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Full-Text Articles in Physical Sciences and Mathematics
Nuclear Magnetic Resonance Studies Of Electrode And Electrolyte Materials For Li-Ion Batteries, Lisa Cirrincione
Nuclear Magnetic Resonance Studies Of Electrode And Electrolyte Materials For Li-Ion Batteries, Lisa Cirrincione
Dissertations, Theses, and Capstone Projects
In this thesis, Nuclear Magnetic Resonance (NMR) spectroscopic techniques are used to study lithium electrode and electrolyte materials for advanced rechargeable lithium ion batteries. Three projects are described in this thesis. The first involves 23Na and 37Al static and magic angle spinning NMR studies of NaAlH4/C anode materials for advanced rechargeable batteries. The second project is a study of paramagnetic lithium transition-metal phosphate cathode materials for Li-ion batteries, where 7Li, and 31P single crystal NMR was used in order to obtain detailed information on the local electronic and magnetic environments. The third project investigates …
Silicon Nanostructures For High Capacity Anodes In Lithium Ion Batteries, Tyler M. Selden
Silicon Nanostructures For High Capacity Anodes In Lithium Ion Batteries, Tyler M. Selden
Theses and Dissertations
In this study we looked at several different silicon nanostructures grown for the purpose of optimizing anodes for lithium ion batteries. We primarily focused on two distinct types of structures, nanospirals, and Rugate structures. The samples were designed to have the mechanical robustness to endure the massive expansion caused by lithiation of silicon. All of the samples were grown using an electron beam evaporator. Scanning electron microscope images show that we have achieved the desired structural growth. The spirals were shown to have an average diameter of 343 nm on polished copper, and 366 nm on unpolished copper. The Rugate …