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Articles 1 - 30 of 108

Full-Text Articles in Physical Sciences and Mathematics

Optimal Technological Modes Of Ion Implantation And Following Annealing For Forming Thin Nanosized Films Of Silicides, A. S. Rysbaev, S. U. Irgashev, A. S. Kasimov, D. Sh. Juraeva, J. B. Khujaniyazov, M. I. Khudoyberdieva Mar 2020

Optimal Technological Modes Of Ion Implantation And Following Annealing For Forming Thin Nanosized Films Of Silicides, A. S. Rysbaev, S. U. Irgashev, A. S. Kasimov, D. Sh. Juraeva, J. B. Khujaniyazov, M. I. Khudoyberdieva

Eurasian Journal of Physics and Functional Materials

The formation of nanosized films of silicides on the surface of Si (111) and Si (100) was studied by the method of low-energy ion implantation. The optimal technological modes of ion implantation and subsequent annealing for the formation of thin nanoscale films of silicides were determined. It is shown that the appearance of new surface superstructures is additional confirmation of the formation of thin silicide films with a single crystal structure.

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Change Of Electrophysical Properties Of The Si(111) And Si(100) Surface In The Process Of Ion Implantation And Next Annealing, A. S. Rysbaev, I. R. Bekpulatov, B. D. Igamov, Sh. X. Juraev Sep 2019

Change Of Electrophysical Properties Of The Si(111) And Si(100) Surface In The Process Of Ion Implantation And Next Annealing, A. S. Rysbaev, I. R. Bekpulatov, B. D. Igamov, Sh. X. Juraev

Eurasian Journal of Physics and Functional Materials

The change in the electrical properties of the Si(111) and Si(100) surfaces during ion implantation and subsequent annealing was studied. The possibilities of controlling of the electrophysical properties of the Si(111) and Si(100) surface layers by the implantation of ions of alkaline and alkaline-earth elements are analyzed. Some electrophysical properties of semiconductors containing p- and n-structures and the possibilities of their application in electronics are discussed.

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Structure And Electrochemical Performance Modulation Of A Lini0.8co0.1mn0.1o2 Cathode Material By Anion And Cation Co-Doping For Lithium Ion Batteries, Rong Li, Yong Ming, Wei Xiang, Chunliu Xu, Guilin Feng, Yongchun Li, Yanxiao Chen, Zhenguo Wu, Ben-He Zhong, Xiaodong Guo Jan 2019

Structure And Electrochemical Performance Modulation Of A Lini0.8co0.1mn0.1o2 Cathode Material By Anion And Cation Co-Doping For Lithium Ion Batteries, Rong Li, Yong Ming, Wei Xiang, Chunliu Xu, Guilin Feng, Yongchun Li, Yanxiao Chen, Zhenguo Wu, Ben-He Zhong, Xiaodong Guo

Australian Institute for Innovative Materials - Papers

Ni-rich layered transition metal oxides show great energy density but suffer poor thermal stability and inferior cycling performance, which limit their practical application. In this work, a minor content of Co and B were co-doped into the crystal of a Ni-rich cathode (LiNi0.8Co0.1Mn0.1O2) using cobalt acetate and boric acid as dopants. The results analyzed by XRD, TEM, XPS and SEM reveal that the modified sample shows a reduced energy barrier for Li+ insertion/extraction and alleviated Li+/Ni2+ cation mixing. With the doping of B and Co, corresponding enhanced cycle stability was achieved with a high capacity retention of 86.1% at 1.0C …

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Flexible And Free-Standing Siox/Cnt Compositefilms For High Capacityand Durable Lithium Ion Batteries, Wenlei Guo, Xiao Yan, Feng Hou, Lei Wen, Yejing Dai, Deming Yang, Xiaotong Jiang, Jian Liu, Ji Liang, Shi Xue Dou Jan 2019

Flexible And Free-Standing Siox/Cnt Compositefilms For High Capacityand Durable Lithium Ion Batteries, Wenlei Guo, Xiao Yan, Feng Hou, Lei Wen, Yejing Dai, Deming Yang, Xiaotong Jiang, Jian Liu, Ji Liang, Shi Xue Dou

Australian Institute for Innovative Materials - Papers

Flexible and free-standing electrode materials are prerequisite and key components for next-generation flexible energy storage and conversion devices. However, it is still a chanllenge to fabricate these materials from a continuous, straightforward, and facile method. Herein, we report a flexible composite film with silicon oxides decorated on few-walled carbon nanotubes, which can be continuously fabricated and directly drawn from the hot zone of the reactor. The composite film can be readily used for electrochemical lithium ion storage with high and reversible specific capacity, good rate capability, and excellent cycling performance. These exceptional characteristics make it very promising for flexible energy …

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Synthesis Of Cose2-Snse2 Nanocube-Coated Nitrogen-Doped Carbon (Nc) As Anode For Lithium And Sodium Ion Batteries, Jin Bai, Huimin Wu, Shiquan Wang, Guangxue Zhang, Chuanqi Feng, Hua-Kun Liu Jan 2019

Synthesis Of Cose2-Snse2 Nanocube-Coated Nitrogen-Doped Carbon (Nc) As Anode For Lithium And Sodium Ion Batteries, Jin Bai, Huimin Wu, Shiquan Wang, Guangxue Zhang, Chuanqi Feng, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

CoSe2-SnSe2/NC nanocubes (CSNC@NC) coated by nitrogen-doped carbon (NC) were synthesized successfully by an ordinary pyrazole polymerization and carbonization process. In comparison with bare CSNC, the CSNC@NC composite exhibited good structural stability and improved electrical conductivity when used as anode. The CSNC@NC electrode showed a stable Li storage capacity (730.41 mAh g−1 over 100 cycles at 0.2 A g−1) and excellent rate performance (402.10 mAh g−1 at 2 A g−1). For Na storage, the discharge capacity could be maintained 279.3 mAh g−1 over 100 cycles at 0.2 A g−1; the lower capacity than that for Li storage maybe caused by the …

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A Multi-Ion, Flux-Corrected Transport Based Hydrodynamic Model For The Plasmasphere Refilling Problem, Kausik Chatterjee, Robert W. Schunk Jan 2019

A Multi-Ion, Flux-Corrected Transport Based Hydrodynamic Model For The Plasmasphere Refilling Problem, Kausik Chatterjee, Robert W. Schunk

All Physics Faculty Publications

The objective of this paper is the application of a newly-developed Flux-Corrected Transport (FCT) based hydrodynamic solution methodology to the plasmasphere refilling problem following a geomagnetic storm. The FCT method is extremely well-suited to the solution of nonlinear partial differential equations with shocks and discontinuities. In this solution methodology, every ion species is modeled as two separate fluids originating from the northern and southern hemispheres. We present refilling results that includes three ion (H+, He+ and O+) species and two neutrals (H and O). We believe that with additional modifications, the model …

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Cryogenic Probe Station At Old Dominion University Center For Accelerator Science, Junki Makita, Jean R. Delayen, Alex Gurevich, Gianluigi Ciovati Jan 2018

Cryogenic Probe Station At Old Dominion University Center For Accelerator Science, Junki Makita, Jean R. Delayen, Alex Gurevich, Gianluigi Ciovati

Physics Faculty Publications

With a growing effort in research and development of an alternative material to bulk Nb for a superconducting radiofrequency (SRF) cavity, it is important to have a cost effective method to benchmark new materials of choice. At Old Dominion University's Center for Accelerator Science, a cryogenic probe station (CPS) will be used to measure the response of superconductor samples under RF fields. The setup consists of a closed-cycle refrigerator for cooling a sample wafer to a cryogenic temperature, a superconducting magnet providing a field parallel to the sample, and DC probes in addition to RF probes. The RF probes will …

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Measurements Of Frequency, Temperature, Rf Field Dependent Surface Resistance Using Superconducting Half-Wave Cavity, Hyekyoung Park, Subashini De Silva, Jean R. Delayen Jan 2018

Measurements Of Frequency, Temperature, Rf Field Dependent Surface Resistance Using Superconducting Half-Wave Cavity, Hyekyoung Park, Subashini De Silva, Jean R. Delayen

Physics Faculty Publications

A theory of surface resistance of superconductor was rigorously formulated by Bardeen, Cooper, Schrieffer more than 50 years ago. Since then the accelerator community has been used the theory as a guideline to improve the surface resistance of the superconducting cavity. It has been observed that the surface resistance is dependent on frequency, temperature and rf field strength, and surface preparation. To verify these dependences, a well-controlled study is required. Although many different types of cavities have been tested, the typical superconducting cavities are built for specific frequencies of their application. They do not provide data other than at its …

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Rf Tests Of Rf-Dipole Prototype Crabbing Cavities For Lhc High Luminosity Upgrade, Subashini De Silva, Hyekyoung Park, Jean R. Delayen, Zi Li Jan 2018

Rf Tests Of Rf-Dipole Prototype Crabbing Cavities For Lhc High Luminosity Upgrade, Subashini De Silva, Hyekyoung Park, Jean R. Delayen, Zi Li

Physics Faculty Publications

The superconducting rf-dipole crabbing cavity is one of the two crabbing cavity designs proposed for the LHC high luminosity upgrade. The proof-of-principle (P-o-P) rf-dipole cavity operating at 400 MHz has demonstrated performance exceeding the design specifications. The prototype cavity for SPS beam test has been designed to include the fundamental power coupler, HOM couplers, and all the ancillary components intended to meet the design requirements. The crab cavities will be installed in the SPS beam line prior to the installation in LHC; this will be the first crabbing cavity operation on a proton beam. The fabrication of two prototype rf-dipole …

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Lessons Learned From Rf-Dipole Prototype Cavities For Lhc High Luminosity Upgrade, Subashini De Silva, Jean R. Delayen, Z. Li, H. Park Jan 2018

Lessons Learned From Rf-Dipole Prototype Cavities For Lhc High Luminosity Upgrade, Subashini De Silva, Jean R. Delayen, Z. Li, H. Park

Physics Faculty Publications

The RF-Dipole Crabbing Cavity designed for the LHC High Luminosity Upgrade includes two higher order mode (HOM) couplers. One of the HOM couplers is an rf filter, which is a high pass filter designed to couple to the horizontal dipole modes and accelerating modes up to 2 GHz, while rejecting the fundamental operating mode at 400 MHz. The coupler consists of a high pass filter circuit where the rejection of the operating mode and transmission of HOMs are sensitive to dimensional deviations. An rf test box has been designed to measure the transmission of the rf filter in order to …

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A Realization Of Modernity: Case Studies In Connectivity And Time, Mari Gorman Sep 2017

A Realization Of Modernity: Case Studies In Connectivity And Time, Mari Gorman

Dissertations, Theses, and Capstone Projects

My stated goal in applying to The Graduate Center was to explore my previous research in diverse fields of study. This research, the result of a formal investigation of acting, was and still is centrally focused on the subject of relationship itself, relationships being what actors create. In pursuit of a greater understanding of the essential nature of relationship in practical terms, a self-organizing complex system that constitutes universal relationship was unexpectedly discovered. As such, this system has been shown to offer solutions to many outstanding problems in diverse areas of study. The Liberal Studies program track, Approaches to Modernity …

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Modeling Local Crabbing Dynamics In The Jleic Ion Collider Ring, Salvador Sosa Guitron, Vasiliy Morozov, Jean Delayen May 2017

Modeling Local Crabbing Dynamics In The Jleic Ion Collider Ring, Salvador Sosa Guitron, Vasiliy Morozov, Jean Delayen

Physics Faculty Publications

The Jefferson Lab Electron-Ion Collider (JLEIC) design considers a 50 mrad crossing angle at the Interaction Point. Without appropriate compensation, this could geometrically reduce the luminosity by an order of magnitude. A local crabbing scheme is implemented to avoid the luminosity loss: crab cavities are placed at both sides of the interaction region to restore a head-on collision scenario. In this contribution, we report on the implementation of a local crabbing scheme in the JLEIC ion ring. The effects of this correction scheme on the stability of proton bunches are analyzed using the particle tracking software elegant.

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Synthesis And Characterization Of Amphiphiles For Mammalian Cell Transfection And Antimicrobial Activity, Joseph William Meisel Aug 2016

Synthesis And Characterization Of Amphiphiles For Mammalian Cell Transfection And Antimicrobial Activity, Joseph William Meisel

Dissertations

Amphiphiles are molecules that contain both water-soluble and water-insoluble components. The dual nature of these molecules engenders remarkable properties including the ability to self-assemble into ordered structures. Cell membranes are composed of amphiphilic phospholipids that organize into a bilayer motif. Synthetic amphiphiles can interact with natural membranes and influence the transport of molecules across the cell membrane. The work elaborated in this report employs amphiphiles to co-assemble with DNA and transport the genetic material across cell membranes. First, a simplified method for interacting DNA with amphiphiles was developed. Second, a series of known ion-transporting compounds were assayed for their interaction …

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Bunch Splitting Simulations For The Jleic Ion Collider Ring, R. Gamage, T. Satogata Jun 2016

Bunch Splitting Simulations For The Jleic Ion Collider Ring, R. Gamage, T. Satogata

Physics Faculty Publications

We describe the bunch splitting strategies for the proposed JLEIC ion collider ring at Jefferson Lab. This complex requires an unprecedented 9:6832 bunch splitting, performed in several stages. We outline the problem and current results, optimized with ESME including general parameterization of 1:2 bunch splitting for JLEIC parameters.

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Electrochemically Active, Novel Layered M-Znv2o6 Nanobelts For Highly Rechargeable Na-Ion Energy Storage, Yan Sun, Chun-Sheng Li, Qiuran Yang, Shulei Chou, Hua-Kun Liu Jan 2016

Electrochemically Active, Novel Layered M-Znv2o6 Nanobelts For Highly Rechargeable Na-Ion Energy Storage, Yan Sun, Chun-Sheng Li, Qiuran Yang, Shulei Chou, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Electrode materials with a three-dimensional (3D) layered framework and excellent electrochemical stability can provide a new avenue for enhancing the overall performance of promising sodium ion batteries. Here, we show that layered monoclinic (m) - ZnV2O6 nanobelts with high chemical activity for Na-ion energy storage have been effectively fabricated via a rapid microwave irradiation method over the reaction time of 8 h, in which the fabricating efficiency is 24.5 times greater in comparison with the traditional hydrothermal method. The morphology and phase evolutions were verified by means of X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. This study also …

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A Green And Facile Way To Prepare Granadilla-Like Silicon-Based Anode Materials For Li-Ion Batteries, Lei Zhang, Ranjusha Rajagopalan, Haipeng Guo, Xianluo Hu, S X. Dou, Hua-Kun Liu Jan 2016

A Green And Facile Way To Prepare Granadilla-Like Silicon-Based Anode Materials For Li-Ion Batteries, Lei Zhang, Ranjusha Rajagopalan, Haipeng Guo, Xianluo Hu, S X. Dou, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

A yolk-shell-structured carbon@void@silicon (CVS) anode material in which a void space is created between the inside silicon nanoparticle and the outer carbon shell is considered as a promising candidate for Li-ion cells. Untill now, all the previous yolk-shell composites were fabricated through a templating method, wherein the SiO2 layer acts as a sacrificial layer and creates a void by a selective etching method using toxic hydrofluoric acid. However, this method is complex and toxic. Here, a green and facile synthesis of granadilla-like outer carbon coating encapsulated silicon/carbon microspheres which are composed of interconnected carbon framework supported CVS nanobeads is reported. …

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Si-Containing Precursors For Si-Based Anode Materials Of Li-Ion Batteries: A Review, Lei Zhang, Xiaoxiao Liu, Qianjin Zhao, Shi Xue Dou, Hua-Kun Liu, Yunhui Huang, Xianluo Hu Jan 2016

Si-Containing Precursors For Si-Based Anode Materials Of Li-Ion Batteries: A Review, Lei Zhang, Xiaoxiao Liu, Qianjin Zhao, Shi Xue Dou, Hua-Kun Liu, Yunhui Huang, Xianluo Hu

Australian Institute for Innovative Materials - Papers

Lithium-ion batteries with high energy density are in demand for consumer electronics, electric vehicles, and grid-scale stationary energy storage. Si is one of the most promising anode materials due to its extremely high specific capacity. However, the full application of Si-based anode materials is limited by poor cycle life and rate capability resulted from low ionic/electronic conductivity and large volume change over cycling. In recent years, great progress has been made in improving the performance of Si anodes by employing nanotechnology. The preparation methods are essentially important, in which the precursors used are crucial to design and control the microstructure …

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Superior Sodium-Ion Storage Performance Of Co3o4@Nitrogen-Doped Carbon: Derived From A Metal–Organic Framework, Ying Wang, Caiyun Wang, Yijing Wang, Hua-Kun Liu, Zhenguo Huang Jan 2016

Superior Sodium-Ion Storage Performance Of Co3o4@Nitrogen-Doped Carbon: Derived From A Metal–Organic Framework, Ying Wang, Caiyun Wang, Yijing Wang, Hua-Kun Liu, Zhenguo Huang

Australian Institute for Innovative Materials - Papers

Nitrogen-doped carbon coated Co 3 O 4 nanoparticles (Co 3 O 4 @NC) with high Na-ion storage capacity and unprecedented long-life cycling stability are reported in this paper. The Co 3 O 4 @NC was derived from a metal – organic framework ZIF-67, where the Co ions and organic linkers were, respectively, converted to Co 3 O 4 nanoparticle cores and nitrogen-doped carbon shells through a controlled two-step annealing process. The Co 3 O 4 @NC shows a porous nature with a surface area of 101 m 2 g 1 . When applied as an anode for sodium ion batteries …

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Mos2 With An Intercalation Reaction As A Long-Life Anode Material For Lithium Ion Batteries, Zhe Hu, Qiannan Liu, Weiyi Sun, Weijie Li, Zhanliang Tao, Shulei Chou, Jun Chen, S X. Dou Jan 2016

Mos2 With An Intercalation Reaction As A Long-Life Anode Material For Lithium Ion Batteries, Zhe Hu, Qiannan Liu, Weiyi Sun, Weijie Li, Zhanliang Tao, Shulei Chou, Jun Chen, S X. Dou

Australian Institute for Innovative Materials - Papers

MoS2 with expanded layers was synthesized and characterized as an anode material for lithium ion batteries in an ether-based electrolyte by cutting off the terminal discharge voltage at 1.0 V to prevent a MoS2 conversion reaction. The as-prepared MoS2 achieved 96% capacity retention even after 1400 cycles and showed good performance in a full cell with LiCoO2 as the counter electrode.

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High-Fidelity Simulations Of Long-Term Beam-Beam Dynamics On Gpus, B. Terzić, K. Arumugam, M. Aturban, C. Cotnoir, A. Godunov, D. Ranjan, M. Stefani, M. Zubair, F. Lin, V. Morozov, Y. Roblin, H. Zhang Jan 2016

High-Fidelity Simulations Of Long-Term Beam-Beam Dynamics On Gpus, B. Terzić, K. Arumugam, M. Aturban, C. Cotnoir, A. Godunov, D. Ranjan, M. Stefani, M. Zubair, F. Lin, V. Morozov, Y. Roblin, H. Zhang

Physics Faculty Publications

Future machines such as the Electron Ion Collider (MEIC), linac-ring machines (eRHIC) or LHeC are particularly sensitive to beam-beam effects. This is the limiting factor for long-term stability and high luminosity reach. The complexity of the non-linear dynamics makes it challenging to perform such simulations typically requiring millions of turns. Until recently, most of the methods have involved using linear approximations and/or tracking for a limited number of turns. We have developed a framework which exploits a massively parallel Graphical Processing Units (GPU) architecture to allow for tracking millions of turns in a sympletic way up to an arbitrary order. …

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Development Of The Electron Cooling Simulation Program For Jleic, H. Zhang, J. Chen, R. Li, Y. Zhang, H. Huang, L. Luo Jan 2016

Development Of The Electron Cooling Simulation Program For Jleic, H. Zhang, J. Chen, R. Li, Y. Zhang, H. Huang, L. Luo

Mathematics & Statistics Faculty Publications

In the JLab Electron Ion Collider (JLEIC) project the traditional electron cooling technique is used to reduce the ion beam emittance at the booster ring, and to compensate the intrabeam scattering effect and maintain the ion beam emittance during collision at the collider ring. A new electron cooling process simulation program has been developed to fulfill the requirements of the JLEIC electron cooler design. The new program allows the users to calculate the electron cooling rate and simulate the cooling process with either DC or bunched electron beam to cool either coasting or bunched ion beam. It has been benchmarked …

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Unraveling The Mechanism Of Selective Ion Transport In Hydrophobic Subnanometer Channels, Hui Li, Joseph S. Francisco, Xiao Cheng Zeng Jan 2015

Unraveling The Mechanism Of Selective Ion Transport In Hydrophobic Subnanometer Channels, Hui Li, Joseph S. Francisco, Xiao Cheng Zeng

Xiao Cheng Zeng Publications

Recently reported synthetic organic nanopore (SONP) can mimic a key feature of natural ion channels, i.e., selective ion transport. However, the physical mechanism underlying the K+/Na+ selectivity for the SONPs is dramatically different from that of natural ion channels. To achieve a better understanding of the selective ion transport in hydrophobic subnanometer channels in general and SONPs in particular, we perform a series of ab initio molecular dynamics simulations to investigate the diffusivity of aqua Na+ and K+ ions in two prototype hydrophobic nanochannels: (i) an SONP with radius of 3.2 Å, and (ii) single-walled …

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Facile Method To Synthesize Na-Enriched Na1+Xfefe(Cn)6 Frameworks As Cathode With Superior Electrochemical Performance For Sodium-Ion Batteries, Weijie Li, Shulei Chou, Jiazhao Wang, Yong-Mook Kang, Jianli Wang, Yong Liu, Qinfen Gu, Hua-Kun Liu, S X. Dou Jan 2015

Facile Method To Synthesize Na-Enriched Na1+Xfefe(Cn)6 Frameworks As Cathode With Superior Electrochemical Performance For Sodium-Ion Batteries, Weijie Li, Shulei Chou, Jiazhao Wang, Yong-Mook Kang, Jianli Wang, Yong Liu, Qinfen Gu, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

Different Na-enriched Na1+xFeFe(CN)6 samples can be synthesized by a facile one-step method, utilizing Na4Fe(CN)6 as the precursor in a different concentration of NaCl solution. As-prepared samples were characterized by a combination of synchrotron X-ray powder diffraction (S-XRD), Mössbauer spectroscopy, Raman spectroscopy, magnetic measurements, thermogravimetric analysis, X-ray photoelectron spectroscopy, and inductively coupled plasma analysis. The electrochemical results show that the Na1.56Fe[Fe(CN)6]·3.1H2O (PB-5) sample shows a high specific capacity of more than 100 mAh g-1 and excellent capacity retention of 97% over 400 cycles. The details structural evolution during …

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Dual Yolk-Shell Structure Of Carbon And Silica-Coated Silicon For High-Performance Lithium-Ion Batteries, L Y. Yang, H Z. Li, Jun Liu, Ziqi Sun, S S. Tang, M Lei Jan 2015

Dual Yolk-Shell Structure Of Carbon And Silica-Coated Silicon For High-Performance Lithium-Ion Batteries, L Y. Yang, H Z. Li, Jun Liu, Ziqi Sun, S S. Tang, M Lei

Australian Institute for Innovative Materials - Papers

Silicon batteries have attracted much attention in recent years due to their high theoretical capacity, although a rapid capacity fade is normally observed, attributed mainly to volume expansion during lithiation. Here, we report for the first time successful synthesis of Si/void/SiO2/void/C nanostructures. The synthesis strategy only involves selective etching of SiO2 in Si/SiO2/C structures with hydrofluoric acid solution. Compared with reported results, such novel structures include a hard SiO2-coated layer, a conductive carbon-coated layer, and two internal void spaces. In the structures, the carbon can enhance conductivity, the SiO2 layer has mechanically …

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Sodium-Difluoro(Oxalato)Borate (Nadfob): A New Electrolyte Salt For Na-Ion Batteries, Juner Chen, Zhenguo Huang, Caiyun Wang, Spencer H. Porter, Baofeng Wang, Wilford Lie, Hua-Kun Liu Jan 2015

Sodium-Difluoro(Oxalato)Borate (Nadfob): A New Electrolyte Salt For Na-Ion Batteries, Juner Chen, Zhenguo Huang, Caiyun Wang, Spencer H. Porter, Baofeng Wang, Wilford Lie, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

A new electrolyte salt, sodium-difluoro(oxalato)borate (NaDFOB), was synthesized and studied, which enables excellent reversible capacity and high rate capability when used in Na/Na0.44MnO2 half cells. NaDFOB has excellent compatibility with various common solvents used in Na-ion batteries, in strong contrast to the solvent dependent performances of NaClO4 and NaPF6. In addition, NaDFOB possesses good stability and generates no toxic or dangerous products when exposed to air and water. All these properties demonstrate that NaDFOB could be used to prepare high performance electrolytes for emerging Na-ion batteries.

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Synthesis Of Different Cuo Nanostructures By A New Catalytic Template Method As Anode Materials For Lithium-Ion Batteries, Xiaohang Ma, Shuang Zeng, Bangkun Zou, Xin Liang, Jia-Ying Liao, Chunhua Chen Jan 2015

Synthesis Of Different Cuo Nanostructures By A New Catalytic Template Method As Anode Materials For Lithium-Ion Batteries, Xiaohang Ma, Shuang Zeng, Bangkun Zou, Xin Liang, Jia-Ying Liao, Chunhua Chen

Australian Institute for Innovative Materials - Papers

CuO powders composed of different rod-like clusters or dandelion-like nanospheres are prepared by a low-temperature thermal decomposition process of Cu(OH)2 precursors, which are obtained via a catalytic template method. A tentative mechanism is proposed to explain the formation and transformation of different Cu(OH)2 nanostructures. X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, field-emission scanning electron microscopy, transmission electron microscopy, infrared spectra analysis, Brunauer-Emmett-Teller measurements, and galvanostatic cell cycling are employed to characterize the structures and electrochemical performance of these CuO samples. The results show that these CuO samples obtained after 500 °C calcination have a stable cycling performance with a reversible …

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3d Fe2(Moo4)3 Microspheres With Nanosheet Constituents As High-Capacity Anode Materials For Lithium-Ion Batteries, Hao Zheng, Shiqiang Wang, Jiazhao Wang, Jun Wang, Lin Li, Yun Yang, Chuanqi Feng, Ziqi Sun Jan 2015

3d Fe2(Moo4)3 Microspheres With Nanosheet Constituents As High-Capacity Anode Materials For Lithium-Ion Batteries, Hao Zheng, Shiqiang Wang, Jiazhao Wang, Jun Wang, Lin Li, Yun Yang, Chuanqi Feng, Ziqi Sun

Australian Institute for Innovative Materials - Papers

Three-dimensional (3D) Fe2(MoO4)3 microspheres with ultrathin nanosheet constituents are first synthesized as anode materials for the lithium-ion battery. It is interesting that the single-crystalline nanosheets allow rapid electron/ion transport on the inside, and the high porosity ensures fast diffusion of liquid electrolyte in energy storage applications. The electrochemical properties of Fe2(MoO4)3 as anode demonstrates that 3D Fe2(MoO4)3 microspheres deliver an initial capacity of 1855 mAh/g at a current density of 100 mA/g. Particularly, when the current density is increased to 800 mA/g, the reversible capacity of Fe2(MoO4)3 anode still arrived at 456 mAh/g over 50 cycles. The large and reversible …

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Crystalline Tio2@C Nanosheet Anode With Enhanced Rate Capability For Lithium-Ion Batteries, Fan Yang, Yuxuan Zhu, Xiu Li, Chao Lai, Wei Guo, Jianmin Ma Jan 2015

Crystalline Tio2@C Nanosheet Anode With Enhanced Rate Capability For Lithium-Ion Batteries, Fan Yang, Yuxuan Zhu, Xiu Li, Chao Lai, Wei Guo, Jianmin Ma

Australian Institute for Innovative Materials - Papers

TiO2@C nanosheets have been obtained by a facile solvothermal method using titanate butoxide and hydrofluoric acid as precursors, followed by our novel carbon coating technique using oleic acid as the carbon source. The TiO2@C nanosheet anode shows a high discharge capacity of 145.8 mA h g-1 after 50 cycles and excellent rate capability.

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Integration Of Mno@Graphene With Graphene Networks Towards Li-Ion Battery Anodes, Wei Guo, Xiu Li, Dickon Ng, Jianmin Ma Jan 2015

Integration Of Mno@Graphene With Graphene Networks Towards Li-Ion Battery Anodes, Wei Guo, Xiu Li, Dickon Ng, Jianmin Ma

Australian Institute for Innovative Materials - Papers

In this work, we have directly integrated MnO@graphene with graphene networks through the thermal decomposition of a Mn-oleate complex in an Ar atmosphere at high temperatures. By introducing dual protective graphene shells and networks, the as-synthesized MnO/graphene composites exhibited superior cycling performance.

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Yolk-Shell Silicon-Mesoporous Carbon Anode With Compact Solid Electrolyte Interphase Film For Superior Lithium-Ion Batteries, Jianping Yang, Yunxiao Wang, Shulei Chou, Renyuan Zhang, Yanfei Xu, Jianwei Fan, Weixian Zhang, Hua-Kun Liu, Dongyuan Zhao, S X. Dou Jan 2015

Yolk-Shell Silicon-Mesoporous Carbon Anode With Compact Solid Electrolyte Interphase Film For Superior Lithium-Ion Batteries, Jianping Yang, Yunxiao Wang, Shulei Chou, Renyuan Zhang, Yanfei Xu, Jianwei Fan, Weixian Zhang, Hua-Kun Liu, Dongyuan Zhao, S X. Dou

Australian Institute for Innovative Materials - Papers

Silicon as an electrode suffers from short cycling life, as well as unsatisfactory rate-capability caused by the large volume expansion (~400%) and the consequent structural degradation during lithiation/delithiation processes. Here, we have engineered unique void-containing mesoporous carbon-encapsulated commercial silicon nanoparticles (NPs) in yolk-shell structures. In this design, the silicon NPs yolk are wrapped into open and accessible mesoporous carbon shells, the void space between yolk and shell provides enough room for Si expansion, meanwhile, the porosity of carbon shell enables fast transport of Li+ ions between electrolyte and silicon. Our ex-situ characterization clearly reveals for the first time that a …

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