Earth Sciences Commons^™

Detection Of The 2010 Chilean Tsunami Using Satellite Altimetry, B. D. Hamlington, R. R. Leben, O. A. Godin, J. F. Legeais, E. Gica, V. V. Titov

CCPO Publications

Tsunamis are difficult to detect and measure in the open ocean because the wave amplitude is much smaller than it is closer to shore. An effective early warning system, however, must be able to observe an impending tsunami threat far away from the shore in order to provide the necessary lead-time for coastal inhabitants to find safety. Given the expansiveness of the ocean, sensors capable of detecting the tsunami must also have very broad areal coverage. The 2004 Sumatra-Andaman tsunami was definitively detected in the open ocean from both sea surface height and sea surface roughness measurements provided by satellite …

Fossil And Contemporary Aerosol Particulate Organic Carbon In The Eastern United States: Implications For Deposition And Inputs To Watersheds, Andrew S. Wozniak, James E. Bauer, Rebecca M. Dickhut

Chemistry & Biochemistry Faculty Publications

Atmospheric particulate matter samples were collected from mid-Atlantic and northeastern U. S. (Virginia and New York, respectively) sites to assess the fossil versus contemporary sources contributing to aerosol organic carbon (OC) and the implications for its deposition to watersheds. Mean particulate matter total OC (TOC) deposition rates (wet + dry deposition) were calculated to be 1.6 and 2.4 mg C m^-2 d^-1 for the Virginia and New York sites, respectively. Wet deposition of particulate TOC was determined to be the dominant depositional mode, accounting for >65% (Virginia) and >80% (New York) of total aerosol TOC deposition. Isotopic mass …

Early Season Depletion Of Dissolved Iron In The Ross Sea Polynya: Implications For Iron Dynamics On The Antarctic Continental Shelf, Peter N. Sedwick, C. M. Marsay, B. M. Sohst, A. M. Aguilar-Islas, M. C. Lohan, M. C. Long, K. R. Arrigo, R. B. Dunbar, M. A. Saito, W. O. Smith, G. R. Ditullio

OES Faculty Publications

The Ross Sea polynya is among the most productive regions in the Southern Ocean and may constitute a significant oceanic CO₂sink. Based on results from several field studies, this region has been considered seasonally iron limited, whereby a "winter reserve" of dissolved iron (dFe) is progressively depleted during the growing season to low concentrations (~ 0.1 nM) that limit phytoplankton growth in the austral summer (December-February). Here we report new iron data for the Ross Sea polynya during austral summer 2005-2006 (27 December-22 January) and the following austral spring 2006 (16 November-3 December). The summer 2005-2006 data show …

Spatio-Temporal Variations In Soil Moisture And Physicochemical Properties Of A Typical Semiarid Sand-Meadow-Desert Landscape As Influenced By Land Use, L. Duan, T. Liu, X. Wang, G. Wang, L. Ma, Y. Luo

Civil & Environmental Engineering Faculty Publications

A good understanding of the interrelations between land cover alteration and changes in hydrologic conditions (e.g., soil moisture) as well as soil physicochemical properties (e.g., fine soil particles and nutrients) is crucial for maintaining the fragile hydrologic and environmental conditions of semiarid land, such as the Horqin Sandy Land in China, but is lacking in existing literature. The objectives of this study were to examine: (1) spatio-temporal variations of soil moisture and physicochemical properties in semiarid land; and (2) how those variations are influenced by land cover alteration. Using the data collected in a 9.71 km2 well-instrumented area of the …

Modern Dirty Sea Ice Characteristics And Sources: The Role Of Anchor Ice, Dennis A. Darby, Wesley B. Myers, Martin Jakobsson, Ignatius Rigor

OES Faculty Publications

Extensive dirty ice patches with up to 7 kg m^-2 sediment concentrations in layers of up to 10 cm thickness were encountered in 2005 and 2007 in numerous areas across the central Arctic. The Fe grain fingerprint determination of sources for these sampled dirty ice floes indicated both Russian and Canadian sources, with the latter dominating. The presence of benthic shells and sea weeds along with thick layers (2-10 cm) of sediment covering 5-10 m² indicates an anchor ice entrainment origin as opposed to suspension freezing for some of these floes. The anchor ice origin might explain the …

Evidence From The Florida Straits For Younger Dryas Ocean Circulation Changes, Jean Lynch-Stieglitz, Matthew W. Schmidt, William B. Curry

OES Faculty Publications

The waters passing through the Florida Straits today reflect both the western portion of the wind-driven subtropical gyre and the northward flow of the upper waters which cross the equator, compensating North Atlantic Deep Water export as part of the large-scale Atlantic meridional overturning circulation. It has been postulated from various lines of evidence that the overturning circulation was weaker during the Younger Dryas cold event of the last deglaciation. We show here that the contrast in the oxygen isotopic composition of benthic foraminiferal tests across the Florida Current is reduced during the Younger Dryas. This most likely reflects a …

Meridional Shifts In The Marine Itcz And The Tropical Hydrologic Cycle Over The Last Three Glacial Cycles, Matthew W. Schmidt, Howard J. Spero

OES Faculty Publications

Paleoproxy studies show a strong correlation between tropical climate and high-latitude temperature variability recorded in the Greenland ice cores over the last glacial cycle. In particular, abrupt cooling events in the Greenland Ice Sheet Project II δ¹⁸O ice record appear synchronous with a southward migration of the Intertropical Convergence Zone (ITCZ) in the Atlantic, a weakening of the Indian and East Asian monsoon systems, and a strengthening of the South American monsoon system. Because this high-to-low-latitude climate teleconnection significantly alters the tropical hydrologic cycle around the globe, it plays a critical role in regulating global climate on glacial-interglacial …

Florida Straits Deglacial Temperature And Salinity Change: Implications For Tropical Hydrologic Cycle Variability During The Younger Dryas, Matthew W. Schmidt, Jean Lynch-Stieglitz

OES Faculty Publications

The prevailing paradigm of abrupt climate change holds that rapid shifts associated with the most extreme climate swings of the last glacial cycle were forced by changes in the strength and northward extension of Atlantic Meridional Overturning Circulation (AMOC), resulting in an abrupt reorganization of atmospheric circulation patterns with global teleconnections. To determine the timing of tropical Atlantic atmospheric circulation changes over the past 21 ka BP, we reconstruct high resolution sea surface temperature and δ¹⁸O_SW (a proxy for surface salinity) records based on Mg/Ca ratios and oxygen isotope measurements in the planktonic foraminifera Globigerinoides ruber from …

Lithospheric Control On The Spatial Pattern Of Azores Hotspot Seafloor Anomalies: Constraints From A Model Of Plume-Triple Junction Interaction, Jennifer E. Georgen

OES Faculty Publications

The Azores hotspot is located near a plate boundary triple junction (TJ) consisting of the Terceira Rift (TER) and two branches of the Mid-Atlantic Ridge (MAR). The seafloor expression of the Azores hotspot has a complex spatial pattern. Latitudinal anomalies in seafloor depth and other data along the MAR extend farther to the south of the inferred location of the mantle heterogeneity than to the north. Longitudinal anomalies span a greater distance to the east of the MAR (along the TER) than to the west. A finite element model is used to investigate how the divergence of three plates away …

Comparison Of Ice Core Dissolved Organic Matter From A Greenland Ice Core By Nanospray Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Joshua Jeremiah Shiloh Marsh

Chemistry & Biochemistry Theses & Dissertations

Recent studies of ice cores have embarked on the task of determining the classes of dissolved organic matter (DOM) present in melt-water from the cores collected in numerous locations in the northern and southern hemispheres. This DOM originally derives from wet precipitation and is thought to reflect atmospheric organic matter derived from anthropogenic and non-anthropogenic sources. Because the amount of DOM is so low, previous studies have necessarily used large sample volumes (greater than 500 mL) to concentrate sufficient ice core DOM necessary for mass spectral analysis. Solid phase extraction (SPE) with C₁₈ resins was followed by evaporative concentration …

Phosphorus Uptake In Rhodomonas Salina (Wislouch) And Its Effect On Allocation And Elimination In Acartia Tonsa (Dana), Danna Palladino

OES Theses and Dissertations

Phosphorus is a key element in important biochemical compounds, such as RNA and phospholipids, and can become limiting in a variety of marine systems. The uptake of phosphorus into biochemical fractions (protein, low molecular weight (LMW) compounds, lipid, polysaccharide and nucleic acid) in Acartia tonsa fed ³³P -labeled Rhodomonas salina was examined. R. salina was cultured on two variations of one media that in one case contained phosphorus in balance and the other out of balance with relation to other standard f/2 components. The P-balanced (PB) media had a N:P ratio of 24.5, which is higher than that found …

Clay Mineral Cycles Identified By Diffuse Spectral Reflectance In Quaternary Sediments From The Northwind Ridge: Implications For Glacial-Interglacial Sedimentation Patterns In The Arctic Ocean, Lyanne N. Yurco, Joseph D. Ortiz, Leonid Polyak, Dennis A. Darby, Kevin A. Crawford

OES Faculty Publications

A Quaternary record of fine-grained sediment composition is used to investigate Arctic Ocean climate variability on glacial-interglacial time scales. Diffuse spectral reflectance data from sediment core P1-92AR-P25 from the Northwind Ridge, north of Alaska, demonstrates cyclic variations in mineralogy. Varimax-rotated R-mode factor analysis of down-core data revealed three major mineralogical assemblages, which were then compared with the content of manganese, a proxy for basin ventilation, and thus glacial-interglacial cycles. Results indicate that factor 1, a smectite + chlorite clay assemblage, was delivered to the core site during interglacials, either by fluvial discharge or sea-ice drift from Siberian rivers or inflow …

Temporal Controls On Dissolved Organic Matter And Lignin Biogeochemistry In A Pristine Tropical River, Democratic Republic Of Congo, Robert G. M. Spencer, Peter J. Hernes, Rosmarie Ruf, Andy Baker, Rachael Y. Dyda, Aron Stubbins, Johan Six

Chemistry & Biochemistry Faculty Publications

Dissolved organic carbon (DOC), lignin biomarkers, and the optical properties of dissolved organic matter (DOM) were measured in the Epulu River (northeast Democratic Republic of Congo) with the aim of investigating temporal controls on the quantity and chemical composition of DOM in a tropical rainforest river. Three different periods defined by stages of the hydrologic regime of the region, (1) post dry flushing period, (2) intermediary period, and (3) start of the dry period/post flush, were sampled. Temporal variability in DOM quantity and quality was observed with highest DOC, lignin concentration (Σ₈) and carbon‐normalized (Λ₈) values …

Mixing By Shear Instability At High Reynolds Number, W. R. Geyer, A. C. Lavery, M. E. Scully, J. H. Trowbridge

CCPO Publications

Shear instability is the dominant mechanism for converting fluid motion to mixing in the stratified ocean and atmosphere. The transition to turbulence has been well characterized in laboratory settings and numerical simulations at moderate Reynolds number-it involves "rolling up", i.e., overturning of the density structure within the cores of the instabilities. In contrast, measurements in an energetic estuarine shear zone reveal that the mixing induced by shear instability at high Reynolds number does not primarily occur by overturning in the cores; rather it results from secondary shear instabilities within the zones of intensified shear separating the cores. This regime is …

Breathing Like A Fish, Petros J. Katsioloudis

STEMPS Faculty Publications

The article offers information on industrial oxygen rebreathers, an underwater breathing equipment used by divers. It states that rebreather is an electromechanical device that supply breathing gas through infusion of oxygen and reprocessing of carbon dioxide by using a chemical scrubber. It mentions that most rebreathers comprise of breathing loop, breathing lungs, and a canister where the scrubber is placed with the partial pressure (pO₂) sensors and interface devices like heads-up display (HUD) to show pO₂ levels. It also discusses types of rebreathers such as the oxygen rebreather, the oldest rebreather mainly used by navy diver, and …

Concentrations, Distributions And Chemical Speciation Of Zinc And Cadmium In The Equatorial And South Atlantic Ocean, Gonzalo G. Carrasco

OES Theses and Dissertations

Certain trace metals are important cofactors in enzymatic systems and are thus, essential for life in the world's oceans. Two of these metals, Zn and Cd, are required by phytoplankton for enzymes that facilitate carbon uptake (Morel and Price, 2003). In seawater the total dissolved concentration of a metal (MTD) is distributed among different chemical species and this chemical speciation dictates a metal's bioavailability. Strong organic metal-binding ligands greatly affect the metal's chemical speciation in the ocean, potentially limiting phytoplankton growth by reducing the concentrations of Zn²⁺ and Cd²⁺, the bioavailable forms of these two metals to …

Variations In Synechococcus Cell Quotas Of Phosphorus, Sulfur, Manganese, Iron, Nickel, And Zinc Within Mesoscale Eddies In The Sargasso Sea, Benjamin S. Twining, Daliangelis Nunez-Milland, Stefan Vogt, Rodney S. Johnson, Peter N. Sedwick

OES Faculty Publications

The quotas of P, S, Mn, Fe, Ni, and Zn in individual Synechococcus cells collected from the surface and deep chlorophyll maximum (DCM) layer of three mesoscale eddies in the Sargasso Sea were measured using synchrotron X-ray fluorescence microscopy. Cells in a mode-water eddy had significantly higher P (57 +/- 10 amol) and Mn (28 +/- 7 zmol) cell quotas than cells collected from a cyclone (22 +/- 2 amol and 10 +/- 1 zmol, respectively) or anticyclone (25 +/- 3 amol and 18 +/- 3 zmol, respectively). Conversely, Ni and Zn quotas were significantly higher in the cells from …

Trace Metal Biogeochemistry In The Western North Pacific, Peter Lynn Morton

OES Theses and Dissertations

Dissolved and suspended particulate samples collected during the Intergovernmental Oceanographic Commission 2002 Contaminant Baseline Survey were analyzed to determine the surface and vertical distributions of Cd, Co, Cu, Mn, Ni Zn and Pb across the western and central North Pacific.

Dissolved trace metal concentrations were measured using a novel isotope dilution-ICP-MS method after extraction over an 8-hydroxyquinoline resin column and validated through the use of the SAFe consensus reference materials. Filtered suspended particulate matter was digested using an HCl/HNO3/HF mixture and analyzed by HR-ICP-MS to obtain total particulate concentrations for the trace metals and other tracer elements such as Al, …

Ancient Dna Analyses Exclude Humans As The Driving Force Behind Late Pleistocene Musk Ox (Ovibos Moschatus) Population Dynamics, Paula F. Campos, Eske Willerslev, Andrei Sher, Ludovic Orlando, Erik Axelsson, Alexei Tikhonov, Kim Aaris-Sorensen, Alex D. Greenwood, Ralf-Dietrich Kahlke, Pavel Kosintsev

Biological Sciences Faculty Publications

The causes of the late Pleistocene megafaunal extinctions are poorly understood. Different lines of evidence point to climate change, the arrival of humans, or a combination of these events as the trigger. Although many species went extinct, others, such as caribou and bison, survived to the present. The musk ox has an intermediate story: relatively abundant during the Pleistocene, it is now restricted to Greenland and the Arctic Archipelago. In this study, we use ancient DNA sequences, temporally unbiased summary statistics, and Bayesian analytical techniques to infer musk ox population dynamics throughout the late Pleistocene and Holocene. Our results reveal …

Benthic Ecology From Space: Optics And Net Primary Production In Seagrass And Benthic Algae Across The Great Bahama Bank, Heidi M. Dierssen, Richard C. Zimmerman, Lisa A. Drake, David J. Burdige

OES Faculty Publications

Development of repeatable and quantitative tools are necessary for determining the abundance and distribution of different types of benthic habitats, detecting changes to these ecosystems, and determining their role in the global carbon cycle. Here we used ocean color remote sensing techniques to map different major groups of primary producers and estimate net primary productivity (NPP) across Great Bahama Bank (GBB). Field investigations on the northern portion of the GBB in 2004 revealed 3 dominant types of benthic primary producers: seagrass, benthic macroalgae, and microalgae attached to sediment. Laboratory measurements of NPP ranged from barely net autotrophic for grapestone sediment …

A Seasonal Study Of Dissolved Cobalt In The Ross Sea, Antarctica: Micronutrient Behavior, Absence Of Scavenging, And Relationships With Zd, Cd, And P., M. A. Saito, T. J. Goepfert, A. E. Noble, E. M. Bertrand, Peter N. Sedwick, Giacomo R. Ditullio

OES Faculty Publications

We report the distribution of cobalt (Co) in the Ross Sea polynya during austral summer 2005-2006 and the following austral spring 2006. The vertical distribution of total dissolved Co (dCo) was similar to soluble reactive phosphate (PO(4)(3-)), with dCo and PO(4)(3-) showing a significant correlation throughout the water column (r(2) = 0.87, 164 samples). A strong seasonal signal for dCo was observed, with most spring samples having concentrations ranging from similar to ~ 45-85 pM, whereas summer dCo values were depleted below these levels by biological activity. Surface transect data from the summer cruise revealed concentrations at the low range …

On The Fractional Solubillity Of Copper In Marine Aerosols: Toxicity Of Aeolian Copper Revisited, Edward R. Sholkovitz, Peter N. Sedwick, Thomas M. Church

OES Faculty Publications

Paytan et al. (2009) argue that the atmospheric deposition of aerosols lead to copper concentrations that are potentially toxic to marine phytoplankton in a large area of tropical and subtropical North Atlantic Ocean. A key assumption in their model is that all marine aerosols (mineral dust and anthropogenic particles) have a high (40%) fractional solubility of copper. Our data show that the fractional solubility of copper for Saharan dust over the Sargasso Sea and Bermuda is significantly lower (1-7%). In contrast, anthropogenic aerosols with non-Saharan sources have significantly higher values (10-100%). Hence, the potential Cu toxicity in the tropical and …

The Widespread Occurrence Of Coupled Carbonate Dissolution/Reprecipitation In Surface Sediments On The Bahamas Bank, David J. Burdige, Xinping Hu, Richard C. Zimmerman

OES Faculty Publications

Using two complimentary approaches (pore water advection/diffusion/reaction modeling and stable isotope mass balance calculations) we show that carbonate dissolution/reprecipitation occurs on early diagenetic time scales across a broad range of sediments on the Great Bahamas Bank. The input of oxygen into the sediments, which strongly controls sediment carbonate dissolution, has two major sources belowground input by seagrasses (that is, seagrass O₂ pumping), and permeability-driven advective pore water exchange. The relative importance of these O₂ delivery mechanisms depends on both seagrass density, and on how bottom water flow interacts with the seagrass canopy and leads to this advective exchange. …

Causes Of Tropical Atlantic Paleo-Salinity Variation During Periods Of Reduced Amoc, Xiuquan Wan, Ping Chang, Matthew W. Schmidt

OES Faculty Publications

During periods of reduced Atlantic meridional overturning circulation (AMOC) associated with a freshening of northern North Atlantic surface water, paleo proxy records indicate a corresponding surface salinity increase over the entire tropical Atlantic. Although latitudinal-shifts in the mean position of the Atlantic Intertropical Convergence Zone (ITCZ) can explain certain features of the paleo salinity reconstructions, this mechanism does not offer an explanation for the reconstructed basin-wide paleo-salinity response to AMOC change. Here, we present new results from general circulation model simulations that suggest the sea surface salinity (SSS) increase in the tropical north Atlantic during periods of weakened AMOC is …

Reactivity And Chemical Characterization Of Dissolved Organic Matter In An Estuary, Hussain A. Abdulla

OES Theses and Dissertations

This dissertation used Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance spectroscopy (¹³C-NMR) data to quantify the changes of major chemical compound classes in high molecular weight (HMW, >1kDa) DOM isolated along a transect from Great Dismal Swamp through the Elizabeth River/Chesapeake Bay system to the coastal Atlantic Ocean off Virginia, USA. Results show that both carboxylic acids and aromatic compounds are lost along the transect, while amide, and carbohydrate moieties could have a mid-transect source.

Addressing the seasonal and spatial changes in the chemical composition of high molecular weight DOM using C/N ratio and δ^{13 …}

A Bio-Optical Model For Syringodium Filiforme Canopies, Margaret A. Stoughton

OES Theses and Dissertations

Seagrasses are significant ecological and biogeochemical agents in shallow water ecosystems throughout the world. In many regions, seagrass meadows occupy a sufficient fraction of the coastal zone, and generate optical signatures that can be observed from space. Bio-optical models of light absorption and scattering by submerged plant canopies for certain species such as Thalassia testudinum and Zostera marina have successfully modeled the plane irradiance distribution and photosynthesis within the submerged canopies. Syringodium filiforme differs &om T. testudinttm and Z marina, in leaf morphology and canopy architecture. The objective of this study was to develop a radiative transfer model that …

Optics And Remote Sensing Of Bahamian Carbonate Sediment Whitings And Potential Relationship To Wind-Driven Langmuir Circulation, H. M. Dierssen, Richard C. Zimmerman, David J. Burdige

OES Faculty Publications

Regions of milky white seas or "whitings" periodically occur to the west of Andros Island along the Great Bahama Bank where the bottom sediment consists of fine-grained aragonite mud. We present measurements of inherent optical properties within a sediment whiting patch and discuss the potential for monitoring the frequency, extent, and quantity of suspended matter from ocean colour satellite imagery. Sea spectral reflectance measured in situ and remotely from space revealed highly reflective waters elevated across the visible spectrum (i.e., "whitened") with a peak at 490 nm. Particulate backscattering was an order of magnitude higher than that measured at other …

Variations In Sea Surface Roughness Induced By The 2004 Sumatra-Andaman Tsunami, O. A. Godin, V. G. Irisov, R. R. Leben, B. D. Hamlington, G. A. Wick

CCPO Publications

Observations of tsunamis away from shore are critically important for improving early warning systems and understanding of tsunami generation and propagation. Tsunamis are difficult to detect and measure in the open ocean because the wave amplitude there is much smaller than it is close to shore. Currently, tsunami observations in deep water rely on measurements of variations in the sea surface height or bottom pressure. Here we demonstrate that there exists a different observable, specifically, ocean surface roughness, which can be used to reveal tsunamis away from shore. The first detailed measurements of the tsunami effect on sea surface height …

Southern Ocean Globec Research And The Future, Eileen Hofmann

CCPO Publications

(First paragraph) The International Global Ocean Ecosystems Dynamics (GLOBEC) Programme will end in early 2010, after almost 20 years. GLOBEC science has provided fundamental changes in our understanding of the scales of interactions in marine ecosystems, alternative views of marine food webs, and the influence of humans in marine ecosystem processes. Since Southern Ocean GLOBEC (SO GLOBEC) was one of the regional research programmes it is appropriate to reflect on i) its specific contributions, ii) how these might guide future Southern Ocean research, and iii) the key gaps for our future understanding of Southern Ocean ecosystems and the impact that …

Photochemical Degradation Of Dissolved Organic Matter And Dissolved Lignin Phenols From The Congo River, Robert G. M. Spencer, Aron Stubbins, Peter J. Hernes, Kenneth Mopper, Anthony K. Aufdenkampe, Rachael Y. Dyda, Vincent L. Mwamba, Arthur M. Mangangu, Jose N. Wabakanghanzi, Johan Six

Chemistry & Biochemistry Faculty Publications

Photochemical degradation of Congo River dissolved organic matter (DOM) was investigated to examine the fate of terrigenous DOM derived from tropical ecosystems. Tropical riverine DOM receives greater exposure to solar radiation, particularly in large river plumes discharging directly into the open ocean. Initial Congo River DOM exhibited dissolved organic carbon (DOC) concentration and compositional characteristics typical of organic rich blackwater systems. During a 57 day irradiation experiment, Congo River DOM was shown to be highly photoreactive with a decrease in DOC, chromophoric DOM (CDOM), lignin phenol concentrations (Σ8) and carbon-normalized yields (Λ8), equivalent to losses of ~45, 85–95, >95 and …