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Full-Text Articles in Chemistry

Synthesis Of New Substituted 6-(Morpholin-4-Yl)-1h-Benzimidazole Derivatives, Canan Kuş Jan 2002

Synthesis Of New Substituted 6-(Morpholin-4-Yl)-1h-Benzimidazole Derivatives, Canan Kuş

Turkish Journal of Chemistry

A series of various substituted benzimidazole derivatives containing fluoro and morpholino substituents at the 5 and 6 positions was synthesized and their structures were identified by spectroscopic techniques.


The Synthesis Of Bromoethoxy And Vinylbenzyloxy Substituted Nlo Chromophores, Michael Joseph Matuszewski Jan 2002

The Synthesis Of Bromoethoxy And Vinylbenzyloxy Substituted Nlo Chromophores, Michael Joseph Matuszewski

Browse all Theses and Dissertations

Multiphoton-absorption processes have recently attracted growing interest because of the potential impact on a wide spectrum of applications, ranging from data storage to photodynamic therapy. From the materials standpoint, particular interest is centered in designing chromophores that exhibit a large two-photon cross-section. The current research is focused on establishing synthetic routes that lead to the formation of derivatives of N,N-diphenyl-(7-benzothiazol-2-yl)-9,9-diethyl-9H-fluoren-2-ylamine which contain meta functionalization. A bromoethoxy functionalized chromophore, N-phenyl-N-(3-(2-bromoethoxy)phenyl)-7-(benzothiazol-2-yl)-9,9-diethyl-9H-fluoren- 2-ylamine , was synthesized and used as a polymer pendent while a vinylbenzyloxy chromophore, N-phenyl-N-(3-(4-vinylbenzyloxy)phenyl)-7- (benzothiazol-2-yl)-9,9-diethyl-9H-fluoren-2-ylamine, was synthesized as a hydrosilation substrate. A compound containing three chromophores, 1,3,5-tris(3-(N-phenyl- 4-(7-(benzothiazol-2-yl)-9,9-diethyl-9H-fluoren-2- ylanilino)phenoxymethyl)benzene, has …