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Articles 751 - 780 of 1935
Full-Text Articles in Earth Sciences
Changing Depositional Environments In An Upper Ordovician Stratigraphic Sequence, Ashlock Formation, Madison County, Kentucky, Kevin G. Greff, Walter S. Borowski
Changing Depositional Environments In An Upper Ordovician Stratigraphic Sequence, Ashlock Formation, Madison County, Kentucky, Kevin G. Greff, Walter S. Borowski
EKU Faculty and Staff Scholarship
We investigate the sedimentology, stratigraphy, and depositional environments of a 7-meter, Upper Ordovician limestone sequence cropping out in Richmond, Madison County, Kentucky. The stratigraphic section lies within the Ashlock Formation with good lateral exposure stretching along 200 meters of a highway roadcut. We took approximately 20 samples from the measured section, focusing on representative samples and lithologic transitions. We use standard laboratory procedures in slabbing rock samples and making thin sections.
The Ashlock Formation here consists of alternating layers of limey mudstone and limestone (field units A through F). Megafossils - brachiopods, bryozoans, trilobites, gastropods, ostracodes, coralline algae, and bivalves …
Terrestrialization In The Late Devonian: A Palaeoecological Overview Of The Red Hill Site, Pennsylvania, Usa, Walter L. Cressler Iii, Edward B. Daeschler, Rudy Slingerland, Daniel A. Peterson
Terrestrialization In The Late Devonian: A Palaeoecological Overview Of The Red Hill Site, Pennsylvania, Usa, Walter L. Cressler Iii, Edward B. Daeschler, Rudy Slingerland, Daniel A. Peterson
Earth & Space Sciences Faculty Publications
No abstract provided.
Lacustrine Sediment Record Of Multiple Quaternary Lava Dams On The Owyhee River, Southeastern Oregon, Caitlin Anne Orem
Lacustrine Sediment Record Of Multiple Quaternary Lava Dams On The Owyhee River, Southeastern Oregon, Caitlin Anne Orem
All Master's Theses
Multiple lava dams and correlating lakes impacted the Quaternary evolution of the Owyhee River. Sediment records from lava-dammed lakes were investigated to understand effects of the West Crater (WC) lava dam (~70 ka), the Saddle Butte 2 lava dam (~144 ka), and the Bogus Rim lava dam (~1.9 Ma). Evidence from the WC lava dam and related features indicates that dam duration consisted of five stages (1) dam and lake formation at ~70 ka; (2) dam overflow and lake sedimentation from ~70–46 ka; (3) removal of lava dam and lake termination from ~46 ka to at least 36 ka; (4) …
Provenance Of The Neoproterozoic Ocoee Supergroup, Eastern Great Smoky Mountains, Suvankar Chakraborty
Provenance Of The Neoproterozoic Ocoee Supergroup, Eastern Great Smoky Mountains, Suvankar Chakraborty
University of Kentucky Doctoral Dissertations
The Ocoee Supergroup is a sequence of Neoproterozoic, immature, continental rift facies clastic sediments. Potential source rocks were tested by analyzing modes of detrital framework minerals, detrital mineral chemistry, whole rock geochemistry and detrital zircon U/Pb geochronology by LA-ICP-MS for Ocoee siltstone-sandstone dominated formations. Ocoee units are arkosic to subarkosic siltstones/sandstones, and ternary tectonic discrimination diagrams confirm a continental basement uplift source. Alkali feldspar predominates over plagioclase feldspar. Detrital feldspar compositions of Ocoee sediments as a group are similar to feldspar in local basement granitic rocks except for high-Ca plagioclase grains present locally in basement granitic rocks. The high alkali …
Benthic Ecology From Space: Optics And Net Primary Production In Seagrass And Benthic Algae Across The Great Bahama Bank, Heidi M. Dierssen, Richard C. Zimmerman, Lisa A. Drake, David J. Burdige
Benthic Ecology From Space: Optics And Net Primary Production In Seagrass And Benthic Algae Across The Great Bahama Bank, Heidi M. Dierssen, Richard C. Zimmerman, Lisa A. Drake, David J. Burdige
OES Faculty Publications
Development of repeatable and quantitative tools are necessary for determining the abundance and distribution of different types of benthic habitats, detecting changes to these ecosystems, and determining their role in the global carbon cycle. Here we used ocean color remote sensing techniques to map different major groups of primary producers and estimate net primary productivity (NPP) across Great Bahama Bank (GBB). Field investigations on the northern portion of the GBB in 2004 revealed 3 dominant types of benthic primary producers: seagrass, benthic macroalgae, and microalgae attached to sediment. Laboratory measurements of NPP ranged from barely net autotrophic for grapestone sediment …
Nebraska Statewide Groundwater-Level Monitoring Report 2010, J. T. Korus, M. E. Burbach, L. M. Howard, R. M. Joeckel
Nebraska Statewide Groundwater-Level Monitoring Report 2010, J. T. Korus, M. E. Burbach, L. M. Howard, R. M. Joeckel
Conservation and Survey Division: Faculty and Staff Publications
No abstract provided.
Holdrege: Nebraska's State Soil
Holdrege: Nebraska's State Soil
Conservation and Survey Division: Faculty and Staff Publications
No abstract provided.
An Inventory And Condition Survey Of The Western Australian Part Of The Nullarbor Region, Peter-Jon A. Waddell, A K. Gardner, P Hennig
An Inventory And Condition Survey Of The Western Australian Part Of The Nullarbor Region, Peter-Jon A. Waddell, A K. Gardner, P Hennig
Technical Bulletins
The inventory and condition survey of the Western Australian part of the Nullarbor region, undertaken by the Department of Agriculture and Food, Western Australia (DAFWA) between 2005 and 2007, describes and maps the natural resources of the region. This survey report provides a baseline record of the existence and condition of the area's natural resources, to assist with the planning and implementation of land management practices. The report identified and described the condition of soils, landforms, vegetation, habitat, ecosystems, and declared plants and animals. It also assessed the impact of pastoralism and made land management recommendations. The Nullarbor region has …
Nebraska Grout Task Force In-Situ Study Of Grout Material 2001 - 2006 And 2007 Dye Tests, Susan Olafsen Lackey, Will F. Myers, Thomas C. Christopherson, Jeffrey J. Gottula
Nebraska Grout Task Force In-Situ Study Of Grout Material 2001 - 2006 And 2007 Dye Tests, Susan Olafsen Lackey, Will F. Myers, Thomas C. Christopherson, Jeffrey J. Gottula
Conservation and Survey Division: Faculty and Staff Publications
No abstract provided.
Understanding Paleoclimate And Human Evolution Through The Hominin Sites And Paleolakes Drilling Project, Andrew Cohen, Ramon Arrowsmith, Anna K. Behrensmeyer, Christopher Campisano, Craig Feibel, Shimeles Fisseha, Roy Johnson, Zelalem Bedaso, Charles Lockwood, Emma Mbua, Daniel Olago, Richard Potts, Kaye Reed, Robin Renaut, Jean-Jacques Tiercelin, Mohammed Umer
Understanding Paleoclimate And Human Evolution Through The Hominin Sites And Paleolakes Drilling Project, Andrew Cohen, Ramon Arrowsmith, Anna K. Behrensmeyer, Christopher Campisano, Craig Feibel, Shimeles Fisseha, Roy Johnson, Zelalem Bedaso, Charles Lockwood, Emma Mbua, Daniel Olago, Richard Potts, Kaye Reed, Robin Renaut, Jean-Jacques Tiercelin, Mohammed Umer
Department of Earth, Environment and Sustainability Faculty Publications
Understanding the evolution of humans and our close relatives is one of the enduring scientific issues of modern times. Since the time of Charles Darwin, scientists have speculated on how and when we evolved and what conditions drove this evolutionary story. The detective work required to address these questions is necessarily interdisciplinary, involving research in anthropology, archaeology, human genetics and genomics, and the earth sciences. In addition to the difficult tasks of finding, describing, and interpreting hominin fossils (the taxonomic tribe which includes Homo sapiens and our close fossil relatives from the last 6 Ma), much of modern geological research …
Markov Models For Linking Environments And Facies In Space And Time (Recent Arabian Gulf, Miocene Paratethys), Bernhard Riegl, Samuel J. Purkis
Markov Models For Linking Environments And Facies In Space And Time (Recent Arabian Gulf, Miocene Paratethys), Bernhard Riegl, Samuel J. Purkis
Marine & Environmental Sciences Faculty Books and Book Chapters
This special publication Perspectives in Carbonate Geology is a collection of papers most of which were presented at a symposium to honor the 80th birthday of Bob Ginsburg at the meeting of Geological Society of America in Salt Lake City in 2005. The majority of the papers in this publication are connected with the study of modern carbonate sediments. Bob Ginsburg pioneered the concept of comparative sedimentology - that is using the modern to compare to and relate to and understand the ancient. These studies are concerned with Bob's areas of passion: coral reefs and sea-level; submarine cementation and formation …
Radiocarbon Date List Xi: Radiocarbon Dates From Marine Sediment Cores Of The Iceland, Greenland, And Northeast Canadian Arctic Shelves And Nares Strait, U. Quillmann, J.T. Andrews, A.E. Jennings, J. Bendle, H. Jonsdottir, G.B. Kristjansdottir, J. Lloyd, S. Olafsdottir, Sarah M. Principato
Radiocarbon Date List Xi: Radiocarbon Dates From Marine Sediment Cores Of The Iceland, Greenland, And Northeast Canadian Arctic Shelves And Nares Strait, U. Quillmann, J.T. Andrews, A.E. Jennings, J. Bendle, H. Jonsdottir, G.B. Kristjansdottir, J. Lloyd, S. Olafsdottir, Sarah M. Principato
Environmental Studies Faculty Publications
Radiocarbon Date List XI contains an annotated listing of 178 AMS radiocarbon dates on samples from marine (169 samples) and lake (9 samples) sediment cores. Marine sediment cores, from which the samples for dating were taken, were collected on the Greenland Shelf, Baffin Bay, and the Eastern Canadian Arctic shelf. About 80% of the marine samples for dating were collected on the SW to N Icelandic shelf. The lake sediment cores were collected in northwestern Iceland. For dating of the marine samples, we submitted molluscs (117 samples), benthic and planktic foraminifera (45 samples), plant macrofauna (3 samples), and one serpulid …
Markov Models For Linking Environments And Facies In Space And Time (Recent Arabian Gulf, Miocene Paratethys), Bernhard Riegl, Samuel J. Purkis
Markov Models For Linking Environments And Facies In Space And Time (Recent Arabian Gulf, Miocene Paratethys), Bernhard Riegl, Samuel J. Purkis
Marine & Environmental Sciences Faculty Articles
If, as comparative sedimentology maintains, knowledge of the Recent can sometimes be helpful to explain the past (and vice-versa), common quantitative denominators might exist between Recent and fossil systems. It may also be possible to describe dynamics and find linkages between space and time with a unique set of quantitative tools. To explore such conceptual links, spatial facies patterns mapped using satellite imagery were compared with temporal patterns in analogous ancient outcropping facies using Markov chains and graphs. Landsat and Ikonos satellite imagery was used to map benthic facies in a nearshore carbonate ramp (Ras Hasyan) and offshore platform system …
Eastern Nebraska Water Resources Assessment (Enwra): Introduction To A Hydrogeological Study, Dana Divine, R. Matthew Joeckel, Jesse T. Korus, P.R. Hanson, Sue Olafsen Lackey
Eastern Nebraska Water Resources Assessment (Enwra): Introduction To A Hydrogeological Study, Dana Divine, R. Matthew Joeckel, Jesse T. Korus, P.R. Hanson, Sue Olafsen Lackey
Conservation and Survey Division: Faculty and Staff Publications
No abstract provided.
Pilot Study: The Nature And Thickness Of The Unsaturated Zone And Delineation Of Confined Aquifers, Sue Olafsen Lackey, Les Howard
Pilot Study: The Nature And Thickness Of The Unsaturated Zone And Delineation Of Confined Aquifers, Sue Olafsen Lackey, Les Howard
Conservation and Survey Division: Faculty and Staff Publications
No abstract provided.
Nebraska Statewide Groundwater-Level Monitoring Report 2009, Jesse T. Korus Dr., Mark E. Burbach
Nebraska Statewide Groundwater-Level Monitoring Report 2009, Jesse T. Korus Dr., Mark E. Burbach
Conservation and Survey Division: Faculty and Staff Publications
No abstract provided.
Soil Carbon And Nitrogen Accumulation In A Forested Debris Flow Chronosequence, California, Judith K. Turk, Robert C. Graham
Soil Carbon And Nitrogen Accumulation In A Forested Debris Flow Chronosequence, California, Judith K. Turk, Robert C. Graham
Conservation and Survey Division: Faculty and Staff Publications
The role of forest soils in the biogeochemical cycling of C and N is most dynamic during the early stages of soil development. To define C and N trends that occur with soil development in a mixed coniferous forest, a chronosequence formed by debris flows was studied. The accumulation rates of total organic C (TOC) and total N (TN) were evaluated in soils on 10 debris flow deposits, ranging from depth, since this was the depth of the shallowest debris flows. Carbon was found to accumulate in the organic horizons at a rate of 26.5 g m−2 yr−1 …
Microtextures Of Cyanobacterial Mats In Siliciclastic Sedimentary Environments (Modern & Ancient): Applications To The Search For Life On Mars, Dina M. Bower
OES Theses and Dissertations
The current Mars Exploration Rover Program (MER) is one of NASA's most successful missions. The aim of the MER is to explore for possible life on the surface of Mars. My thesis developed new methods of how to detect and to identify microbial mats in siliciclastic sediments (modern and ancient), and to make recommendations on the applicability of MISS as biosignatures. Predominantly, I employed instrumentation portable by future rovers. To search for life on other planets, we need to have information on how this life might look. Most astrobiological studies therefore focus on Earthly analogues of life and its habitats. …
Records Of Natural Fires And The Sorption Of Polycyclic Aromatic Hydrocarbons (Pahs) By Black Carbon And Carbon Chars In Sediments From Oriole Lake (Sequoia National Park), Kevyn Bollinger
Senior Honors Projects
This project investigates the interaction between Black Carbon and Polycyclic Aromatic Hydrocarbons (PAHs) in lake sediments from Oriole Lake in Sequoia National Park California. The interaction between Black Carbon and PAHs is of interest because little is known with respect to the availability and the time scale within which black carbon adsorbs PAHs in a natural system. Black Carbon and PAHs both will eventually be degraded in the environment but the relevant timescales of sorption and degradation are unknown. Field work for this project was conducted July 16-21, 2007 at Oriole Lake in Sequoia National Park California. Sequoia National Park …
An Ordovician Global Reference Section Recently Selected In Oklahoma, Daniel Goldman, Stephen A. Leslie, Stig M. Bergström, Jaak Nõlvak, Seth A. Young, Stanley C. Finney
An Ordovician Global Reference Section Recently Selected In Oklahoma, Daniel Goldman, Stephen A. Leslie, Stig M. Bergström, Jaak Nõlvak, Seth A. Young, Stanley C. Finney
Department of Earth, Environment and Sustainability Faculty Publications
Ordovician fossil faunas are characterized by a marked biogeographic differentiation that results in a minimal similarity between most North American faunas and those of major Ordovician areas elsewhere in the world. This provincial distribution of most fossils has led to establishment of different schemes of fossil-based regional stages in, for instance, North America, Baltoscandia, China, and the British Isles.
Because these chrono-stratigraphic units have been largely based on shelly fossils with distributions restricted to a particular region, it has been impossible in most cases to establish a precise international correlation of these regional stages. Furthermore, some general terms, such as …
Soil Chemistry Northwest New Mexico, Larry V. Benson
Soil Chemistry Northwest New Mexico, Larry V. Benson
United States Geological Survey: Datasets
These data result from soil chemistry samples extracted from several regions in northwest New Mexico and were used in the following publications:
Larry V. Benson, J. Stein, H. Taylor, R. Friedman, and T. C. Windes. 2006. The agricultural productivity of Chaco Canyon and the source(s) of pre-Hispanic maize found in the Pueblo Bonito Great House. In: J. E. Staller, R. H. Tykot, and B. F. Benz, eds. Histories of Maize: Multidisciplinary Approaches to the Prehistory, Linguistics, Biogeography, Domestication, and Evolution of Maize, 289–314. Elsevier/Academic Press.
Larry V. Benson. 2017. The Chuska Slope as an agricultural alternative to Chaco …
A Stratigraphic And Depositional Interpretation Of A Sand Quarry In Middle Georgia, Jessica Taylor
A Stratigraphic And Depositional Interpretation Of A Sand Quarry In Middle Georgia, Jessica Taylor
Theses and Dissertations
Analysis of sediments from two sand quarries in Mauk, Georgia indicate braided stream environment. Sediment samples of both Pleistocene and Cretaceous age were collected, sedimentary features such as trough cross-bedding along with laminar bedding were recorded, and photos were taken to document the scale and stratigraphic sequences of the sediments. Petrified wood was collected throughout the two sand quarries indicating a terrestrial origin. Post-depositional modifications seen at some of sites include load and flame structures. Sediment samples were examined for grain-size distributions and other sediment textures.
Comparison Of Landslides And Their Related Outburst Flood Deposits, Owyhee River, Southeastern Oregon, Shannon Marian Othus
Comparison Of Landslides And Their Related Outburst Flood Deposits, Owyhee River, Southeastern Oregon, Shannon Marian Othus
All Master's Theses
Numerous landslides have entered the Owyhee River canyon north of Rome, Oregon. As the river flows through different lithologic units, the style of mass wasting changes from large slump events and small rock falls to large earthflows. The change in mechanism of mass wasting from upstream to downstream seems to depend on several factors: (1) the ratio of the basalt cap to the exposed underlying sediments, (2) the composition of underlying sediments, (3) the canyon geometry, and (4) the extent and frequency of mass wasting. All three mechanisms of mass wasting have the ability to block the river channel and …
The 2004 And 1861 Tsunami Deposits On Simeulue Island, Western Sumatra, Katherine Frances Whitlow
The 2004 And 1861 Tsunami Deposits On Simeulue Island, Western Sumatra, Katherine Frances Whitlow
All Master's Theses
Megathrust earthquakes and associated tsunamis along the subduction zone along western Sumatra represent a significant seismic hazard that is not well understood. I present the results of mapping, paleoseimologic, and geochronologic studies of tsunami deposits exposed on Simeulue Island, western Sumatra, to document the timing of past tsunamis. Three field sites were targeted to conduct these studies: Inor, Busong Bay, and Langi Bay. Stratigraphic relationships, geochronologic data, and grain size analyses from these field sites show evidence of a tsunami that occurred in 1861 following a Mw ~8.5 earthquake. A wood fragment collected from an excavation at Inor yielded an …
Turbulent Lifestyle: Microbial Mats On Earth’S Sandy Beaches—Today And 3 Billion Years Ago, Nora Noffke
Turbulent Lifestyle: Microbial Mats On Earth’S Sandy Beaches—Today And 3 Billion Years Ago, Nora Noffke
OES Faculty Publications
Archean Earth history is very difficult to reconstruct. Until recently, only bacterial cells preserved in chert, microborings, and stromatolites provided the few clues to ancient life. Now, siliciclastic “microbially induced sedimentary structures” (MISS) are adding to our knowledge of both past life and paleoenvironments. MISS rise from the interaction of photoautotrophic microbial mats with physical sediment dynamics in siliciclastic, shallow-marine settings. Archean MISS can be understood through observations of living microbial mats and modern biotic-physical sedimentary processes. Such geobiological studies are key to the interpretation of the early evolution of prokaryotes. For example, the 2.9 Ga Pongola Supergroup, South Africa, …
Origin And Paleoclimatic Significance Of Late Quaternary Loess In Nebraska: Evidence From Stratigraphy, Chronology, Sedimentology, And Geochemistry, Daniel R. Muhs, E. Arthur Bettis Iii, John N. Aleinikoff, John P. Mcgeehin, Jossh Beann, Gary Skipp, Brian D. Marshall, Helen M. Roberts, William C. Johnson, Rachel Benton
Origin And Paleoclimatic Significance Of Late Quaternary Loess In Nebraska: Evidence From Stratigraphy, Chronology, Sedimentology, And Geochemistry, Daniel R. Muhs, E. Arthur Bettis Iii, John N. Aleinikoff, John P. Mcgeehin, Jossh Beann, Gary Skipp, Brian D. Marshall, Helen M. Roberts, William C. Johnson, Rachel Benton
United States Geological Survey: Staff Publications
Loess is one of the most extensive surficial geologic deposits in mid-continental North America, particularly in the central Great Plains region of Nebraska. Last-glacial-age loess (Peoria Loess) reaches its greatest known thickness in the world in this area. New stratigraphic, geochronologic, mineralogic, and geochemical data yield information about the age and provenance of Peoria Loess, as well as evaluation of recent climate models.
Rates Of Carbonate Dissolution In Permeable Sediments Estimated From Porewater Profiles: The Role Of Sea Grasses, David J. Burdige, Richard C. Zimmerman, Xinping Hu
Rates Of Carbonate Dissolution In Permeable Sediments Estimated From Porewater Profiles: The Role Of Sea Grasses, David J. Burdige, Richard C. Zimmerman, Xinping Hu
OES Faculty Publications
In this study we estimate sediment carbonate dissolution rates for sandy sea grass sediments on the Bahamas Bank using an inverse pore-water advection/diffusion/reaction model constrained by field observations. This model accounts for sea grass O2 input to these sediments, and also parameterizes pore-water advection through these permeable sediments as a nonlocal exchange process. The resulting rates of carbonate dissolution are positively correlated with sea grass density, and are comparable with previous rate estimates for Florida Bay sediments. In contrast, the advective uptake of O2 by these sediments decreased with increasing sea grass density. This suggests that the competing …
Colloid Mediated Transport Of Heavy Metals In Soils Following Reclamation With And Without Biosolid Application, Jarrod O. Miller
Colloid Mediated Transport Of Heavy Metals In Soils Following Reclamation With And Without Biosolid Application, Jarrod O. Miller
University of Kentucky Doctoral Dissertations
Soils disturbed by strip mining practices may have increased colloid loads moving to groundwater resources, also enhancing the transport of contaminants into our water resources. We hypothesize that contaminant transport within soils following mining is enhanced by colloid mobility. Two sites were chosen for this study, a 30-year old reclaimed strip mine in southwest Virginia and a recently mined area from eastern Kentucky. Intact reclaimed soil monoliths were retrieved from sandstone derived soils in southwestern Virginia. Reclaimed monoliths from eastern Kentucky were recreated in the lab. Intact undisturbed (native) soil monoliths representing the soils before mining were also sampled for …
The Global Stratotype Section And Point (Gssp) For The Base Of The Katian Stage Of The Upper Ordovician Series At Black Knob Ridge, Southeastern Oklahoma, Usa, Daniel Goldman, Stephen A. Leslie, Jaak Nõlvak, Seth Young, Stig M. Bergström, Warren D. Huff
The Global Stratotype Section And Point (Gssp) For The Base Of The Katian Stage Of The Upper Ordovician Series At Black Knob Ridge, Southeastern Oklahoma, Usa, Daniel Goldman, Stephen A. Leslie, Jaak Nõlvak, Seth Young, Stig M. Bergström, Warren D. Huff
Department of Earth, Environment and Sustainability Faculty Publications
The International Subcomission on Ordovician Stratigraphy (ISOS) of the International Commission on Stratigraphy (ICS) recently defined the base of the global Upper Ordovician Series to be at the first appearance datum (FAD) of the graptolite species Nemagraptus gracilis in the Fågelsång GSSP in southern Sweden. This designation recognized the tremendous utility for global correlation of the first appearance of a cosmopolitan taxon that occurs within a consistent succession of other first appearance datums (e.g., Finney and Bergström, 1986; Bergström et al., 2000). Current efforts by the ISOS have focused on subdividing the Upper Ordovician into three stages and choosing appropriate …
Sulfur Geochemistry And Diagenesis In A Gas Hydrate Terrane, Cascadia Margin, Offshore Oregon: Role Of Anaerobic Methane Oxidation, David Deigert, Walter S. Borowski
Sulfur Geochemistry And Diagenesis In A Gas Hydrate Terrane, Cascadia Margin, Offshore Oregon: Role Of Anaerobic Methane Oxidation, David Deigert, Walter S. Borowski
EKU Faculty and Staff Scholarship
We present sulfide mineral data from south Hydrate Ridge located in a gas hydrate terrane, offshore Oregon. Sulfide sulfur concentration and the isotopic composition of sulfur (d34S) in authigenic sulfide minerals are analyzed from sediment samples collected on Ocean Drilling Project (ODP) Leg 204. Shallow sediment samples (<25 >mbsf) assess the relative importance of anaerobic methane oxidation (AMO) as a biogeochemical process, both here and at the Blake Ridge, another well known gas hydrate terrane offshore southeastern United States. Deep samples (>25 mbsf) are used to evaluate sulfur diagenesis and its controls from early Pleistocene to the …25>