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Full-Text Articles in Physical Sciences and Mathematics

Sediment Interstitial Dissolved Mercury And Carbon Relationships In An Artificial And Natural Marsh, James River, Virginia, Apostolos Katsaounis Jul 1977

Sediment Interstitial Dissolved Mercury And Carbon Relationships In An Artificial And Natural Marsh, James River, Virginia, Apostolos Katsaounis

OES Theses and Dissertations

Thirty six sediment cores were collected during August, 1976 and January, 1977 in order to examine the relationships between dissolved organic carbon and total dissolved mercury in the interstitial water of two marshes located near Windmill Point, James River, 16 km downstream from Hopewell, Virginia. The Windmill Point marsh development site is a dredged material disposal island in the James River. The reference marsh which does not contain dredged material, is located 2.3 km upstream at Ducking Stool Point.

The concentrations of dissolved organic carbon and total dissolved mercury showed no significant difference between the two marshes. Trends in the …


Light Scattering Studies Of Rotational And Vibrational Relaxations Of Acetonitrile In Carbon Tetrachloride, Scott L. Whittenburg, C. H. Wang May 1977

Light Scattering Studies Of Rotational And Vibrational Relaxations Of Acetonitrile In Carbon Tetrachloride, Scott L. Whittenburg, C. H. Wang

Chemistry and Biochemistry Faculty Publications

The rotational and vibrational relaxation times of acetonitrile–carbon tetrachloride solutions were investigated as a function of concentration, viscosity, and temperature using depolarized Rayleigh and Raman scattering. Using a Fabry‐Perot interferometer and single frequency laser source, we have shown that reliable results for the single particle orientational correlation times (τs) for CH3CN can be obtained by carrying out a concentration dependent depolarized Rayleigh scattering study. Raman scattering was shown to yield inconsistent results for τs in CH3CN. At constant viscosity, it was found that the Rayleigh scatteringrelaxation time (τRay) of CH3 …