Physical Sciences and Mathematics Commons^™

Attosecond Transient Absorption In Gases And High Harmonic Generation In Solids, Mengxi Wu

LSU Doctoral Dissertations

We present a theoretical study of attosecond transient absorption in gases and high harmonic generation in solids. In this thesis, different features in the attosecond transient absorption laser-dressed spectrum are studied, including features near bright (dipole allowed) atomic states and features that appear approximately one or two laser photons away from the bright states due to the laser-induced coupling to dark (non-dipole allowed) states. The calculations are carried out using both numerical and analytic solutions to the time-dependent Schr\"odinger equation (TDSE). From these solutions, several models of time-dependent absorption and electron dynamics at the femtosecond time scale are presented. We …

Single Molecule Electrophoresis And Optical Detection Using Thermoplastic Nanofluidic Devices: An Experimental And Simulation Study, Kumuditha Madushanka Weerakoon Ratnayake

LSU Doctoral Dissertations

Nanofludic devices provide a great platform for single molecular analysis. The unique phenomena in nanoscale gained such interest in investigating the single molecular behavior in nanochannels. Sizes less than 200 nm in one or two-dimensional structures have lead to fascinating observations not accessible in microscale. When a single molecule translocates through a nanotube it interacts with channel walls by adsorption/ desorption, van der Waals interactions and hydrophilic interactions providing a mechanism for separation without any extra additives. Moreover, double layer thickness governed by the background electrolyte plays a vital role. We report single molecular electrophoresis phenomena in nanochannels and nanoslits …

Interpretation Of Geochemical Signatures From Modern Carbonate Springs To The Rock Record, Benjamin Maas

LSU Doctoral Dissertations

Despite the importance of carbonate aquifers as reservoirs of oil, of water, and of carbon dioxide, questions remain about the diagenetic processes that enhance porosity and permeability. Some of the questions are: 1) what are the water-rock interactions that control the geochemistry of spring waters; 2) are the geochemical signatures of saline-fresh water mixing zones preserved in the carbonate rock record; and 3) how much carbon dioxide outgases along spring runs? To address these questions, two field sites, one in Oklahoma (the site of an active saline-fresh water mixing zone) and the other in Colorado, the location of a former …

Detection And Recognition Of R/F Devices Based On Their Unintended Electromagnetic Emissions Using Stochastic And Computational Intelligence Methods, Shikhar Prasad Acharya

Doctoral Dissertations

"Radio Frequency (RF) devices produce some amount of Unintended Electromagnetic Emissions (UEEs). UEEs are generally unique to a device and can be thought of as a signature of the device. This property of uniqueness of UEEs can be used to detect and identify the device producing the emission. The problem with UEEs is that they are very low in power and are often buried deep inside the noise band which makes them difficult to detect. There are two types of UEE detection methods. The first one is called stimulated detection method where the UEEs of a device are enhanced using …

Mineral And Geochemical Attributes Of The Midcontinent Rift Sequence; An Application For Deep Carbon Dioxide Sequestration, Alsedik Mohamed Ali Abousif

Doctoral Dissertations

"The potential for using the Oronto Group of the Midcontinent Rift (MCR) Sequence for CO₂ sequestration has been disparaged because of low porosity-permeability characteristics, which are largely a result of extensive calcite cementation. This study investigated the potential for using the MCR as a target for CO₂ sequestration by examining reactions involving detrital host-rock minerals at high pressure-temperature conditions that could provide dissolved Ca²⁺, Mg²⁺, and Fe²⁺, and then precipitating these cations as carbonate minerals. The effect of carbonic acid on cement dissolution was also evaluated with respect to enhancing porosity and …

Shear Wave Splitting Analysis Beneath Tien Shan: Geodynamic Implications Of Complex Anisotropy, Solomon Gerra Cherie

Doctoral Dissertations

"In spite of numerous studies, the mechanisms for the crustal shortening, mountain formation and associated tectonism leading to complex or simply seismic anisotropy formation beneath the Tien Shan Orogenic Belt is still debated. The most popular hypotheses suggested for the existence of seismic anisotropy are small-scale mantle convection, regional scale resistive basal shear and APM induced asthenospheric flow. Here, we used shear-wave splitting (SWS) measurements with good azimuthal coverage to provide additional constraints on the various models proposed by previous studies. One of the most effective approaches utilized to constrain convective mantle flow patterns is the splitting of P-to-S converted …

Vrcc-3d+: Qualitative Spatial And Temporal Reasoning In 3 Dimensions, Nathan Eloe

Doctoral Dissertations

"Qualitative Spatial Reasoning (QSR) has varying applications in Geographic Information Systems (GIS), visual programming language semantics, and digital image analysis. Systems for spatial reasoning over a set of objects have evolved in both expressive power and complexity, but implementations or usages of these systems are not common. This is partially due to the computational complexity of the operations required by the reasoner to make informed decisions about its surroundings. These theoretical systems are designed to focus on certain criteria, including efficiency of computation, ease of human comprehension, and expressive power. Sadly, the implementation of these systems is frequently left as …

Origin And Stratigraphic Architecture Of The Middle Permian Lower And Upper Quanzijie Low-Order Cycles, Bogda Mountains, Nw China, Jonathan Obrist-Farner

Doctoral Dissertations

"This study is carried out in the Bogda Mountains, NW China, and aims to provide a detailed sedimentary, stratigraphic, environmental, and paleoclimatic reconstruction in the paleo-mid-latitude along the east coast of Pangea. The Middle Permian lower and upper Quanzijie low-order cycles (QZJ LCs) provide a nearly complete sedimentary record in an area were little is known. In the first part of this work, the previously-established QZJ LC is divided into two LCs on the basis of regional stratigraphic correlation and major changes in depositional environments and tectonic and climatic processes. The newly-established lower QZJ LC is mainly composed of meandering …

Enabling Near-Term Prediction Of Status For Intelligent Transportation Systems: Management Techniques For Data On Mobile Objects, Lasanthi Nilmini Heendaliya

Doctoral Dissertations

"Location Dependent Queries (LDQs) benefit from the rapid advances in communication and Global Positioning System (GPS) technologies to track moving objects' locations, and improve the quality-of-life by providing location relevant services and information to end users. The enormity of the underlying data maintained by LDQ applications - a large quantity of mobile objects and their frequent mobility - is, however, a major obstacle in providing effective and efficient services. Motivated by this obstacle, this thesis sets out in the quest to find improved methods to efficiently index, access, retrieve, and update volatile LDQ related mobile object data and information. …

Constitutive Activity In Orphan G Protein Coupled Receptors, Adam Lee Martin

Doctoral Dissertations

"The goal of this research was to use a distal signaling pathway analysis to evaluate the extent of agonist independent constitutive signaling among orphan class-A G protein coupled receptors (GPCRs). These receptors translate extracellular signals via conformational change into intracellular activation of different G proteins and subsequent second messenger synthesis. These small molecules regulate cellular biochemistry, eventually leading to nuclear signaling that results in changes in gene expression. Some GPCRs are capable of signaling in the absence of an activating ligand, a phenomenon called constitutive activity that is inhibited via an "inverse-agonist". The use of cAMP dependent Luciferase expression is …

Synthesis, Characterization And Application Of Acrylic Colloidal Unimolecular Polymer (Cup), Ameya Manohar Natu

Doctoral Dissertations

"Colloidal Unimolecular Polymer (CUP) particles were prepared by the process of water reduction on amphiphilic acrylic copolymers prepared via free radical polymerization technique. The formation of CUP particles was driven by the polymer-polymer interaction being greater than the polymer-solvent interaction and entropically favored by release of the water. It was demonstrated by Dynamic Light Scattering technique that CUP particles based on copolymers below 13,000 MW were unstable and the particles aggregated to a higher particle size. For the polymers with molecular weight (MW) above 13,000, a good correlation between the theoretical and experimental CUP particle size was observed. The rheology …

Volterra Difference Equations, Nasrin Sultana

Doctoral Dissertations

"This dissertation consists of five papers in which discrete Volterra equations of different types and orders are studied and results regarding the behavior of their solutions are established. The first paper presents some fundamental results about subexponential sequences. It also illustrates the subexponential solutions of scalar linear Volterra sum-difference equations are asymptotically stable. The exact value of the rate of convergence of asymptotically stable solutions is found by determining the asymptotic behavior of the transient renewal equations. The study of subexponential solutions is also continued in the second and third articles. The second paper investigates the same equation using the …

Computational Intelligence Based Complex Adaptive System-Of-Systems Architecture Evolution Strategy, Siddharth Agarwal

Doctoral Dissertations

The dynamic planning for a system-of-systems (SoS) is a challenging endeavor. Large scale organizations and operations constantly face challenges to incorporate new systems and upgrade existing systems over a period of time under threats, constrained budget and uncertainty. It is therefore necessary for the program managers to be able to look at the future scenarios and critically assess the impact of technology and stakeholder changes. Managers and engineers are always looking for options that signify affordable acquisition selections and lessen the cycle time for early acquisition and new technology addition. This research helps in analyzing sequential decisions in an evolving …

Computing And The Electrical Transport Properties Of Coupled Quantum Networks, Casey Andrew Cain

Doctoral Dissertations

In this dissertation a number of investigations were conducted on ballistic quantum networks in the mesoscopic range. In this regime, the wave nature of electron transport under the influence of transverse magnetic fields leads to interesting applications for digital logic and computing circuits. The work specifically looks at characterizing a few main areas that would be of interest to experimentalists who are working in nanostructure devices, and is organized as a series of papers. The first paper analyzes scaling relations and normal mode charge distributions for such circuits in both isolated and open (terminals attached) form. The second paper compares …

Performance Analysis And Modelling Of Hybrid Photovoltaic-Thermal Solar Panels, Nicole C. Annis

Doctoral Dissertations

A photovoltaic-thermal (PVT) panel was constructed, tested, and modelled using both MATLAB and TRNSYS. During the experimental testing, which took place on the Missouri University of Science and Technology campus in Rolla, Missouri; two identical PVT panels were tested alongside two PV panels to gather an electrical baseline for comparison. Approximately 69 days’ worth of data were of data were collected during the summer of 2014. The PV electrical, PVT electrical, PVT thermal and PVT combined (electrical and thermal) efficiencies were 3.5-5.6%, 3.4-5.4%, 20.9-11.6%, and 24.3-17.0%, respectively.

A MATLAB program was developed using existing equations for one-dimensional, quasi-steady model of …

Accuracy Of Theory For Calculating Electron Impact Ionization Of Molecules, Hari Chaluvadi

Doctoral Dissertations

The study of electron impact single ionization of atoms and molecules has provided valuable information about fundamental collisions. The most detailed information is obtained from triple differential cross sections (TDCS) in which the energy and momentum of all three final state particles are determined. These cross sections are much more difficult for theory since the detailed kinematics of the experiment become important. There are many theoretical approximations for ionization of molecules. One of the successful methods is the molecular 3-body distorted wave (M3DW) approximation. One of the strengths of the DW approximation is that it can be applied for any …

Investigation Of Robust Optimization And Evidence Theory With Stochastic Expansions For Aerospace Applications Under Mixed Uncertainty, Harsheel R. Shah

Doctoral Dissertations

One of the primary objectives of this research is to develop a method to model and propagate mixed (aleatory and epistemic) uncertainty in aerospace simulations using DSTE. In order to avoid excessive computational cost associated with large scale applications and the evaluation of Dempster Shafer structures, stochastic expansions are implemented for efficient UQ. The mixed UQ with DSTE approach was demonstrated on an analytical example and high fidelity computational fluid dynamics (CFD) study of transonic flow over a RAE 2822 airfoil.

Another objective is to devise a DSTE based performance assessment framework through the use of quantification of margins and …

Seismological Investigation Of The Okavango Rift, Botswana, Youqiang Yu

Doctoral Dissertations

The mechanisms of rifting have been intensively investigated using geological and geophysical techniques beneath mature rift zones. However, current understanding on the earliest stages of rifting is seriously limited. Here we employ recently archived data from 17 broadband seismic stations traversing northern Botswana to conduct the first shear wave splitting and mantle transition zone (MTZ) studies within the Okavango Rift Zone (ORZ). The ORZ is an incipient continental rift situated at the terminal of the southwestern branch of the East African Rift System. The resulting normal MTZ thickness and consistently rift-parallel fast polarizations imply an absence of significant thermal anomalies …

Pulsed Inductive Plasma Studies By Spectroscopy And Internal Probe Methods, Warner C. Meeks

Doctoral Dissertations

The broad effort of the Missouri Plasmoid Experiment is to elucidate the energy conversion processes in a pulsed inductive discharge due to the presence of plasma. The test article is a 440 to 490 kHz theta-pinch (or solenoidal) geometry coil with a stored energy of around 80 joules. In this work experimental hydrogen, helium, argon and xenon data at back-fill pressures of 10 to 100 mTorr (1.3 to 133.3 Pa) are obtained and interpreted. Spectral and internal probe studies were performed on MPX Mk.I and Mk.II devices, respectively. IR spectra were acquired in the Mk.I device for argon and xenon. …

Process Design, Dynamics, And Techno-Economic Analysis Of A Sustainable Coal, Wind, And Small Modular Nuclear Reactor Hybrid Energy System, Kyle Lee Buchheit

Doctoral Dissertations

"The availability of cheap electricity is one of the biggest factors for improving quality of life. With the debate on the effects of carbon dioxide emissions continuing, several countries have either implemented or are considering the reduction of emissions through various economic means. The inclusion of a monetary penalty on carbon emissions would increase the prices of electricity produced by carbon-based sources. The push for large-scale renewable sources of energy has met problems with regards to energy storage and availability. The proposed coal, wind, and nuclear hybrid energy system would combine a renewable energy source, wind, with traditional and stable …

Privacy-Preserving Query Processing Over Encrypted Data In Cloud, Yousef M. Elmehdwi

Doctoral Dissertations

"The query processing of relational data has been studied extensively throughout the past decade. A number of theoretical and practical solutions to query processing have been proposed under various scenarios. With the recent popularity of cloud computing, data owners now have the opportunity to outsource not only their data but also data processing functionalities to the cloud. Because of data security and personal privacy concerns, sensitive data (e.g., medical records) should be encrypted before being outsourced to a cloud, and the cloud should perform query processing tasks on the encrypted data only. These tasks are termed as Privacy-Preserving Query Processing …

Synthesis And Characterization Of Vanadium Oxide Nanomaterials, Tyler M. Fears

Doctoral Dissertations

"This dissertation focuses on the synthesis and characterization of vanadium oxide nanomaterials and neutron-transparent Li-ion battery electrolytes.

Vanadium oxide gels were synthesized via the epoxide-assisted gelation of VOCl₃ using epichlorohydrin in ethanol. This represents the first epoxide-assisted gelation developed for vanadium oxide gels and serves as a potential economical replacement for the fabrication of vanadium oxide gels via the hydrolysis of vanadium alkoxides. Though epoxide-assisted gelation has been demonstrated for a number of transition metal oxides, the gelation mechanism observed here for VOCl₃ appears to be unique.

While investigating the electrochemical and structural properties of lithium vanadates, it …

Quantification Of Information Flow In Cyber Physical Systems, Li Feng

Doctoral Dissertations

"In Cyber Physical Systems (CPSs), traditional security mechanisms such as cryptography and access control are not enough to ensure the security of the system since complex interactions between the cyber portion and physical portion happen frequently. In particular, the physical infrastructure is inherently observable; aggregated physical observations can lead to unintended cyber information leakage. Information flow analysis, which aims to control the way information flows among different entities, is better suited for CPSs than the access control security mechanism. However, quantifying information leakage in CPSs can be challenging due to the flow of implicit information between the cyber portion, the …

Methods And Algorithms For Service Selection And Recommendation (Preference And Aggregation Based), Kenneth Kofi Fletcher

Doctoral Dissertations

"In order for service users to get the best service that meets their requirements, they prefer to personalize their non-functional attributes, such as reliability and price. However, the personalization makes it challenging because service providers have to deal with conflicting non-functional attributes when selecting services for users. In addition, users may sometimes want to explicitly specify their trade-offs among non-functional attributes to make their preferences known to service providers. Typically, users' service search requests with conflicting non-functional attributes may result in a ranked list of services that partially meet their needs. When this happens, it is natural for users to …

Mechanical Characteristics Of Organically Modified Fly Ash-Kaolinite Mixtures, Xin Kang

Doctoral Dissertations

"Fly ash is a hazardous waste material to the environment. Beneficial reuse of fly ash, however, brings economic and environmental benefits, i.e., decreases the cost of disposal, reduces greenhouse gas emission, and improves mechanical properties of construction materials. Due to the lack of pozzolanic properties, the reuse rate of Class F fly ash in geotechnical engineering is relatively low (ACAA 2013). In order to promote the effectiveness and sustainability of high volume reuse of class F fly ash in geotechnical engineering, biopolymers (Chitosan, and Xanthan gum) and synthetic polymers (Polyethylene Oxide, PEO) were used instead of the traditional stabilizers to …

Effects Of N-Acetylcysteine Amide In Preventing/Treating Cataracts, Sri Krishna Yasaswi Maddirala

Doctoral Dissertations

"Cataract, the opacification of an eye lens, is a common pathological abnormality of the lens accounting for approximately 50% of all blindness. The only effective treatment currently available for a cataract is the surgical removal of the affected lens and replacement with an artificial lens for the restoration of vision. Although, cataract surgery is considered to be a very successful procedure in terms of visual outcome, the cost of surgery, need for trained personnel and surgeons, and postsurgical complications, limit the worldwide availability and accessibility of this procedure. Hence, alternative preventive and treatment procedures are worthy of investigation. The lens …

Holocene Sedimentology And Stratigraphy Of Coastal Sediments In An Arid Climate, Al Qahmah, Southern Red Sea, Saudi Arabia, Abdullah Ibrahim Nabhan

Doctoral Dissertations

"Holocene sedimentary deposits in Al Qahmah coast, southern Red Sea, in Saudi Arabia have been accumulated on an arid siliciclastic coast in a rift tectonic setting. This study provides a detail interpretation and analysis of sedimentary facies, stratigraphy, depositional environment, and major geological processes. Two studies have been undertaken. First, petrological study of composition and texture of modern sediments and facies mapping delineate facies distribution and mechanisms of sediment transport and deposition. A unique suite of complex riverine, wave, tidal, wind, and chemical and biological processes affect the composition, texture, and distribution of the facies. Second, the depositional environments of …

The Synthesis And Characterization Of Water-Reducible Nanoscale Colloidal Unimolecular Polymer (Cup) Particles, Cynthia J. Riddles

Doctoral Dissertations

"The coatings industry has adapted to more stringent guidelines in paint formulations. Current VOC (volatile organic compound) limits placed by the federal government have pushed the industry toward the development of paint formulations which have very little to no VOC's. The development of Colloidal Unimolecular Polymer (CUP) particles is a step in the direction of providing a resin system which exists in zero VOC aqueous dispersion.

The CUP particles are a part of the polymer field of Single Chain Nano Particles (SCNP) and ranged in diameters of 3-9 nm. The research presented in this dissertation describes the synthesis and design …

Distributed State Verification In The Smart Grid Using Physical Attestation, Thomas Patrick Roth

Doctoral Dissertations

"A cyber process in a distributed system can fabricate its internal state in its communications with its peers. These state fabrications can cause other processes in the distributed system to make incorrect control decisions. Cyber-physical systems have a unique advantage in the detection of falsified states because processes typically have observable effects on a shared physical infrastructure. This physical infrastructure acts as a high-integrity message channel that broadcasts changes in individual process states. The objective of this research is to demonstrate that there are cases where physical feedback from the shared infrastructure can be used to detect state fabrications. To …

Analytical And Numerical Studies Of Photo-Injected Charge Transport In Molecularly-Doped Polymers, Amrita Roy Chowdhury

Doctoral Dissertations

"The mobility of photo-injected charge carriers in molecularly-doped polymers (MDPs) exhibits a commonly observed, and nearly universal Poole-Frenkel field dependence, µ ~ exp [square root (ß₀E)], that has been shown to arise from the correlated Gaussian energy distribution of transport sites encountered by charges undergoing hopping transport through the material. Analytical and numerical studies of photo-injected charge transport in these materials are presented here with an attempt to understand how specific features of the various models developed to describe these systems depend on the microscopic parameters that define them. Specifically, previously published time-of-flight mobility data for the molecularly …