Physical Sciences and Mathematics Commons^™

Seismological Investigation Of The Okavango Rift, Botswana, Youqiang Yu

Doctoral Dissertations

The mechanisms of rifting have been intensively investigated using geological and geophysical techniques beneath mature rift zones. However, current understanding on the earliest stages of rifting is seriously limited. Here we employ recently archived data from 17 broadband seismic stations traversing northern Botswana to conduct the first shear wave splitting and mantle transition zone (MTZ) studies within the Okavango Rift Zone (ORZ). The ORZ is an incipient continental rift situated at the terminal of the southwestern branch of the East African Rift System. The resulting normal MTZ thickness and consistently rift-parallel fast polarizations imply an absence of significant thermal anomalies …

Pulsed Inductive Plasma Studies By Spectroscopy And Internal Probe Methods, Warner C. Meeks

Doctoral Dissertations

The broad effort of the Missouri Plasmoid Experiment is to elucidate the energy conversion processes in a pulsed inductive discharge due to the presence of plasma. The test article is a 440 to 490 kHz theta-pinch (or solenoidal) geometry coil with a stored energy of around 80 joules. In this work experimental hydrogen, helium, argon and xenon data at back-fill pressures of 10 to 100 mTorr (1.3 to 133.3 Pa) are obtained and interpreted. Spectral and internal probe studies were performed on MPX Mk.I and Mk.II devices, respectively. IR spectra were acquired in the Mk.I device for argon and xenon. …

Process Design, Dynamics, And Techno-Economic Analysis Of A Sustainable Coal, Wind, And Small Modular Nuclear Reactor Hybrid Energy System, Kyle Lee Buchheit

Doctoral Dissertations

"The availability of cheap electricity is one of the biggest factors for improving quality of life. With the debate on the effects of carbon dioxide emissions continuing, several countries have either implemented or are considering the reduction of emissions through various economic means. The inclusion of a monetary penalty on carbon emissions would increase the prices of electricity produced by carbon-based sources. The push for large-scale renewable sources of energy has met problems with regards to energy storage and availability. The proposed coal, wind, and nuclear hybrid energy system would combine a renewable energy source, wind, with traditional and stable …

Privacy-Preserving Query Processing Over Encrypted Data In Cloud, Yousef M. Elmehdwi

Doctoral Dissertations

"The query processing of relational data has been studied extensively throughout the past decade. A number of theoretical and practical solutions to query processing have been proposed under various scenarios. With the recent popularity of cloud computing, data owners now have the opportunity to outsource not only their data but also data processing functionalities to the cloud. Because of data security and personal privacy concerns, sensitive data (e.g., medical records) should be encrypted before being outsourced to a cloud, and the cloud should perform query processing tasks on the encrypted data only. These tasks are termed as Privacy-Preserving Query Processing …

Synthesis And Characterization Of Vanadium Oxide Nanomaterials, Tyler M. Fears

Doctoral Dissertations

"This dissertation focuses on the synthesis and characterization of vanadium oxide nanomaterials and neutron-transparent Li-ion battery electrolytes.

Vanadium oxide gels were synthesized via the epoxide-assisted gelation of VOCl₃ using epichlorohydrin in ethanol. This represents the first epoxide-assisted gelation developed for vanadium oxide gels and serves as a potential economical replacement for the fabrication of vanadium oxide gels via the hydrolysis of vanadium alkoxides. Though epoxide-assisted gelation has been demonstrated for a number of transition metal oxides, the gelation mechanism observed here for VOCl₃ appears to be unique.

While investigating the electrochemical and structural properties of lithium vanadates, it …

Quantification Of Information Flow In Cyber Physical Systems, Li Feng

Doctoral Dissertations

"In Cyber Physical Systems (CPSs), traditional security mechanisms such as cryptography and access control are not enough to ensure the security of the system since complex interactions between the cyber portion and physical portion happen frequently. In particular, the physical infrastructure is inherently observable; aggregated physical observations can lead to unintended cyber information leakage. Information flow analysis, which aims to control the way information flows among different entities, is better suited for CPSs than the access control security mechanism. However, quantifying information leakage in CPSs can be challenging due to the flow of implicit information between the cyber portion, the …

Methods And Algorithms For Service Selection And Recommendation (Preference And Aggregation Based), Kenneth Kofi Fletcher

Doctoral Dissertations

"In order for service users to get the best service that meets their requirements, they prefer to personalize their non-functional attributes, such as reliability and price. However, the personalization makes it challenging because service providers have to deal with conflicting non-functional attributes when selecting services for users. In addition, users may sometimes want to explicitly specify their trade-offs among non-functional attributes to make their preferences known to service providers. Typically, users' service search requests with conflicting non-functional attributes may result in a ranked list of services that partially meet their needs. When this happens, it is natural for users to …

Mechanical Characteristics Of Organically Modified Fly Ash-Kaolinite Mixtures, Xin Kang

Doctoral Dissertations

"Fly ash is a hazardous waste material to the environment. Beneficial reuse of fly ash, however, brings economic and environmental benefits, i.e., decreases the cost of disposal, reduces greenhouse gas emission, and improves mechanical properties of construction materials. Due to the lack of pozzolanic properties, the reuse rate of Class F fly ash in geotechnical engineering is relatively low (ACAA 2013). In order to promote the effectiveness and sustainability of high volume reuse of class F fly ash in geotechnical engineering, biopolymers (Chitosan, and Xanthan gum) and synthetic polymers (Polyethylene Oxide, PEO) were used instead of the traditional stabilizers to …

Effects Of N-Acetylcysteine Amide In Preventing/Treating Cataracts, Sri Krishna Yasaswi Maddirala

Doctoral Dissertations

"Cataract, the opacification of an eye lens, is a common pathological abnormality of the lens accounting for approximately 50% of all blindness. The only effective treatment currently available for a cataract is the surgical removal of the affected lens and replacement with an artificial lens for the restoration of vision. Although, cataract surgery is considered to be a very successful procedure in terms of visual outcome, the cost of surgery, need for trained personnel and surgeons, and postsurgical complications, limit the worldwide availability and accessibility of this procedure. Hence, alternative preventive and treatment procedures are worthy of investigation. The lens …

Holocene Sedimentology And Stratigraphy Of Coastal Sediments In An Arid Climate, Al Qahmah, Southern Red Sea, Saudi Arabia, Abdullah Ibrahim Nabhan

Doctoral Dissertations

"Holocene sedimentary deposits in Al Qahmah coast, southern Red Sea, in Saudi Arabia have been accumulated on an arid siliciclastic coast in a rift tectonic setting. This study provides a detail interpretation and analysis of sedimentary facies, stratigraphy, depositional environment, and major geological processes. Two studies have been undertaken. First, petrological study of composition and texture of modern sediments and facies mapping delineate facies distribution and mechanisms of sediment transport and deposition. A unique suite of complex riverine, wave, tidal, wind, and chemical and biological processes affect the composition, texture, and distribution of the facies. Second, the depositional environments of …

The Synthesis And Characterization Of Water-Reducible Nanoscale Colloidal Unimolecular Polymer (Cup) Particles, Cynthia J. Riddles

Doctoral Dissertations

"The coatings industry has adapted to more stringent guidelines in paint formulations. Current VOC (volatile organic compound) limits placed by the federal government have pushed the industry toward the development of paint formulations which have very little to no VOC's. The development of Colloidal Unimolecular Polymer (CUP) particles is a step in the direction of providing a resin system which exists in zero VOC aqueous dispersion.

The CUP particles are a part of the polymer field of Single Chain Nano Particles (SCNP) and ranged in diameters of 3-9 nm. The research presented in this dissertation describes the synthesis and design …

Distributed State Verification In The Smart Grid Using Physical Attestation, Thomas Patrick Roth

Doctoral Dissertations

"A cyber process in a distributed system can fabricate its internal state in its communications with its peers. These state fabrications can cause other processes in the distributed system to make incorrect control decisions. Cyber-physical systems have a unique advantage in the detection of falsified states because processes typically have observable effects on a shared physical infrastructure. This physical infrastructure acts as a high-integrity message channel that broadcasts changes in individual process states. The objective of this research is to demonstrate that there are cases where physical feedback from the shared infrastructure can be used to detect state fabrications. To …

Analytical And Numerical Studies Of Photo-Injected Charge Transport In Molecularly-Doped Polymers, Amrita Roy Chowdhury

Doctoral Dissertations

"The mobility of photo-injected charge carriers in molecularly-doped polymers (MDPs) exhibits a commonly observed, and nearly universal Poole-Frenkel field dependence, µ ~ exp [square root (ß₀E)], that has been shown to arise from the correlated Gaussian energy distribution of transport sites encountered by charges undergoing hopping transport through the material. Analytical and numerical studies of photo-injected charge transport in these materials are presented here with an attempt to understand how specific features of the various models developed to describe these systems depend on the microscopic parameters that define them. Specifically, previously published time-of-flight mobility data for the molecularly …

Essays On Unit Root Testing In Time Series, Xiao Zhong

Doctoral Dissertations

"Unit root tests are frequently employed by applied time series analysts to determine if the underlying model that generates an empirical process has a component that can be well-described by a random walk. More specifically, when the time series can be modeled using an autoregressive moving average (ARMA) process, such tests aim to determine if the autoregressive (AR) polynomial has one or more unit roots. The effect of economic shocks do not diminish with time when there is one or more unit roots in the AR polynomial, whereas the contribution of shocks decay geometrically when all the roots are outside …

Long-Term Litter Decomposition Controlled By Manganese Redox Cycling, Marco Keiluweit, Peter Nico, Mark E. Harmon, Jingdong Mao, Jennifer Pett-Ridge, Markus Kleber

Chemistry & Biochemistry Faculty Publications

Litter decomposition is a keystone ecosystem process impacting nutrient cycling and productivity, soil properties, and the terrestrial carbon (C) balance, but the factors regulating decomposition rate are still poorly understood. Traditional models assume that the rate is controlled by litter quality, relying on parameters such as lignin content as predictors. However, a strong correlation has been observed between the manganese (Mn) content of litter and decomposition rates across a variety of forest ecosystems. Here, we show that long-term litter decomposition in forest ecosystems is tightly coupled to Mn redox cycling. Over 7 years of litter decomposition, microbial transformation of litter …

On Testing Common Indices For Several Multi-Index Models: A Link-Free Approach, Xuejing Liu

Doctoral Dissertations

"To avoid the curse of dimensionality, and to help us better understand the structure of the high dimensional data, methods for dimension reduction are clearly called for. The common linear dimension reduction techniques for single population include principal component analysis (PCA) which is unsupervised in regression and supervised Partial Least Squares (PLS). Modern sufficient dimension reduction techniques, like the ones we consider, constitute a form of supervised linear dimension reduction which outperform PCA and PLS without the underlying model assumptions.

In practice, we often deal with situations where the same variables are being measured on objects from different groups, and …

Occurrence, Monitoring And Removal Of Drinking Water Contaminants By Advanced Technologies, Danielle Marie West

Doctoral Dissertations

"In order to maintain drinking water primary standards compliance under the USEPA Stage 2 Disinfectant Disinfection Byproducts Rule, drinking water treatment plants (DWTPs) are switching from free chlorine (FC) to chloramines (MCA). Concerns are raised as MCA disinfection has been linked N-nitrosamine formation. N-nitrosamines are a group of nitrogenous DBPs (N-DBPs) which are highly carcinogenic in comparison to regulated DBPs (THMs and HAAs, generated by FC disinfection). Also in the forefront of drinking water concerns are other emerging drinking water contaminants such as perchlorate. Perchlorate is a contaminant which can enter drinking water from natural deposits or through introduction by …

Nano-Structured Materials For Energy Storage Applications, Dongxue Zhao

Doctoral Dissertations

"Hydrogen is a non-polluting and efficient energy carrier. One barrier to utilizing hydrogen is a reliable storage method. NaAlH₄ is the prototypical example of a complex metal hydride with high hydrogen storage capacities (~ 5.5 wt.%) and acceptable reaction temperatures of around 100⁰ when using catalyst. On decomposition of these complex hydrides, such as NaAlH₄, one is left with monohydride NaH. The kinetics of diffusion in the monohydrides is important because reversibility hinges on mass transport and the formation of [AlH₄]^- anions that must structurally coordinate with the alkali metal cation on hydrogen absorption. …

Discrete Analogues Of Some Classical Special Functions, Thomas Joseph Cuchta

Doctoral Dissertations

"Analogues of special functions on time scales are studied with special focus on the time scale 𝕋 = hℤ. Functions investigated in particular include complex monomials, new trigonometric functions, Gaussian bell, Hermite and Laguerre polynomials, Bessel functions, and hypergeometric series"--Abstract, page iii.

Small Sample Saddlepoint Confidence Intervals In Epidemiology, Pasan Manuranga Edirisinghe

Doctoral Dissertations

"In section 1, we develop a novel method of confidence interval construction for directly standardized rates. These intervals involve saddlepoint approximations to the intractable distribution of a weighted sum of Poisson random variables and the determination of hypothetical Poisson mean values for each of the age groups. Simulation studies show that, in terms of coverage probability and length, the saddlepoint confidence interval (SP) outperforms four competing confidence intervals obtained from the moment matching (M8), gamma-based (G1,G4) and ABC bootstrap (ABC) methods.

In section 2, we first consider Brillinger's classical model for a vital rate estimate with a random denominator. We …

Characterization Of Terrestrial Dissolved Organic Matter Fractionated By Ph And Polarity And Their Biological Effects On Plant Growth, Rachel L. Sleighter, Paolo Caricasole, Kristen M. Richards, Terry Hanson, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Background: Humic substances are ubiquitous in the environment, complex mixtures, and known to be beneficial to plant growth. To better understand and identify components responsible for plant growth stimulation, a terrestrial aquatic DOM sample was fractionated according to pH and polarity, obtaining acid-soluble and acid-insoluble portions, as well as acid-soluble hydrophobic and hydrophilic fractions using C18. The various fractions were characterized then evaluated for their biological effects on plant growth using bioassays with corn at two carbon rates.

Results: Approximately 43% and 57% of the carbon, and 31% and 69% of the iron, was found in the acid-insoluble and acid-soluble …

Small Sample Umpu Equivalence Testing Based On Saddlepoint Approximations, Renren Zhao

Doctoral Dissertations

"In the first section, we consider small sample equivalence tests for exponentiality. Statistical inference in this setting is particularly challenging since equivalence testing procedures typically require a much larger sample size, in comparison to classical "difference tests", to perform well. We make use of Butler's marginal likelihood for the shape parameter of a gamma distribution in our development of equivalence tests for exponentiality. We consider two procedures using the principle of confidence interval inclusion, four Bayesian methods, and the uniformly most powerful unbiased (UMPU) test where a saddlepoint approximation to the intractable distribution of a canonical sufficient statistic is used. …

Quantum Inspired Algorithms For Learning And Control Of Stochastic Systems, Karthikeyan Rajagopal

Doctoral Dissertations

"Motivated by the limitations of the current reinforcement learning and optimal control techniques, this dissertation proposes quantum theory inspired algorithms for learning and control of both single-agent and multi-agent stochastic systems.

A common problem encountered in traditional reinforcement learning techniques is the exploration-exploitation trade-off. To address the above issue an action selection procedure inspired by a quantum search algorithm called Grover's iteration is developed. This procedure does not require an explicit design parameter to specify the relative frequency of explorative/exploitative actions.

The second part of this dissertation extends the powerful adaptive critic design methodology to solve finite horizon stochastic optimal …

Efficient Cryptographic Primitives: Secure Comparison, Binary Decomposition And Proxy Re-Encryption, Feng Li

Doctoral Dissertations

”Data outsourcing becomes an essential paradigm for an organization to reduce operation costs on supporting and managing its IT infrastructure. When sensitive data are outsourced to a remote server, the data generally need to be encrypted before outsourcing. To preserve the confidentiality of the data, any computations performed by the server should only be on the encrypted data. In other words, the encrypted data should not be decrypted during any stage of the computation. This kind of task is commonly termed as query processing over encrypted data (QPED).

One natural solution to solve the QPED problem is to utilize fully …

Transverse Momentum Dependent (Tmd) Parton Distribution Functions: Status And Prospects, R. Angeles-Martinez, A. Bacchetta, I. I. Balitsky, D. Boer, M. Boglione, R. Boussarie, F. A. Ceccopieri, I. O. Cherednikov, P. Connor, M. G. Echevarria, G. Ferrera, J. Grados Luyando, F. Hautmann, H. Jung, T. Kasemets, K. Kutak, J. P. Lansberg, A. Lelek, G. Lykasov, J. D. Madrigal Martinez, P. J. Mulders, E. R. Nocera, E. Petreska, C. Pisano, R. Plaċakyte, V. Radescu, M. Radici, G. Schnell, I. Scimemi, A. Signori, L. Szymanowski, S. Taheri Monfared, F.F. Van Der Veken, H. J. Van Haevermaet, P. Van Mechelen, A. A. Vladimirov, S. Wallon

Physics Faculty Publications

We review transverse momentum dependent (TMD) parton distribution functions, their application to topical issues in high-energy physics phenomenology, and their theoretical connections with QCD resummation, evolution and factorization theorems. We illustrate the use of TMDs via examples of multi-scale problems in hadronic collisions. These include transverse momentum q_T spectra of Higgs and vector bosons for low q_T, and azimuthal correlations in the production of multiple jets associated with heavy bosons at large jet masses. We discuss computational tools for TMDs, and present the application of a new tool, TMD_LIB, to parton density fits and parameterizations.

Development Of Srf Cavity Tuners For Cern, K. Artoos, R. Calaga, O. Capatina, T. Capelli, F. Carra, L. Dassa, N. Kuder, R. Leuxe, P. Minginette, W. Venturini Delsolaro, G. Villiger, C. Zanoni, P. Zhang, S. Verdu-Andrés, B. Xiao, G. Burt, J. Delayen, Hyekyoung Park, T. Jones, N. Templeton

Physics Faculty Publications

Superconducting RF cavity developments are currently on-going for new accelerator projects at CERN such as HIE ISOLDE and HL-LHC. Mechanical RF tuning systems are required to compensate cavity frequency shifts of the cavities due to temperature, mechanical, pressure and RF effects on the cavity geometry. A rich history and experience is available for such mechanical tuners developed for existing RF cavities. Design constraints in the context of HIE ISOLDE and HL-LHC such as required resolution, space limitation, reliability and maintainability have led to new concepts in the tuning mechanisms. This paper will discuss such new approaches, their performances and planned …

Control Of Synchrotron Radiation Effects During Recirculation With Bunch Compression, D. R. Douglas, S. V. Benson, R. Li, Y. Roblin, C. D. Tennant, Geoffrey A. Krafft, Balŝa Terzić, C. -Y. Tsai

Physics Faculty Publications

Studies of beam quality preservation during recirculation * have been extended to generate a design of a compact arc providing bunch compression with positive momentum compaction ** and control of both incoherent and coherent synchrotron radiation (ISR and CSR) effects using the optics balance methods of diMitri et al.***. In addition, the arc/compressor generates very little micro-bunching gain. We detail the beam dynamical basis for the design, discuss the design process, give an example solution, and provide simulations of ISR and CSR effects. Reference will be made to a complete analysis of micro-bunching effects ****.

Anisotropy Reversal Of The Upper Critical Field At Low Temperatures And Spin-Locked Superconductivity In K₂Cr₃As₃, F. F. Balakirev, T. Kong, M. Jaime, R. D. Mcdonald, C. H. Mielke, A. Gurevich, P. C. Canfield, S. L. Bud'ko

Physics Faculty Publications

We report measurements of the anisotropic upper critical field H_c2(T) for K₂Cr₃As₃ single crystals up to 60 T and T > 0.6K. Our results show that the upper critical field parallel to the Cr chains, H^∥_c2(T), exhibits a paramagnetically limited behavior, whereas the shape of the H^⊥_c2(T) curve (perpendicular to the Cr chains) has no evidence of paramagnetic effects. As a result, the curves H^⊥_c2(T) and H^∥_c2(T) cross at T ≈ 4K, so that the anisotropy parameter _H(T)=H …

Current-Induced Depairing In The Bi₂Te₃/Fete Interfacial Superconductor, M. N. Kunchur, C. L. Dean, N. Shayesteh Moghadam, J. M. Knight, Q. L. He, H. Liu, J. Wang, R. Lortz, I. K. Sou, Alex Gurevich

Physics Faculty Publications

We investigated current induced depairing in the Bi₂Te₃/FeTe topological insulator-chalcogenide interface superconductor. The measured depairing current density provides information on the magnetic penetration depth and superfluid density, which in turn shed light on the nature of the normal state that underlies the interfacial superconductivity.

Virtuality Distributions And Pion Transition Form Factor, A. V. Radyushkin

Physics Faculty Publications

Using the example of hard exclusive transition process ᵞ*ᵞ → π⁰ at the handbag level, we outline basics of a new approach to transverse momentum dependence in hard processes. In coordinate representation, matrix elements of operators (in the simplest case, bilocal 𝒪(0, z)) describing a hadron with momentum p, are functions of (pz) and z² parametrized through virtuality distribution amplitudes (VDA) Φ(x, σ), with x being Fourier-conjugate to (pz) and σ Laplace-conjugate to z2. For intervals with z⁺ = 0, we introduce the transverse momentum distribution amplitude (TMDA) Ψ(x, k_⊥), and write it in terms of VDA …