Earth Sciences Commons^™

A Probabilistic Deep Learning Framework For Retrieving Chlorophyll-A From Hyperspectral Imagery: Integrating Channel Attention And Mixture Density Networks, Wenzhao Li, Surendra Maharjan, Rejoice Thomas, Junde Chen, Hesham Morgan, Michael J. Garay, Olga V. Kalashnikova, Shahryar Fazli, Charles Ichoku, Hesham El-Askary

Mathematics, Physics, and Computer Science Faculty Articles and Research

Accurate monitoring of Chlorophyll-a (Chla) is critical for assessing aquatic ecosystem health, yet ecological complexity often leads to ambiguous spectral signatures in satellite data. Traditional deterministic models assume a one-to-one mapping between spectra and pigments, often failing to capture these high-dimensional analytical challenges. In this study, we propose a novel deep learning architecture, the Channel Attention-Mixture Density Network (CA-MDN), to retrieve Chla from the National Aeronautics and Space Administration (NASA) Earth Surface Mineral Dust Source Investigation (EMIT) hyperspectral mission. The CA-MDN integrates an attention mechanism to dynamically select ecologically relevant spectral bands and employs a probabilistic output layer to quantify …

Monitoring Strategies In Cave Microclimate Studies, Nenad Buzjak, Dalibor Paar, Aurel Persoiu, Christos Pennos, Franci Gabrovšek, Valerija Rossi

International Journal of Speleology

Cave atmospheres are spatially confined but dynamical systems that influence subterranean ecosystems, geomorphological processes, registration and preservation of climatic signals in sedimentary archives, cultural heritage, and conservation management. Despite major advances in cave climatology, methodological approaches to microclimate monitoring remain fragmented and are in some cases still shaped by the long-standing assumption that cave air temperature simply reflects the mean annual surface temperature. This paper revisits that assumption and develops an experience- and literature-based methodological framework for cave microclimate research. Key terminology is addressed by distinguishing between cave climate, cave microclimate, and cave meteorology, and by situating microclimatic variability within …

Electrocatalytic Degradation Of Methylene Blue Using Rgo, Sb2o3, And Rgo-Sb2o3 Composite Ink-Based Electrodes, Maria Irene Myers Armas, Andrea M. Fletes, Thomas Eubanks, Arnulfo Mar, Jason Parsons, Helia Magali Morales

School of Integrative Biological & Chemical Sciences Faculty Publications

Water pollution from industrial dyes is a critical challenge due to the resistance of these types of compounds to degradation and potentially harmful effects on living organisms and human health. In this study, the electrochemical degradation of methylene blue (MB) was investigated using ink-based copper foam electrodes with reduced graphene oxide (rGO), antimony trioxide (Sb2O3), and rGO/Sb2O3 composites. The materials used to synthesize the electrodes were characterized by X-ray diffraction (XRD), which showed the successful synthesis of GO, rGO, and the Sb2O3-rGO composite. Additionally, the synthesized electrodes were examined using SEM. The MB degradation was studied using kinetic behavior and …

Systematic Synthesis Of Crispr/Cas Applications For Enhancing Salt Tolerance In Crops: A Decade Of Progress And Challenges, Xindi Sun, Fusheng Wu, Zhuanzhuan Ma, Guohao Liang, Shumei Chen, Xutong Hu, Shugao Fan, Ying Zhao

School of Mathematical & Statistical Sciences Faculty Publications

Soil salinity is a major constraint on global crop productivity, driving the need for salt-tolerant varieties. While CRISPR-Cas genome editing offers targeted solutions for trait improvement, significant biological and technical bottlenecks limit its application in conferring salt stress resilience. This systematic summarizes findings from 83 peer-reviewed studies (2015–2024) employing CRISPR/Cas technologies to improve salt tolerance in five major crops (rice, wheat, maize, sorghum, barley). Our systematic review reveals that early single-gene edits achieved modest gains (30–50% Na⁺ exclusion) but often showed limited yield gains in field settings, potentially due to compensatory regulation and environmental variation. The literature suggests that multiplex …

The World's Largest Saddle Dam At Risk: Multisensor Geohazard Analysis And Downstream Impacts, Hesham El-Askary, Hesham Morgan, Surendra Maharjan, Ali Elgendy, Wenzhao Li, Rejoice Thomas, Austin Madson, Cyril Rakovski

Mathematics, Physics, and Computer Science Faculty Articles and Research

The Grand Ethiopian Renaissance Dam (GERD) Saddle Dam, which holds approximately 89% of the main reservoir's live storage, is one of the largest and most critical auxiliary dams globally; its construction on Ethiopia's Blue Nile has consequently raised significant regional and international concerns regarding potential environmental impacts and geohazard risks. This study presents a comprehensive risk assessment of the GERD Saddle Dam by integrating high-resolution satellite data (GRACE, Sentinel-1, Sentinel-2, WorldView-3), hydrological modeling (SWAT), Persistent Scatterer Interferometry (PSI), geospatial analysis, and advanced statistical techniques. The results highlight critical structural vulnerabilities, including groundwater infiltration estimated at approximately 41 ± 6.2 billion …

To Hold Or Sell Breeding Cattle In The Rangelands, Department Of Primary Industries And Regional Development, Western Australia

Animal production and livestock factsheets

In a dry season where feed, water and finances are limited, removing less productive animals as soon as possible is a good option. This will free up feed for more productive animals and help preserve ground cover.

This page provides some of the information and a process for making decisions about holding or selling breeding cattle.

Supporting Data – Urban Stream, Cardinal Court, Isu, Normal, November 9, 2023 To May 1, 2025, Eric Wade Peterson, Ava Miller

Faculty Publications - Geography, Geology, and the Environment

Between November 9, 2023 to May 1, 2025, water samples were collected upstream and downstream along a segment of a stream adjacent to Cardinal Court on the Illinois State University campus. At each location, samples were collected at the surface. In-situ measurements of Dissolved Oxygen, Specific Conductance, and Temperature were recorded with a YSI 85. Anion samples were analyzed using a Ion Chromatograph for fluoride (F^-), chloride (Cl^-), nitrate as nitrogen (NO3-N), phosphate (PO₄^3-), and sulfate (SO₄^2-). The available dataset provides the recorded field parameters and the analyzed ion concentrations.

A High-Resolution Daily Precipitation Fusion Framework Integrating Radar, Satellite, And Nwp Data Using Machine Learning Over South Korea, Hyoju Park, Hiroyuki Miyazaki, Menas Kafatos, Seung Hee Kim, Yangwon Lee

Institute for ECHO Articles and Research

Accurate precipitation mapping is essential for effective disaster management; however, individual radar, satellite, and numerical weather prediction products often struggle in the topographically complex terrain of South Korea. This study proposes a high-resolution (~500 m) daily precipitation fusion framework that integrates Korea Meteorological Administration (KMA) radar, Global Precipitation Measurement (GPM) Integrated Multi-Satellite Retrievals for GPM (IMERG), and Local Data Assimilation and Prediction System (LDAPS) data. The framework employs a Random Forest model augmented with a monthly Empirical Cumulative Distribution Function (ECDF) correction. Auxiliary predictors are incorporated to enhance physical interpretability and stability, including terrain attributes to represent orographic effects, land-cover …

Pitfalls Of Multiplied 3d Landforms Projection: Mapping Deep Multilevel Cave Systems In The Alps (Gamssteig Cave System, Göll Massif), Mateusz Golicz, Jacek Szczygieł

International Journal of Speleology

Cave mapping represents one of the most complex challenges in geomorphological cartography, as it must convey the true three-dimensional geometry of subterranean spaces such as overlapping passages, irregular cross-sections, and variable ceiling and floor morphologies, within a two-dimensional framework. This study examines the methodological and interpretive challenges of cave mapping, utilizing the Gamssteighöhle cave in the Austrian Alps as a case study. During the 11 years of exploration, over 10 km of passages were surveyed using the DistoX vector survey method. Yet, the complex morphological forms necessitated deviations from the standard symbology recommended by the International Union of Speleology. Several …

Evolutionary Mechanisms Of Nanopores And Adsorption Capacity In Shales Under Scco2-Water-Rock Interactions, Feng Guangjun, Wang Meng, Zhu Yanming, Song Yu, Dai Xuguang, Zheng Sijian, Xie Hong, Shang Fuhua

Coal Geology & Exploration

Background Supercritical carbon dioxide (ScCO₂ )-enhanced shale oil and gas recovery serves as an effective approach to geologic CO₂ sequestration. Injecting ScCO₂ into shale reservoirs can trigger complex ScCO₂-water-rock interactions, thereby altering the material composition, nanopore structure, and adsorption capacity of shales. Examining their evolutionary processes represents a critical scientific issue in the evaluation of CO₂ sequestration efficiency. Methods This study investigated the shales of the Longmaxi Formation in the southeastern Chongqing area. Through simulation experiments on ScCO₂-water-rock interactions and by integrating X-ray diffraction (XRD), low-pressure CO₂/N₂ adsorption, fractal …

Advances In Research On Co2 Corrosion Mechanisms, Modification, And Application Of Cements For Injection Wells In Geologic Co2 Sequestration, Hao Feng, Zhang Zongfeng, Wang Hongmin, Du Shuai, Huang Da, Yang Xuefeng, Wang Kexin, Zhang Yu

Coal Geology & Exploration

Background and Merhod The wellbore integrity of CO₂ injection wells plays a critical role in maintaining the long-term safe operation of geologic CO₂ sequestration (GCS) projects. Well cement serves as the foremost wellbore integrity barrier, and its durability under GCS has emerged as a hot research topic both at home and abroad. This study systematically reviews the advances in research on the chemical corrosion mechanism of well cement under the operating conditions of GCS, technologies for cement modification for enhanced resistance to CO₂ corrosion, and non-Portland cement systems. Furthermore, the directions for the future development of well …

Numerical Simulations Of The Safety Of Geologic Co2 Storage In Saline Aquifers In The Enping Sag, Pearl River Mouth Basin, Yu Tao, Li Xiwen, Yang Yunshi, Chen Bingbing, Ji Zemin, He Chang, Jiang Lanlan, Song Yongchen

Coal Geology & Exploration

Background Since the beginning of the Industrial Revolution, excessive CO₂ emissions have aggravated the greenhouse effect. Against this backdrop, CO₂ capture, utilization, and storage (CCUS) technology has emerged as a critical countermeasure. Particularly, geologic CO₂ storage holds enormous application potential. China has implemented a demonstration project of geologic CO₂ storage in saline aquifers located in the Enping Sag, Pearl River Mouth Basin. Nevertheless, this sag exhibits formation dip angles and widely distributed fracture zones, which affect CO₂ migration and storage. Methods Focusing on the Enping Sag, this study established a two-dimensional model of the saline …

Research Progress And Prospects Of Full Flowsheet Coal-Based Ccus, Sang Shuxun, Liu Shiqi, Zheng Sijian, Huang Fansheng, Liu Tong, Chen Siming, Zhou Xiaozhi, Han Sijie, Tian Yuchen, Xiang Wenxin, Bai Yansong

Coal Geology & Exploration

Background The engineering-oriented, full flowsheet coal-based carbon capture, utilization, and storage (CCUS) technology is the key to efficient, clean coal utilization and carbon emission reduction. It represents a major technology that is urgently needed to ensure the energy security of China and achieve the strategic goals of peak carbon dioxide emissions and carbon neutrality of the country. Based on previous research efforts of the authors’ team, this study reviews the current status of this technology, reveals its integration mechanisms, and attempts to establish a pattern and scheme for CCUS cluster deployment in coal energy bases. Furthermore, it discusses the future …

An Experimental Study On Nonlinear Seepage Characteristics In Coal Seams During Ch4 Displacement Through N2 And Co2 Flooding, Li Zefeng, Huang Mengru, Zhang Hongzhong, Lan Jianping, Song Jinsuo, Fan Shixing

Coal Geology & Exploration

Background Coal seams in China are generally characterized by low porosity (<5%) and low permeability (0.001×10^–3μm²), leading to low coalbed methane (CBM, dominated by CH₄) drainage efficiency. Gas flooding-enhanced CBM drainage technology plays a significant role in surface CBM drainage, underground CBM pre-drainage, and deep geologic CO₂ storage. Methods This study investigated four common types of gases: N₂ and CO₂ for flooding, CH₄ to be displaced, and He for blank control. Based on the physical properties of these gases and employing methods including the quasi-static method, the gas flow rate method, and the Reynolds …

Research And Application Of A Decision Support Platform For Geologic Co2 Storage Siting Based On A Global Case Database, Zhou Yinbang, Wang Rui, Zhen Yan, Dai Quanqi, Cheng Chuanjie

Coal Geology & Exploration

Objective Under the strategic background of reaching the goals of peak CO₂ emissions and carbon neutrality, there is an urgent need to address the core issue of geologic CO₂ storage (GCS) siting in the advancement of large-scale GCS deployment. Establishing a decision support platform based on a global GCS case database can provide key data and historical experience references for GCS siting, reduce storage risks and costs, and accelerate industrial layout. Furthermore, the platform can offer a scientific basis for formulating related policies and conducting technological R&D.Methods This study proposed and developed a comprehensive evaluation system for …

Carbon Sequestration Technology: Challenges And Urgent Critical Scientific Issues, Li Xiaochun, Liu Tianyu, Zhang Liwei, Zhou Hong, Liu Guizhen, Wang Yan, Gan Manguang, Li Qi

Coal Geology & Exploration

Objective Carbon sequestration technology represents a core approach to achieving carbon neutrality. However, its large-scale application remains constrained by multiple technical and scientific challenges. Methods Based on an analysis of existing carbon sequestration projects, this study identified four major challenges in carbon sequestration: (1) high uncertainty in the assessment of CO₂ sequestration capacity; (2) low injectivity of low-permeability discontinuous reservoirs; (3) a limited understanding of long-term mechanical stability; and (4) significant difficulty in assessing the risks of CO₂ leakage. Results To address these challenges, this study proposes the common issues currently faced by carbon sequestration technology, and, accordingly, …

Designation And Classification Of Co2 Storage Technologies, Ma Fubo, Yang Xuechao, Zhou Zhengwu, Liu Hongliang, Chang Jia, Yi Jiayao, Wang Yan

Coal Geology & Exploration

Objective and Method Currently, there remains a lack of criteria for technical certification, designation, and classification of carbon dioxide (CO₂) storage technologies due to their cross-disciplinary nature and ambiguous scopes. To address this issue, this study proposes technical certification criteria and designation principles, as well as analyzes four types of common CO₂ storage technologies: geologic storage, underground space storage, ocean water storage, and utilization and storage. Accordingly, a classification philosophy and scheme for these technologies is determined.Results and Conclusions In terms for technical certification criteria, a CO₂ storage technology has to meet four criteria: (1) …

An Improved Model Of Trans-Critical Ch4 And Co2 Adsorption In Coals Based On Monolayer Adsorption And Adsorption Potential Theories, Song Xuemei, Zhang Kun, Sang Shuxun, Ma Mengya, Liu Huihu, Xu Hongjie

Coal Geology & Exploration

Objective and Method Adsorbed phase density represents a key parameter for determining gas adsorption capacity in coals. Using bituminous coal samples from the Huainan and Huaibei mining areas in Anhui Province, this study carried out high-pressure isothermal adsorption experiments of CO₂ and CH₄ at temperatures of 24 ℃, 36 ℃, and 48 ℃. In combination with the quantitative characterization of pore structures in coals using low-temperature liquid nitrogen adsorption (LNA) experiments and mercury intrusion porosimetry (MIP), this study analyzed the high-pressure trans-critical CH₄ and CO₂ adsorption processes in coals. Meanwhile, based on the Gibbs excess adsorption, …

Research Advances And Prospects Of Geologic Co2 Sequestration Models, Hu Chenlin, Dong Cheng, Sang Shuxun, Tang Yong, Li Xin, Zhang Bin, Zhao Lingfeng

Coal Geology & Exploration

Background The urgent need to respond to global climate change and to achieve carbon neutrality is driving geologic CO₂ sequestration technology to be increasingly large-scale, safe, and intelligent. Since the CO₂ sequestration process involves multi-physical field coupling, the engineering feasibility and long-term safety of CO₂ sequestration heavily rely on the capacity of numerical models to perform accurate characterization of complex subsurface processes. Therefore, establishing a model system, covering the entire process consisting of injection, migration, sequestration, and monitoring, that is suitable for various geobodies for CO₂ sequestration has emerged as a foundation for the engineering application …

Distribution Characteristics And Mechanisms Of Ch4 And Co2 Adsorption In Montmorillonite Nanopores In Water-Bearing And Saline Environments, Du Kai, Rui Zhenhua, Qian Cheng, Chen Siwei

Coal Geology & Exploration

Background Carbon capture, utilization, and storage (CCUS) has emerged as a significant way to reduce greenhouse gas emissions under the guidance of the strategic goals of peak carbon dioxide emissions and carbon neutrality. With the continuous exploitation of unconventional hydrocarbon resources such as shale oil and gas, varying water-bearing and salinity conditions exert significant impacts on the occurrence stability and seepage behavior of CO₂, thereby reducing the efficiency and safety of CO₂ storage. Therefore, a thorough understanding of the competitive behavior and distribution patterns of CO₂ and other gases in shale nanopores under varying water-bearing and …

Table Of Contents, The Editors

Coal Geology & Exploration

No abstract provided.

Multi-Scale Source-Sink Matching And Transportation Route Optimization For Geologic Co2 Sequestration Of Industrial Co2 Stationary Sources In Jiangsu Province, Tian Yuchen, Liu Shiqi, Zhang Helong, Mo Hang, Wang Dexi, Sang Shuxun, Wang Jun, Wang Wenkai, Zheng Sijian

Coal Geology & Exploration

Objective CO₂ stationary sources tend to show a dispersed distribution, while carbon sinks are concentrated in specific sedimentary basins. The resulting significant source-sink mismatch in space restricts the large-scale applications of carbon capture, utilization, and storage (CCUS) technology. Therefore, reducing CCUS costs by investigating source-sink matching and optimizing CO₂ transportation routes under a multi-scale spatial framework is the key to the engineering applications of CCUS. Methods Targeting representative industrial CO₂ stationary sources and carbon sinks in Jiangsu Province, this study established source-sink matching models on multiple scales covering hydrocarbon reservoirs, sags, and basins. Based on both the …

Reaction Mechanisms During Co2 Absorption In Ethanolamine Solutions, Teng Weiwei, Wu Yan, Fan Yuxin, Liao Tao, Wang Zicheng, Yu Hui, Li Meng, Xu Xiaoling

Coal Geology & Exploration

Objective Presently, CO₂ capture technology based on the ethanolamine solutions suffers from drawbacks such as high energy consumption and elevated costs. A primary method to address these challenges is to construct blended amine solutions by synergistically integrating the absorption and desorption advantages of different types of ethanolamines. Hydroxyethyl ethylenediamine (AEEA) and N-methyldiethanolamine (MDEA) represent two major commonly used absorbents, and their blending necessitates an accurate understanding of their CO₂ absorption patterns, including CO₂ loading capacity, the ion-concentration distribution patterns of reaction products, and reaction orders. Currently, their absorption mechanisms remain poorly understood, and there is a lack …

Concept Of Cccus Technology For Co2 Recycling In Deep Unmineable Coal Seams, Liang Weiguo, Yan Jiwei, Zhu Dijie, Guo Hongguang, Gong Li, Niu Dong

Coal Geology & Exploration

Background China possesses substantial resources of deep unmineable coal seams, which hold considerable potential for CO₂ sequestration. However, simply sequestrating CO₂ in deep coal seams incurs high economic costs while also wasting deep coal resources. The microbial conversion of sequestrated CO₂ into methane (CH₄) enables circular carbon capture, utilization, and storage (CCCUS), which is of great significance for the sustainable development of both resources and the environment.Methods Using a range of methods, including experimental study, theoretical analysis, and engineering simulations, CCCUS in deep unmineable coal seams is designed to (1) reveal the mechanisms behind …

A Method Of Carbon Emission Accounting And Pathways Of Emission Reduction Through Reduction Through Ccus For Underground Coal Mines, Xu Shen, Wang Meng, Dai Xuguang, Qiu Yuxin, Tuo Jialong, Li Wenhao, Gao Jie

Coal Geology & Exploration

Objective Coal production and utilization lead to substantial carbon emissions, and the carbon emissions from underground coal mines have attracted increasing attention. However, research on emission reduction pathways in coal mines remains nascent. Methods The Y Coal Mine was investigated in this study. Using methods including life cycle assessment (LCA), emission factor approach, and monitoring, this study identified the boundaries for carbon emission accounting and determined the sources, total amount, and characteristics of carbon emissions from the coal mine. Furthermore, a framework of carbon emission reduction through CCUS was established based on the principle of carbon capture, utilization, and storage …

Performance And Carbonation Mechanisms Of Multi-Source Solid Waste-Based Carbon-Sequestering Backfill Materials For Coal Mines, Guo Qingwen, Li Dongyin, Wang Shen, Liu Songhui, Li Quanjiang, Li Song

Coal Geology & Exploration

Objective The reutilization of solid waste such as coal gangue and steel slag is critical to green mining. Preparing solid waste-based carbon-sequestering backfill materials and then filling them into coal mine goaves emerge as an important approach to solid waste utilization, carbon emission reduction, and green coal mining.Methods Based on the designed mix proportions of a high-solid-waste system consisting of steel slag and coal gangue, in which steel slag was used to compensate for the insufficient carbonation reactivity of coal gangue, this study prepared solid waste-based backfill material samples composed of coal gangue, steel slag, and cement. Through mechanical …

Huff-N-Puff Experiments Of Mixed Co2 And Formation Water For Enhanced Oil Recovery Of Shale Oil In The Subei Basin, Xiao Pufu, Zhang Jie, Yang Zhengmao, Wang Rui, Cui Maolei, Lei Mengmeng, Tian Yunfei, Zeng Jun, Liu Yuwei

Coal Geology & Exploration

Objective In the Subei Basin, the depletion-drive development of shale oil following reservoir volume fracturing faces challenges such as rapid production decline and low oil recovery. To address these issues, this study explored an experimental method of CO₂ + formation water (also referred to as carbonated water) huff and puff for enhanced oil recovery (EOR) by combining the felsic, clayey, and organic-rich characteristics of shale oil reservoirs in the Subei Basin, along with CO₂ high pressure quality exchange technology. Methods Through multiple physical simulation experiments in the laboratory, combined with nuclear magnetic resonance (NMR) experiment technology, this study …

Numerical Simulation Of Co2 Sequestration Combined With Enhanced Geothermal Energy Extraction In Deep Saline Aquifers, Xie Zehao, Zhang Liehui, Zhao Yulong, Cao Cheng, Kou Zuhao, Zhang Deping, Li Jinlong

Coal Geology & Exploration

Objectives and Methods Deep saline aquifers represent ideal spaces for geologic CO₂ sequestration while also featuring high geothermal gradients and abundant geothermal resources. The combination of CO₂ sequestration and geothermal energy extraction holds great significance for enhancing the CO₂ sequestration effect and achieving integrated resource development of deep saline aquifers. Therefore, this study proposed a development approach that combined CO₂ sequestration with geothermal energy extraction in deep saline aquifers and established a thermo-hydro-chemical coupling numerical simulation model of the gas-water two-phase flow. Accordingly, it explored the optimal injection mode, production and injection well patterns, and injection …

Numerical Simulations Of The Impacts Of Co2-Induced Calcite Dissolution On The Permeability And Elastic Parameters Of Rocks, Yang Bo, Xu Tianfu, Feng Guanhong, Zhu Huixing

Coal Geology & Exploration

Objective CO₂ dissolution in water tends to induce mineral reactions, thus significantly changing the pore structure of rocks and further affecting their seepage and mechanical properties. This phenomenon poses a major impact on the suitability and long-term safety of geologic CO₂ sequestration engineering. Methods Using a simulation technology that combines the lattice Boltzmann method (LBM) and the finite element method (FEM), this study systematically investigated the calcite dissolution characteristics of calcite-bearing rock samples under varying injection rates of a saturated solution of CO₂. Furthermore, the dynamic evolution patterns of the permeability and elastic parameters (bulk and …

Advances And Prospects Of Research On In Situ Co2 Mineralization Storage In Basalts, Wang Xiao, Wu Bin, Shi Xiangchao, Ye Zhongbin, Wei Bing, Wang Guanhua, Alvarado Vladimir, Huang Kailin, Yang Zeyong

Coal Geology & Exploration

Background CO₂ storage in basalts, enjoying distinct advantages of rapid mineralization and high safety, has gradually emerged as a hot research topic both in China and abroad. This study presents a systematic review of the current status of research on the mechanisms of in situ CO₂ mineralization storage, the evolutionary characteristics of the physical properties of strata under the condition of mineralization reactions, and representative demonstration projects. On this basis, the future research directions are proposed. Advances The in situ CO₂ mineralization storage in basalts is essentially a process of CO₂-water-rock reactions, achieved primarily through …