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Inorganic Chemistry

2010

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Full-Text Articles in Other Chemistry

(2e)-1-(6-Chloro-2-Methyl-4-Phenylquinolin-3-Yl)-3-Phenylprop-2-En-1-One, Tan Kong Wai, Viji A. J., Vijayakumar V., Sarveswari S. Jan 2010

(2e)-1-(6-Chloro-2-Methyl-4-Phenylquinolin-3-Yl)-3-Phenylprop-2-En-1-One, Tan Kong Wai, Viji A. J., Vijayakumar V., Sarveswari S.

Tan Kong Wai

In the title compound, C(25)H(18)ClNO, the conformation about the C=C double bond is E. Significant twists are evident in the molecule, with the benzene ring forming a dihedral angle of 53.92 (11)degrees with the quinolinyl residue. Further, the chalcone residue is approximately perpendicular to the quinolinyl residue [C(q)-C(q)-C(c)-O(c) torsion angle = -104.5 (3)degrees, where q = quinolinyl and c = chalcone]. In the crystal, the presence of C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions leads to supramolecular layers lying parallel to ((1) over bar 02).