Earth Sciences Commons^™

Paragneiss Zircon Geochronology And Trace Element Geochemistry, North Qaidam Hp/Uhp Terrane, Western China, Chris G. Mattinson, Joseph L. Wooden, Jian-Xin Zhang, D. K. Bird

All Faculty Scholarship for the College of the Sciences

In the southeastern part of the North Qaidam terrane, near Dulan, paragneiss hosts minor peridotite and UHP eclogite. Zircon geochronology and trace element geochemistry of three paragneiss samples (located within a ∼3 km transect) indicates that eclogite-facies metamorphism resulted in variable degrees of zircon growth and recrystallization in the three samples. Inherited zircon core age groups at 1.8 and 2.5 Ga suggest that the protoliths of these rocks may have received sediments from the Yangtze or North China cratons. Mineral inclusions, depletion in HREE, and absence of negative Eu anomalies indicate that zircon U-Pb ages of 431 ± 5 Ma …

Anthropogenic Osmium In Rain And Snow Reveals Global-Scale Atmospheric Contamination, Cynthia Chen, Peter N. Sedwick, Mukul Sharma

Dartmouth Scholarship

Osmium is one of the rarer elements in seawater, with typical concentration of approximately 10 x 10(-15) g g(-1) (5.3 x 10(-14) mol kg(-1)). The osmium isotope composition ((187)Os/(188)Os ratio) of deep oceans is 1.05, reflecting a balance between inputs from continental crust (approximately 1.3) and mantle/cosmic dust (approximately 0.13). Here, we show that the (187)Os/(188)Os ratios measured in rain and snow collected around the world range from 0.16 to 0.48, much lower than expected (>1), but similar to the isotope composition of ores (approximately 0.2) that are processed to extract platinum and other metals to be used primarily …

Coesite In Eclogite From The North Qaidam Mountains And Its Implications, Jian-Xin Zhang, Fan-Cong Meng, Jin-Ping Li, Chris G. Mattinson

All Faculty Scholarship for the College of the Sciences

Coesite provides direct evidence for ultrahigh pressure metamorphism. Although coesite has been found as inclusions in zircon in paragneiss of the north Qaidam Mountains, it has never been identified in eclogite. In this contribution, based on petrographic observations and in situ Raman microprobe spectroscopy, coesite was identified as inclusions in garnet of eclogite from the Aercituoshan, Dulan UHP metamorphic unit, north Qaidam Mountains. Coesite is partly replaced by quartz, showing a palisade texture. This is the first report on coesite in eclogite from the north Qaidam Mountains, and is also supported by garnet-omphacite-phengite geothermobarometry (2.7–3.25 GPa, 670–730°C). Coesite and its …

Exhumation Of The Inyo Mountains, California: Implications For The Timing Of Extension Along The Western Boundary Of The Basin And Range Province And Distribution Of Dextral Fault Slip Rates Across The Eastern California Shear Zone, Jeffrey Lee, Daniel F. Stockli, Lewis A. Owen, Robert C. Finkel, Roman Kislitsyn

All Faculty Scholarship for the College of the Sciences

New geologic mapping, tectonic geomorphologic, ¹⁰Be terrestrial cosmogenic nuclide, and (U-Th)/He zircon and apatite thermochronometric data provide the first numerical constraints on late Cretaceous to late Quaternary exhumation of the Inyo Mountains and vertical slip and horizontal extension rates across the eastern Inyo fault zone, California. The east-dipping eastern Inyo fault zone bounds the eastern flank of the Inyo Mountains, a prominent geomorphic feature within the western Basin and Range Province and eastern California shear zone. (U-Th)/He zircon and apatite thermochronometry yield age patterns across the range that are interpreted as indicating: (1) two episodes of moderate to rapid …

Riparian And Associated Habitat Characteristics Related To Nutrient Concentrations And Biological Responses Of Small Streams In Selected Agricultural Areas, United States, 2003–04, Ronald B. Zelt, Mark D. Munn

United States Geological Survey: Publications

Physical factors, including both in-stream and riparian habitat characteristics that limit biomass or otherwise regulate aquatic biological condition, have been identified by previous studies. However, linking the ecological significance of nutrient enrichment to habitat or landscape factors that could allow for improved management of streams has proved to be a challenge in many regions, including agricultural landscapes, where many ecological stressors are strong and the variability among watersheds typically is large. Riparian and associated habitat characteristics were sampled once during 2003–04 for an intensive ecological and nutrients study of small perennial streams in five contrasting agricultural landscapes across the United …

Cave Minerals Of San Salvador Island, Bahamas, Bogdan P. Onac, Jonathan Sumrall, John E. Mylroie, Joe B. Kearns

Environmental Sustainability Books

This volume describes the results of a 2009 fieldwork season focusing on the cave minerals found in karst environments throughout San Salvador Island in the Bahamian archipelago. The caves visited represent a sampling of pit and flank margin caves. Each cave description includes a map.

Using Chromium Stable Isotopes To Monitor Chromium Reactive Transport: Oxidation Experiments And Field Studies, Alejandro Villalobos Aragon

Open Access Theses & Dissertations

Chromium (Cr) is a common contaminant found at a number of sites globally. Cr sources can be either anthropogenic or natural. Cr occurs in nature in two valences, with Cr(VI) being carcinogenic, more toxic and mobile than Cr(III). Reduction of Cr(VI) to Cr(III) is a common remediation strategy, but monitoring Cr reduction using only concentration and speciation analyses is a difficult endeavor because concentrations can be affected by dilution and advection in addition to reduction. Cr isotopes are fractionated during reduction processes, so monitoring isotopic changes in Cr may be a faster and more effective way to monitor reduction. This …

Geochemical Fingerprinting Of Volcanic Airfall Deposits : A Tool In Stratigraphic Correlation, Soumava Adhya

Legacy Theses & Dissertations (2009 - 2024)

Chemical fingerprints of volcanic airfall deposits obtained from high-precision electron microprobe analysis of glass and phenocrysts phases provide geochemical correlations with temporal precision unattainable by other methods. In this research electron microprobe analysis (EMA) techniques, to fingerprint chemically and correlate fresh and altered volcanic airfall deposits, have been utilized to test the value of this tool for future research on stratigraphic correlation. The following samples were chosen from within a variety of sedimentary rocks widely separated spatially and temporally:

Mercury Uptake By Aquatic Macrophytes In Urban And Rural Watersheds, Albany County, Ny, Bernd G. Neumann

Geology Theses and Dissertations

Plants growing in metalliferous soils may restrict metal uptake and transport depending on metal concentration, sediment characteristics, and plant species. As native plants are replaced by invasives, different patterns of metal cycling can occur, making continued study of this process important. Sediments and tissues of four aquatic plant species/genera: Phragmites australis (common reed); Iris versicolor (blueflag iris); Typha latifolia (broadleaf cattail); and genera Cyperus sp. (sedge) from three urban and two rural sites in Albany County, NY were analyzed for total mercury (Hg_­T) by cold vapor atomic absorption spectroscopy. Sediments were also measured for organic carbon (OC) by …

Biogenic Tracers Through The Holocene On The Alaskan Shelf, Carie A. Curry

OES Theses and Dissertations

Dramatic environmental changes in the Arctic Ocean have been observed for the last two decades including changing the amount of sea ice thickness and extent, and increased river discharge. In order to put these and other current day observations into historical context and perhaps reveal mechanisms controlling them, a suite of paleo-proxies were used to analyze two high resolution cores collected on the 2005 HOTRAX expedition. The goals of this research were: (1) develop an analytical method for determining biogenic calcite, (2) identify the major sources of biogenic matter into the system over the Holocene, and (3) assemble the history …

Estimating Variation In Stiffness And Volume Change Of Clays From Geochemical And Index Properties, Cynthia Roxanna Zuniga

Open Access Theses & Dissertations

Clayey soils from six different locations in Texas were analyzed and evaluated with respect to their expansion and shrinkage and change in stiffness associated with moisture content variation. These soils consist of five high plasticity-index (PI) clays (PI greater than 25) and one low-PI clay (PI = 17). The behavior of the clays changes dramatically with moisture content fluctuation, thus causing stiffness and volume changes throughout the year. Total or differential volume movements caused by swell or shrinkage strains of expansive soils and reduction in modulus can exert enough pressure to damage the pavements and cause maintenance problems.

The intent …

Suswa Volcano, Kenya Rift: Evidence Of Magma Mixing, Na-F Complexing And Eruptions Triggered By Recharge, Vanessa Veronica Espejel Garcia

Open Access Theses & Dissertations

The Cenozoic East African rift system (EARS) is a sequence of grabens, intraplate transforms, accommodation zones, and abundant magmatism. The Central Kenya Peralkaline Province (CKPP) includes a variety of volcanic rocks -trachyte, pantellerite, comendite, phonolite, trachy-basalt, basaltic trachy-andesite, and basalt- which erupted from volcanoes including: Mount Kenya; Eburru and the Greater Olkaria volcanic complexes; Longonot, Menengai, and Suswa volcanoes; and Ndabibi, Elmenteita, and Tandamara mafic volcanic fields. Only two of the volcanoes, Mount Kenya (on the flank of the central graben) and Suswa (the southernmost of the CKPP volcanoes), have phonolites as part of their assemblage.

The evolution of Suswa …

Zinc And Copper Isotopes As Tracers Of Anthropogenic Contamination In A Sediment Core From An Urban Lake, Anita Thapalia

Open Access Theses & Dissertations

Concentration data alone are often insufficient to resolve metal sources. This study applies stable Zn and Cu isotopes to fingerprint and track the sources of these metals in a sediment core from Lake Ballinger near Seattle, Washington, USA. The base of the Lake Ballinger core pre-dates settlement in the region, while the upper sections record the impact of atmospheric emissions from the nearby Tacoma smelter, as well as Cu and Zn inputs from urban sources. δ⁶⁶Zn and δ⁶⁵Cu varied by 0.42 / and 0.29 /, respectively, over the >300 year core record. Isotopic changes were correlated …

Early Neoproterozoic Origin Of The Metazoan Clade Recorded In Carbonate Rock Texture: Reply, Fritz Neuweiler, Elizabeth C. Turner, David J. Burdige

OES Faculty Publications

We (Neuweiler et al., 2009) used scanning electron microscopic, fluorescence spectroscopic, fluorescence microscopic, and thin-section analytical work from modern, Cretaceous, Silurian, and early Neoproterozoic reefal material to make a geological case for an early Neoproterozoic origin of animals. In a modern analogue for ancient petrographic textures, degradative calcification of the extracellular collagenous matrix (ECM) of a modern siliceous sponge can be directly observed (Neuweiler et al., 2007).

Export Of Terrestrial Dissolved Organic Matter Along A River To Ocean Transect Of The Lower Chesapeake Bay Investigated By Advanced Analytical Techniques, Rachel Leigh Sleighter

Chemistry & Biochemistry Theses & Dissertations

Ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) has proved essential for the complete separation of the thousands of peaks present in natural organic matter (NOM), a complex assemblage of organic molecules present in water, soils, and sediments. An improved understanding of its composition is crucial to understand how pollutants interact with NOM and how NOM cycles through global carbon cycles.

Optimizing the acquisition and handling of the FTICR mass spectra is the first step to obtaining high quality data. A simple method to internally calibrate the peaks in the complex spectra, using naturally present fatty …

Mineralogy And Micromorphology Of An Atacama Desert Soil, Chile: A Model For Hyperarid Pedogenesis, Michael S. Howell

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Atacama Desert is the oldest and driest desert on Earth. Hyperarid soils in this desert are dominated by rare (or exclusive) salt minerals and assemblages. Previous research details salt origins and abundance, however pedogenic processes involved in salt distribution are not adequately explained. Therefore, the main goal of this investigation was to identify and document evidence for hyperarid pedogenesis (via salt mineralogy and soil micromorphology) at a field site, Oficina Ercilla, located ~80 km northeast of Antofagasta, Chile within the Central Depression and hyperarid core of the Atacama Desert. This study presents an interpretational model for hyperarid pedogenesis, which …

Sequence And Chemostratigraphic Study Across The Basal Eureka Quartzite Unconformity In The Great Basin, Nevada: Implications For The Origin Of The Late Ordovician Carbon Isotope Excursion, Apostolos Paul Kosmidis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The positive carbon isotope (δ 13 C) excursion from the late Middle Ordovician Copenhagen Formation that underlies the Eureka Quartzite in central Nevada has been hypothesized to record a global cooling event ∼10 Myr prior to the well-recognized Late Ordovician Hirnantian glaciation (∼443 Ma). However, direct evidence for pre-Hirnantian continental glaciation remains scarce, raising uncertainties in the relationship between the inferred eustatic sea-level fall and the origin of the positive δ 13 C excursion. Additionally, previous stratigraphic studies from southern Nevada and California suggest relative sea-level fall in excess of ∼ 150 meters, which exceeds estimates for younger glacial periods …

In Situ Element Quantification In The Hydrothermal Diamond Anvil Cell Using Synchrotron X-Ray Fluorescence With Applications Toward Subduction Zone Processes, Steven Joseph Maglio

UNLV Theses, Dissertations, Professional Papers, and Capstones

Yttrium is used in geochemical investigations of arc volcanics and metamorphic geothermometers. The ability to use Y as a geochemical tool is predicated on an understanding of the mobility of Y during fluid-saturated conditions attending metamorphic and igneous processes. The goal of this work was to use the hydrothermal diamond anvil cell (HDAC) and synchrotron radiation X-ray fluorescence to quantify, in situ, the concentration of Y in aqueous fluids at 2-5 GPa and 650 - 800 °C; conditions likely at the oceanic lithosphere - mantle wedge interface in subduction zones. Previous studies have used modified diamond anvils which limits their …

Organic Chemostratigraphic Markers Characteristic Of The (Informally Designated) Anthropocene Epoch, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Recognizing the tremendous collective impact of humans on the environment in the industrial age, the proposed designation of the current time period as the Anthropocene Epoch has considerable merit. One of the signature activities during this time continues to be the intensive extraction, processing, and combustion of fossil fuels. While fossil fuels themselves are naturally-occurring, they are most often millions of years old and associated with deeply buried strata. They may be found at the surface, for example, as natural oil seeps or coal seam outcrops, but these are relatively rare occurrences. Fossil fuels and their myriad by-products become the …

Determining Chemical Signatures Of Geologic Materials For Establishing Provenience Of Anasazi Red And Gray Wares Using Esem-Eds And Icp-Ms, Champagne Springs Ruins, Co, Steven Mathew Di Naso

All-Inclusive List of Electronic Theses and Dissertations

Compositional analyses of prehistoric ceramics and geological materials allow archaeologists to establish provenience of artifacts through comparative analysis of the materials used in prehistoric ceramic production. Where pottery clay pastes and tempering constituents originate from locally or regionally available geological materials, identifying their chemical composition and their geographic location and distribution facilitates a better understanding of the inter and intra socio-spatial and socioeconomic patterns among neighboring communities. The Champagne Springs Ruins were occupied during the late Pueblo I (A.D. 700 -A.D. 900) to early Pueblo II (A.D. 900 TO A.D. 1100) periods. The traditional view of local ceramic production from …

Geogram 2008, David J. Keeling, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

A Study Of Nife(X)Cr(2-X)O4 By Laser Micro-Raman Spectroscopy, Lucas Wilson, Markus Vasquez, John Farley, Allen L. Johnson, Brian D. Hosterman

Undergraduate Research Opportunities Program (UROP)

Standards of spinels, composed of two metals and oxygen with the formula AB2O4, are being created with known composition to identify spinels in samples of unknown composition by comparison with the spectra obtained from the standards. Laser micro-Raman spectroscopy allows the identification of chemical species based on their unique vibrational modes. The degree to which spinels of varying composition can be identified will be determined. This will aid in the study of the corrosion of steel by liquid metal. Spinels are a likely component of the oxide layer. Understanding the composition of the products of corrosion leads to an understanding …

Co2 Sequestration – Controlling Co2 Emissions To The Atmosphere Through Capture And Long-Term Storage, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about CO₂ sequestration. Defines direct and indirect sequestration and discusses the role of the Plains CO₂ Reduction (PCOR) Partnership in advancing sequestration projects. [This item is an outdated or superseded version and retained for historical purposes only. It may no longer reflect current information, policies, or practices.]

A Multi-Tracer Study Of Saltwater Origin, Cross-Formational Flow, And The Geochemical Evolution Of Groundwater In The Southern High Plains Aquifer Along The Western Caprock Escarpment, East-Central New Mexico, Jeff Langman

Open Access Theses & Dissertations

Sustainable management of groundwater resources requires sufficient knowledge of the distribution of fresh and saline groundwater and the processes affecting saltwater intrusion that may influence the beneficial use of groundwater. A hydrogeologic investigation that coupled various chemical and isotopic tracers, including 3H/3He, 14C, δD, δ18O, 87Sr/86Sr, and δ11B, with the physical characteristics of the aquifer was conducted to determine source waters, the origin of saltwater and its influence through cross-formational flow, and water-rock interactions in the Southern High Plains aquifer along the Western Caprock Escarpment. Sub-aquifers or local flow systems are present along the Western Caprock Escarpment, and the study …

Soil Chemistry Northwest New Mexico, Larry V. Benson

United States Geological Survey: Datasets

These data result from soil chemistry samples extracted from several regions in northwest New Mexico and were used in the following publications:

Larry V. Benson, J. Stein, H. Taylor, R. Friedman, and T. C. Windes. 2006. The agricultural productivity of Chaco Canyon and the source(s) of pre-Hispanic maize found in the Pueblo Bonito Great House. In: J. E. Staller, R. H. Tykot, and B. F. Benz, eds. Histories of Maize: Multidisciplinary Approaches to the Prehistory, Linguistics, Biogeography, Domestication, and Evolution of Maize, 289–314. Elsevier/Academic Press.

Larry V. Benson. 2017. The Chuska Slope as an agricultural alternative to Chaco …

Middle Crustal Ductile Deformation Patterns In Southern Tibet: Insights From Vorticity Studies In Mabja Dome, Jackie Langille

All Master's Theses

Mabja Dome, southern Tibet, exposes mid-crustal rocks proposed to have originated from a southward flowing mid-crustal channel. Kinematic, mean kinematic vorticity (Wm), and metamorphic petrography analyses on these mid-crustal rocks were performed to test this hypothesis. Kinematic indicators show a transition with structural depth from top-north and top-south shear to solely top-south shear. Along the northernmost transects, Wm in schists and orthogneisses range from 0.52–0.84 (63–36% pure shear). Wm for quartzites ranges from 0.9–0.99 (27–1% pure shear). Deformation temperatures increase from ~450 °C in the chloritoid-zone to ~700 °C in the sillimanite-zone and were recorded between ~35–16 Ma. These patterns …

Turbulent Lifestyle: Microbial Mats On Earth’S Sandy Beaches—Today And 3 Billion Years Ago, Nora Noffke

OES Faculty Publications

Archean Earth history is very difficult to reconstruct. Until recently, only bacterial cells preserved in chert, microborings, and stromatolites provided the few clues to ancient life. Now, siliciclastic “microbially induced sedimentary structures” (MISS) are adding to our knowledge of both past life and paleoenvironments. MISS rise from the interaction of photoautotrophic microbial mats with physical sediment dynamics in siliciclastic, shallow-marine settings. Archean MISS can be understood through observations of living microbial mats and modern biotic-physical sedimentary processes. Such geobiological studies are key to the interpretation of the early evolution of prokaryotes. For example, the 2.9 Ga Pongola Supergroup, South Africa, …

Origin And Paleoclimatic Significance Of Late Quaternary Loess In Nebraska: Evidence From Stratigraphy, Chronology, Sedimentology, And Geochemistry, Daniel R. Muhs, E. Arthur Bettis Iii, John N. Aleinikoff, John P. Mcgeehin, Jossh Beann, Gary Skipp, Brian D. Marshall, Helen M. Roberts, William C. Johnson, Rachel Benton

United States Geological Survey: Staff Publications

Loess is one of the most extensive surficial geologic deposits in mid-continental North America, particularly in the central Great Plains region of Nebraska. Last-glacial-age loess (Peoria Loess) reaches its greatest known thickness in the world in this area. New stratigraphic, geochronologic, mineralogic, and geochemical data yield information about the age and provenance of Peoria Loess, as well as evaluation of recent climate models.

Arctic Perennial Ice Cover Over The Last 14 Million Years, Dennis A. Darby

OES Faculty Publications

Knowledge of the long-term history of the perennial ice is an important issue that has eluded study because the Cenozoic core material needed has been unavailable until the recent Arctic Coring Expedition (ACEX). Detrital Fe oxide mineral grains analyzed by microprobe from the last 14 Ma (164 m) of the ACEX composite core on the Lomonosov Ridge were matched to circum-Arctic sources with the same mineral and 12-element composition. These precise source determinations and estimates of drift rates were used to determine that these sand grains could not be rafted to the ACEX core site in less than a year. …

Paleogene Mirelands Of The Upper Mississippi Embayment, Western Kentucky, Jennifer Marie Klein O'Keefe

University of Kentucky Doctoral Dissertations

Detailed petrography, geochemistry, and palynology together describe the depositional environments and paleoecology of an abandoned meander-fill system in western Kentucky. Oriented block petrography reveals alternating clay-rich and attrinite-rich zones of variable thickness. Woody tissues, where present, do not show dessication features and deflation layers could not be identified. Overall, petrography is indicative of a topogenous mire. Mire palyno-assemblages are less diverse than assemblages reported from clays in the region. Castanea-Cupuliferoidaepollenites assemblages dominate the entire system and other tree pollen are common; fungal spores are relatively uncommon. Weighted statistical analyses reveal ecological groupings beyond this dominance and define botanical succession within …