Physical Sciences and Mathematics Commons^™

Summer Research Fellowship Project Descriptions 2023, Clark Science Center's Summer Research Fellows Program

SURF Abstracts (Women in Science)

A summary of research done by Smith College’s 2023 Summer Research Fellowship (SURF) Program participants. Ever since its 1967 start, SURF has been a cornerstone of Smith’s science education. Supervised by faculty mentor-advisors drawn from the Clark Science Center and connected to its eighteen science, mathematics, and engineering departments and programs and associated centers and units. At summer’s end, SURF participants were asked to summarize their research experiences for this publication.

Synthesis Of Copper Nano/Microparticles Via Thermal Decomposition And Their Conversion To Copper Oxide Film, Çağdaş Allahverdi̇

Turkish Journal of Chemistry

Copper nano/microparticles were synthesized in octadecene at 290 °C by thermal decomposition method. Copper acetate monohydrate, stearic acid, and 1-octadecanol were used as copper precursor, capping and mild reducing agents, respectively, at the synthesis. Borosilicate glass substrates submerged into the reaction solution during the synthesis were coated by copper nano/ microparticles. Thermal decomposition and coating techniques were combined in this study. Copper nano/microparticles were thoroughly characterised via X-ray powder diffraction, X-ray photoelectron, Raman, and attenuated total reflectance-Fourier transform infrared spectroscopies, and scanning and transmission electron microscopies. The average minimum Feret?s diameter of these synthesized copper particles was measured as ~87 …

Natural Language Processing In The Legal Domain, Daniel Martin Katz, Dirk Hartung, Lauritz Gerlach, Abhik Jana, Michael J. Ii Bommarito

Research Collection Yong Pung How School Of Law

In this paper, we summarize the current state of the field of NLP and Law with a specific focus on recent technical and substantive developments. To support our analysis, we construct and analyze a corpus of more than six hundred NLP and Law related papers published over the past decade. Our analysis highlights several major trends. Namely, we document an increasing number of papers written, tasks undertaken, and languages covered over the course of the past decade. We observe an increase in the sophistication of the methods which researchers deployed in this applied context. Slowly but surely, Legal NLP is …

Novel Reproductive Data On Blue Sucker, Cycleptus Elongatus (Cypriniformes: Catostomidae), From Northeastern Arkansas, C.T. Mcallister, D.G. Cloutman, E.M. Leis, H.W. Robison

Journal of the Arkansas Academy of Science

Nothing has been published in the scientific literature concerning the reproductive biology of the Blue Sucker, Cycleptus elongatus in Arkansas. We examined seven female C. elongatus collected in late February 2021 and 2022 and again in early March 2023 from the Black River, Lawrence County. Egg mass (g) averaged 15.8% of the total weight of these gravid females. It appears that this sucker can spawn as early as February in this population. This is the first time information on female reproduction in this species has been published from any population of C. elongatus in the state.

New Geographic Distributional Records For Two Lampreys (Petromyzontiformes: Petromyzontidae) In Arkansas, With Notes On Histopathology, C.T. Mcallister, H.W. Robison, E.M. Leis, D.G. Cloutman, A.C. Camus

Journal of the Arkansas Academy of Science

The recent update (2nd edition) of the Fishes of Arkansas includes what is known, to date, on the geographic distribution of five species of lampreys that occur in the state. Here, we provide new distributional records on two of those species, the chestnut lamprey (Ichthyomyzon castaneus) and southern brook lamprey (I. gagei), as well as documenting host-parasite information (histopathology) caused by the former species.

Development And Evaluation Of A Multifrequency Ultrafast Doppler Spectral Analysis (Mfudsa) Algorithm For Wall Shear Stress Measurement: A Simulation And In Vitro Study, Andrew Malone, Sean Cournane, Izabela Naydenova, James F. Meaney, Andrew J. Fagan, Jacinta Browne

Articles

Cardiovascular pathology is the leading cause of death and disability in the Western world, and current diagnostic testing usually evaluates the anatomy of the vessel to determine if the vessel contains blockages and plaques. However, there is a growing school of thought that other measures, such as wall shear stress, provide more useful information for earlier diagnosis and prediction of atherosclerotic related disease compared to pulsed-wave Doppler ultrasound, magnetic resonance angiography, or computed tomography angiography. A novel algorithm for quantifying wall shear stress (WSS) in atherosclerotic plaque using diagnostic ultrasound imaging, called Multifrequency ultrafast Doppler spectral analysis (MFUDSA), is presented. …

Analog Holographic Wavefront Sensor For Defocus And Spherical Aberration Measurement Recorded In A Photopolymer, Emma Branigan, Suzanne Martin, Matthew Sheehan, Kevin Murphy

Articles

An analog holographic wavefront sensor (AHWFS), for measurement of low and high order (defocus and spherical aberration) aberration modes has been developed as volume phase holograms in a photopolymer recording medium. This is the first time that high order aberrations such as spherical aberration can be sensed using a volume hologram in a photosensitive medium. Both defocus and spherical aberration were recorded in a multi-mode version of this AHWFS. Refractive elements were used to generate a maximum and minimum phase delay of each aberration which were multiplexed as a set of volume phase holograms in an acrylamide based-photopolymer layer. The …

Improving The Angular Visibility Of Photopolymer-Based Reflection Holograms For Sensing Applications, Tatsiana Mikulchyk, Kevin Murphy, John Walsh, Suzanne Martin, Dervil Cody, Izabela Naydenova

Articles

Volume reflection hologram-based sensors are designed to visibly change colour in response to a target stressor or analyte. However, reflection holograms fabricated in thick photopolymer films are highly angularly selective, making these sensors challenging to view and interpret by non-experts. Here, the use of speckle holography to improve the visibility of reflection holograms is presented. A novel recording approach combining speckle recording techniques with Denisyuk reflection recording geometry is described. The recorded speckle reflection grating operates as a series of multiplexed reflection gratings with a range of spatial frequencies, capable of reflecting light at a wider range of angles. A …

Probe–Integrated Electrochemical Sensing Platform For Measuring Trace Levels Of Parathion Pesticides Residues In Water Using Au- Nanoparticles Anchored Nafion Nano Composite Modified Glassy Carbon Electrode, H. Alwael, S.H. Al-Sedran, Mohamed Oubaha, N.A.A. Asiri, A.S. Bashammakh, A.S. Alharthy, N.A. Albassami, T.N. Abduljabbar, G.I. Mohamed, H.M. Nassef, E.A. Bahaidarah, B.G. Alhogbi, M.S. El-Shahawi

Articles

Nanomaterial represents a principal driver to the adoption of electrochemical sensors for pesticides residues in water. Thus, the current strategy reports facile and highly sensitive electrochemical probe for monitoring parathion residues in water. The probe was based upon the use of Au nanoparticles (AuNPs) functionalized Nafion nanocomposites modified glassy carbon electrode (Au NPs/Nafion/GCE). The surface morphology, effective surface area and electrocatalytic performance of the Au NPs/Nafion/GCE were recorded and assigned using a scanning electron microscopy (SEM), cyclic voltammetry (CV) and electronic spectra. A straightforward protocol based upon combination of Au NPs/Nafion/GCE and square wave- adsorptive cathodic stripping voltammetry at pH …

Review-Electrode Kinetics And Electrolyte Stability In Vanadium Flow Batteries, Andrea Bourke, Daniela Oboroceanu, Nathan Quill, Catherine Lenihan, Maria Alhajji Safi Maria Alhajji Safi, Mallory A. Miller, Robert F. Savinell, Jesse S. Wainright, Varsha Sasikumarsp, Maria Rybalchenko, Pupak Amini, Niall Dalton, Robert P. Lynch, D. Noel Buckley

Articles

Two aspects of vanadium flow batteries are reviewed: electrochemical kinetics on carbon electrodes and positive electrolyte stability. There is poor agreement between reported values of kinetic parameters; however, most authors report that kinetic rates are faster for VIV/VV than for VII/VIII. Cycling the electrode potential increases the rates of both reactions initially due to roughening but when no further roughening is observed, the VII/VIII and VIV/VV reactions are affected oppositely by the pretreatment potential. Anodic pretreatment activates the electrode for the VII/VIII reaction, and deactivates it for VIV/VV. Three states of the carbon surface are suggested: reduced and oxidized states …

Effects Of Flexibility In Coarse-Grained Models For Bovine Serum Albumin And Immunoglobulin G, Frank Hirschmann, Hender Lopez, Felix Roosen-Runge, Tilo Seydel, Frank Schreiber, Martin Oettel

Articles

We construct a coarse-grained, structure-based, low-resolution, 6-bead flexible model of bovine serum albumin (BSA, PDB: 4F5S), which is a popular example of a globular protein in biophysical research. The model is obtained via direct Boltzmann inversion using all-atom simulations of a single molecule, and its particular form is selected from a large pool of 6-bead coarse-grained models using two suitable metrics that quantify the agreement in the distribution of collective coordinates between all-atom and coarse-grained Brownian dynamics simulations of solutions in the dilute limit. For immunoglobulin G (IgG), a similar structure-based 12-bead model has been introduced in the literature [Chaudhri …

Global Short-Term Mortality Risk And Burden Associated With Tropical Cyclones From 1980 To 2019: A Multi-Country Time-Series Study, Wenzhong Huang, Shansan Li, Thomas Vogt, Rongbin Xu, Shilu Tong, Tomas Molina, Pierre Masselot, Antonio Gasparrini, Ben Armstrong, Mathilde Pascal, Dominic Roye, Chris Fook Sheng Ng, Ana Maria Vicedo-Cabrera, Joel Schwartz, Eric Lavigne, Haidong Kan, Patrick J. Goodman, Ariana Zeka, Masahiro Hashizume, Magali Hurtado Dias, Cesar De La Cruz Valencia, Xerxes Seposo, Baltazar Nunes, Joana Madureira, Ho Kim, Whanhee Lee, Aurelio Tobias, Carmen Iniguez, Yue Leon Guo, Shih-Chun Pan, Antonella Zanobetti, Tran Ngoc Dang, Do Van Dung, Tobias Geiger, Christian Otto, Amanda Johnson, Simon Hales, Pei Yu, Zhengyu Yang, Elizabeth A. Ritchie, Yuming Guo

Articles

The global spatiotemporal pattern of mortality risk and burden attributable to tropical cyclones is unclear. We aimed to evaluate the global short-term mortality risk and burden associated with tropical cyclones from 1980 to 2019.

Use Of Machine Learning Methods In Automatic Assessment Programming Assignments, Botond Tarcsay

Masters

Programming has become an important skill in today’s world and is taught widely both in traditional settings and online. Instructors need to assess increasing amounts of student work. Unit testing can contribute to the automation of the grading process; however, it cannot assess the structures, style and partially correct source code or differentiate between levels of achievement. The topic of this thesis is an investigation into the use of machine learning methods for assessing the correctness and quality of code, with the ultimate goal of assisting instructors in the grading process. In this research, we have used nine different machine …

Collective Relaxation Processes In Nonchiral Nematics, Neelam Yadav, Yuri Panarin, Wanhe Jiang, Georg H. Mehl, Jagdish Vij

Articles

Nematic–nematic transitions in a highly polar nematic compound are studied, in thick cells in which the molecules are aligned parallel to the substrates but perpendicular to the applied electric field, using dielectric spectroscopy in the frequency range 1 Hz to 10 MHz over a wide temperature range. The studied compound displays three nematic phases under cooling from the isotropic phase: ubiquitous nematic N; high polarizability NX; and ferroelectric nematic NF. Two collective processes were observed. The dielectric strength and relaxation frequency of one of the processes P2 showed a dependence on the thickness of the cell. The process P1 is …

Teaching Without Walls: A Portraiture Study Of Nature-Based Educators In Duluth, Minnesota, Christina Wild

Antioch University Dissertations & Theses

This dissertation explores the lived experience of nature-based educators in Duluth, Minnesota. Portraiture served as the methodological framework for learning about how teachers in Duluth got into teaching and why they remain on the job. Teacher turnover and attrition is a national problem exacerbated by the COVID-19 pandemic. Yet, teachers who perceive better working conditions are less likely to leave the profession. In addition, nature-based education has positive influences on students. Past research in nature-based education has looked at students rather than teachers. This study’s findings offer key lessons in the stories of educators who stay in teaching and experience …

Navigating Opportunities To Improve Youth Outcomes In A Least Developed Country: An Action Research Study, Naomi Docilait

Antioch University Dissertations & Theses

The ambitious United Nations-adopted Sustainable Development Goals (SDGs) require the concentrated effort of governments, the business sector, and other key stakeholders, including women and youth, for its success. Effective leadership will be essential for different sectors to integrate these development goals into strategic plans and operational activities in the service of realizing this agenda by 2030. Unfortunately for Least Developed Countries (LDCs), the COVID-19 pandemic caused the worst economic outcomes in 30 years. For this group of countries, the pandemic has negatively influenced efforts to eradicate poverty and improve social outcomes. This setback makes achieving the Sustainable Development Goals by …

A Comparison Of Tung Oil Resin Reinforcements Using Fibrous Proteins And Peptides For Biological And Materials Applications, Parker L. Williams

College of Graduate Studies: Theses & Dissertations

In this study a tung oil based thermoset was reinforced with collagen and fibroin, and the resulting composites were analyzed for their physical properties. Tung tree seed oil is a great candidate for biobased polymer production because its triglycerides are primarily made of alpha eleostearic acid, a fatty acid with three conjugated carbon-carbon double bonds. These double bonds allow for mechanically strong crosslinking in the polymer. It has been observed that polymerized tung oil forms a gel. This issue has been addressed using divinylbenzene (DVB) and n-butyl methacrylate (BMA) as co-monomers. Similar bio-based polymers have been studied and tend to …

A Novel Approach To Detecting And Mitigating Keyloggers, Damilola Osedumbi Elelegwu

College of Graduate Studies: Theses & Dissertations

As the digital world gets increasingly ingrained in our daily lives, cyberattacks—especially those involving malware—are growing more complex and common, which calls for developing innovative safeguards. Keylogger spyware, which combines keylogging and spyware functionalities, is one of the most insidious types of cyberattacks. This malicious software stealthily monitors and records user keystrokes, amassing sensitive data, such as passwords and confidential personal information, which can then be exploited. This research work introduces a novel browser extension designed to thwart keylogger spyware attacks effectively. The extension is underpinned by a cutting-edge algorithm that meticulously analyzes input-related processes, promptly identifying and flagging any …

Insights Into Initial Continental Rifting Of Marginal Seas From Seismic Evidence For Slab Relics In The Mid-Mantle Of The Woodlark Rift, Southwestern Pacific, Youqiang Yu, Frederik Tilmann, Stephen S. Gao, Kelly H. Liu, Jiaji Xi

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The initiation and evolution of marginal seas, especially those developing under a convergent setting, is one of the more enigmatic aspects of plate tectonics. Here, we report the presence of slab relics in the mid-mantle of the Woodlark rift in the southwestern Pacific based on a new map of the topography of the mantle discontinuities from a receiver function analysis and evidence from body-wave tomography. the widespread mantle transition-zone thickening rules out active mantle upwelling, and the revealed slab relics in both the upper and middle mantle may hydrate the upper mantle, which can be expected to further weaken the …

Insights To Surfactant Huff-Puff Design In Carbonate Reservoirs Based On Machine Learning Modeling, Ya Yao, Yue Qiu, Yue Cui, Mingzhen Wei, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surfactants could react with adsorbates on carbonate rock surface to alter wettability from oil-wetness to water-wetness, which is effective to enhance oil recovery. Surfactant huff-puff treatment is mostly applied for this purpose and the resulting surfactant performance is the outcome of complex interfacial processes. Currently, the effect of important parameters on surfactant performance is not completely reported and the contribution of each parameter to surfactant performance is hard to be quantified. Traditional methods to optimize surfactant performance are time-consuming and show strong dependency on extensive experiments. in this paper, we address these problems from machine learning (ML) perspectives. Several ML …

Erratum: New Estimates Of The Magnitude Of The Sea-Level Jump During The 8.2 Ka Event, (Geology (2022), 50(1), (86–90), (10.1130/G49296.1)), Jonathan Obrist-Farner, Mark Brenner, Jeffery R. Stone, Marta Wojewódka-Przybył, Thorsten Bauersachs, Andreas Eckert, Marek Locmelis, Jason H. Curtis, Susan R.H. Zimmerman, Alex Correa-Metrio, Lorenz Schwark, Edward Duarte, Antje Schwalb, Etienne Niewerth, Paula Gabriela Echeverría-Galindo, Liseth Pérez

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

No abstract provided.

Coating Compositions And Methods For Using The Same, Fateme Rezaei, Thomas P. Schuman, Glenn C. Morrison

Patents

Coating compositions and methods for using the same are disclosed. The coating compositions can include an aminosilica adsorbent. The coating compositions can adsorb CO2.

Prediction Of Kinase-Substrate Associations Using The Functional Landscape Of Kinases And Phosphorylation Sites, Marzieh Ayati, Serhan Yılmaz, Filipa Blasco Tavares Pereira Lopes, Mark R. Chance, Mehmet Koyutürk

Computer Science Faculty Publications

Protein phosphorylation is a key post-translational modification that plays a central role in many cellular processes. With recent advances in biotechnology, thousands of phosphorylated sites can be identified and quantified in a given sample, enabling proteome-wide screening of cellular signaling. However, for most (> 90%) of the phosphorylation sites that are identified in these experiments, the kinase(s) that target these sites are unknown. To broadly utilize available structural, functional, evolutionary, and contextual information in predicting kinase-substrate associations (KSAs), we develop a network-based machine learning framework. Our framework integrates a multitude of data sources to characterize the landscape of functional relationships …

Adaptive Resolution Loss: An Efficient And Effective Loss For Time Series Self-Supervised Learning Framework, Kevin Garcia, Juan Manuel Perez, Yifeng Gao

Computer Science Faculty Publications

Time series data is a crucial form of information that has vast opportunities. With the widespread use of sensor networks, largescale time series data has become ubiquitous. One of the most prominent problems in time series data mining is representation learning. Recently, with the introduction of self-supervised learning frameworks (SSL), numerous amounts of research have focused on designing an effective SSL for time series data. One of the current state-of-the-art SSL frameworks in time series is called TS2Vec. TS2Vec specially designs a hierarchical contrastive learning framework that uses loss-based training, which performs outstandingly against benchmark testing. However, the computational cost …

An Intertwined Cauchy––Schwarz–Type Inequality Based On A Lagrange–Type Identity, Iosif Pinelis

Michigan Tech Publications

Based on an apparently new Lagrange-type identity, a Cauchy–Schwarz-type inequality is proved. The mentioned identity is obtained by using certain “macro” variables; it is hoped that such a method can be used to prove or produce other identities and inequalities.

Superheating Field In Superconductors With Nanostructured Surfaces, W. P. M. R. Pathirana, A. Gurevich

Physics Faculty Publications

We report calculations of a dc superheating field H_sh in superconductors with nanostructured surfaces. Numerical simulations of the Ginzburg-Landau (GL) equations were performed for a superconductor with an inhomogeneous impurity concentration, a thin superconducting layer on top of another superconductor, and superconductor-insulator-superconductor (S-I-S) multilayers.The superheating field was calculated taking into account the instability of the Meissner state with a nonzero wavelength along the surface, which is essential for realistic values of the GL parameter κ. Simulations were done for the materials parameters of Nb and Nb₃Sn at different values of κ and the mean free paths. We …

Further Investigation Of Lead Exposure As A Potential Threatening Process For A Scavenging Marsupial Species, D. J. Hutchinson, E. M. Jones, J. M. Pay, J. R. Clarke, Michael T. Lohr, J. O. Hampton

Research outputs 2022 to 2026

There is a growing recognition of the harmful effects of lead exposure on avian and mammalian scavengers. This can lead to both lethal and non-lethal effects which may negatively impact wildlife populations. Our objective was to assess medium-term lead exposure in wild Tasmanian devils (Sarcophilus harrisii). Frozen liver samples (n = 41), opportunistically collected in 2017–2022, were analysed using inductively coupled plasma mass spectrometry (ICP-MS) to determine liver lead concentrations. These results were then used to calculate the proportion of animals with elevated lead levels ( > 5 mg/kg dry weight) and examine the role of explanatory variables that may have …

Plastic Storage In River Sediments Across An Urbanization Gradient In The Ipswich Watershed In Massachusetts, Jackie L. Harris

Honors Theses and Capstones

The importance of plastic pollution research has become apparent as plastic pollution has increased exponentially since its introduction in the 1950s. Plastics mechanically break down into minuscule particles called microplastics, which are plastic particles with a size range of 0.1 micrometers (μm) to 5 millimeters (mm). Most of the research on microplastic pollution has centered around marine ecosystems rather than freshwater ecosystems. More freshwater microplastic research to date is emerging but is still nascent and sparse. Furthermore, the idea that rivers are merely conduits of microplastics to the ocean is even more limited and ignores microplastic loading and retention in …

Low Frequency Waves Due To He+ As Observed By The Ulysses Spacecraft, Anastasia V. Marchuk

Honors Theses and Capstones

We surveyed magnetic field data from the Ulysses spacecraft and found examples of magnetic waves with characteristics that point to excitation by newborn pickup He+. With interstellar neutrals as the likely source for the pickup ions, we have modeled the ion production rates and used them to produce wave excitation rates that we compare to the background turbulence rates. The source ions are thought to be always present, but the waves are seen when growth rates are comparable to or exceed the turbulence rates. With the exception of the fast latitude scans, and unlike the waves excited by newborn interstellar …

General-Purpose Planning Algorithms In Partially-Observable Stochastic Games, Bryan Mckenney

Honors Theses and Capstones

Partially observable stochastic games (POSGs) are difficult domains to plan in because they feature multiple agents with potentially opposing goals, parts of the world are hidden from the agents, and some actions have random outcomes. It is infeasible to solve a large POSG optimally. While it may be tempting to design a specialized algorithm for finding suboptimal solutions to a particular POSG, general-purpose planning algorithms can work just as well, but with less complexity and domain knowledge required. I explore this idea in two different POSGs: Navy Defense and Duelyst.

In Navy Defense, I show that a specialized algorithm framework, …