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Articles 151 - 180 of 423
Full-Text Articles in Earth Sciences
Evaluating Seasonal Nutrient Fluxes In Emerging And Eroding Wetlands Of The Louisiana Delta Plain, Kiran Upreti
Evaluating Seasonal Nutrient Fluxes In Emerging And Eroding Wetlands Of The Louisiana Delta Plain, Kiran Upreti
LSU Doctoral Dissertations
Deltaic wetlands can ameliorate high NO3- loads via denitrification, a dominant NO3- reduction pathway in inland and coastal habitats. Dissimilatory Nitrate Reduction to Ammonia (DNRA), in contrast to denitrification, conserves N within the system and has been found to be favored over denitrification with increase in salinity and temperature. There are no studies in the Louisiana Deltaic plain with simultaneous estimation of denitrification and DNRA. Increased P availability has been shown to increase denitrification so it is essential to understand P biogeochemistry when studying N cycle. Here, we evaluated net denitrification using N2:Ar and …
In Situ Geochemistry Of Middle Ordovician Dolomites Of The Upper Mississippi Valley, Achim D. Herrmann
In Situ Geochemistry Of Middle Ordovician Dolomites Of The Upper Mississippi Valley, Achim D. Herrmann
Faculty Publications
The dolomitization and diagenetic history of Ordovician carbonates of southern Wisconsin is complex. Previous studies attributed dolomitization to various diagenetic factors and environments. In this study, high-resolution, in situ laser ablation inductively coupled mass spectrometry analysis of rare earth element patterns of dolomite was used to assess the diagenetic fluids responsible for dolomitization of the Ordovician Decorah Formation. Integrated geochemical data and petrographic evidence suggest that the dolostones are formed in two different diagenetic realms: shallow burial and hydrothermal. Shallow burial dolomites exhibit three distinct rare earth element patterns. Dolomite from the middle portion of the Guttenberg Member exhibits light …
Monitoring Sediment Dynamics And Vegetation Competition Based On Micro-Topography And Terrestrial Lidar For Wetland Restoration, Xukai Zhang
LSU Doctoral Dissertations
With the ability to attenuate wave and limit erosion, coastal wetlands are important to protect shoreline for coastal communities. Micro-topography in coastal wetlands has a significant influence on hydrology, habitat variability and ecosystem functions. However, when mapping micro-topography by terrestrial LiDAR in coastal environments, the coverage of dense vegetation leads to a relatively low chance of laser penetration through the canopy to the ground. This dissertation proposes a rapid and flexible terrain mapping solution for the densely vegetated coastal environment by integrating crown structure from terrestrial LiDAR with terrain samples from GPS. The validated results in the study site demonstrate …
Short Communication: The Topographic Analysis Kit (Tak) For Topotoolbox, Adam M. Fortes
Short Communication: The Topographic Analysis Kit (Tak) For Topotoolbox, Adam M. Fortes
Faculty Publications
Quantitative analysis of digital topographic data is an increasingly important part of many studies in the geosciences. Initially, performing these analyses was a niche endeavor, requiring detailed domain knowledge and programming skills, but increasingly broad, flexible, open-source code bases have been developed to increasingly democratize topographic analysis. However, many of these analyses still require specific computing environments and/or moderate levels of knowledge of both the relevant programming language and the correct way to take these fundamental building blocks and conduct an efficient and effective topographic analysis. To partially address this, we have written the Topographic Analysis Kit (TAK), which leverages …
A Multi-Proxy Approach To Refining Paleotempestology Records On The Northern Gulf Of Mexico Coast, Marianne Elizabeth Dietz
A Multi-Proxy Approach To Refining Paleotempestology Records On The Northern Gulf Of Mexico Coast, Marianne Elizabeth Dietz
LSU Doctoral Dissertations
Reconstructing pre-historic hurricane activity is typically accomplished through the analysis of sandy overwash deposits identified in coastal lake settings. This method has been used successfully in many parts of the world and can extend the hurricane record thousands of years into the past. However, this approach also has its limitations. This dissertation addresses some of the limitations associated with geologic proxies used to reconstruct hurricane landfalls in the absence of historic data and tests new proxies for the identification of hurricane-derived overwash deposits. Modern storm deposits from two sites on the northern Gulf of Mexico coast are analyzed in detail …
An Evaluation Of Modified Bed Load Sediment Transport Equations For Enhanced Sediment Transport Quantification In Steep Mountain Streams – Case Study Little Fountain Creek, Colorado Springs, Co., James Emerson Smith Iv
An Evaluation Of Modified Bed Load Sediment Transport Equations For Enhanced Sediment Transport Quantification In Steep Mountain Streams – Case Study Little Fountain Creek, Colorado Springs, Co., James Emerson Smith Iv
LSU Master's Theses
In mountainous regions, extreme floods occur every year, placing societies and infrastructures at risk. Communities rely on local, state, and federal agencies to emplace flood structures, perform flood risk assessments, and simulate catastrophic events. While, our ability to quantify and predict the movement of sediment in streams with low gradients is well developed (Bathurst, 1987), our ability to quantify and predict the movement of sediment along steep mountain streams (SMS) has not been developed to a similar degree (Yager, 2012; Schneider, 2016). To most effectively manage mountainous watersheds and understand the risk associated with flood events, scientists must better understand …
Analysis Of Fluvial Scroll Bar Development With Surface Wave Inversion: False River, Louisiana, Blake Odom
Analysis Of Fluvial Scroll Bar Development With Surface Wave Inversion: False River, Louisiana, Blake Odom
LSU Master's Theses
The development of ridge-and-swale scroll bar topography of meandering river point bars is not well understood. We hypothesize that scroll bars formed during lateral accretion by the landward migration of transverse bars. To explore this, we relate the scroll bar topography to the internal sedimentary structure. We acquire, invert, and interpolate three pseudo-2D shear wave velocity profiles in two regions of the False River point bar, a Mississippi river oxbow lake in Pointe Coupee Parish Louisiana. Prior studies provide electrical conductivity well logs and cores as well as SH seismic reflection images along the same seismic surveys. LiDAR elevation data …
New Borehole Breakout Derived Stress Constraints And Their Implications For Stress Heterogeneity Near High Risk Fault Systems In The Santa Barbara Channel, Southern California, Edward Harris Pritchard
New Borehole Breakout Derived Stress Constraints And Their Implications For Stress Heterogeneity Near High Risk Fault Systems In The Santa Barbara Channel, Southern California, Edward Harris Pritchard
LSU Master's Theses
The Santa Barbara Channel represents the offshore portion of the Ventura Basin in Southern California. Ongoing transpression related to a regional left step in the San Andreas Fault has led to the formation of E-W trending en-echelon fault systems, with both north and south dips, which accommodate varying rates of localized shortening across the basin. Recent studies have suggested that faults within the northern region of the channel could be capable of a multisegment rupture and producing a Mw 7.7–8.1 tsunamigenic earthquake. However, dynamic rupture models producing these results have not accounted for stress heterogeneity, which is …
Three-Dimensional Flow, Morphologic Change, And Sediment Deposition And Distribution Of Actively Evolving Neck Cutoffs Located On The White River, Arkansas, Derek Allen Richards
Three-Dimensional Flow, Morphologic Change, And Sediment Deposition And Distribution Of Actively Evolving Neck Cutoffs Located On The White River, Arkansas, Derek Allen Richards
LSU Doctoral Dissertations
Neck cutoffs are important and prominent features of alluvial rivers yet detailed field-based research of neck cutoffs has been insufficient to fully characterize three-dimensional flow, morphologic change, and sediment deposition and distribution. The main objectives of this research are to examine the formation and evolution of neck cutoffs by characterizing the flow field, morphology, and sediment distribution through neck cutoffs with complex planform configurations located on the White River, Arkansas. Results led to the production of two conceptual models. The flow model has main hydrodynamic characteristics of (1) tight bend flow resulting from flow redirection of nearly 180° through the …
A Regional Survey Of River-Plume Sedimentation On The Mississippi River Delta Front, Andrew J. Courtois
A Regional Survey Of River-Plume Sedimentation On The Mississippi River Delta Front, Andrew J. Courtois
LSU Master's Theses
Many studies of the Mississippi River Delta (MRD) have shown historic declines in sediment load over the last few decades. Recent studies also reported that ~50% of the suspended load during floods is sequestered within the delta. While the impact of declining sediment load on wetland loss is relatively well documented, submarine sedimentary processes on the delta front during this recent period of are understudied. To better understand modern sediment dispersal and deposition across the Mississippi River Delta Front, 31 multicores were collected in June 2017 from locations extending offshore from the main river outlets in water depths of 25-280 …
The Sedimentology And Origins Of A Giant Mass Transport Complex: The Nataraja Slide, Arabian Sea, Sarah Dailey
The Sedimentology And Origins Of A Giant Mass Transport Complex: The Nataraja Slide, Arabian Sea, Sarah Dailey
LSU Master's Theses
A giant mass transport complex (MTC) was recently discovered in the eastern Arabian Sea exceeding in volume all but one other known complex on passive margins worldwide. The complex, named the Nataraja Slide, was drilled by IODP Expedition 355 in two locations where it is ~300 m (Site U1456) and ~200 m thick (Site U1457). The top is defined by the presence of both reworked microfossil assemblages and deformation structures, such as folding and faulting. The deposit consists of two main phases of mass wasting, each which consists of smaller pulses, with generally fining upward cycles, all emplaced just prior …
High-Dimensional Isotope Relationships, Yuyang He
High-Dimensional Isotope Relationships, Yuyang He
LSU Doctoral Dissertations
High-dimensional isotope relationships describes the relationships of two or more element or position-specific (PS) elements in the same molecule or ion. It provides us more powerful tools to study reaction mechanisms and dynamics. Chapter 1 is about dual or multiple stable isotope relationship on δ-δ (or δ'-δ') space. While temporal data sampled from a closed-system can be treated by a Rayleigh Distillation Model (RDM), spatial data should be treated by a Reaction-Transport Model (RTM). Here we compare the results of a closed-system RDM to a RTM for systems with diffusional mass transfer by simulating the trajectories on nitrate's δ'18 …
Effects Of Natural And Anthropogenic Forcing On Marsh Channel Evolution, Jeremiah Robinson
Effects Of Natural And Anthropogenic Forcing On Marsh Channel Evolution, Jeremiah Robinson
LSU Master's Theses
Wetlands have many ecological and physical properties that are essential for coastal communities. These ecosystems sustain local economies, provide essential habitats, are a source of numerous ecological and biological services, and protect coastal populations from storms. Of the many wetland types, salt marshes are among the most vulnerable to environmental changes. Salt marshes quickly respond to natural and human-driven perturbations and their high rate of loss in the last century is cause for concern.
In this project the rate of marsh loss driven by channel widening was measured through a comparative analysis of modern high resolution images and historic aerial …
Predicting River Stage Using Recurrent Neural Networks, Eric Rohli
Predicting River Stage Using Recurrent Neural Networks, Eric Rohli
LSU Master's Theses
River stage prediction is an important problem in the water transportation industry. Accurate river stage predictions provide crucial information to barge and tow boat operators, port terminal captains, and lock management officials. Shallow river levels caused by prolonged drought impact the loading capacity of barges and tow boats. High river levels caused by excessive rainfall or snowmelt allow for greater tow capacities but make downstream transportation and lock management risky. Current academic river height prediction systems utilize either time series statistical analysis or machine learning algorithms to forecast future river heights, but systems that combine these two areas often limit …
Groundwater And Thermal Legacy Of A Large Paleolake In Taylor Valley, East Antarctica As Evidenced By Airborne Electromagnetic And Sedimentological Techniques, Krista Falcon Myers
Groundwater And Thermal Legacy Of A Large Paleolake In Taylor Valley, East Antarctica As Evidenced By Airborne Electromagnetic And Sedimentological Techniques, Krista Falcon Myers
LSU Master's Theses
During the Last Glacial Maximum, grounded ice in the Ross Sea extended into the otherwise ice-free McMurdo Dry Valleys, creating a series of large ice dammed paleolakes. Grounded ice within the mouth of Taylor Valley allowed for lake levels to reach elevations not possible at modern day and formed what is known as Glacial Lake Washburn (GLW). GLW extended from the eastern portion of Taylor Valley roughly 20 km west to a level ~300 m higher than modern day Lake Fryxell. The formation and existence of GLW has been debated, though previous studies correlate the timing of GLW with early …
Spatial Trends And Variability Of Marsh Accretion Rates In Barataria Basin, Louisiana, Usa Using 210pb And 137cs Radiochemistry, Samuel Bryant Shrull
Spatial Trends And Variability Of Marsh Accretion Rates In Barataria Basin, Louisiana, Usa Using 210pb And 137cs Radiochemistry, Samuel Bryant Shrull
LSU Master's Theses
Coastal Louisiana is presently experiencing large amounts of coastal land loss with estimated rates exceeding 50 km2 lost per year. In an attempt to mitigate or reverse land loss, billions of dollars are earmarked for restoration projects that promote land reclamation, habitat stabilization, and defending against saline intrusion. This study was performed in an effort to better understand spatial trends of accretion rates in Barataria Basin in coastal Louisiana. Data for this project came from twenty-five shallow cores extracted over a broad span of the entire basin, from freshwater to saline environments. Cores were processed for 137Cs and …
Glyphosate In Soils: Retention, Transport, And Effect Of Phosphate, Joshua Padilla
Glyphosate In Soils: Retention, Transport, And Effect Of Phosphate, Joshua Padilla
LSU Master's Theses
Glyphosate [N-(phosphonomethyl) glycine)] (GPS) is currently the most commonly used herbicide worldwide, and is generally considered as immobile in soils. However, numerous reports of the environmental occurrence of the herbicide coupled with recent evidence of human toxicity require further investigation as to the behavior of GPS in the soil environment. The objectives of this study were to quantify GPS sorption and mobility in two Louisiana agricultural soils with varying physiochemical properties; Commerce silt loam and Sharkey clay. Results of batch sorption studies indicated a high affinity of both soils for solvated GPS, with 24-hour Freundlich partitioning coefficients of 158 and …
Joint Geodetic And Seismic Analysis Of Englacial And Subglacial Hydraulic Effects On Surface Crevassing Near A Seasonal, Glacier-Dammed Lake On Gornergletscher, Switzerland, Louis Stephen Garcia
Joint Geodetic And Seismic Analysis Of Englacial And Subglacial Hydraulic Effects On Surface Crevassing Near A Seasonal, Glacier-Dammed Lake On Gornergletscher, Switzerland, Louis Stephen Garcia
LSU Master's Theses
Glacial outburst floods are difficult to predict and threaten human life. These events are characterized by rapid draining of glacier-dammed lakes via the sub/englacial hydraulic network to the proglacial stream. The glacier-dammed lake on Gornergletscher in Switzerland, which fills and drains each summer, provides an opportunity to study this hazard. For three drainages (2004, 2006, and 2007), icequakes (IQ) are tracked as well as on-ice GPS movement. The seasonal seismic networks had 8 – 24 three-component stations and apertures of about 300 – 400 m on the glacier surface. The seasonal GPS arrays contained 4 – 8 GPS antennae on …
A Novel Multiproxy Approach To Reconstructing Sea Surface Temperature In The Southwestern Gulf Of Mexico, Marissa Anne Vara
A Novel Multiproxy Approach To Reconstructing Sea Surface Temperature In The Southwestern Gulf Of Mexico, Marissa Anne Vara
LSU Master's Theses
Coral Sr/Ca is a widely-used proxy for sea surface temperature (SST); however, discrepancies in the coral Sr/Ca-SST relationship among colonies of the same species makes uncertainty in absolute temperature reconstructions larger than the climate signal yet climate variability studies are possible. Furthermore, the riverine input of terrestrial carbonate weathering products to the coastal waters can disrupt the coral Sr/Ca-SST signal by changing local seawater chemistry. This study evaluates the fidelity and reproducibly of coral SST proxies (Sr/Ca, Li/Ca, Mg/Li, Sr-U, Mg/Ca, and U/Ca) and a riverine-upwelling proxy (Ba/Ca) in four Orbicella faveolata colonies in two reefs offshore from Veracruz, Mexico …
Micropaleontological Record Of A Preserved, Late Pleistocene Bald Cypress Forest On The Northern Gulf Of Mexico Inner Shelf, Jonathan Thien Truong
Micropaleontological Record Of A Preserved, Late Pleistocene Bald Cypress Forest On The Northern Gulf Of Mexico Inner Shelf, Jonathan Thien Truong
LSU Master's Theses
A cluster of previously buried Taxodium distichum stumps are exposed and preserved in growth position at the bottom of a trough on the inner Gulf of Mexico (GOM) continental shelf in 18 m water depth and 13 km offshore Orange Beach, AL. Radiocarbon ages from wood and optically stimulated luminescence (OSL) dating of sediments suggest a Marine Isotope Stage (MIS) 3 age, or older. This study builds on the previous work of Gonzalez (2018) and Obeclz (2017). Five biofacies were identified in vibracore collected in 2015 and 2016: 1) the Holocene Mississippi-Alabama-Florida (MAFLA) sand sheet, 2) a Holocene interbedded sand …
Reconstruction Of Antarctic Cenozoic Paleoenvironments Through Palynological Analysis Of Subglacial Lake And Ice Stream Sediments, Patrick Baudoin
Reconstruction Of Antarctic Cenozoic Paleoenvironments Through Palynological Analysis Of Subglacial Lake And Ice Stream Sediments, Patrick Baudoin
LSU Master's Theses
The West Antarctic Ice Sheet (WAIS), with a large portion being grounded below sea level, is historically known for its instability. Timing and evaluating the magnitude of WAIS advance and retreat is essential to improve our understanding of control mechanisms. The scarcity of accessible subglacial geology in areas such as the Siple Coast in West Antarctica limits our understanding and ability to gauge WAIS response to environmental changes. To evaluate the ice-sheet history around the Siple Coast, i.e., when it was last covered by vegetation, access to sediment immediately below the ice-sheet is essential. In the absence of large-scale drilling, …
Investigating Trace Metal Sequestration Of Reducing Environments In Modern And Ancient Settings, Adam Charles Turner
Investigating Trace Metal Sequestration Of Reducing Environments In Modern And Ancient Settings, Adam Charles Turner
LSU Doctoral Dissertations
The incorporation of trace metals into a variety of reducing sediments are important proxies for the oxic state of the water mass in which the sediments form. While much work has been done interpreting these proxies, questions remain on the exact processes and products in which trace metal proxies form. This work employs bulk geochemical techniques to investigate circulation in the Late Pennsylvanian North American Midcontinent Sea (NAMS), and then uses sequential extractions to further understand the chemical phases in which trace metals are incorporated. Sequential extractions are then used to further investigate how trace metals are sequestered in modern …
Stratigraphic Reconstruction Of A Late Pleistocene Bald Cypress Forest Discovered On The Northern Gulf Of Mexico Continental Shelf, Suyapa Michell Gonzalez Rodriguez
Stratigraphic Reconstruction Of A Late Pleistocene Bald Cypress Forest Discovered On The Northern Gulf Of Mexico Continental Shelf, Suyapa Michell Gonzalez Rodriguez
LSU Master's Theses
A previously buried bald cypress forest (Taxodium distichum) was discovered on the continental shelf, offshore of Orange Beach, Alabama, USA, in ~20 m water depth. The forest was exhumed by Hurricane Ivan in 2004, and is now exposed as stumps in life position in a trough located in the northern Gulf of Mexico continental shelf seafloor. We are investigating the local stratigraphy, paleo-landscape, and mode of forest preservation of this unique site. In August 2015 and July 2016, submersible vibracores (18 in total) were collected. Core analysis included: bulk density and imaging via Geotek multi sensor core logger, …
Investigating Uranium Incorporation In Modern Carbonates By Sequential Extraction: Applied To The Permian - Triassic Boundary In Lung Cam, Vietnam, Christopher Michael Wray
Investigating Uranium Incorporation In Modern Carbonates By Sequential Extraction: Applied To The Permian - Triassic Boundary In Lung Cam, Vietnam, Christopher Michael Wray
LSU Master's Theses
The Uranium (U) isotopic system can be used to model the extent of global-scale ocean anoxia by utilizing the 238U/235U ratios as a paleo-redox indicator (δ238U). While recent studies have shown promise with the use of this novel proxy, variability is seen in modern carbonate sediment samples suggesting that more work is needed in order to understand elemental U uptake during early marine diagenesis. This thesis utilizes a sequential extraction methodology in order to understand the distribution of authigenic U within carbonate sediments.
This thesis consists of four parts, (1) an evaluation and modification of a sequential extraction methodology for …
Vertical Sediment Accretion In Jamaica Bay Wetlands, New York, Ryan Christopher Clarke
Vertical Sediment Accretion In Jamaica Bay Wetlands, New York, Ryan Christopher Clarke
LSU Master's Theses
Over the last century, ~60% of the saltmarsh wetlands in Jamaica Bay (in the Gateway National Recreation Area of the Greater New York City region) have been converted to intertidal or subtidal unvegetated mudflats and projections suggest that all of Jamaica Bay’s saltmarsh wetlands may disappear within the next two decades. After landfall of Hurricane Sandy in 2012 and to better understand environmental controls on the maintenance of the remaining Jamaica Bay wetlands, cores were collected from twelve saltmarsh locations in the bay to study the chronology of wetland vertical accretion and mineral sediment accumulation. In association with the United …
Sh-Wave Seismic Reflection Imaging And Inversion: An Analysis Of Architectural And Physical Properties Of A Near-Surface Point-Bar, Nathan William Benton
Sh-Wave Seismic Reflection Imaging And Inversion: An Analysis Of Architectural And Physical Properties Of A Near-Surface Point-Bar, Nathan William Benton
LSU Master's Theses
Both architecture and physical properties of near-surface point-bar sediment packages have not be imaged or analyzed via SH-wave seismic reflection surveying, respectively. Point-bar architecture within near-surface environments characterized by conductive, saturated, and/or unconsolidated sediments cannot be well-imaged with other remote sensing methods compared to the SH-wave seismic reflection surveying method. The physical properties that distinguish different point-bar sediment packages are variably altered during early-stage diagenetic processes such as compaction and dewatering, thereby changing SH-wave seismic velocities and subsequently shear impedance of different sediment packages. This study accomplishes two objectives by acquiring, processing, and inverting seismic reflection data from two surveys …
Topographic Control On Post-Lgm Groundings Of The West Antarctic Ice Sheet In The Whales Deep Basin, Eastern Ross Sea, Matthew Danielson
Topographic Control On Post-Lgm Groundings Of The West Antarctic Ice Sheet In The Whales Deep Basin, Eastern Ross Sea, Matthew Danielson
LSU Master's Theses
By the peak of the Last Glacial Maximum (LGM), the West Antarctic Ice Sheet (WAIS) had advanced to the outer continental shelf of eastern Ross Sea trough basins. During the post-LGM retreat, the WAIS paused several times within 75 km of the Whales Deep Basin (WDB) shelf edge. An overlapping stack of seven grounding zone wedges (GZWs) records the locations of these groundings. Here we used ~7500 km of seismic reflection data to map the subglacial unconformity that was eroded when WAIS was grounded at the shelf edge, i.e., prior to the deposition of the backstepping GZWs. With respect to …
Signal Propagation, Provenance, And Climate Records In The Indus Submarine Canyon Since The Last Deglacial, Yuting Li
LSU Doctoral Dissertations
The Monsoon is one of the most powerful climatic phenomena on Earth and controls environments in South Asia. Erosion and weathering patterns are influenced by monsoon variations and can be reconstructed through marine sediment records. However, such reconstruction is based on the assumption that such sediments are representative of the onshore basins from which they are sourced. Debate continues regarding the degree to which storage and recycling homogenize short-term variations in sediment compositions. The Indus Submarine Canyon links the river mouth and the deep-water fan of the Indus drainage system. Determining how sediment fluxes through this canyon is important if …
Sediment And Plant Dynamics In A Degrading Coastal Louisiana Landscape, Glenn Michael. Suir
Sediment And Plant Dynamics In A Degrading Coastal Louisiana Landscape, Glenn Michael. Suir
LSU Doctoral Dissertations
Alterations to Louisiana’s river systems and local hydrology have resulted in reduced freshwater, sediment, and nutrient inputs into wetland landscapes, causing significant negative impacts on marsh productivity and stability. To combat these losses many restoration projects have been constructed or planned throughout coastal Louisiana. Typical goals of wetland restoration efforts are to conserve, create, or enhance wetland form, and to achieve wetland function that approaches natural conditions. Failure to adequately maintain wetland elevation and hydrology can have serious implications on sedimentation and vegetation processes, which significantly reduces the likelihood of reaching structural and functional targets. Measures of wetland condition have …
Legacy Contaminants In The Northern Gulf Of Mexico Shelf, Jessica N. Landry
Legacy Contaminants In The Northern Gulf Of Mexico Shelf, Jessica N. Landry
LSU Master's Theses
The Mississippi River watershed is the third largest in the world and drains from 31 states in the United States. Due to its route through the U.S., it passes through hundreds of EPA labeled Superfund sites as well as agricultural and suburban watersheds. These sites are known to have historical chemical contamination, and as a result chemicals can be transported by runoff down the Mississippi River into the Gulf of Mexico where their ultimate fate is unknown. Organochlorine chemicals are known to be persistent and are found in agricultural land as well as US EPA Superfund sites, especially DDT, PCBs, …