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Full-Text Articles in Chemistry
Tetrabutylammonium Benzoate‐Initiated Polymerization Of Propylene Oxide, Xuemin Chen, Michael R. Van De Mark
Tetrabutylammonium Benzoate‐Initiated Polymerization Of Propylene Oxide, Xuemin Chen, Michael R. Van De Mark
Chemistry Faculty Research & Creative Works
The polymerization of propylene oxide by the benzoate anion was aided through the use of the tetrabutylammonium counterion. The effect of the tetrabutylammonium ion was to increase the solubility of the salt and to increase the ion separation. The polymerization was carried out in a pressure reactor at temperatures from 40 to 108°C, producing polymer yields of 2–78%. The study addressed the general effects of solvent, temperature, and ratio of initiator to monomer. © 1993 John Wiley & Sons, Inc. Copyright © 1993 John Wiley & Sons, Inc.
Characterization Of Epoxy Resins For Use In The Resin Transfer Molding Process, Christina Kaye Short
Characterization Of Epoxy Resins For Use In The Resin Transfer Molding Process, Christina Kaye Short
Dissertations, Theses, and Masters Projects
No abstract provided.
Cross-Linking Additives As Smoke Suppressants For Poly(Vinyl Chloride), Steven Alfred Terranova
Cross-Linking Additives As Smoke Suppressants For Poly(Vinyl Chloride), Steven Alfred Terranova
Dissertations, Theses, and Masters Projects
No abstract provided.
A Study Of Molecular Order And Motion In Nematic Liquid Crystal Mixtures, Jon Michael Goetz
A Study Of Molecular Order And Motion In Nematic Liquid Crystal Mixtures, Jon Michael Goetz
Dissertations, Theses, and Masters Projects
Materials which flow like fluids, but possess anisotropic properties like molecular crystals, are called 'liquid crystals'. Studies of liquid crystals contribute to our understanding of how molecular orientation influences macroscopic properties. This thesis presents experimental and theoretical investigations of molecular order and dynamics in nematic liquid crystal systems. First, deuterium nuclear magnetic resonance is used to determine the degree of orientational order of both components of a liquid crystal mixture simultaneously. The temperature dependence of the four order parameters is interpreted using a newly developed mean field theory of nematic binary mixtures composed of biaxial molecules. Next, mean field theory …