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Bulletin of National University of Uzbekistan: Mathematics and Natural Sciences

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Extraction Conductometric Determination Of Scandium And Thorium In Kaolins, Nigora Kutlimurotova, Zulayho Smanova, Habibulla Tojimuhamedov, Zuhra Yaxshiyeva, Jasur Tursunqulov Jun 2018

Extraction Conductometric Determination Of Scandium And Thorium In Kaolins, Nigora Kutlimurotova, Zulayho Smanova, Habibulla Tojimuhamedov, Zuhra Yaxshiyeva, Jasur Tursunqulov

Bulletin of National University of Uzbekistan: Mathematics and Natural Sciences

A method for extraction - conductometric determination of scandium and thorium with tributyl phosphate and trioctyl phosphine oxide in kaolin was developed. The equivalent electrical conductivity of the complex of scandium and thorium with 2,7-dinitrozo-1,8-dihydroxynaphthalene-3,6-disulfonic acid was found. A scheme for the separation and determination of kaolin content is proposed. The isotherms of scandium and thorium extraction are constructed. It was shown that at a concentration of nitric acid of 15.6 M they do not interfere with the determination of thorium and scandium.