise formation was considered too great of an obstacle for turquoise mineralization. In this study, geologic, mineralogical, and geochemical techniques provide overwhelming evidence that the novaculite-hosted Mona Lisa Mine in Arkansas does produce turquoise. X-ray diffraction and Raman spectroscopy have confirmed the structural nature of the material and identified other phosphate minerals, such as crandallite, often found in assemblage with …

Using Thermal Units To Predict Biomass Accumulation And Total Nitrogen Uptake For Cover Crops In Arkansas, Mila Victório Pessotto

Graduate Theses and Dissertations

Including cover crops in agricultural production systems is an important management practice. Cover cropping can improve soil health, increase plant-available nitrogen (N), provide surface residue to prevent erosional soil loss, increase water infiltration, and increase weed suppression. Cover crops growth can be predicted using thermal days or growing degree days [GDD] similar to commodity crops such as corn (Zea mays L.) or rice (Oryza sativa). Growing degree day calculations are a well-known tool to predict crop growth stage or development stage and can be adapted for use in any plant species, including cover crops. Identifying and developing the relationship between …

Arkansas Bulletin Of Water Research - Issue 2021-2022, Erin Grantz, Lillie Haddock, Brian E. Haggard

Arkansas Bulletin of Water Research

The Arkansas Bulletin of Water Research (Bulletin) is a publication of the Arkansas Water Resources Center (AWRC). We publish the Bulletin to communicate the major findings of research funded by the Water Resources Research Act Section 104(b) in Arkansas. This research is relevant to Arkansas water stakeholders, and the Bulletin provides an easily searchable and aesthetically engaging access option.

This is the fourth publication of the Bulletin. This issue contains final reports from research projects that were funded by the 104(b) program in fiscal years 2019 and 2020. The articles in this issue can be cited as an AWRC publication. …

The Times, They Are A-Changin': Tracking Shifts In Mental Health Signals From Early Phase To Later Phase Of The Covid-19 Pandemic In Australia, Siqin Wang, Xiao Huang, Tao Hu, Mengxi Zhang, Zhenlong Li, Huan Ning, Jonathan Corcoran, Asaduzzaman Khan, Yan Liu, Jiajia Zhang, Xiaoming Li

Geosciences Faculty Publications and Presentations

Introduction Widespread problems of psychological distress have been observed in many countries following the outbreak of COVID-19, including Australia. What is lacking from current scholarship is a national-scale assessment that tracks the shifts in mental health during the pandemic timeline and across geographic contexts.

Methods Drawing on 244 406 geotagged tweets in Australia from 1 January 2020 to 31 May 2021, we employed machine learning and spatial mapping techniques to classify, measure and map changes in the Australian public’s mental health signals, and track their change across the different phases of the pandemic in eight Australian capital cities.

Results Australians’ …

Minimum Dataset And Metadata Guidelines For Soil-Test Correlation And Calibration Research, Nathan A. Slaton, Sarah E. Lyons, Deanna L. Osmond, Sylvie M. Brouder, Steve W. Culman, Gerson L. Drescher, Luciano C. Gatiboni, John Hoben, Peter J.A. Kleinman, Joshua M. Mcgrath, Robert O. Miller, Austin Pearce, Amy L. Shober, John T. Spargo, Jeff J. Volenec

Crop, Soil and Environmental Sciences Faculty Publications and Presentations

Soil-test correlation and calibration data are essential to modern agriculture, and their continued relevance is underscored by the expansion of precision farming and the persistence of sustainable soil management priorities. In support of transparent, science-based fertilizer recommendations, we seek to establish a core set of required and recommended information for soil-test P and K correlation and calibration studies, a minimum dataset, building on previous research. The Fertilizer Recommendation Support Tool (FRST) project team and collaborators are developing a national database that will support a soil-test-based nutrient management decision aid tool. The FRST team includes over 80 scientists from 37 land-grant …

Investigating Depth Estimation To Archaeological Magnetic Source Bodies, Jeremy G. Menzer

Graduate Theses and Dissertations

Magnetometry is the most widely applied archaeo-geophysical technique. Current practice standards employ the technique to map only in a two-dimensional plan view fashion, but in deep geologic studies depth estimators are routinely applied to magnetic datasets. These estimators provide three-dimensional information to magnetic source-bodies. There are many different depth estimators employed in geologic study that all require various degrees of processing complexity. This study investigates two mathematically simple techniques, half-width rules and multi-height methods. Half-width rules are likely the oldest depth estimators within the field while multi-height techniques are but a minor footnote in the literature. The applicability of these …

Field Evaluation Of Struvite As A Phosphorus Source, Niyi Sunday Omidire

Graduate Theses and Dissertations

Phosphorus (P) is an element that is crucial in many biological processes in all forms of life and is not substitutable. Excess P in wastewaters leading to the degradation of receiving waters or eutrophication once released is a major environmental concern. Removal of excess P from wastewater as the mineral struvite (MgNH4PO4·6H2O) could be a promising solution to reduce P discharge into receiving waters and can potentially provide a valuable fertilizer-P source for agricultural production. The objectives of this project were to evaluate the effects of: 1) chemically precipitated struvite (CPST), compared to triple superphosphate (TSP) and an unamended control …

Cover Crop Effects On Near-Surface Soil Aggregate Stability In The Southern Mississippi Valley Loess (Mlra 134), Chandler M. Arel

Crop, Soil and Environmental Sciences Undergraduate Honors Theses

Intensive agricultural cultivation within major land resource area (MLRA) 134, the Southern Mississippi Valley Loess, has led to soil erosion, soil compaction, and the overall destabilization of near-surface soil aggregates. The use of cover crops during the agricultural offseason has been shown to help alleviate soil compaction and provide stabilizing effects against soil erosion, which are particularly important as the silty soils of MLRA 134 have a large erosion potential. This study evaluated the effects of cover crop and no-cover crop treatment on silt-loam soils within MLRA 134. Treatments were implemented during Fall 2018 and Fall 2019 and consisted of …

Analysis Of Titan's Fluvial Features Using Numerical Modeling, Jeshurun Horton

Mechanical Engineering Undergraduate Honors Theses

River channels have been observed near the Huygens probe landing site on the surface of Titan, along with evidence of rounded water ice boulders transported through fluid flow. Evidence near the landing site suggests active flow of liquid methane, which has motivated the study of the effects of sediment load and channel sizes on Titan’s fluvial features. A numerical model is used to determine the viscosity, flow velocity, and critical boulder transport diameter based on channel size, slope, and a range of sediment concentrations. This model achieves two ends: first, observed boulder diameters are used to determine the ideal channel …

Nutrient Uptake And Management Strategies In Recirculating Hydroponic Systems, Lauren Leigh Houston

Graduate Theses and Dissertations

Nutrient management in recirculating hydroponic systems requires the periodic replenishment of water and nutrients to the nutrient solution reservoir. Common nutrient management strategies, such as replenishing the reservoir with fresh solution and maintaining a constant solution electrical conductivity (EC), can lead to ion accumulation and nutrient imbalances since nutrients are taken up by roots and depleted from solution at different rates. To avoid nutritional disorders, commercial growers typically dump and replace the hydroponic solution periodically, which is wasteful and has an economic cost. A potential alternative is to specially formulate the nutrient replenishment solution to balance the supply of nutrients …