Earth Sciences Commons^™

Organic Carbon Decay Mediated By A Mesopelagic Microbial Community: The Relevance Of Carbon Pools And Broad Biochemical Composition, Noah J. Craft, Alexander B. Bochdansky

OES Faculty Publications

The mesopelagic zone is a site of strong microbially driven particle attenuation with depth and thus plays a crucial role in controlling the transfer efficiency of the ocean's biological pump. However, little quantitative information exists on the dependency of decay processes on the source material. Here we followed the decay of ¹⁴C-labeled dead particulate organic carbon (POC) and dissolved organic carbon (DOC) from three different phytoplankton species, and two incubations of live diatoms, in mesopelagic water over 3 months. Commonly used first-order kinetics failed to adequately describe the decay of organic material as rate constants varied from day to day. …

Evidence Of Mineral Alteration In A Salt Marsh Subterranean Estuary: Implications For Carbon And Trace Element Cycling, J. J. Tamborski, M. J. Eagle, M. T. Thorpe, M. A. Charette, B. L. Kurylyk, S. Rahman, K. D. Kroeger, J. O'Keefe Suttles, A. G. Mann, T. W. Brooks, Z. A. Wang

OES Faculty Publications

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments …

Seasonality Of Submarine Groundwater Discharge Pathways In A Coastal Lagoon Revealed By Radium Isotopes: The Importance Of Porewater Exchange In Summer, Júlia Rodriguez-Puig, Valentí Rodellas, Marc Diego-Feliu, Andres Alcolea, Joaquín Jiménez-Martínez, Irene Alorda-Montiel, Aaron Alorda-Kleinglass, Francisco Pereira, Marisol Manzano, Javier Gilabert, Jordi Garcia-Orellana

OES Faculty Publications

Chemical fluxes supplied by Submarine Groundwater Discharge (SGD) can be relevant for coastal ecosystems, particularly lagoonal environments. An appropriate understanding of SGD requires constraining the magnitude and composition of its different pathways. However, the evaluation of SGD pathways is often limited to independent estimations, lacking a comprehensive understanding of the groundwater processes at play. In this study, we combined a Ra mass balance and hydrogeological modeling to simultaneously estimate different SGD pathways flowing into a coastal lagoon. We assessed water fluxes derived from fresh SGD, long-scale recirculation of seawater, and porewater exchange (PEX) into Mar Menor, a highly anthropized coastal …

Radon And Radium Isotope Signatures On A Massive Ice- And Permafrost-Rich Coastline, Lauren Kipp, Gwénaëlle Chaillou, Markus Kienast, Joseph Tamborski, Dustin Whalen

OES Faculty Publications

Rapid warming in the Arctic is degrading permafrost and massive ice deposits, which releases solutes previously trapped in ice and frozen soils into groundwater, rivers, and the coastal ocean. Radium and radon isotopes are enriched in groundwaters and may therefore have utility as tracers for the delivery of permafrost-derived solutes to the ocean, particularly if massive ice- or permafrost-derived meltwaters have a distinct isotopic ratio. The ratio of radium isotopes within massive ice deposits can also be used to constrain timescales of ice segregation, as the four isotopes will decay with known rates once removed from contact with sediments. Here …

Multi-Centennial Spatial Coherency Among Atlantic Tropical Cyclones From Simulated And Reconstructed Storm Records, Richard M. Sullivan, Elizabeth Wallace, Sylvia Dee, Gabiel A. Vecchi, Wenchang Yang, Kerry Emanuel

OES Faculty Publications

Proxy-based reconstructions of long-term Atlantic tropical cyclone (TC) variability reveal low-frequency oscillations in regional TC landfalls over the Common Era. However, the limited spatial coverage and increased uncertainty of the proxy records complicates assessments of this feature. Here we present a new multi-ensemble set of synthetic TCs downscaled from the Last Millennium Reanalysis project, which is based on sea surface temperatures that more accurately reflect past conditions. Throughout ensemble members, there are coherent multi-centennial shifts in landfalls with persistent intervals of increased (decreased) occurrence along the eastern US concurrent with inverse activity in the southwest Caribbean and Gulf of Mexico, …

Core-Top Constraints On The Ecology And Paleothermometry Of Planktic Foraminifera In The Indian Ocean, Ryan H. Glaubke, Elisabeth L. Sikes, Natalie E. Umling, Katherine A. Allen, Matthew W. Schmidt

OES Faculty Publications

The magnesium-to‑calcium ratio (Mg/Ca) of fossil foraminifera is a widely used geochemical proxy for reconstructing past ocean temperatures. Culturing experiments have shown that, for some species, nonthermal influences like salinity and carbonate chemistry play a non-trivial role in the incorporation of Mg into foraminiferal calcite. Inclusion of these variables into Mg/Ca calibrations have provided a better fit to core top and sediment trap data in some recent studies, but the widespread covariation of potential control variables in the open ocean and the lack of multivariate calibrations for some species warrants additional work. Here, we assess Mg/Ca calibrations for four common …

Successful Eastern Oyster (Crassostrea Virginica) Recruitment On Intertidal Artificial Substrates In Virginia, Usa, Rochelle D. Seitz, Kathleen E. Knick, Emily Suchonic, Amanda Pysher

OES Faculty Publications

Declines of eastern oyster (Crassostrea virginica) populations and scarcity of natural oyster shell necessitate quantifying the effectiveness of artificial oyster reef substrates over varying environmental conditions. Oyster castles are often used in intertidal areas with moderate wave energy; however, new concrete, natural-looking substrates, GROW Reef Tiles, are now available. Eastern oyster recruitment and size on oyster castles (OC) and GROW Reef Tiles (GT), with 27% higher surface area on OC, were assessed three times over 25 months in locations with varying salinity. Four sites in the Chesapeake Bay region were examined: Cherrystone Inlet, Mockhorn Bay, Elizabeth River, and …

Unveiling Hidden Mercury And Methylmercury Sources: The Role Of Submarine Groundwater Discharge In Coastal Lagoons, Céline Lavergne, Júlia Rodriguez-Puig, Clara Ruiz-González, Maria Montero-Curiel, Gemma Casas, Daniel Romano-Gude, Irene Alorda-Montiel, Júlia Dordal-Soriano, Aaron Alorda-Kleinglass, Marc Diego-Feliu, Javier Gilabert, Alex Campillo-De La Maza, Cristina Romera-Castillo, Natalia Torres-Rodriguez, Lars-Eric Heimbürger-Boavida, Jordi Garcia-Orellana, Valenti Rodellas, Andrea G. Bravo

OES Faculty Publications

Mercury loads from Submarine Groundwater Discharge (SGD) may represent an overlooked source of methylmercury (MeHg) to the ocean, affecting human and ecosystem health. The SGD process involves the flow of fresh, saline, or mixed groundwater from coastal aquifers into the oceans classified in different components. Existing studies rarely report the fluxes supplied by the different SGD components; therefore, the relevance of SGD as a source of mercury remains unclear. We aimed to quantify SGD-driven mercury/methylmercury fluxes to the coast, focusing on the largest coastal lagoon in the western Mediterranean. We measured total dissolved mercury and MeHg in surficial and porewaters …

Yucatan Hurricane Activity Highlights Common Era Tropical Cyclone Dipole, Richard M. Sullivan, Peter J. Van Hengstum, Elizabeth J. Wallace, Sloan Coats, Jeffrey P. Donnelly, Robert Korty, Shawna N. Little, Martin G. Maas Vargas, Luis Mejia-Ortiz, Eduard G. Reinhardt, Courtney Schumacher, Anne E. Tamalavage, Tyler S. Winkler

OES Faculty Publications

Tropical cyclone (TC) impacts along the western Atlantic and Caribbean margin are not spatially uniform. Proxy based reconstructions of Common Era TC activity highlight this non-uniform distribution at centennial-millennial timescales. However, the sparse geographic scope of these reconstructions impedes our assessment of TC landfalls across broader spatial domains. This work presents a compilation of new and existing TC reconstructions from the Yucatan Peninsula for comparison with a contemporaneous compilation from New England, showing that these regions occupy distal nodes of a low-frequency TC dipole. Increased Yucatan (New England) storminess is closely linked to intervals of Northern Hemisphere warming (cooling) and …

The Large-Scale Flow Dynamics And Controls On Recurving Eastern North Pacific Tropical Cyclones, Alexander Kyle Mitchell

Electronic Theses & Dissertations (2024 - present)

While eastern North Pacific (EPAC) tropical cyclones (TCs) most often move westward over open water, a subset deviates from this typical path, recurving toward higher latitudes or making landfall along the North American coastline. Because such events are relatively rare, they have received less attention, despite their significant contributions to rainfall and wildfire activity across the southwestern United States. This dissertation identifies and characterizes the spatial variability of EPAC TC tracks, analyzes the synoptic environments associated with TC recurvature near the North American coast, presents a detailed case study of two recurving EPAC TCs from late September to early October …

Evaluation Of Practical Methods To Determine If A Karst Creek Is Gaining Or Losing: Case Study Of Leith Creek, Elizabeth Jones

Graduate Theses/Dissertations

Karst landscapes are abundant in Missouri, with features such as caves, springs, and sinkholes that form through the dissolution of limestone. Leith Creek is a small stream in Polk County, Missouri fed by two springs and the shallow unconfined Springfield Plateau aquifer, a highly karstified aquifer which is made up of limestone and minor interbedded shale-mudstone units. To determine if Leith Creek is gaining or losing, stream flow, water chemistry and temperature sensors were monitored. Stream flow results required multiple visits to take measurements while temperature sensors required two visits, one to install the dataloggers and another to remove the …

Investigating The Thermal Stratification Patterns Of A Shallow Polymictic Boreal Shield Lake And The Effectiveness Of Models In Predicting Shallow Lake Thermal Profiles, Matthew Roberts

Theses and Dissertations (Comprehensive)

Thermal stratification is a core process of lakes which plays a critical role in shaping the ecological dynamics of lakes, influencing major processes like nutrient cycling and oxygen availability. For shallow polymictic lakes, thermal stratification patterns present some unique differences due to the complex and variable nature of these lakes. In this thesis, I examined thermal stratification in a shallow polymictic lake in northwestern Ontario during the ice-free season of 2019 to investigate the frequency, duration, and driving factors of thermal stratification. The lake underwent 146 separate stratification events, with a median duration of 2 hours per event, with a …

The Relative Contribution Of Deep And Shallow Benthic Sources To Iron Supply In The Ross Sea, With Specific Emphasis On The Ross Bank, Blair J.W. Greenan, Michael S. Dinniman, Dennis J. Mcgillicuddy Jr., Peter N. Sedwick, Stefanie L. Mack, Walker O. Smith Jr.

OES Faculty Publications

Summer primary productivity in the Ross Sea is limited by the availability of dissolved iron (DFe) in the euphotic zone. Previous studies have suggested that benthic sources dominate the supply of DFe to the upper water column in the southern Ross Sea polynya. The purpose of this study is to investigate whether these benthic sources are derived from shallow banks or deeper areas of the continental shelf. Our study combines analysis of in situ observations near Ross Bank with a physical ocean model simulation in an overlapping summertime period to investigate the vertical supply of DFe. Two passive tracer dyes …

The Δ¹³C Signature Of Dissolved Organic And Inorganic Carbon Reveals Complex Carbon Transformations Within A Salt Marsh, Meagan J. Eagle, Kevin D. Kroeger, John W. Pohlman, Joseph J. Tamborski, Zhaohui Aleck Wang, T. W. Brooks, Jennifer O. Keefe Suttles, Adrian Mann

OES Faculty Publications

Coastal wetlands have high rates of atmospheric CO₂ uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L^-¹), dissolved organic carbon …

Dust Deposition To The Sargasso Sea: A Comparison Of Estimates Using Aluminum In The Surface Ocean Versus Aerosols And Rainwater, T. E. Williams, P. N. Sedwick, B. M. Sohst, K. N. Buck, S. Caprara, R. J. Johnson, D. C. Ohnemus, J. A. Resing, L. E. Sofen, A. Tagliabue, B. S. Twining

OES Faculty Publications

As a major component of mineral aerosol that partially dissolves in seawater, aluminum (Al) has been used to estimate time-averaged dust fluxes to the ocean, based on dissolved aluminum (DAl) concentrations and an assumed replacement time of DAl (tau DAl) in the surface mixed layer, along with the fractional solubility (Als) and mass abundance of Al in dust. We apply this method in the Bermuda region using seasonal water-column DAl concentrations, and compare our results with fluxes estimated from Al measured in Bermuda aerosols and rain. Inventories of DAl over the maximum mixed-layer depth of 200 m and empirically derived …

Dynamics Of Water Mass Exchange Across The Central Ross Sea Slope, Yuanjie Chen, Zhaoru Zhang, Pasquale Castagno, Xianxian Han, Michael S. Dinniman, Zhiqiang Liu, Chuning Wang

OES Faculty Publications

The central Ross Sea slope (CRSS) is a critical region for water mass exchange, significantly influencing the physical and biological processes of the Ross Sea shelf and the global overturning circulation. This study utilizes a high-resolution ocean-ice shelf-sea ice coupled model to investigate the mechanisms driving this exchange, involving the onshore transport of circumpolar deep water (CDW) and the offshore transport of dense shelf water (DSW). Combining numerical simulations and mooring observations, this work reveals high-frequency oscillations with a periodicity of ∼32 hr in CDW transport induced by Topographic Rossby Waves and DSW transport induced by cyclonic eddies. These findings …

Elucidating The Role Of Marine Benthic Carbon In A Changing World, Cristina Schultz, Jessica Y. Luo, Damian C. Brady, Robinson W. Fulwiler, Matthew H. Long, Colleen M. Petrik, Jeremy M. Testa, Heather M. Benway, David Burdige, Marta M. Cecchetto, Isa Elegbede, Natalya Evans, Alexandra Frenzel, Kayla Gillen, Lisa C. Herbert, Heidi K. Hirsh, Gennadi Lessin, Lisa Levin, Kanchan Maiti, Sairah Malkin, Sarah L. Mincks, Stanley Nmor, Anh Pham, James Pinckney, Christophe Rabouille, Shaily Rahman, Subhadeep Rakshit, Nicholas E. Ray, Dalton K. Sasaki, Samantha A. Siedlecki, Christopher Somes, Aron Stubbins, Olivier Sulpis, Cleuza Trevisan, Yiyang Xu, Hang Yin

OES Faculty Publications

The ocean plays a major role in controlling atmospheric carbon at decadal to millennial timescales, with benthic carbon representing the only geologic-scale storage of oceanic carbon. Despite its importance, detailed benthic ocean observations are limited and representation of the benthic carbon cycle in ocean and Earth system models (ESMs) is mostly empirical with little prognostic capacity, which hinders our ability to properly understand the long-term evolution of the carbon cycle and climate change-related feedbacks. The Benthic Ecosystem and Carbon Synthesis (BECS) working group, with the support of the US Ocean Carbon & Biogeochemistry Program (OCB), identified key challenges limiting our …

Unfolding Cascading Impacts Of Changing South Asia Monsoon On A Hindu Kush Himalayas Basin, Surendra Maharjan, Wenzhao Li, Shahryar Fazli, Arshad Ansari, Suraj Tiwari, Roma Thakurathi, Rejoice Thomas, Hesham El-Askary

Mathematics, Physics, and Computer Science Faculty Articles and Research

Study region

Study focus

New hydrological insights for the region

Organic Alkalinity Distributions, Characteristics, And Application To Carbonate System Calculations In Estuarine And Coastal Systems, Christopher W. Hunt, Joseph Salisbury, Xuewu Liu, Robert H. Byrne

Faculty Publications

The capacity of aquatic systems to buffer acidification depends on the sum contributions of various chemical species to total alkalinity (TA). Major TA contributors are inorganic, with carbonate and bicarbonate considered the most important. However, growing evidence shows that many rivers, estuaries, and coastal waters contain dissolved organic molecules with charge sites that create organic alkalinity (OrgAlk). This study describes the first comparison of (1) OrgAlk distributions and (2) acid–base properties in contrasting estuary-plume systems: the Pleasant (Maine, USA) and the St. John (New Brunswick, CA). The substantial concentrations of OrgAlk in each estuary were sometimes not conservative with salinity …

Geomorphic Evolution Of St. Augustine Inlet, St. Johns County, Florida, Kristen Becker

Theses and Dissertations

Tidal inlets interrupt longshore sediment transport, influencing adjacent beach morphology and allowing the exchange of water and sediment between the open oceans and protected back barrier bay. Inlets evolve through a combination of natural processes and are highly dynamic zones where sediment exchanges cause shifting shoreline positions nearby and create new morphological features. Barrier islands/beaches that are close in proximity to inlets evolve and are an important natural feature that dissipates wave energy and protects inland areas. Both natural and anthropogenic processes that affect barrier islands will be investigated during this study, including storm activity, waves, wind, water level, and …

Performance Of Acoustic Telemetry And Space Use Of Pallid Sturgeon In The Lower Platte River, Nebraska, Christopher F. Pullano

School of Natural Resources: Dissertations, Theses, and Student Research

Pallid Sturgeon (Scaphirhynchus albus) are centenarian, potamodromous, rheophiles that historically occupied the Missouri River and Mississippi River basins. Listed on the U.S. Endangered Species Act in 1990, population declines are attributed to habitat fragmentation and degradation, as well as overharvest, and hybridization. A knowledge gap exists regarding the extent to which tributaries facilitate key life stages for Pallid Sturgeon. This study evaluated the capacity of acoustic telemetry to monitor the movements of Pallid Sturgeon in a shallow, braided tributary to the Missouri River. The specific objectives were to (1) evaluate the environmental variables influencing the performance of acoustic …

Sedimentary Characteristics Of Flood Deposits In Coastal And Fluvial Environments: Examples From Washover Fans (North Carolina, Usa) And Floodplain Deposits (Mississippi, Usa), Shara Gremillion

Dissertations

Extreme flooding from severe and prolonged meteorological events and / or overbanking rivers are some of the most deadly and expensive disasters globally, impacting millions of lives, the environment, and property. People living in vulnerable areas, such as near coasts and rivers, are the first to be impacted with effects of these flood hazards. Scientific studies and their results can aid communities and officials in planning and preparing for those flood impacts. In this three-part study, flood impacts from coastal storms in North Carolina, and flooding along the Mississippi River (MSR) in the state of Mississippi, USA are assessed from …

Sea Surface Temperatures, The Gulf Of Mexico Loop Current, Hurricane Ian, And Their Junction, Alexander K. Nickerson

USF Tampa Graduate Theses and Dissertations

In the first chapter, a climatology was created for the deep Gulf of Mexico, West Florida Shelf, and Tampa Bay. These climatologies were compared to each other and to global temperatures. Seasonal variability is shown to be a product of bathymetry as well as latitude. In Chapter Two, using the self-organizing map neural network, patterns of the Gulf of Mexico Loop Current were analyzed to establish phases with necessary and sufficient conditions for translation from one phase to the next. Two separate patterns of evolution were established from these analyses, and empirical arguments are used to confirm the findings from …

Evaporation Basins For Salinity Management, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

An evaporation basin is an engineered earth structure designed to safely store and evaporate saline water discharged from drainage or pumping, while protecting high-value agricultural land, natural assets or built infrastructure.

DPIRD recommends that evaporation basins should form part of an integrated water and salinity management program. Information on this page is a guide only.

It is recommended that landholders seek expert advice plus engineering design and related support from qualified contractors.

Measuring Soil Salinity, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

To make sound decisions on managing saline sites, you need to know the source of salt, how salinisation is occurring, the landscape context, and most importantly, the actual salt concentration of the soil.

The most common 'measures' of salt concentration are actually estimates based on electrical conductivity of a soil and water solution. Soil salt content can be measured in a laboratory by measuring the total dissolved solids in a sample. In the field, salt concentration can also be estimated using electromagnetic induction-based soil sensors.

Roaded Catchments In Wa, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

Roaded catchments are earthwork structures designed to increase the amount of run-off from the catchment above a receiving farm dam.

Roaded catchments are lined with clay and compacted to make a smooth surface that reduces infiltration and increases run-off. Roaded catchments should discharge into a silt trap and then into a dam (excavated earth tank). This combined structure should be fenced to exclude livestock.

The Department of Primary Industries and Regional Development recommends that roaded catchments are part of an integrated water and salinity management program.

The information in this page is only a guide – seek expert advice before …

Managing Subsurface Water In Wa, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

The Department of Primary Industries and Regional Development (DPIRD) recommends that subsurface water management is part of an integrated water and salinity program. An integrated program can help to lower water tables and alleviate problems with waterlogging, rising salinity, and infrastructure damage.

Local Hydroclimate Alters Interpretation Of Speleothem Δ18o Records, E. W. Patterson, V. Skiba, A. Wolf, M. L. Griffiths, D. Mcgee, T. N. Bùi, M. X. Trần, T. H. Đinh, Q. Đỗ-Trọng, Gregory R. Goldsmith, V. Ersek, K. R. Johnson

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Oxygen isotopes (δ¹⁸O) are the most commonly utilized speleothem proxy and have provided many foundational records of paleoclimate. Thus, understanding processes affecting speleothem δ¹⁸O is crucial. Yet, prior calcite precipitation (PCP), a process driven by local hydrology, is a widely ignored control of speleothem δ¹⁸O. Here we investigate the effects of PCP on a stalagmite δ¹⁸O record from central Vietnam, spanning 45 – 4 ka. We employ a geochemical model that utilizes speleothem Mg/Ca and cave monitoring data to correct the δ¹⁸O record for PCP effects. The resulting record …

Liming Acidic Soils Creates Profits, Land Use Options But Often More Emissions, Sud Kharel, Christophe D'Abbadie, Amir Abadi Ghadim, Chris Gazey, Ross Kingwell

Natural Resources Research Articles

Context

Soil acidity constrains crop production in Australia. The practice of liming can reduce soil acidity but produces greenhouse gas emissions.

Aims

By examining land use sequences over three decades at a range of locations in Western Australia, this study aims to identify firstly where and when liming might boost farm profits and secondly, what emissions and land use management flexibilities are generated by liming.

Methods

Bioeconomic simulation modelling is used to identify the gross margins and emissions associated with liming in land use sequences at 14 locations in Western Australia. Three intensities of cropping and three different rotational sequences …

Detection Of Seismic Microwave Radiation Anomalies In Snow-Covered Mountainous Terrain: Insights From Two Recent Earthquakes In The Pamir–Tien Shan Region, Feng Jing, Meng Jiang, Ramesh P. Singh

Mathematics, Physics, and Computer Science Faculty Articles and Research

When earthquakes occur in high-mountain areas during the winter season, the epicentral region is often covered by a snow layer, which can be either thin or thick. The presence of snow and/or ice layers affects the detection of thermal anomalies associated with seismic signals. Taking into account the penetration capabilities of microwaves, microwave brightness temperature data were analyzed by using the index of microwave radiation anomaly to study the response of the epicentral region associated with two recent strong earthquakes in Central Asia, which occurred in snow-covered mountainous areas. Increased microwave radiation was observed within one week prior to the …