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2025

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Articles 11761 - 11790 of 11876

Full-Text Articles in Physical Sciences and Mathematics

Painting Liberation: A Visual Ontology Of The Interplay Of Mind And Consciousness In Book Four Of The Yoga Sūtras, Melissa Townsend Jan 2025

Painting Liberation: A Visual Ontology Of The Interplay Of Mind And Consciousness In Book Four Of The Yoga Sūtras, Melissa Townsend

Monsoon: South Asian Studies Association Journal

This presentation explores how artistic practice can illuminate philosophical questions about the nature of mind, consciousness, and liberation as articulated in Book Four of the Yoga Sūtras of Patañjali. Through a series of paintings that visually translate these sūtras, I propose that art offers a unique, experiential means of engaging with the complex relationship between citta (mind) and puruṣa (consciousness).

The paintings function as a form of “visual ontology,” inviting viewers to engage with abstract philosophical concepts in a sensory, tangible way. By depicting the interplay between the mutable processes of the mind and the unchanging awareness of consciousness, these …


Runner Locating With Multiple Probes, Kola Akinrele, Axel Brandt, Elizabeth Breen, Catherine Erbes, Matthew Lee, Patrick O’Doherty, Weston Rainer Jan 2025

Runner Locating With Multiple Probes, Kola Akinrele, Axel Brandt, Elizabeth Breen, Catherine Erbes, Matthew Lee, Patrick O’Doherty, Weston Rainer

2025 Faculty Bibliography

In the runner locating variation of cops and robbers on a graph, a chaser attempts to locate an invisible runner by probing a single vertex v each turn, from which the chaser learns the runner’s distance. The runner is then permitted to stay at his current vertex or move to an adjacent vertex other than v. A graph is locatable if the chaser is able to locate the runner in a finite number of turns, and the location number of a graph is the minimum number of turns necessary to determine the runner’s location regardless of the runner’s evasion strategy. …


Catalytic Innovation For Sustainable Styrene Production: Green Chemistry Strategies Utilizing Octahedral Ruthenium (Ii) Complexes Supported By A Single Bipyridine Ligand, Kennedy G. Musso, Brandon Quillian, Clifford Padgett, Jose Jimenez Jan 2025

Catalytic Innovation For Sustainable Styrene Production: Green Chemistry Strategies Utilizing Octahedral Ruthenium (Ii) Complexes Supported By A Single Bipyridine Ligand, Kennedy G. Musso, Brandon Quillian, Clifford Padgett, Jose Jimenez

College of Graduate Studies: Theses & Dissertations

This study investigates: 1) the synthesis and reactivity of the mono- substituted systems, [κ²-(t-bipy)Ru(NCMe)2(Ph)(PR3)][BArF'] supported by different ancillary ligands PR3 = (P(OCH3)3 and P(CH3)3) and a single bidentate ligand, 4,4′-di-tert-butyl-2,2′-bipyridine (t-bipy), and 2) UV/heat formation of di-PR3 and tri-PR3 systems supported by a single bidentate ligand to better understand the mechanism of styrene production. Utilizing [(η6-p-cymene)RuI(µ-I)]2 (1), the complexes (η6-p-cymene)RuI2(P(OCH3)3) (2) and (η6-p-cymene)RuI2(P(CH3)3) (3) were synthesized and phenylated to produce (η6-p-cymene)RuI(Ph)(PR3) (6; PR3 = P(OCH3)3 and 7; PR3 = P(CH3)3). Complex 4, (η6-p-cymene)RuCl2(P(CH3)3), was also synthesized and phenylated to produce (η6-p-cymene)RuClPh(P(CH3)3) (5) to understand the impact of chloride versus iodine …


Financial Named Entity Recognition: How Far Can Llm Go?, Yi-Te Lu, Yintong Huo Jan 2025

Financial Named Entity Recognition: How Far Can Llm Go?, Yi-Te Lu, Yintong Huo

Research Collection School Of Computing and Information Systems

The surge of large language models (LLMs) has revolutionized the extraction and analysis of crucial information from a growing volume of financial statements, announcements, and business news. Recognition for named entities to construct structured data poses a significant challenge in analyzing financial documents and is a foundational task for intelligent financial analytics. However, how effective are these generic LLMs and their performance under various prompts are yet need a better understanding. To fill in the blank, we present a systematic evaluation of state-of-the-art LLMs and prompting methods in the financial Named Entity Recognition (NER) problem. Specifically, our experimental results highlight …


Numerical Analysis And The Deal.Ii Implementation Of An Efficient And Robust Parameterized Ensemble Algorithm For Navier Stokes Flow In The Convection-Dominated Regimes, Brandiece Berry Jan 2025

Numerical Analysis And The Deal.Ii Implementation Of An Efficient And Robust Parameterized Ensemble Algorithm For Navier Stokes Flow In The Convection-Dominated Regimes, Brandiece Berry

All ETDs from UAB

Ensemble methods are widely used to approximate solutions for the Navier-Stokes Equations to account for inherent uncertainties within the system. This work goes about the numerical analysis and efficiency assessment of a fully discretized Ensemble Eddy Viscosity (EEV) model for the incompressible Stochastic Navier-Stokes Equations. The model is efficient due to the use of ensemble methods. Through a single coefficient matrix for $J$ realizations, we reduce computational cost and thereby ensure computational efficiency. It is found that the model is robust with the inclusion of the eddy viscosity term, as an additional uncertainty quantification. Finally, we verify theoretical convergence rates …


Food Insecurity Among Graduate Students At The University Of Alabama At Birmingham, Amy Elizabeth Callahan Jan 2025

Food Insecurity Among Graduate Students At The University Of Alabama At Birmingham, Amy Elizabeth Callahan

All ETDs from UAB

College food insecurity (FI) has grown steadily as a field of research over the past fifteen years. Existing research primarily has demonstrated that FI is a persistent problem with various risk factors and myriad potential impacts on students, though graduate students are largely understudied in favor of undergraduate and aggregated student populations. Given the unique circumstances graduate students face, as well as expected demographic differences such as age and household characteristics, this is a serious gap in the literature. This dissertation aims to investigate graduate student food insecurity in the United States, and particularly at the University of Alabama at …


Elucidating Non-Canonical Interactions Of Mcl1 With The P53 Family Of Tumor Suppressors, Alexus Marie Acton Jan 2025

Elucidating Non-Canonical Interactions Of Mcl1 With The P53 Family Of Tumor Suppressors, Alexus Marie Acton

All ETDs from UAB

Various signaling mechanisms contribute to a cancers cell’s ability to survive through the stressors of tumorigenesis. Canonically, when a cell is exposed to irreversible stress, the induction to apoptosis is regulated by the Bcl-2 family of apoptotic regulators. However, to accommodate for the stressors of tumor progression, many solid tumors over express one of the pro-survival proteins (e.g., BCL2, BCLxL, MCL1) allowing for persistent growth without the induction to cell death. Over the past 10 years, researchers have investigated how over expression of these pro-survival proteins contribute to chemoresistance to standard of care therapies. To sensitize cells to these apoptotic …


Analysis Of Gas Station Drugs Using Gas Chromatography Mass Spectrometry And Fourier Transform Infrared Spectroscopy, Megan Joos Jan 2025

Analysis Of Gas Station Drugs Using Gas Chromatography Mass Spectrometry And Fourier Transform Infrared Spectroscopy, Megan Joos

All ETDs from UAB

Gas stations and head shops are a seemingly safe and legal marketplace for drug purchase. However, although marketed as dietary supplements or cognitive enhancers, the products sold there have been known to contain psychoactive substances which may be mislabeled or actually contain regulated substances. This study investigates the composition of such products, specifically those labeled as kratom and non-kratom Mitragyna species using gas chromatography-mass spectrometry (GC-MS) and those labeled as phenibut using GC-MS and fourier transform infrared spectroscopy (FTIR). Samples were acquired from retailers in the Birmingham, AL area. The products underwent both qualitative and quantitative analysis of their ingredients …


Investigating Risk Of Suboptimal Hiv Treatment Outcomes (Treatment Failure And Disengagement) Among Pregnant And Postpartum Women Living With Hiv, Kevin Owuor Jan 2025

Investigating Risk Of Suboptimal Hiv Treatment Outcomes (Treatment Failure And Disengagement) Among Pregnant And Postpartum Women Living With Hiv, Kevin Owuor

All ETDs from UAB

The joint United Nations Programme on HIV/AIDS (UNAIDS) has set targets to end the HIV epidemic by improving HIV diagnosis, treatment, and viral suppression to reduce new infections and improve health outcomes for people living with HIV (PLHIV), including pregnant and postpartum women living with HIV (PPWH). After diagnosis, linking PPWH to antiretroviral (ART) treatment is critical to suppress the virus and prevent mother-to-child transmission (MTCT) of HIV. Continuous engagement in care is essential for achieving and maintaining virologic suppression in the peripartum and postpartum period for PPWH, both for their own health and the health of their family. Disengagement …


Radioactive Seed Localization For The Resection Of Nonpalpable Breast Lesions, Katherine Ward Jan 2025

Radioactive Seed Localization For The Resection Of Nonpalpable Breast Lesions, Katherine Ward

All ETDs from UAB

Accurate localization of malignant tissues is critical in breast cancer treatment to ensure effective therapy while minimizing damage to surrounding healthy tissues. Radioactive seed localization, specifically using Iodine-125 (I-125), is a prominent method due to its precision and minimally invasive nature. However, this technique poses a risk of radiation exposure to adjacent healthy tissues. This study aims to quantify the radiation dose to healthy breast tissue from I-125 seed implantation by employing two distinct computational approaches: a hemisphere breast model in MATLAB and Monte Carlo simulations in Mathematica. The American Association of Physicists in Medicine (AAPM) Task Group 43 (TG- …


A Collaborative Assessment Of Coastal Ocean Acidification Monitoring In Maine & Standard Operating Procedures And Best Practices For The Collection Of Continuous Ph Data In Coastal Marine Environments, Christopher W. Hunt, Curtis Bohlen, Mike Doan, Jeremy Miller Jan 2025

A Collaborative Assessment Of Coastal Ocean Acidification Monitoring In Maine & Standard Operating Procedures And Best Practices For The Collection Of Continuous Ph Data In Coastal Marine Environments, Christopher W. Hunt, Curtis Bohlen, Mike Doan, Jeremy Miller

Faculty Publications

The ‘Sensor Squad’ of the Maine Ocean Climate Collaborative is the product of a 2023 Maine Coastal and Marine Climate Action Fund grant to conduct “A two-year pilot project designed to address and overcome technological barriers to ocean acidification data collection, develop protocols to elevate quality assurance and ensure comparable data, and meet regularly to discuss project results and data compilation”. The Squad consists of representatives from Friends of Casco Bay (FOCB), Wells National Estuarine Research Reserve (WNERR), and the University of New Hampshire (UNH). This report is a summary of their efforts to assess affordable, repeatable means of continuously …


Uso De Herramientas De Inteligencia Artificial Generativa Por Parte De Docentes En Una Escuela Del Suroeste De Puerto Rico, Glorimar N. Rodríguez Guiliani Jan 2025

Uso De Herramientas De Inteligencia Artificial Generativa Por Parte De Docentes En Una Escuela Del Suroeste De Puerto Rico, Glorimar N. Rodríguez Guiliani

Theses and Dissertations

Esta disertación aplicada fue diseñada para investigar el nivel de conocimiento, uso y dificultades que enfrentan los docentes de quinto a duodécimo grado en una escuela privada del suroeste de Puerto Rico respecto a tecnologías emergentes las cuales presentan desafíos significativos para los docentes y los estudiantes. Se exploró la utilización de herramientas de inteligencia artificial generativa (GenAI) como ChatGPT dentro y fuera del aula para actividades pedagógicas y administrativas.

Los hallazgos revelaron una notable carencia en el conocimiento docente sobre el uso y habilidades de la inteligencia artificial. Se identificó, también, una deficiencia en la capacidad de los docentes …


Explicit Inverse Of Symmetric, Tridiagonal Near Toeplitz Matrices With Strictly Diagonally Dominant Toeplitz Part, Bakytzhan Kurmanbek, Yogi Erlangga, Yerlan Amanbek Jan 2025

Explicit Inverse Of Symmetric, Tridiagonal Near Toeplitz Matrices With Strictly Diagonally Dominant Toeplitz Part, Bakytzhan Kurmanbek, Yogi Erlangga, Yerlan Amanbek

All Works

Let T n = tridiag ( - 1 , b , - 1 ) , an n x n symmetric, strictly diagonally dominant tridiagonal matrix ( divided by b divided by > 2 ). This article investigates tridiagonal near-Toeplitz matrices T n & colone; [ t i , j ] , obtained by perturbing the ( 1 , 1 ) and ( n , n ) entry of T n . Let t 1 , 1 = t n , n = b not equal b . We derive exact inverses of T n . Furthermore, we demonstrate that these results …


Designing Ai To Foster Acceptance: Do Freedom To Choose And Social Proof Impact Ai Attitudes Among British And Arab Populations?, Sameha Alshakhsi, Mohamed Basel Almourad, Areej Babkir, Dena Al-Thani, Ala Yankouskaya, Christian Montag, Raian Ali Jan 2025

Designing Ai To Foster Acceptance: Do Freedom To Choose And Social Proof Impact Ai Attitudes Among British And Arab Populations?, Sameha Alshakhsi, Mohamed Basel Almourad, Areej Babkir, Dena Al-Thani, Ala Yankouskaya, Christian Montag, Raian Ali

All Works

This study examines the impact of two key AI modalities–freedom of choice (FoC) and social proof (SP)–on public attitudes toward AI, focusing on cultural differences between UK and Arab participants. FoC refers to the option of selecting a non-AI, possibly human, alternative, while SP means knowing that others have used AI without issues. Four scenarios were designed, combining the presence or absence of these modalities. The context was a customer service chatbot for a telecommunications company, familiar to all participants. A total of 639 participants (316 British and 323 Arab) were introduced to the modalities and then the scenarios in …


Atomic Physics For Everyone: An Introduction To Atomic Physics, Quantum Mechanics, And Precision Spectroscopy With No College-Level Prerequisites, Will Raven Jan 2025

Atomic Physics For Everyone: An Introduction To Atomic Physics, Quantum Mechanics, And Precision Spectroscopy With No College-Level Prerequisites, Will Raven

Open Educational Resources: Textbooks

This open access textbook introduces beginning undergraduate students and high school students to the world of quantum mechanics and atomic spectroscopy. Requiring no previous knowledge of physics and no math beyond basic algebra and sines and cosines, this book focuses on concepts to make the excitement of atomic physics more accessible for learners than ever before. It comes replete with learning goals, exercises and solutions, and an optional experimental component, making this text readily adoptable for both the classroom and the undergraduate lab. The book takes the reader on a lively and engaging tour through topics at the forefront of …


Computer Science For Middle School (Cs4ms), Melani Loney, Lisa Steffian, Tancy J. Vandecar-Burdin Jan 2025

Computer Science For Middle School (Cs4ms), Melani Loney, Lisa Steffian, Tancy J. Vandecar-Burdin

Center for Educational Partnerships Publications

This session will discuss the project Computer Science for Middle School and the associated findings. This Virginia Department of Education funded project provides computer science Professional Development opportunities for in-service teachers, located in Southeastern Virginia, who instruct students in middle school grades 6- 8. Participating teachers learn to integrate computer science standards into core and elective content through online, asynchronous microcredentials and in-person Summer Workshops. The presentation will include project findings and next steps including teacher efficacy for implementing the computer science standards before and after completing the microcredentials and their students’ attitudes about computer science.


Avoiding Racial Equity Detours: Racial Equity Trainers’ Visions Of Racially Equitable Residential Environmental Education, Anna Mooney Ph.D. Jan 2025

Avoiding Racial Equity Detours: Racial Equity Trainers’ Visions Of Racially Equitable Residential Environmental Education, Anna Mooney Ph.D.

Antioch University Dissertations & Theses

This study investigated how racial equity trainers envision racially equitable residential environmental education (REE). While addressing racial inequities has been central to environmental scholarship, equity detours undergirded by systemic power structures continue to pose significant barriers in addressing inequities in practice. The research explored the question: “How do racial equity trainers envision racially equitable residential environmental education?” Using constructivist grounded theory and drawing on portraiture’s “search for goodness,” the study conducted 1-hour virtual interviews with six racial equity trainers, employing iterative coding through the constant comparative method. A 2-hour virtual focus group and subsequent 30-minute “dissertation reality check” provided additional …


The Role Of Floodplain Complexity In Wood Turtle Habitat Use, Laura S. Deming Jan 2025

The Role Of Floodplain Complexity In Wood Turtle Habitat Use, Laura S. Deming

Antioch University Dissertations & Theses

Wood turtles occupy cold, low-gradient riverine habitat throughout the northeastern United State and southeastern Canada. Stream alterations, such as dams, channel straightening, and floodplain development have diminished the natural hydrologic and sedimentation regimes that result in complex channel and floodplain geomorphology. Studies throughout the species’ range have quantified many aspects of their habitat, but none have quantified components of geomorphology of wood turtle sites. The goal of this study was to explore the role of stream channel and floodplain geomorphology in wood turtle habitat use, with specific objectives to (1) quantify components of stream channel and floodplain geomorphic complexity, (2) …


Canary In The Alpine: Shifts In Snowbed Plant Communities Over Time In The Adirondack Mountains Of New York, Katie Rhodes Jan 2025

Canary In The Alpine: Shifts In Snowbed Plant Communities Over Time In The Adirondack Mountains Of New York, Katie Rhodes

Antioch University Dissertations & Theses

Due to their unique species diversity and vulnerability, alpine snowbed communities have the potential to serve as early detection or ‘canary’ communities that can inform scientific understanding of the timing and physical manifestation of a changing alpine ecosystem. In the summer of 2008, fifteen alpine snowbed vegetation community transects over 5 mountain summits were established and studied in the High Peaks Wilderness Complex within the Adirondack State Park by the New York Natural Heritage Program. Each transect was 5 meters long and encompassed five 1x1 meter subplots. These transects were relocated and surveyed again in the summer of 2024 in …


Cultural Relativism: Addressing Diversity And Expression Of Culture Through Dress, Robert L. Woods, Maureen Archer-Festa, Rachel Raskin, Alyssa Dana Dana Adomaitis Jan 2025

Cultural Relativism: Addressing Diversity And Expression Of Culture Through Dress, Robert L. Woods, Maureen Archer-Festa, Rachel Raskin, Alyssa Dana Dana Adomaitis

Publications and Research

As America becomes more diverse, so do postsecondary institutions. While they also reflect the world's political, social, and economic climate, institutions of higher learning continuously seek newer and inventive ways to include better culturally diverse students in their programs and campus life. Multicultural education is a set of educational strategies developed to teach students about diverse groups' histories, cultures, and contributions. Moreover, Multiculturalism has become a way of teaching that promotes inclusion, diversity, and democratic learning. If left unaddressed, however, it can breed biases that isolate students, manifest hate crimes, and increase a school's retention rates (Gruman, 2016). Having received …


Rings With Q-Torsionfree Canonical Modules, Naoki William Endo, Laura P. Ghezzi, Shiro S. Goto, Jooyoun Hong Phd, Shin-Ichiro Iai, Toshinori Kobayashi, Naoyuki Matsuoka, Ryo Takahashi Jan 2025

Rings With Q-Torsionfree Canonical Modules, Naoki William Endo, Laura P. Ghezzi, Shiro S. Goto, Jooyoun Hong Phd, Shin-Ichiro Iai, Toshinori Kobayashi, Naoyuki Matsuoka, Ryo Takahashi

Publications and Research

Let A be a Noetherian local ring with canonical module K A . We characterize A when K A is a torsionless, reflexive, or q-torsionfree module for an integer q ≥ 3 . If A is a Cohen–Macaulay ring, H.-B. Foxby proved in 1974 that the A-module K A is q-torsionfree if and only if the ring A is q-Gorenstein. With mild assumptions, we provide a generalization of Foxby’s result to arbitrary Noetherian local rings admitting the canonical module. In particular, since the reflexivity of the canonical module is closely related to the ring being Gorenstein …


Predictive Modeling For Healthcare Data Using Nonlinear Bayesian Methods, Prince Kofi Asare Jan 2025

Predictive Modeling For Healthcare Data Using Nonlinear Bayesian Methods, Prince Kofi Asare

Theses and Dissertations

Unplanned hospital readmissions represent a significant challenge for healthcare systems, contributing to substantial financial burdens and highlighting gaps in patient care coordination. In the U.S., approximately 20% of Medicare beneficiaries are readmitted within 30 days, costing billions annually. Social determinants of health, such as income, housing stability, and social support, account for up to 80% of health outcomes, yet their integration into predictive models remains underexplored. This study introduces a novel Bayesian framework for predicting 30-day readmission risk, combining Gaussian Process models with spike-and-slab priors and Bayesian Lasso regression with Laplace priors. Utilizing Markov Chain Monte Carlo methods, the approach …


Leveraging Deep Learning Models And Social Media Data For Enhanced Situation Awareness In Disaster Management, Ademola Abdulganiyu Adesokan Jan 2025

Leveraging Deep Learning Models And Social Media Data For Enhanced Situation Awareness In Disaster Management, Ademola Abdulganiyu Adesokan

Doctoral Dissertations

"In recent years, social media has become a crucial source of real-time data for disaster management, supporting emergency responses when traditional channels like 911 are overcrowded and overwhelmed. It offers authorities valuable data for developing effective strategies, especially when swift actions are essential to save lives. However, the informal language, ambiguous meanings, and irrelevant content on social media pose challenges to accurate classification and hinder the efficient extraction of disaster-relevant information, leading to inefficiencies in emergency response efforts.

This research focuses on seven key questions: i) How can we detect, classify, and analyze hate and offensive tweet emotions during large-scale …


Metal-Free Photoredox Catalysis For The S-Trifluoromethylation Of Thiols And Investigation Of Ph-Dependent Decontamination Of Dimethyl Chlorophosphate, A Nerve Agent Simulant, Via Hydrolysis With Azoles, Raheemat Rafiu Jan 2025

Metal-Free Photoredox Catalysis For The S-Trifluoromethylation Of Thiols And Investigation Of Ph-Dependent Decontamination Of Dimethyl Chlorophosphate, A Nerve Agent Simulant, Via Hydrolysis With Azoles, Raheemat Rafiu

Doctoral Dissertations

"Organofluorine chemistry plays a critical role in synthetic chemistry due to the unique properties of fluorine. However, the S-trifluoromethylation of thiols remains underexplored, with existing methods often relying on toxic and expensive organometallic catalysts. Given the advantages of S-trifluoromethylated compounds, including enhanced pharmacological activity and improved metabolic stability, we developed a green and cost-effective method for the synthesis of S-CF3 compounds using diacetyl as the organic catalyst and Langloi's reagent as the trifluoromethylating reagent. This reaction, which proceeds under mild conditions using visible light photoredox catalysis, works across various substrate scopes, including aromatic, heteroaromatic, and aliphatic thiols.

Chemical Warfare Agents …


Polybenzodiazine Aerogels: All-Nitrogen Analogues Of Polybenzoxazines - Synthesis, Characterization, And Their Application In Carbon Dioxide Capture, Vaibhav Edlabadkar Jan 2025

Polybenzodiazine Aerogels: All-Nitrogen Analogues Of Polybenzoxazines - Synthesis, Characterization, And Their Application In Carbon Dioxide Capture, Vaibhav Edlabadkar

Doctoral Dissertations

"The rapidly risen concentration of carbon dioxide in the atmosphere over recent years contributed to global warming and ocean acidification. Carbon capture is viewed as an essential tool from keeping atmospheric CO2 levels from rising further. This thesis focuses on the development of new materials for high capacity and selective adsorption of CO2. One such material was based on a newly synthesized tetrahydroquinazoline (THQ), which was designed as an all-nitrogen analogue of main-stream benzoxazine monomers. THQ solutions in DMF gelled at 100 °C via HCl-catalyzed ring opening polymerization to polybenzodiazine (PBDAZ) wet gels, which were dried in …


Photoionization Of Spin-Polarized Rydberg Atoms Out Of A Continuous Wave Optical Dipole Trap, Kevin Lee Romans Jan 2025

Photoionization Of Spin-Polarized Rydberg Atoms Out Of A Continuous Wave Optical Dipole Trap, Kevin Lee Romans

Doctoral Dissertations

"Recent research has demonstrated the need for a fully differential experiment on the photoionization of 6Li Rydberg atoms in a continuous wave (cw) laser field, as this would provide a new path forward for studying never before accessible atom-light interactions. Rydberg atoms are back in the focus of intense research due to their peculiar properties, which make them interesting candidates for quantum optics and information applications. In this work, we study the ionization of such Rydberg atoms, due to their interaction with a trapping laser field, by utilizing a reaction microscope (ReMi) capable of measuring photoelectron momentum distributions with …


Applications Of Tetramethyl-Guanidine Supported Cationic Transition Metal Sites Towards C─N Bond Construction Methodologies And [3+2] Cycloaddition Reactions, Suraj Kumar Sahoo Jan 2025

Applications Of Tetramethyl-Guanidine Supported Cationic Transition Metal Sites Towards C─N Bond Construction Methodologies And [3+2] Cycloaddition Reactions, Suraj Kumar Sahoo

Doctoral Dissertations

"We present a family of divalent cationic bipodal and tripodal M(II) reagents (M = Mn, Fe, Co) supported by superbasic tetramethyl-guanidinyl (TMG) residue framework with applications towards C─N bond construction methodologies. These cationic reagents possess unique characteristics since their enhanced Lewis acidity facilitates in situ elaboration of the primary nitrene-transfer product (aziridine). Indeed, further aziridine-ring opening and cycloaddition of several dipolarophiles (nitriles, alkenes, ketones) permits the three-component synthesis of valuable five-membered N-heterocycles, commonly found in pharmaceuticals and agrochemicals.

We undertake a more systematic study to unravel parameters that make certain divalent metal sites more suitable as catalysts for the in-situ …


Provenance Of The Uppermost Carboniferous–Lower Triassic Sandstones, Bogda Mountains, Nw China: Implications On The Late Paleozoic Tectonic History Of The Southern Central Asian Orogenic Belt, Sixuan Wu Jan 2025

Provenance Of The Uppermost Carboniferous–Lower Triassic Sandstones, Bogda Mountains, Nw China: Implications On The Late Paleozoic Tectonic History Of The Southern Central Asian Orogenic Belt, Sixuan Wu

Doctoral Dissertations

"The Permian-Triassic period represents a significant but insufficiently understood tectonic transition stage in the southern Central Asian Orogenic Belt (CAOB) between the Paleozoic continental amalgamation and Cenozoic orogenic reactivation. This study integrates fieldwork, petrographic, and detrital zircon geochronological data to document the trend of depositional environments, framework grain compositions, and dates of detrital zircon grains of the uppermost Carboniferous–Lower Triassic sandstones from three study areas in Bogda Mountains, the greater Turpan-Junggar basin, NW China, to decipher the spatial and temporal changes in the provenance lithology and area and reconstruct the unroofing history of the southern CAOB.

In the first part …


Quantum And Classical Phase Transitions In Disordered Systems, Gaurav Ramesh Khairnar Jan 2025

Quantum And Classical Phase Transitions In Disordered Systems, Gaurav Ramesh Khairnar

Doctoral Dissertations

This work examines the effects of quenched disorder on classical and quantum phase transitions. There are countless examples of phase transitions in nature. Here, we study phase transitions in condensed matter with the help of simple models that focus on the essential unifying features of the problems. We are particularly interested in investigating how the presence of disorder changes the behavior of the system in the vicinity of a phase transition.

Here, we discuss three closely related problems regarding phase transitions. First we consider the behavior of highly diluted magnets with varying dilution levels in order to explain the unusual …


Development Of Dual-Scan Nuclear Magnetic Resonance (Nmr) Pulse Programs For Spin-Lattice Relaxation Measurements, Zachary Mayes Jan 2025

Development Of Dual-Scan Nuclear Magnetic Resonance (Nmr) Pulse Programs For Spin-Lattice Relaxation Measurements, Zachary Mayes

Doctoral Dissertations

This research develops and refines the Split Inversion Pulse and Recovery (SIP R) methodology for spin-lattice relaxation (T₁) measurements in NMR spectroscopy. SIP R introduces a two-scan difference technique using a split inversion pulse sequence, where the 180° pulse is split into two 90° pulses phase-shifted with respect to each other. This approach simplifies data fitting, requiring only two parameters to extract T₁ values, compared to the traditional inversion-recovery method, which needs three. The SIP-R-DS and SIP-R-S adaptations extend this framework by incorporating selective NMR resonance excitations, enhancing its applicability to cross-polarization experiments and enabling unobstructed NOE measurements. These adaptations …