Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
- Discipline
- Publication Type
- File Type
Articles 1 - 3 of 3
Full-Text Articles in Physical Sciences and Mathematics
Magnetic-Field-Induced Alignment-To-Orientation Conversion In Sodium, G. Schinn, Xianming Han
Magnetic-Field-Induced Alignment-To-Orientation Conversion In Sodium, G. Schinn, Xianming Han
Xianming Han
We report a detailed investigation of excited-state alignment-to-orientation conversion in the presence of an external magnetic field. This counterintuitive phenomenon occurs under intermediate-coupling conditions. A weak, linearly polarized, cw laser beam was used to excite and align the Na 3P3/2 state in an atomic beam along the z direction. The degree of circular polarization of the resulting fluorescence was detected along the z direction as a function of magnetic-field strength. The spectrally integrated transitions originating from individual F levels of the 3S1/2 state yield a maximum circular-polarization fraction of ∼40%; integrating the circular polarization over all the allowed 3S1/2-3P3/2 transitions …
Synthetic Strategies For Tailoring The Physicochemical And Magnetic Properties Of Hydrophobic Magnetic Ionic Liquids, Omprakash Nacham, Kevin D. Clark, Honglian Yu, Jared L. Anderson
Synthetic Strategies For Tailoring The Physicochemical And Magnetic Properties Of Hydrophobic Magnetic Ionic Liquids, Omprakash Nacham, Kevin D. Clark, Honglian Yu, Jared L. Anderson
Jared L. Anderson
Magnetic ionic liquids (MILs) are a subclass of ionic liquids (ILs) containing paramagnetic components and are readily manipulated by an external magnetic field. Due to their hydrophilic nature, very few applications of MILs in aqueous systems have been reported. In this study, three general classes of hydrophobic MILs including monocationic, symmetrical/unsymmetrical dicationic, and symmetrical/unsymmetrical tricationic MILs were synthesized and characterized. By tuning the structure of the MIL, various physicochemical properties including water solubility, magnetic susceptibility, and melting point were regulated. MILs synthesized with the benzimidazolium cation were shown to exhibit lower water solubility (0.1% (w/v)) when compared to those containing …
Magnetic-Field-Induced Alignment-To-Orientation Conversion In Sodium, G. W. Schinn, Xianming Han
Magnetic-Field-Induced Alignment-To-Orientation Conversion In Sodium, G. W. Schinn, Xianming Han
Scholarship and Professional Work - LAS
We report a detailed investigation of excited-state alignment-to-orientation conversion in the presence of an external magnetic field. This counterintuitive phenomenon occurs under intermediate-coupling conditions. A weak, linearly polarized, cw laser beam was used to excite and align the Na 3P3/2 state in an atomic beam along the z direction. The degree of circular polarization of the resulting fluorescence was detected along the z direction as a function of magnetic-field strength. The spectrally integrated transitions originating from individual F levels of the 3S1/2 state yield a maximum circular-polarization fraction of ∼40%; integrating the circular polarization over all the allowed 3S1/2-3P3/2 transitions …