Physical Sciences and Mathematics Commons^™

Chemostratigraphic And Paleoclimatic Studies Of Cloverly Formation, Northern Wyoming, U.S.A, Queen Amarachi Kalu

Graduate Theses and Dissertations

The Early – Late Cretaceous transition in Western North America recorded a period of rapid climatic and tectonic change in Earth’s history. Major climate events associated with large igneous province eruptions caused several instances of ocean anoxic events (OAE) and perturbations to the global carbon (C) – cycle. These perturbations to the global C-cycle are observed in the bulk organic C record of both marine and terrestrial deposits and can be used to correlate units across major depositional basins. Major efforts are being made to generate time-constrained palaeontologic and paleoclimate information from the North American Cordilleran foreland basin and C-isotope …

Geochemical Characterization Of The Bone Spring Formation, Delaware Basin, Using Chemostratigraphy And Integrated Petrophysics, David Tonner

Electronic Theses and Dissertations

The Delaware Basin forms part of West Texas's and New Mexico’s famous petroleum-generating Permian Basin. The Bone Spring Formation is a prolific hydrocarbon producer within this basin, creating one of the world’s richest oil shales. This formation has lithological sequences that are characterized by repeating carbonate and siliciclastic intervals of a third-order cycle which can largely be correlated to highstand and lowstand systems tracts, respectively. Lithological complexity and facies change are manifested by debris flows, turbidites, and slumps. In addition to glacio-eustasy, both tectonism and broader Milankovitch cycles have influenced the depositional history. Previous investigations have utilized cores and wireline …

Application Of Chemostratigraphic Methods To Floodplain Alluvial Deposits Within The Big Harris Creek Basin, North Carolina, Samantha N. Sullivan, Jerry R. Miller, Carmen L. Huffman

Chemistry & Biochemistry Faculty Publications

Big Harris Creek, North Carolina, possesses a geomorphic history and alluvial stratigraphic record similar to many drainages in southern Appalachian Piedmont. An approximately 1 km reach of Upper Stick Elliott Creek, a tributary to Big Harris Creek, was used herein to (1) explore the use of chemostratigraphic methods to define and correlate late Holocene alluvial deposits along this relatively uncontaminated rural stream containing legacy sediments (historic, anthropogenically derived deposits), and (2) interpret depositional floodplain processes within small (<10 km²), headwater drainages. The lithofacies within four floodplain sections were described in channel banks and sampled at about 5 cm intervals. …

Age And Chemostratigraphy Of The Finlayson Lake District, Yukon: Implications For Volcanogenic Massive Sulfide (Vms) Mineralization And Tectonics Along The Western Laurentian Continental Margin, Matthew J. Manor, Stephen J. Piercey, Donald C. Murphy, Corey J. Wall

Geosciences Faculty Publications and Presentations

The Yukon-Tanana terrane in the Finlayson Lake district, Yukon, represents one of the first arc–back-arc systems that formed adjacent to the Laurentian continental margin in the mid-Paleozoic. Back-arc rocks contain many large and high-grade volcanogenic massive sulfide (VMS) deposits. This study integrates U-Pb zircon geochronology, lithogeochemistry, and Hf-Nd isotopes to establish precise controls on tectonomagmatic activity adjacent to the western Laurentian margin in the Late Devonian to Early Mississippian. High-precision chemical abrasion- (CA-) ID-TIMS U-Pb zircon geochronology defines coeval arc (ca. 363.1 to 348 Ma) and back-arc (ca. 363.3 to 355.0 Ma) magmatism in the Finlayson Lake district that intruded …

Using Geochemical Composition To Determine Paleo Environmental Conditions And Source Inputs In Paleozoic Rocks Within The Central Kansas Uplift Usa, Christiana Fumnanya Eziashi

Master's Theses

Paleoenvironmental conditions, sediment characteristics and lateral continuity using chemostratigraphy are not well established for stratigraphic units associated with some small fields within the Central Kansas Uplift (CKU). Samples of drill cuttings recovered from six wells (Hottman #1, and Hottman-Furthmeyer#1, Yocemento #1, Mong Benno #2, Rhian #3 and Worcester #1) at 10 ft intervals between 3150 ft and 3900 ft below ground level, were processed and analyzed using X-ray fluorescence (XRF) and X-Ray diffraction (XRD). The XRF technique was used to determine elemental compositions, and XRD was used to determine mineral content. The composition of the rock cuttings was used to …

Geochemical Characterization Of The Utica Shale Play Using Xrf-Based Chemostratigraphy In Ohio, Barbara Kemeh, Julie M. Bloxson

Electronic Theses and Dissertations

The Utica shale is an extensive gas shale play within the Appalachian Basin, expanding from Quebec through New York, into Pennsylvania, West Virginia and Ohio. Currently a target for gas exploration, it is also the source rock for much of the Paleozoic reservoirs throughout the basin. However, the Utica-Point Pleasant lithology varies significantly across the Appalachian Basin which can make it challenging to characterize.

The Utica shale Play consists of the Trenton/Lexington Limestones, Point Pleasant Formation and Utica shale. The Point Pleasant Formation and Utica shale are often grouped together, especially in Ohio because they are difficult to visually distinguish …

Carbon-Isotope Chemostratigraphy And Fluvial Sedimentology Of The Moenave Formation, Utah, Jordan Oefinger

Graduate Theses and Dissertations

The end Triassic extinction (ETE) is one of the largest mass extinction events of the Phanerozoic, and it has been hypothesized that this event, as well as the Triassic-Jurassic (TJ) boundary, are preserved within the Moenave Formation of the Colorado Plateau. Identification of this boundary within southwest Utah sections of the Colorado Plateau region is critical for better understanding the relationship between climate change and the ETE in terrestrial, low latitude paleoenvironments. The Moenave Formation is well exposed in Blacks Canyon of Zion National Park and in the nearby Warner Valley, where detailed sedimentologic observations and carbon isotope sampling have …

Chemostratigraphy Of Carbonate Gravity Flows Of The Wolfcamp Formation In Crockett County, Midland Basin, Texas, Alex Blizzard, Julie Bloxson

Electronic Theses and Dissertations

Sediment gravity flows into deep-water environments are important stratigraphic traps in lithologically diverse reservoirs generating multiple plays for hydrocarbon exploration. These highly heterogeneous deposits can be studied by utilizing chemostratigraphy and higher-order sequence stratigraphy; being an accurate method for reservoir characterization. Studying these gravity flows along a carbonate platform’s slope can further expand an understanding of the stratigraphy that is filling adjacent basins. The application of elemental analyses can support in identifying mineralogy that impact reservoir quality, especially when conventional testing cannot be applied.

This study utilizes five cores containing the Wolfcamp Formation from the southeastern slope of the Central …

Chronostratigraphic Correlation Of The Burnt Bluff Group Across The Michigan Basin, Usa, Mohammed A. Al-Musawi

Masters Theses

In the Michigan Basin, the Burnt Bluff Group (BBG) is lower Middle Silurian in age (Llandovery), and is composed of limestones and dolostones. The BBG is bounded above by the Schoolcraft Formation and below by the Cabot Head Shale. The BBG in northern Lower Michigan is composed of three formations, including the Lime Island, Byron, and Hendricks, which reflect deposition on a broad shallow marine shelf. In contrast, the BBG in central Michigan is composed of a single lithologic unit called informally the “undifferentiated BBG (UD-BBG),” which reflects deposition in a deeper marine basin. Lithostratigraphically, the three formations in the …

A Joint Xrf-Δ13CCarb Chemostratigraphic Approach For Characterizing Paleo-Environmental Processes In The Mudstone-Dominated Wolfcamp Formation Of West Texas, Frank Tamakloe

Theses and Dissertations--Earth and Environmental Sciences

The Late Paleozoic Ice Age represents a dynamic period in Earth system history recording a shift from icehouse to greenhouse conditions. Concomitant with this change was a series high-frequency, high-amplitude sea level fluctuations leading to the deposition of “Kansas type” cyclothems in the Mid-Continent, and a similar rhythmic expression of interbedded shales and carbonates in the Midland Basin. Stable isotope geochemistry is a particularly powerful tool when examining these mud-rich successions because changes in organic matter partitioning may be recorded first in δ¹³C_DIC of sea-water and consequently in δ¹³C_carb of marine rocks. The δ …

The Geochemical Signatures Of The Silurian?Devonian Succession In Easternsaudi Arabia, Mohamed Soua

Turkish Journal of Earth Sciences

This study was performed on 663 sandstone core and cutting samples taken from the Silurian?Devonian succession in five wells, located in eastern Saudi Arabia. This study aimed to correlate the Tawil Formation in the study wells, defining the lower Qalibah/ Tawil and upper Tawil/Jauf boundaries. The Tawil Formation is mostly characterized by clastic-dominated fluvial to marginal marine depositional environments. A chemostratigraphic correlation workflow was established using key element ratios and comprising four zones (C1 to C4) and five subzones (C2-1 to C2-3 and C3-1-C3-2). The chemostratigraphic zonation allowed robust characterization of stratigraphy in the uppermost Qalibah, Tawil, and lower Jauf …

X-Ray Fluorescence Analysis Of Tuscaloosa Marine Shale Cuttings From Horizontally Drilled Wells, Xiaotian Wang

Electronic Theses and Dissertations

The Upper Cretaceous Tuscaloosa Marine Shale (TMS) is a gray to black fissile marine shale deposited at depth of between 10,000 and 20,000 ft near the ancient Gulf of Mexico. The TMS has been gradually developed as a hydrocarbon reservoir in the past several decades. But there are rare researches evaluating geochemical properties based on chemostratigraphy of the TMS. The objective of this research is to spatially evaluate geophysical properties and chemostratigraphy of the TMS, to characterize elemental changes along well paths and to evaluate the effect of basic sample clean on XRF results. The data available for this study …

Application Of Handheld Ed-Xrf For High-Resolution Chemostratigraphy In Texturally Homogeneous Carbonate Mudstones: Salina A-1 Carbonate (Silurian), Michigan Basin, Matthew A. Hemenway

Masters Theses

Handheld energy dispersive x-ray fluorescence spectrometry (ED-XRF) is routinely used to observe elemental variability in fine-grained siliciclastics but has been applied rarely in fine-grained carbonates. Here, ED-XRF chemostratigraphy is utilized in the texturally homogenous, mudstones of the Silurian A-1 Carbonate (A-1C), Michigan Basin. Previous studies on the A-1C focused on the stratigraphic relationship with the underlying Niagaran reefs, so little is known about the geological variability in the basin center. In this study, high-resolution elemental data from nine cores were integrated with petrographic and mineralogical observations to evaluate two hypotheses: (1) Texturally homogeneous, basin-center mudstones in the A-1C have spatially …

Constraining Kura And South Caspian Basin Maikop Source Rock Stratigraphy, Deposition, And Timing Using Chemostratigraphy Of Redox-Sensitive Metals And Re-Os Geochronology, Alex M. Washburn

Theses and Dissertations

The Oligocene-Miocene Maikop Series in the South Caspian and Kura Basins is the key petroleum source rock for both offshore and onshore petroleum development in Azerbaijan. The Maikop is a thick (up to 3 km) succession of silty mudstones containing up to 15% total organic carbon (TOC), but is greatly lacking diagnostic microfaunal assemblages useful for dating and stratigraphically constraining the deposition of the mudstone. Current stratigraphic constraints relying on microfaunal assemblages, radiostratigraphy, and chemostratigraphy are robust, but key information is still missing. This study adds numerical age data to Maikop stratigraphy through Re-Os geochronology. Of five sample suites analyzed …

Sequence Stratigraphy, Chemostratigraphy, And Biostratigraphy Of Lower Ordovician Units In Northeastern And Western Central Utah: Regional Implications, Colter R. Davis

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Lower to Middle Ordovician Garden City Formation and Pogonip Group are mixed carbonate and sandy marine rocks deposited on the western margin of ancestral North America. The Garden City Formation was deposited in the Northern Utah Basin and the Pogonip Group was deposited in the Ibex Basin. These two basins experienced different rates of subsidence that resulting in significant thickness differences between rock units and different rock types related to sea level change. This study provides a unique opportunity to examine changes in rock types, rock chemistry, and fossil types as sea level changed within two separate basins in …

Stratigraphic, Geochemical, And Geochronological Analysis Of The Wolfcamp-D Interval, Midland Basin, Texas, Zachary S. Perlman

Theses and Dissertations--Earth and Environmental Sciences

Subsurface data derived from ~388 ft of drill core from Martin County (TX) were used to understand the depositional setting of the Wolfcamp-D, a petroleum producing interval in the Midland Basin. Elemental geochemistry collected via x-ray fluorescence revealed a highly variable depositional history marked by the deposition of diverse siliciclastic and carbonate lithofacies. Integration of multiple datasets resulted in the interpretation of nine lithofacies, whose deposition appears cyclical. Correlations between molybdenum and total organic carbon indicate slow recharge of bottom waters and anoxic/euxinicconditions within the basin. The presence of phosphatic nodules coinciding with siliceous black mudrocks suggested high levels of …

Stratigraphic, Geochemical, And Well Log Analysis Of The Wolfcamp-D Unconventional Play In The Central Midland Basin, Texas, Patrick Thomas Ryan

Theses and Dissertations--Earth and Environmental Sciences

This M.S. thesis utilizes diverse subsurface datasets from the central Midland Basin, a recently reinvigorated petroleum producing region, to better understand the depositional history of the prospective Wolfcamp-D interval. An integrated set of methods were applied to ~320 ft of drill core from Midland County (Texas). Elemental chemostratigraphy collected via x-ray fluorescence highlights the pervasive fine-scale variability in the stratigraphy of the core, and aided in the classification of three different mudrock facies types. Organic-rich, siliceous mudrocks are cyclically interbedded with aluminum-rich mudrocks and carbonates throughout the Wolfcamp-D. Trace metal correlations with total organic carbon indicate slow bottom-water recharge from …

Paleoclimate Implications From Stable Isotope Analysis Of Sedimentary Organic Carbon And Vertebrate Fossils From The Cedar Mountain Formation, Ut, U.S.A., Garrett Andrew Hatzell

Graduate Theses and Dissertations

Oxygen and carbon isotopic compositions of fossilized vertebrate teeth and bone were analyzed to determine isotopic values of vertebrate faunal diet from the early Cretaceous Cedar Mountain Formation of Utah. Results for δ18O of PO4 (δ18Op) (Suarez et al., 2014) from the same data set have been compared to the δ18O of CO3 (δ18Oc) portion of teeth and turtle shell to determine if diagenetic alteration of the isotopes has occurred by plotting the line of best fit equation that models the relationship between unaltered δ18OP and δ18OC of modern mammals from Iacumin et al., 1996. Results indicate slight diagenesis of …

Terrestrial Impacts Of The Central Atlantic Magmatic Province On Western Pangea, Todd Kenneth Knobbe

Graduate Theses and Dissertations

Earth's climate is predominantly controlled by the fluctuation of greenhouse gases, specifically CO2 and CH4, over geologic time. The late Triassic is a period of abrupt climate change that has been associated with a disruption to the global carbon cycle due the emplacement of the Central Atlantic Magmatic Province (CAMP). Evidence has shown that this global carbon cycle perturbation may be the culprit for the end-Triassic extinction. The Whitmore Point Member of the Moenave Formation is a lacustrine deposit with a disputed age of either late Triassic or early Jurassic and currently no absolute dating techniques can be applied to …

The Late Ordovician Biogeochemical Carbon Cycle, John Garrecht Metzger

Arts & Sciences Electronic Theses and Dissertations

The isotopic composition of the carbonate carbon (δ13Ccarb) is one of the best tools for understanding the biogeochemical carbon cycle through Earth history. δ13Ccarb is also used to chemostratigraphically correlate coeval strata. This dissertation has three main foci that all utilize δ13Ccarb as the common data type. The geologic interval investigated was the Late Ordovician (458-444 Ma) with emphasis on the Guttenberg δ13C excursion, a globally correlated, positive ~3 / event that is ~400 kyr in duration. In the first topic we evaluate post-depositional alteration (i.e., diagenesis) of δ13Ccarb signals. In the second topic, we make reconstructions of sea level …

Lower Aptian Comparative Stratigraphy Of The Basco-Cantabrian Region (Spain) And Eastern Cordillera (Colombia): Implications For Local Factors In The Depositional Record Of Oceanic Anoxic Event 1a (Oae-1a), Tatiana Gaona Narvaez

FIU Electronic Theses and Dissertations

An important episode of carbon sequestration, Oceanic Anoxic Event 1a (OAE-1a), characterizes the Lower Aptian worldwide, and is mostly known from deeper-water settings. The present work of two Lower Aptian deposits, Madotz (N Spain) and Curití Quarry (Colombia), is a multiproxy study that includes fossil assemblages, microfacies, X-ray diffraction bulk and clay mineralogy, elemental analyses (major, minor, trace elements), Rock-Eval pyrolysis, biomarkers, inorganic and organic carbon content, and stable carbon isotopes. The results provide baseline evidence of the local and global controlling environmental factors influencing OAE-1a in shallow-water settings. The data also improve our general understanding of the conditions under …

The Stable Isotope Stratigraphy And Paleosols Of North America's Most Southern Exposure Of Late Paleocene/Early Eocene Fossiliferous Continental Deposits: Documenting The Initial Eocene Thermal Maximum In Big Bend National Park, Texas, Paul David White

LSU Doctoral Dissertations

A chemostratigraphic section across the Paleocene/Eocene boundary, using the stable isotopes of carbon and oxygen, has been developed for North America's most southern exposure of early Paleogene continental deposits in which the boundary is constrained by fossil mammals. A negative carbon excursion has been identified within C24r. The range in d¹³C values is from -8.1 to -13.2‰. Until the development of the chemostratigraphic section it was uncertain if the earliest Eocene was recorded in Big Bend. An early Wasatchian (Wa1) fossil site occurs stratigraphically higher than the carbon excursion and has yielded the stratigraphically lowest Hyracotherium in the …

Organic Geochemical Analysis Of Late-Glacial And Early-Holocene Ecosystem Changes: A Case Study From Northern New England Lakes, Michael A. Kruge, Andrea Lini

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The lacustrine sedimentary archive of organic remains provides important evidence for the reconstruction of the environmental histories of lakes and their watersheds, recording the response of the Earth's biota to changes on scales varying from the local to the global. The last Glacial-Interglacial transition presents an opportunity to investigate how, and at what rates, watershed and lake ecosystems were established on once glaciated, carbon and nutrient-poor landscapes. The small lakes of northern Vermont (USA) provide an appropriate setting in which to investigate such changes.

As part of a multidisciplinary study of three Vermont lake sediment cores, samples ranging in age …