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Full-Text Articles in Physical Sciences and Mathematics

A Comprehensive Review On Controlling Surface Composition Of Pt-Based Bimetallic Electrocatalysts, Binwei Zhang, Huiling Yang, Yunxiao Wang, Shi Xue Dou, Hua-Kun Liu Apr 2018

A Comprehensive Review On Controlling Surface Composition Of Pt-Based Bimetallic Electrocatalysts, Binwei Zhang, Huiling Yang, Yunxiao Wang, Shi Xue Dou, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

With increasing energy demands worldwide, significant efforts have been made to develop superior electrocatalysts for efficient energy conversion systems. Among all the electrocatalysts exploited, Pt-based bimetallic nanomaterials stand out by virtue of their high catalytic activity and relatively low cost due to the introduction of a nonprecious metal component. It should be noted that electrocatalytic reactions only take place on the surface of catalysts, so investigations of the surface composition of Pt-based bimetallic nanomaterials are necessary for practical electrocatalysts. In this review, recent studies on controlling the surface composition of Pt-based bimetallic catalysts for the oxygen reduction reaction, formic acid …


In Operando Mechanism Analysis On Nanocrystalline Silicon Anode Material For Reversible And Ultrafast Sodium Storage, Lei Zhang, Xianluo Hu, Chaoji Chen, Haipeng Guo, Xiaoxiao Liu, Gengzhao Xu, Haijian Zhong, Shuang Cheng, Peng Wu, Jiashen Meng, Yunhui Huang, Shi Xue Dou, Hua-Kun Liu Mar 2018

In Operando Mechanism Analysis On Nanocrystalline Silicon Anode Material For Reversible And Ultrafast Sodium Storage, Lei Zhang, Xianluo Hu, Chaoji Chen, Haipeng Guo, Xiaoxiao Liu, Gengzhao Xu, Haijian Zhong, Shuang Cheng, Peng Wu, Jiashen Meng, Yunhui Huang, Shi Xue Dou, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Presently, lithium-ion batteries (LIBs) are the most promising commercialized electrochemical energy storage systems. Unfortunately, the limited resource of Li results in increasing cost for its scalable application and a general consciousness of the need to find new type of energy storage technologies. Very recently, substantial effort has been invested to sodium-ion batteries (SIBs) due to their effectively unlimited nature of sodium resources. Furthermore, the potential of Li/Li+ is 0.3 V lower than that of Na/Na+, which makes it more effective to limit the electrolyte degradation on the outer surface of the electrode.[1] Nevertheless, one major obstacle for the commercial application …


The Murray Darling Basin Plan Is Not Delivering - There's No More Time To Waste, Quentin Grafton, Darla Hatton Macdonald, David Paton, Graham P. Harris, Henning Bjornlund, Jeffery D. Connor, John Quiggin, John Williams, Lin Crase, Richard T. Kingsford, Sarah Ann Wheeler Jan 2018

The Murray Darling Basin Plan Is Not Delivering - There's No More Time To Waste, Quentin Grafton, Darla Hatton Macdonald, David Paton, Graham P. Harris, Henning Bjornlund, Jeffery D. Connor, John Quiggin, John Williams, Lin Crase, Richard T. Kingsford, Sarah Ann Wheeler

SMART Infrastructure Facility - Papers

More than five years after the Murray Darling Basin Plan was implemented, it's clear that it is not delivering on its key objectives. The Basin Plan, at its core, is about reducing the amount of water that can be extracted from its streams, rivers and aquifers. It includes an environmental water strategy to improve the conditions of the wetlands and rivers of the basin. The Productivity Commission will conduct a five-yearly inquiry into the effectiveness of the Basin Plan in 2018. It is high time to explain what is really going on in the Basin and water recovery. For this …


Comparison Study On Development Path For Small And Medium-Sized Enterprises E-Commerce Using Complex Fuzzy Sets, Lipeng Feng, Jun Ma, Yong Wang, Jie Yang Jan 2018

Comparison Study On Development Path For Small And Medium-Sized Enterprises E-Commerce Using Complex Fuzzy Sets, Lipeng Feng, Jun Ma, Yong Wang, Jie Yang

SMART Infrastructure Facility - Papers

E-commerce has grown exponentially in the past decade in global market. In China most E-commerce enterprises are small and medium-sized (SMEs). Compared to their large-sized counterparts, SMEs have to face many obstacles when extending their E-commerce businesses. In view of the complexity and periodicity of criteria in SMEs' development, the paper develop an evaluation method using complex fuzzy sets (CFS) to help them select appropriate development path. Then the paper focuses on a case study in Chongqing, China and compares the results with two other different methods (TOPSIS and COPRAS). The study indicates that the presented work can better handle …


Review Of Modelling Air Pollution From Traffic At Street-Level - The State Of The Science, Hugh I. Forehead, Nam N. Huynh Jan 2018

Review Of Modelling Air Pollution From Traffic At Street-Level - The State Of The Science, Hugh I. Forehead, Nam N. Huynh

SMART Infrastructure Facility - Papers

Traffic emissions are a complex and variable cocktail of toxic chemicals. They are the major source of atmospheric pollution in the parts of cities where people live, commute and work. Reducing exposure requires information about the distribution and nature of emissions. Spatially and temporally detailed data are required, because both the rate of production and the composition of emissions vary significantly with time of day and with local changes in wind, traffic composition and flow. Increasing computer processing power means that models can accept highly detailed inputs of fleet, fuels and road networks. The state of the science models can …


Employing The Model Based Systems Engineering Methodologies To Develop A Domain Specific Language For Contracting Of Infrastructure Projects, Farid Shirvani, Pascal Perez, Peter Campbell, Ghassan Beydoun Jan 2018

Employing The Model Based Systems Engineering Methodologies To Develop A Domain Specific Language For Contracting Of Infrastructure Projects, Farid Shirvani, Pascal Perez, Peter Campbell, Ghassan Beydoun

SMART Infrastructure Facility - Papers

The procurement of infrastructure systems by the public sector is very costly, long and not transparent since the processes are based on preparing huge amounts of documents which are difficult to be kept consistent and to be used (e.g. bid evaluation). Acquisition architecture frameworks (AF) are metamodels, developed to model the whole enterprise/system life cycle stages including system procurement. Our previous study analyzed the currently used AFs such as DoDAF, MoDAF and TRAK to assess their adequacy and efficiency in modelling the infrastructure projects. The results showed that many of the procurement related concerns are overlooked such as financial matters …


A Genetic Column Generation Algorithm For Sustainable Spare Part Delivery: Application To The Sydney Droppoint Network, Michelle E. Dunbar, Simon Belieres, Nagesh Shukla, Mehrdad Amirghasemi, Pascal Perez, Nishikant Mishra Jan 2018

A Genetic Column Generation Algorithm For Sustainable Spare Part Delivery: Application To The Sydney Droppoint Network, Michelle E. Dunbar, Simon Belieres, Nagesh Shukla, Mehrdad Amirghasemi, Pascal Perez, Nishikant Mishra

SMART Infrastructure Facility - Papers

Modern-day logistics companies require increasingly shorter lead-times in order to cater for the increasing popularity of on-demand services. There is consequently an urgent need for fast scheduling algorithms to provide high quality, real-time implementable solutions. In this work we model a spare part delivery problem for an on-demand logistics company, as a variant of vehicle routing problem. For large delivery networks, the optimisation solution technique of column generation has been employed successfully in a variety of vehicle routing settings and is often used in combination with exact methods for solving problems with a large number of variables. Challenges may arise …


Improving Connectivity Between Coastal Economics And Capital Cities, Fariba Ramezani, Joseph J. Branigan, Pascal Perez Jan 2018

Improving Connectivity Between Coastal Economics And Capital Cities, Fariba Ramezani, Joseph J. Branigan, Pascal Perez

SMART Infrastructure Facility - Papers

Tourism industry plays a significant role in NSW economy, directly contributing $17.3 billion to NSW Gross State Product (GSP) in 2016-17. Adding the indirect impacts of this sector, the total contribution of tourism to the NSW GSP will increase to $34.2 billion in the same year. The globally known attractions such as the Opera House, Bondi Beach and the Harbour Bridge make Sydney the most visited tourist destination in the State, especially for international tourists. The Illawarra region is also a nationally and internationally recognised tourist destination due to its proximity to Sydney, its unique natural resources such as the …


Towards The Right Ordering Of The Sequence Of Models For The Evolution Of A Population Using Agent-Based Simulation, Morgane Dumont, Johan Barthelemy, Nam N. Huynh, Timoteo Carletti Jan 2018

Towards The Right Ordering Of The Sequence Of Models For The Evolution Of A Population Using Agent-Based Simulation, Morgane Dumont, Johan Barthelemy, Nam N. Huynh, Timoteo Carletti

SMART Infrastructure Facility - Papers

Agent based modelling is nowadays widely used in transport and the social science. Forecasting population evolution and analysing the impact of hypothetical policies are often the main goal of these developments. Such models are based on sub-models defining the interactions of agents either with other agents or with their environment. Sometimes, several models represent phenomena arising at the same time in the real life. Hence, the question of the order in which these sub-models need to be applied is very relevant for simulation outcomes. This paper aims to analyse and quantify the impact of the change in the order of …


Residual Stresses Induced In T Butt Welds From Submerged Arc Welding Of High Strength Thick Section Steel Members, Glen Sloan, S Pearce, Valerie M. Linton, X Ficquet, E Kingston, I Brown Jan 2018

Residual Stresses Induced In T Butt Welds From Submerged Arc Welding Of High Strength Thick Section Steel Members, Glen Sloan, S Pearce, Valerie M. Linton, X Ficquet, E Kingston, I Brown

SMART Infrastructure Facility - Papers

The overall residual stress profiles of a weld fabricated structures such as a submarine pressure hull fabricated using high strength welds joining quench and tempered steels is complex as they are the net profiles from the build-up or relaxation of the residual stresses induced into the welds and structural members from each step in the fabrication process. University of Adelaide with its research partners has attempted to increase the knowledge of residual stresses in this type of structure by undertaking a comprehensive residual stress measurement program using test pieces representing each stage of the fabrication of a submarine pressure hull …


Metal-Oxygen Bonds: Stabilizing The Intermediate Species Towards Practical Li-Air Batteries, Yuyang Hou, Yuqing Liu, Zhen Zhou, Lili Liu, Haipeng Guo, Hua-Kun Liu, Jiazhao Wang, Jun Chen Jan 2018

Metal-Oxygen Bonds: Stabilizing The Intermediate Species Towards Practical Li-Air Batteries, Yuyang Hou, Yuqing Liu, Zhen Zhou, Lili Liu, Haipeng Guo, Hua-Kun Liu, Jiazhao Wang, Jun Chen

Australian Institute for Innovative Materials - Papers

Rechargeable nonaqueous Li-air batteries are attracting much attention due to their far higher theoretical energy density than lithium-ion batteries. However, Li-air batteries suffers from poor round-trip efficiency, low rate capability and poor cycle life. To reduce charge overpotentials by understanding reaction mechanism and to operate in ambient air instead of pure oxygen are prerequisites to realization of practical Li-air batteries. Here, we demonstrate a practical Li-air battery using Mo 2 C/CNT as a potential promoter with high round-trip efficiency (∼80%) and improved cycling performance (40 cycles) because Mo 2 C stabilizes the intermediate species from reduction of both O 2 …


The Effect Of Amorphous Tio2 In P25 On Dye-Sensitized Solar Cell Performance, Kadhim Al-Attafi, Andrew Nattestad, Qijie Wu, Yusuke Ide, Yusuke Yamauchi, Shi Xue Dou, Jung Ho Kim Jan 2018

The Effect Of Amorphous Tio2 In P25 On Dye-Sensitized Solar Cell Performance, Kadhim Al-Attafi, Andrew Nattestad, Qijie Wu, Yusuke Ide, Yusuke Yamauchi, Shi Xue Dou, Jung Ho Kim

Australian Institute for Innovative Materials - Papers

P25 is one of the most widely used forms of titanium(IV) oxide (TiO2), routinely utilised in dye-sensitised solar cells (DSCs), where it is often employed as a control, in spite of its poorly defined nature and the typically low device efficiency (or possibly because of this). Work by Park in 2000 and later by Lin et al. suggests that the rutile component might not be to blame for this, as has often been claimed. Recently it has been observed that P25 has quite a sizable amorphous content. A method to selectively remove this non-crystalline material has been developed, allowing for …


Recent Progress In 2d Materials For Flexible Supercapacitors, Yan Han, Yu Ge, Yunfeng Chao, Caiyun Wang, Gordon G. Wallace Jan 2018

Recent Progress In 2d Materials For Flexible Supercapacitors, Yan Han, Yu Ge, Yunfeng Chao, Caiyun Wang, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

High performance supercapacitors coupled with mechanical flexibility are needed to drive flexible and wearable electronics that have anesthetic appeal and multi-functionality. Two dimensional (2D) materials have attracted attention owing to their unique physicochemical and electrochemical properties, in addition to their ability to form hetero-structures with other nanomaterials further improving mechanical and electrochemical properties. After a brief introduction of supercapacitors and 2D materials, recent progress on flexible supercapacitors using 2D materials is reviewed. Here we provide insights into the structure-property relationships of flexible electrodes, in particular free-standing films. We also present our perspectives on the development of flexible supercapacitors.


Raman Studies On Silicene And Germanene, Yani Liu, Jincheng Zhuang, Weichang Hao, Yi Du Jan 2018

Raman Studies On Silicene And Germanene, Yani Liu, Jincheng Zhuang, Weichang Hao, Yi Du

Australian Institute for Innovative Materials - Papers

Two-dimensional (2D) group IV elemental materials are expected to have similar electronic features to their lightest analogue, graphene. The favorable hybridization state of heavier group IV elements is the sp 3 state, leading to buckled structures instead of a planar one. These buckled structures could modulate the vibrational properties of these 2D materials by introducing a strain effect. In this review, the authors focus on the recent research on the Raman spectra of silicene and Germanene from both the theoretical and experimental sides. The abundant superstructures of silicene and Germanene are formed due to the different interaction strengths between silicene/germanene …


Control Of Superconductivity By Means Of Electric-Field-Induced Strain In Superconductor/Piezoelectric Hybrids, D Stamopoulos, M Zeibekis, Shujun Zhang Jan 2018

Control Of Superconductivity By Means Of Electric-Field-Induced Strain In Superconductor/Piezoelectric Hybrids, D Stamopoulos, M Zeibekis, Shujun Zhang

Australian Institute for Innovative Materials - Papers

The controlled modification of superconductivity by any means, specifically in hybrid systems, has attracted much interest in the recent decades. Here, we present experimental data and phenomenological modeling on the control of T C of superconducting (SC) Nb thin films, with thickness 3 nm ≤ dNb≤50 nm, under the application of in-plane strain, S(E ex ) induced by an external out-of-plane electric field, E ex to piezoelectric (PE) single crystals, namely, (1-x)Pb(Mg 1/3 Nb 2/3 )O 3 -xPbTiO 3 (PMN-xPT), with x = 0.27 and 0.31. We report experimental modification of T C of Nb by E ex , accurately …


Electrochemical And Electrostatic Cleavage Of Alkoxyamines, Long Zhang, Eduardo Laborda, Nadim A. Darwish, Benjamin B. Noble, Jason Tyrell, Sandra Pluczyk, Anton P. Le Brun, Gordon G. Wallace, Joaquin Gonzalez, M Coote, Simone Ciampi Jan 2018

Electrochemical And Electrostatic Cleavage Of Alkoxyamines, Long Zhang, Eduardo Laborda, Nadim A. Darwish, Benjamin B. Noble, Jason Tyrell, Sandra Pluczyk, Anton P. Le Brun, Gordon G. Wallace, Joaquin Gonzalez, M Coote, Simone Ciampi

Australian Institute for Innovative Materials - Papers

Alkoxyamines are heat-labile molecules, widely used as an in situ source of nitroxides in polymer and materials sciences. Here we show that the one-electron oxidation of an alkoxyamine leads to a cation radical intermediate that even at room temperature rapidly fragments, releasing a nitroxide and carbocation. Digital simulations of experimental voltammetry and current-time transients suggest that the unimolecular decomposition which yields the "unmasked" nitroxide (TEMPO) is exceedingly rapid and irreversible. High-level quantum computations indicate that the collapse of the alkoxyamine cation radical is likely to yield a neutral nitroxide radical and a secondary phenylethyl cation. However, this fragmentation is predicted …


Superhydrophobic Shape Memory Polymer Arrays With Switchable Isotropic/Anisotropic Wetting, Zhongjun Cheng, Dongjie Zhang, Tong Lv, Hua Lai, Enshuang Zhang, Hongjun Kang, Yongzhen Wang, Pengchang Liu, Yuyan Liu, Yi Du, Shi Xue Dou, Lei Jiang Jan 2018

Superhydrophobic Shape Memory Polymer Arrays With Switchable Isotropic/Anisotropic Wetting, Zhongjun Cheng, Dongjie Zhang, Tong Lv, Hua Lai, Enshuang Zhang, Hongjun Kang, Yongzhen Wang, Pengchang Liu, Yuyan Liu, Yi Du, Shi Xue Dou, Lei Jiang

Australian Institute for Innovative Materials - Papers

Smart surfaces with tunable wettability have aroused much attention in the past few years. However, to obtain a surface that can reversibly transit between the lotus-leaf-like superhydrophobic isotropic and rice-leaf-like superhydrophobic anisotropic wettings is still a challenge. This paper, by mimicking microstructures on both lotus and rice leaves, reports such a surface that is prepared by creating micro/nanostructured arrays on the shape memory polymer. On the surface, the microstructure shapes can be reversibly changed between the lotus-leaf-like random state and the rice-leaf-like 1D ordered state. Accordingly, repeated switch between the superhydrophobic isotropic and anisotropic wettings can be displayed. Research results …


Super-Compatible Functional Boron Nitride Nanosheets/Polymer Films With Excellent Mechanical Properties And Ultra-High Thermal Conductivity For Thermal Management, Jiemin Wang, Yuanpeng Wu, Ye Xue, Dan Liu, Xuebin Wang, Xiao Hu, Yoshio Bando, Weiwei Lei Jan 2018

Super-Compatible Functional Boron Nitride Nanosheets/Polymer Films With Excellent Mechanical Properties And Ultra-High Thermal Conductivity For Thermal Management, Jiemin Wang, Yuanpeng Wu, Ye Xue, Dan Liu, Xuebin Wang, Xiao Hu, Yoshio Bando, Weiwei Lei

Australian Institute for Innovative Materials - Papers

High heat-dissipation polymers are currently in great demand especially with the rapid development of electronic devices. However, traditional polymer composites usually suffer from both low thermal conductivity due to poor dispersibility and low concentration of fillers in the polymer matrix. To address this issue, it is necessary to improve the compatibility between the thermal conductive fillers and polymer matrix. Here, we designed a highly water-soluble functionalized boron nitride (FBN) nanosheet. Unlike most functional BN nanosheets that are only dispersible in water with polymer matrix at low concentrations, our FBN nanosheets can be mutually dispersed with aqueous polymers such as polyvinyl …


Enhanced Thermoelectric Performance Through Synergy Of Resonance Levels And Valence Band Convergence Via Q/In (Q = Mg, Ag, Bi) Co-Doping, Lijuan Zhang, Peng Qin, Chao Han, Jian Li Wang, Zhenhua Ge, Qiao Sun, Zhenxiang Cheng, Zhen Li, Shi Xue Dou Jan 2018

Enhanced Thermoelectric Performance Through Synergy Of Resonance Levels And Valence Band Convergence Via Q/In (Q = Mg, Ag, Bi) Co-Doping, Lijuan Zhang, Peng Qin, Chao Han, Jian Li Wang, Zhenhua Ge, Qiao Sun, Zhenxiang Cheng, Zhen Li, Shi Xue Dou

Australian Institute for Innovative Materials - Papers

The temperature-dependent evolution of heavy-hole valence band contribution to the Seebeck coefficients of SnTe-based thermoelectric materials is revealed in situ by neutron and synchrotron powder diffraction. The additional carriers with high effective mass are created in a heavy-hole valence band above 493 K, which contribute to the electrical transport, and lead to a significant enhancement of the Seebeck coefficient at high temperature. In addition, remarkably improved electrical transport properties are achieved through the synergetic effects of the resonance levels, the valence band convergence, and the carrier concentration optimization by co-doping with Mg & In, Ag & In and Bi & …


Charging Ahead: How Australia Is Innovating In Battery Technology, Jonathan Knott Jan 2018

Charging Ahead: How Australia Is Innovating In Battery Technology, Jonathan Knott

Australian Institute for Innovative Materials - Papers

Lithium-ion remains the most widespread battery technology in use today, thanks to the fact that products that use it are both portable and rechargeable. It powers everything from your smartphone to the "world's biggest battery" in South Australia. Demand for batteries is expected to accelerate in coming decades with the increase in deployment of electric vehicles and the need to store energy generated from renewable sources, such as solar photovoltaic panels. But rising concerns about mining practices and shortages in raw materials for lithium-ion batteries - as well as safety issues - have led to a search for alternative technologies.


Porous Zr2sc-Carbon Composite Microspheres: Possible Radiation Tolerant Sorbents And Transmutation Hosts For Technetium-99, Nicholas Scales, Jun Chen, Robert Aughterson, Inna Karatchevtseva, Attila Stopic, Gregory R. Lumpkin, Vittorio Luca Jan 2018

Porous Zr2sc-Carbon Composite Microspheres: Possible Radiation Tolerant Sorbents And Transmutation Hosts For Technetium-99, Nicholas Scales, Jun Chen, Robert Aughterson, Inna Karatchevtseva, Attila Stopic, Gregory R. Lumpkin, Vittorio Luca

Australian Institute for Innovative Materials - Papers

The preparation, characteristics and adsorption properties of novel porous carbon-ceramic composite microspheres are presented. The composites were synthesised by a simple ion exchange process involving the cationic Zr tetramer and commonly-available macroporous sulphonated polystyrene-divinylbenzene cation exchange resins, with subsequent carbothermal reduction at 1350 °C. The materials were extensively characterised with respect to composition, chemical structure and porosity. Carbothermal reduction of the Zr-loaded templates resulted in formation of crystallites of the MAX phase zirconium sulphide carbide (Zr 2 SC) embedded within a highly microporous carbon framework with a macroporous secondary structure inherited from the resin template. Despite the high BET surface …


Alkaline Fuel Cells With Novel Gortex-Based Electrodes Are Powered Remarkably Efficiently By Methane Containing 5% Hydrogen, Klaudia K. Wagner, Prerna Tiwari, Gerhard F. Swiegers, Gordon G. Wallace Jan 2018

Alkaline Fuel Cells With Novel Gortex-Based Electrodes Are Powered Remarkably Efficiently By Methane Containing 5% Hydrogen, Klaudia K. Wagner, Prerna Tiwari, Gerhard F. Swiegers, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Numerous electric and gas utilities are actively pursuing "power-to-gas" technology, which involves using unwanted, excess renewable energy to manufacture hydrogen gas (H 2 ) that is then injected into the existing natural gas pipeline network in 5-10% by volume. This work reports an alkaline fuel cell that has the potential to harness such gas mixtures for downstream generation of electric power. The fuel cell, which employs novel Gortex-based electrodes layered with Pd/Pt catalysts, generates electricity remarkably efficiently when fuelled with methane (CH 4 ) containing 5% hydrogen. Methane constitutes the major component of natural gas. The fuel cell has been …


Readily Exfoliated Tise2 Nanosheets For High-Performance Sodium Storage, Dan Zhang, Guoqiang Zhao, Peng Li, Yu Zhang, Wenbin Qiu, Jie Shu, Yinzhu Jiang, Shi Xue Dou, Wenping Sun Jan 2018

Readily Exfoliated Tise2 Nanosheets For High-Performance Sodium Storage, Dan Zhang, Guoqiang Zhao, Peng Li, Yu Zhang, Wenbin Qiu, Jie Shu, Yinzhu Jiang, Shi Xue Dou, Wenping Sun

Australian Institute for Innovative Materials - Papers

Materials with sheet-like morphologies are highly desirable candidates for energy storage and conversion applications, due to the confined atomic thickness and high surface area, which would largely improve the electrochemical reaction kinetics. In this work, the sodium storage performance of TiSe 2 nanosheets and corresponding sodiation/desodiation reaction mechanism are studied for the first time. TiSe 2 nanosheets are readily exfoliated from bulk TiSe 2 after quick ultrasonication or grinding. The TiSe 2 nanosheets exhibit a reversible capacity of 147mAhg -1 at 0.1Ag -1 , and show excellent rate capability with a capacity of 103mAhg -1 at an ultra-high current density …


Origin Of Magnetic Flux-Jumps In Nb Films Subject To Mechanical Vibrations And Corresponding Magnetic Perturbations, Igor A. Golovchanskiy, Alexey V. Pan, Tom H. Johansen, Jonathan George, Igor Rudnev, Anatoly B. Rosenfeld, Sergey Fedoseev Jan 2018

Origin Of Magnetic Flux-Jumps In Nb Films Subject To Mechanical Vibrations And Corresponding Magnetic Perturbations, Igor A. Golovchanskiy, Alexey V. Pan, Tom H. Johansen, Jonathan George, Igor Rudnev, Anatoly B. Rosenfeld, Sergey Fedoseev

Australian Institute for Innovative Materials - Papers

In this paper the origin of flux-jumps in Nb thin films is established during magnetization measurements using a vibrating sample magnetometer (VSM). Magnetization measurements of the flux avalanche activity show its strong dependence on frequency and amplitude of VSM vibration. In particular, under certain conditions the vibrations induce a transition from a stable superconducting critical state to an undercritical state, accompanied by the 20-fold drop in the magnetic moment. These features allow the elucidation of the origin of the flux-jumps. In contrast to the commonly assumed thermomagnetic instabilities to be responsible for the flux-jumps in Nb films, our results provide …


Suppression Of The Photocatalytic Activity Of Tio2 Nanoparticles Encapsulated By Chitosan Through A Spray-Drying Method With Potential For Use In Sunblocking Applications, Alexander Morlando, Vitor Sencadas, Dean Cardillo, Konstantin K. Konstantinov Jan 2018

Suppression Of The Photocatalytic Activity Of Tio2 Nanoparticles Encapsulated By Chitosan Through A Spray-Drying Method With Potential For Use In Sunblocking Applications, Alexander Morlando, Vitor Sencadas, Dean Cardillo, Konstantin K. Konstantinov

Australian Institute for Innovative Materials - Papers

Solar exposure, in particular to UVA and UVB radiation, is a major carcinogen through direct DNA damage and the production of reactive oxygen species (ROS). Inorganic UV filters present in sunscreening agents, such as titanium dioxide (TiO 2 ), are commonly employed for protection however, due to their photocatalytic nature, they have been shown to instigate the production of ROS when irradiated with UV radiation, which in turn can lead to the degradation of the sunscreening formulation and subsequent damage to the skin. In this work, chitosan/TiO 2 nanocomposite particles were produced via a spray-drying method, in a single step, …


Enhanced Uv-Light Detection Based On Zno Nanowires/Graphene Oxide Hybrid Using Cost-Effective Low Temperature Hydrothermal Process, Tariq Alzoubi, Hamzeh Qutaish, Esraa Al-Shawwa, Sameh Hamzawy Jan 2018

Enhanced Uv-Light Detection Based On Zno Nanowires/Graphene Oxide Hybrid Using Cost-Effective Low Temperature Hydrothermal Process, Tariq Alzoubi, Hamzeh Qutaish, Esraa Al-Shawwa, Sameh Hamzawy

Australian Institute for Innovative Materials - Papers

A new low-cost optimized hydrothermal process of direct synthesis of ZnO nanowires (NWs)/graphene oxide (GO) hybrid on silicon substrates at a low growth temperature (∼60°C) is reported. The careful optimization of the growth conditions and ZnO/GO relative ratios have resulted in high-density ZnO NWs formation with homogenous density and size distributions directly on GO sheets. The fabricated nanocomposites were intensively investigated by employing different structural, optical and electrical characterization techniques such as SEM, EDX, XRD, FTIR, UV-VIS and I-V. SEM analysis showed a formation of highly dense ZnO NWs on GO sheets with homogenous size di stributions with average approximate …


Nature Of Magnetism In Thiol-Capped Gold Nanoparticles Investigated With Muon Spin Rotation, M H. Dehn, D J. Arseneau, T Buck, David L. Cortie, D G. Fleming, Shirin King, W A. Macfarlane, Andrew M. Mcdonagh, R M. L Mcfadden, David R. G Mitchell, R F. Kiefl Jan 2018

Nature Of Magnetism In Thiol-Capped Gold Nanoparticles Investigated With Muon Spin Rotation, M H. Dehn, D J. Arseneau, T Buck, David L. Cortie, D G. Fleming, Shirin King, W A. Macfarlane, Andrew M. Mcdonagh, R M. L Mcfadden, David R. G Mitchell, R F. Kiefl

Australian Institute for Innovative Materials - Papers

Muon spin rotation/relaxation measurements show clear evidence for magnetism in 2.2 nm gold nanoparticles capped with butanethiol. At low temperatures (1.8 K), there is significant spin relaxation which decreases as a function of both the applied longitudinal magnetic field and increasing temperature. The results indicate that there are spatially inhomogeneous electronic moments that fluctuate with a wide distribution of correlation times. Possible explanations are discussed.


Hybrid Nanoarchitecturing Of Hierarchical Zinc Oxide Wool-Ball-Like Nanostructures With Multi-Walled Carbon Nanotubes For Achieving Sensitive And Selective Detection Of Sulfur Dioxide, Ni Luh Wulan Septiani, Yusuf Valentino Kaneti, Brian Yuliarto, Nugraha Nugraha, Hermawan Dipojono, Toshiaki Takei, Jungmok You, Yusuke Yamauchi Jan 2018

Hybrid Nanoarchitecturing Of Hierarchical Zinc Oxide Wool-Ball-Like Nanostructures With Multi-Walled Carbon Nanotubes For Achieving Sensitive And Selective Detection Of Sulfur Dioxide, Ni Luh Wulan Septiani, Yusuf Valentino Kaneti, Brian Yuliarto, Nugraha Nugraha, Hermawan Dipojono, Toshiaki Takei, Jungmok You, Yusuke Yamauchi

Australian Institute for Innovative Materials - Papers

This work reports a facile glycerol-assisted solvothermal method for synthesizing hierarchical three-dimensional (3D) wool-ball-like zinc oxide (ZnO) nanostructures and their subsequent modifications with multi-walled carbon nanotubes (MWCNTs) as modifiers for achieving sensitive and selective detection of toxic sulfur dioxide (SO2) gas. Structurally, the as-synthesized 3D wool-ball-like ZnO is assembled of two-dimensional (2D) plate-like structures, which themselves are arranged by numerous small nanoparticles. Furthermore, in this work we observed an interesting new phenomenon in which when a high concentration of MWCNTs is introduced, many small nanorods grew on the surface of the plate-like structures which assemble the 3D wool-ball-like ZnO nanostructures. …


An Electrosynthesized 3d Porous Molybdenum Sulfide/Graphene Film With Enhanced Electrochemical Performance For Lithium Storage, Yu Ge, Caiyun Wang, Yong Zhao, Yong Liu, Yunfeng Chao, Tian Zheng, Gordon G. Wallace Jan 2018

An Electrosynthesized 3d Porous Molybdenum Sulfide/Graphene Film With Enhanced Electrochemical Performance For Lithium Storage, Yu Ge, Caiyun Wang, Yong Zhao, Yong Liu, Yunfeng Chao, Tian Zheng, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Molybdenum sulfide/graphene composites are promising anode materials for lithium-ion batteries (LIBs). In this work, MoS x /graphene composite film with an ideal 3D porous structure is developed via a facile and straightforward electrochemical route. The MoS x nanoparticles are uniformly anchored on the graphene nanosheets that are randomly arranged, resulting in MoS x /graphene composites with well-developed porous structure. Benefiting from such structure and the synergistic effect from two components, this material shows a high specific capacity over 1200 mA h g −1 , an excellent rate performance, and superior cycling stability. The dominating pseudocapacitive behavior in Li storage contributes …


Two-Dimensional Nanostructures For Sodium-Ion Battery Anodes, Jianfeng Mao, Tengfei Zhou, Yang Zheng, Hong Gao, Hua-Kun Liu, Zaiping Guo Jan 2018

Two-Dimensional Nanostructures For Sodium-Ion Battery Anodes, Jianfeng Mao, Tengfei Zhou, Yang Zheng, Hong Gao, Hua-Kun Liu, Zaiping Guo

Australian Institute for Innovative Materials - Papers

Sodium-ion batteries (SIBs) have attracted great attention recently due to the abundance of sodium resources, particularly for large-scale electric energy storage applications for renewable energy and smart grids. More and more nanostructured anode materials have been developed with the aims of high energy density, high cycling stability, and excellent rate capability, in which two-dimensional (2D) nanostructures are showing promise due to their shortened paths for sodium ion transportation and larger surface areas for sodium ion absorption. Moreover, 2D materials (e.g. graphene) have been proved to be excellent supporting and conducting agents in SIB anodes due to their high electrical conductivity …