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Articles 1 - 12 of 12
Full-Text Articles in Physical Sciences and Mathematics
Photoelectron Angular Distributions From Rotationally Resolved Autoionizing States Of N2, Alexander M. Chartrand, Elizabeth F. Mccormack, Ugo Jacovella, David M P Holland, Berenger Gans, Xiaofeng Tang, Gustavo A. García, Laurent Nahon, Stephen T. Pratt
Photoelectron Angular Distributions From Rotationally Resolved Autoionizing States Of N2, Alexander M. Chartrand, Elizabeth F. Mccormack, Ugo Jacovella, David M P Holland, Berenger Gans, Xiaofeng Tang, Gustavo A. García, Laurent Nahon, Stephen T. Pratt
Physics Faculty Research and Scholarship
The single-photon, photoelectron-photoion coincidence spectrum of N2 has been recorded at high (~1.5 cm–1 ) resolution in the region between the N2+ X 2Σg+, v+ = 0 and 1 ionization thresholds by using a double-imaging spectrometer and intense vacuum-ultraviolet light from the Synchrotron SOLEIL. This approach provides the relative photoionization cross section, the photoelectron energy distribution, and the photoelectron angular distribution as a function of photon energy. The region of interest contains autoionizing valence states, vibrationally autoionizing Rydberg states converging to vibrationally excited levels of the N2+ X 2 …
The Effect Of Preflood Nitrogen And Flood Establishment Timing On Rice Development, Nitrogen Uptake And Grain Yield, Tyler Richmond
The Effect Of Preflood Nitrogen And Flood Establishment Timing On Rice Development, Nitrogen Uptake And Grain Yield, Tyler Richmond
Graduate Theses and Dissertations
Urea-N fertilizer is typically applied at the 5-leaf stage to rice (Oryza sativa L.) grown in a dry-seeded, delayed-flood production system. How long the preflood-N can be delayed without adverse effects on yield potential is poorly understood. The research objective was to determine the effects of preflood-N application and flood establishment timing on aboveground-N content, 50% heading, yield components, and grain yield. Trials were established on silt loam soils at the Pine Tree Research Station (PTRS) and Rice Research and Extension Center (RREC) during 2015 and 2016. Urea-N was applied at 0, 45, 90, 135, and 180 kg N ha-1 …
Nutrient Contamination From Non-Point Sources: Dissolved Nitrate And Ammonium In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Hunter R. Evans, Walter S. Borowski, Jonathan M. Malzone
Nutrient Contamination From Non-Point Sources: Dissolved Nitrate And Ammonium In Surface And Subsurface Waters At Eku Meadowbrook Farm, Madison County, Kentucky, Reid E. Buskirk, Hunter R. Evans, Walter S. Borowski, Jonathan M. Malzone
EKU Faculty and Staff Scholarship
Agricultural activities often contaminate watersheds with excess nutrients leading to poor water quality and eutrophication. We assayed dissolved nutrient levels in surface and subsurface waters of Eastern Kentucky University’s Meadowbrook Farm in order to assess levels of dissolved nutrients leaving its farmland and draining into the Muddy Creek watershed. The Farm raises both crops and livestock so that nutrient sources include fertilizer and manure. We sampled springs, runoff, and subsurface pipe drainage as well as Muddy Creek on six days from May to August 2016 under a variety of weather conditions. Using established, standard colorimetric methods, we measured nitrate (NO …
N2o Emissions From California Farmlands: A Review, Elizabeth Verhoeven, Engil Isadora Pujol Pereira, Charlotte Decock, Gina Garland, Taryn Kennedy, Emma Suddick, William Horwath, Johan Six
N2o Emissions From California Farmlands: A Review, Elizabeth Verhoeven, Engil Isadora Pujol Pereira, Charlotte Decock, Gina Garland, Taryn Kennedy, Emma Suddick, William Horwath, Johan Six
School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations
Of the greenhouse gases emitted from cropland, nitrous oxide (N2O) has the highest global warming potential. The state of California acknowledges that agriculture both contributes to and is affected by climate change, and in 2016 it adopted legislation to help growers reduce emissions of greenhouse gases, explicitly including N2O. Nitrous oxide emissions can vary widely due to environmental and agronomic factors with most emission estimates coming from temperate grain systems. There is, however, a dearth of emission estimates from perennial and vegetable cropping systems commonly found in California's Mediterranean climate. Therefore, emission factors (EFs) specific to California conditions are needed …
Nutrient Addition Shifts Plant Community Composition Towards Earlier Flowering Species In Some Prairie Ecoregions In The U.S. Central Plains, Lori Biederman, Brent Mortensen, Philip Fay, Nicole Hagenah, Johannes Knops, Kimberly La Pierre, Ramesh Laungani, Eric Lind, Rebecca L. Mcculley, Sally Power, Eric Seabloom, Pedro Tognetti
Nutrient Addition Shifts Plant Community Composition Towards Earlier Flowering Species In Some Prairie Ecoregions In The U.S. Central Plains, Lori Biederman, Brent Mortensen, Philip Fay, Nicole Hagenah, Johannes Knops, Kimberly La Pierre, Ramesh Laungani, Eric Lind, Rebecca L. Mcculley, Sally Power, Eric Seabloom, Pedro Tognetti
Plant and Soil Sciences Faculty Publications
The distribution of flowering across the growing season is governed by each species’ evolutionary history and climatic variability. However, global change factors, such as eutrophication and invasion, can alter plant community composition and thus change the distribution of flowering across the growing season. We examined three ecoregions (tall-, mixed, and short-grass prairie) across the U.S. Central Plains to determine how nutrient (nitrogen (N), phosphorus, and potassium (+micronutrient)) addition alters the temporal patterns of plant flowering traits. We calculated total community flowering potential (FP) by distributing peak-season plant cover values across the growing season, allocating each species’ cover to only those …
Decomposition Of Black Mangrove (Avicennia Germinans ) Leaf Litter: Calibrating Estuarine Indicators Of Functional Recovery, Leticia Martinez Contreras
Decomposition Of Black Mangrove (Avicennia Germinans ) Leaf Litter: Calibrating Estuarine Indicators Of Functional Recovery, Leticia Martinez Contreras
Theses and Dissertations
Decomposition of plant material produced by mangroves and other macrophytes in estuaries occurs in both sediments and the water column. Early and intense processing could be more common in the water. In a previous study, in situ decomposition rates of Black Mangrove (Avicennia germinans ) leaf litter suspended in the water column differed among three estuaries in south Texas with moderate differences in salinity, water temperature, available nitrogen (N), and tidal flow. A series of microcosm experiments were conducted to determine the influence, within observed ranges in the estuaries, of these water variables on mass loss of Black Mangrove …
Analysis Of Carbon And Nitrogen Stable Isotope Levels In Side-Blotched Lizards ( Uta Stansburiana ) Fed Varying Diets, Kati Mattinson
Analysis Of Carbon And Nitrogen Stable Isotope Levels In Side-Blotched Lizards ( Uta Stansburiana ) Fed Varying Diets, Kati Mattinson
Physics Capstone Projects
When attempting to determine the diet of wild animals, a limited number of techniques currently exist. Often, biologists look at the stomach contents or feces of an animal, if they cannot observe what it is eating directly. However, these techniques often cannot be used with reptiles because they may not eat often or may have an empty stomach when the contents of their stomach are examined. Many ecologists have begun to use stable isotopes of carbon and nitrogen to determine what an animal has eaten. Stable isotopes are useful because unlike radioactive isotopes, stable isotopes do not decay and thus …
Nitrogen Sustainability: Impediments To Action And Communication, Eric E. Jorgensen
Nitrogen Sustainability: Impediments To Action And Communication, Eric E. Jorgensen
Journal of Environmental Sustainability
“Sustainability” is widely used to imply the presence of explicit consideration of environmentally friendly needs and that high societal-value is placed on those needs. However, it is abundantly clear after 30 years that talking about sustainability and achieving it are two entirely different things. The core concept underlying sustainability is that current human practices and activities be conducted so as to not degrade prospects for future generations. With nitrogen, conflicts about sustainability in-theory and sustainability in-practice are close to the surface because of nitrogen’s central role in food production and economic activity. Measures of nitrogen inputs commonly range as high …
Drivers Of Nitrogen Transfer In Stream Food Webs Across Continents, B. C. Norman, M. R. Whiles, S. M. Collins, A. S. Flecker, S. K. Hamilton, S. L. Johnson, E. J. Rosi-Marshall, L. R. Ashkenas, W. B. Bowden, C. L. Crenshaw, T. Crowl, W. K. Dodds, R. O. Hall, R. El-Sabaawi, N. A. Griffiths, E. Marti, W. H. Mcdowell, S. D. Peterson, H. M. Rantala, T. Riis, K. S. Simon, J. L. Tank, S. A. Thomas, D. Von Schiller, J. R. Webster
Drivers Of Nitrogen Transfer In Stream Food Webs Across Continents, B. C. Norman, M. R. Whiles, S. M. Collins, A. S. Flecker, S. K. Hamilton, S. L. Johnson, E. J. Rosi-Marshall, L. R. Ashkenas, W. B. Bowden, C. L. Crenshaw, T. Crowl, W. K. Dodds, R. O. Hall, R. El-Sabaawi, N. A. Griffiths, E. Marti, W. H. Mcdowell, S. D. Peterson, H. M. Rantala, T. Riis, K. S. Simon, J. L. Tank, S. A. Thomas, D. Von Schiller, J. R. Webster
School of Natural Resources: Faculty Publications
Studies of trophic-level material and energy transfers are central to ecology. The use of isotopic tracers has now made it possible to measure trophic transfer efficiencies of important nutrients and to better understand how these materials move through food webs. We analyzed data from thirteen 15N-ammonium tracer addition experiments to quantify N transfer from basal resources to animals in headwater streams with varying physical, chemical, and biological features. N transfer efficiencies from primary uptake compartments (PUCs; heterotrophic microorganisms and primary producers) to primary consumers was lower (mean: 11.5%, range:100%). Total N transferred (as a rate) was greater in streams …
Partitioning Assimilatory Nitrogen Uptake In Streams: An Analysis Of Stable Isotope Tracer Additions Across Continents, J. L. Tank, E. Martí, T. Riis, D. Von Schiller, A. J. Reisinger, W. K. Dodds, M. R. Whiles, L. R. Ashkenas, W. B. Bowden, S. M. Collins, C. L. Crenshaw, T. A. Crowl, N. A. Griffiths, N. B. Grimm, S. K. Hamilton, S. L. Johnson, W. H. Mcdowell, B. M. Norman, E. J. Rosi, K. S. Simon, S. A. Thomas, J. R. Webster
Partitioning Assimilatory Nitrogen Uptake In Streams: An Analysis Of Stable Isotope Tracer Additions Across Continents, J. L. Tank, E. Martí, T. Riis, D. Von Schiller, A. J. Reisinger, W. K. Dodds, M. R. Whiles, L. R. Ashkenas, W. B. Bowden, S. M. Collins, C. L. Crenshaw, T. A. Crowl, N. A. Griffiths, N. B. Grimm, S. K. Hamilton, S. L. Johnson, W. H. Mcdowell, B. M. Norman, E. J. Rosi, K. S. Simon, S. A. Thomas, J. R. Webster
School of Natural Resources: Faculty Publications
Headwater streams remove, transform, and store inorganic nitrogen (N) delivered from surrounding watersheds, but excessive N inputs from human activity can saturate removal capacity. Most research has focused on quantifying N removal from the water column over short periods and in individual reaches, and these ecosystem-scale measurements suggest that assimilatory N uptake accounts for most N removal. However, cross-system comparisons addressing the relative role of particular biota responsible for incorporating inorganic N into biomass are lacking. Here we assess the importance of different primary uptake compartments on reach-scale ammonium (NH4+-N) uptake and storage across a wide range …
Effects Of Silvopasture Establishment On Aqueous And Gaseous Soil N Losses At The University Of New Hampshire Organic Dairy Research Farm, Kathryn Ann Slebodnik
Effects Of Silvopasture Establishment On Aqueous And Gaseous Soil N Losses At The University Of New Hampshire Organic Dairy Research Farm, Kathryn Ann Slebodnik
Honors Theses and Capstones
The expansion of local agriculture in the New England region is putting increased pressure on farmers to expand their arable land base. While clear-cutting is a traditional method of converting forested land to agriculture, it is known for having adverse ecological impacts. To minimize these impacts, farmers can create a silvopasture which incorporates a portion of the original forest canopy into pastures or crop fields. This study evaluates the impact of land-use changes for agriculture on soil nitrogen (N) retention. In particular, this study investigates the differences in soil N turnover, gaseous loss, and aqueous loss among an established forest, …
A Novel Method For Determination Of Ammonium Isotope Ratios With Electrospray Ionization Mass Spectrometry, Rebecca J. Chmiel
A Novel Method For Determination Of Ammonium Isotope Ratios With Electrospray Ionization Mass Spectrometry, Rebecca J. Chmiel
Honors Theses
Nitrogen (15N) isotope tracer studies are an invaluable tool for understanding the rate of N transformations in the environment. A mechanistic understanding of N cycling is critical to management of excess N availability in freshwater and marine ecosystems. Conventional methods for measuring 15N:14N of dissolved inorganic nitrogen species are time consuming and require large sample volumes. Here, we present a technique for measuring 15N:14N in ammonium (NH4+) using electrospray ionization mass spectrometry (ESI-MS). NH4+ present in small volumes of sample (3 ml) is complexed with phenol via …