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Articles 661 - 690 of 9578
Full-Text Articles in Physical Sciences and Mathematics
Modified Polysulfone Nanofiltration Membrane Synthesis For Hydraulic Fracturing Water Recycle, Blake Alexander Johnson
Modified Polysulfone Nanofiltration Membrane Synthesis For Hydraulic Fracturing Water Recycle, Blake Alexander Johnson
Graduate Theses and Dissertations
The use of hydraulic fracturing has resulted in significant increases in the yield of oil and natural gas, as water pumped into wells at high pressure cracks the formations and releases the hydrocarbons that are locked in the rocks. This process has created large volumes of brackish water that is very difficult to process and is often disposed of into injection wells. Suspended solids and some dissolved solids are more readily removed, but the multivalent ions found in certain salts can precipitate in a well and complicate the reuse of flowback in future hydraulic fracturing operations.
Nanofiltration, a membrane separation …
Evaluation Of Conservation Practices Through Simulation Modeling And Tool Development, Gurdeep Singh
Evaluation Of Conservation Practices Through Simulation Modeling And Tool Development, Gurdeep Singh
Graduate Theses and Dissertations
For the first objective, predicted impacts of selected Mississippi River Basin Initiative (MRBI) conservation practices (CPs) on sediment and nutrient loss were assessed. The study area was L’Anguille River Watershed (LRW), a priority focus watershed of the MRBI program and the simulated CPs were filter strip, critical area planting, grade stabilization structure, irrigation land leveling, irrigation pipeline, irrigation water management, and nutrient management. The Soil and Water Assessment Tool (SWAT) model was calibrated (1998 – 2005) and validated (2006 – 2012) for flow, sediment, total phosphorus (TP), and nitrate-nitrogen (NO3-N) at the Colt site (503 sq. km. drainage area) and …
Photochemistry Of A Series Of Weakly Coupled Dinuclear Ruthenium(Ii) Complexes, Latisha Michelle Puckett
Photochemistry Of A Series Of Weakly Coupled Dinuclear Ruthenium(Ii) Complexes, Latisha Michelle Puckett
Graduate Theses and Dissertations
An improved synthetic method was developed for symmetric ruthenium(II) polypyridine complexes with the form L2Ru(diphen)RuL2. The scope of the reaction was investigated in regards to the ligands, bridging ligands, and starting materials. Several ligands were successful in the synthesis, including 2,2’-bipyridine (bpy), 4,4’-dimethyl-2,2’-dipyridyl (dmb), 1,10-phenanthroline (phen), 4,7-diphenyl-1,10-phenanthroline (dpphen), and 3,4,7,8-tetramethyl-1,10-phenanthroline (tmphen). Ligands that did not react to form symmetric dimeric complexes were 2,2’-bipyrazine, bpz, and 2,2’-bipyrimidine, bpm.
Dpp, 2,3-bis(2-pyridyl)-pyrazine, effectively replaced diphen as the bridging ligand to produce (phen)2Ru(dpp)Ru(phen)24+. However, replacing the [Ru(CO)2Cl2]n with Ru(DMSO)4Cl2 did not prove successful. The newly developed synthesis was also applied to the synthesis of …
Defining The Potassium Nutritional Requirements And Distribution Among Plant Parts Of Representative Soybean Cultivars From Different Maturity Groups, Md. Rasel Parvej
Defining The Potassium Nutritional Requirements And Distribution Among Plant Parts Of Representative Soybean Cultivars From Different Maturity Groups, Md. Rasel Parvej
Graduate Theses and Dissertations
The potassium (K) requirement of soybean [Glycine max (L.) Merr.] was investigated to determine whether cultivar sensitivity to K deficiency was affected by growth habit (determinate or indeterminate) and how cultivars from each growth habit accumulate and distribute K among plant structures. We also diagnosed K deficiency across reproductive growth stages (R2-6) using trifoliolate leaf- and petiole-K concentrations and at harvest (R8) using seed-K concentration. Soybean responded similarly to K deficiency in terms of yield, selected yield components, and seed-K concentration, regardless of growth habit. The yield loss from K deficiency was greatest on the middle to upper nodes of …
Influence Of Shelling Temperature And Time On The Optical And Structural Properties Of Cuins2/Zns Quantum Dots, Colette Robinson
Influence Of Shelling Temperature And Time On The Optical And Structural Properties Of Cuins2/Zns Quantum Dots, Colette Robinson
Graduate Theses and Dissertations
CIS/ZnS core/shell QDs are an important class of nanomaterials for optoelectronic, photovoltaic and photoluminescence applications. They consist of lower toxicity materials than the prototypical II-VI Cd-based QDs and show long fluorescence lifetimes, which generates prospective in biological imaging applications. It is vital to develop reproducible synthetic methods for this new class of nanomaterials in order to maintain small sizes with high QYs. CIS core QDs have been shelled with ZnS at various temperatures from 90-210°C for reaction times ranging from 20-140 minutes to examine the role of thermodynamics and kinetics on the shell growth. Using HR-TEM and ICP-MS, it was …
Calorimetry And Body Composition Research In Broilers And Broiler Breeders, Justina Victoria Caldas Cueva
Calorimetry And Body Composition Research In Broilers And Broiler Breeders, Justina Victoria Caldas Cueva
Graduate Theses and Dissertations
Indirect calorimetry to study heat production (HP) and dual energy X-ray absorptiometry (DEXA) for body composition (BC) are powerful techniques to study the dynamics of energy and protein utilization in poultry. The first two chapters present the BC (dry matter, lean, protein, and fat, bone mineral, calcium and phosphorus) of modern broilers from 1 – 60 d of age analyzed by chemical analysis and DEXA. DEXA has been validated for precision, standardized for position, and equations and validations developed for chickens under two different feeding levels. These equations are unique to the machine and software in use. Research in broilers …
Swat Model Simulation Of Bioenergy Crop Impacts On Water Quality In Cache River Watershed, Eeshan Kumar
Swat Model Simulation Of Bioenergy Crop Impacts On Water Quality In Cache River Watershed, Eeshan Kumar
Graduate Theses and Dissertations
Energy security through increased biofuel production is one of the components of the Energy Independence and Security Act (EISA) 2007. As per EISA 2007 mandate, appropriate independent research institutes are required to assess concerns to natural biodiversity due to biofuel production and report it to the Congress through the Environment Protection Agency (EPA). Planners, researchers, and agencies concerned with environmental regulations, ideally, would like to have location-specific information about the impacts for developing appropriate management interventions. This study examines long-term impacts on water quality in response to targeted (i.e. marginal lands) production of biofuel crops by setting up two SWAT …
The Structural Analysis Of Enola And Greenbrier, Arkansas Earthquake Swarms: Cause And Effect?, Minella Majenu
The Structural Analysis Of Enola And Greenbrier, Arkansas Earthquake Swarms: Cause And Effect?, Minella Majenu
Graduate Theses and Dissertations
Almost 20 years after the remarkable earthquake swarm of 1982, near the town of Enola, Arkansas, with more than 40,000 micro-earthquakes, another event revisited the same North-Central Arkansas region in 2001. Nine years later, in 2010, a huge swarm event shook the northern part of Faulkner County, around the city of Guy. The following year, this seismic swarm event apparently migrated southward towards the city of Greenbrier, with an increase in the number of yearly recorded events. A 13km previously unrecognized, NE trending Guy-Greenbrier basement fault was revealed as a result of these swarm events.
Within the vicinity of the …
Neural Decomposition Of Time-Series Data For Effective Generalization, Luke Godfrey
Neural Decomposition Of Time-Series Data For Effective Generalization, Luke Godfrey
Graduate Theses and Dissertations
We present a neural network technique for the analysis and extrapolation of time-series data called Neural Decomposition (ND). Units with a sinusoidal activation function are used to perform a Fourier-like decomposition of training samples into a sum of sinusoids, augmented by units with nonperiodic activation functions to capture linear trends and other nonperiodic components. We show how careful weight initialization can be combined with regularization to form a simple model that generalizes well. Our method generalizes effectively on the Mackey-Glass series, a dataset of unemployment rates as reported by the U.S. Department of Labor Statistics, a time-series of monthly international …
Hydrology-Biology Response Relationships In The Ozark Highlands, Dustin Thomas Lynch
Hydrology-Biology Response Relationships In The Ozark Highlands, Dustin Thomas Lynch
Graduate Theses and Dissertations
I examined flow-ecology relationships among stream communities in the Ozark Highlands, USA. I sampled fish, crayfish, and benthic macroinvertebrates during two consecutive summers, including a drought year (2012) and a flood year (2013). Biological response variables related to community structure were assessed via two different statistical methods: an Information Theoretic approach relating response variables to a priori selected predictor variables incorporating hydrology, habitat, geomorphology, and water quality, and canonical ordination using forward selection to relate these same response variables to a large assortment of hydrologic metrics. In addition to assessing metrics related to predicted natural flow, flow alteration at gaged …
Flow Experience In Virtual Worlds: Individuals Versus Dyads, Fiona Fui-Hoon Nah, Brenda Eschenbrenner
Flow Experience In Virtual Worlds: Individuals Versus Dyads, Fiona Fui-Hoon Nah, Brenda Eschenbrenner
Research Collection School Of Computing and Information Systems
Flow is a state of mind in which one is deeply absorbed and immersed in an activity to the point where nothing else matters. Although flow can occur in solitary and social contexts, which context fosters greater flow is unclear. Consistent with self-determination theory, dyads working collaboratively achieved higher states of flow than individuals working alone. In other words, dyads achieved higher states of focused concentration and experienced greater temporal dissociation than individuals working alone. Surprisingly and contradictory to previous findings, dyads did not experience greater enjoyment than individuals working alone. We attributed this surprising finding to the hedonic nature …
Understanding Psychophysiological Correlates Of User Experience Using Electroencephalogram (Eeg), Fiona Fui-Hoon Nah, Keng Siau, Randall Minas, Nathan W. Twyman, Nicholas A. Rollins, Wenbo Wang, Xi Wang
Understanding Psychophysiological Correlates Of User Experience Using Electroencephalogram (Eeg), Fiona Fui-Hoon Nah, Keng Siau, Randall Minas, Nathan W. Twyman, Nicholas A. Rollins, Wenbo Wang, Xi Wang
Research Collection School Of Computing and Information Systems
The objective of this research is to understand psychophysiological correlates of user experience using electroencephalogram (EEG). We will conduct an experimental study to assess the psychophysiological differences across three states of user experience – flow, boredom, and anxiety – and compare them with the neutral state as a baseline. EEG measurement provides a plethora of data that can be decomposed using different analytical procedures. We will utilize one type of analysis, timefrequency decomposition, to examine changes in frequency (e.g., alpha/beta/theta band) over time. These frequency bands correlate with different cognitive states. In this study, we will use Event Related Spectral …
A Benchmark And Comparative Study Of Video-Based Face Recognition On Cox Face Database, Zhiwu Huang, S. Shan, R. Wang, H. Zhang, S. Lao, A. Kuerban, X. Chen
A Benchmark And Comparative Study Of Video-Based Face Recognition On Cox Face Database, Zhiwu Huang, S. Shan, R. Wang, H. Zhang, S. Lao, A. Kuerban, X. Chen
Research Collection School Of Computing and Information Systems
Face recognition with still face images has been widely studied, while the research on video-based face recognition is inadequate relatively, especially in terms of benchmark datasets and comparisons. Real-world video-based face recognition applications require techniques for three distinct scenarios: 1) Videoto-Still (V2S); 2) Still-to-Video (S2V); and 3) Video-to-Video (V2V), respectively, taking video or still image as query or target. To the best of our knowledge, few datasets and evaluation protocols have benchmarked for all the three scenarios. In order to facilitate the study of this specific topic, this paper contributes a benchmarking and comparative study based on a newly collected …
Learning Query And Image Similarities With Ranking Canonical Correlation Analysis, Ting Yao, Tao Mei, Chong-Wah Ngo
Learning Query And Image Similarities With Ranking Canonical Correlation Analysis, Ting Yao, Tao Mei, Chong-Wah Ngo
Research Collection School Of Computing and Information Systems
One of the fundamental problems in image search is to learn the ranking functions, i.e., similarity between the query and image. The research on this topic has evolved through two paradigms: feature-based vector model and image ranker learning. The former relies on the image surrounding texts, while the latter learns a ranker based on human labeled query-image pairs. Each of the paradigms has its own limitation. The vector model is sensitive to the quality of text descriptions, and the learning paradigm is difficult to be scaled up as human labeling is always too expensive to obtain. We demonstrate in this …
Coordinated Persuasion With Dynamic Group Formation For Collaborative Elderly Care, Budhitama Subagdja, Ah-Hwee Tan
Coordinated Persuasion With Dynamic Group Formation For Collaborative Elderly Care, Budhitama Subagdja, Ah-Hwee Tan
Research Collection School Of Computing and Information Systems
Ageing in place demands a new paradigm of inhouse caregiving allowing many aspects of daily lives to be tackled by smart appliances and technologies. The important challenges include the effective provision of recommendations by multiple parties of caregiver constituting changes of the user's behavior. In this multiagent environment, interdependencies between agents become major issues to tackle. This paper presents an approach of dynamic group formation for autonomous caregiving agents to collaborate in recommending different aspects of well-being. The approach supports the agents to regulate the timing of their recommendations, prevent conflicting messages, and cooperate to make more effective persuasions. A …
Bl-Mle: Block-Level Message-Locked Encryption For Secure Large File Deduplication, Rongmao Chen, Yi Mu, Guomin Yang, Fuchun Guo
Bl-Mle: Block-Level Message-Locked Encryption For Secure Large File Deduplication, Rongmao Chen, Yi Mu, Guomin Yang, Fuchun Guo
Research Collection School Of Computing and Information Systems
Deduplication is a popular technique widely used to save storage spaces in the cloud. To achieve secure deduplication of encrypted files, Bellare et al. formalized a new cryptographic primitive named message-locked encryption (MLE) in Eurocrypt 2013. Although an MLE scheme can be extended to obtain secure deduplication for large files, it requires a lot of metadata maintained by the end user and the cloud server. In this paper, we propose a new approach to achieve more efficient deduplication for (encrypted) large files. Our approach, named block-level message-locked encryption (BL-MLE), can achieve file-level and block-level deduplication, block key management, and proof …
A Bayesian Recommender Model For User Rating And Review Profiling, Mingming Jiang, Dandan Song, Lejian Liao, Feida Zhu
A Bayesian Recommender Model For User Rating And Review Profiling, Mingming Jiang, Dandan Song, Lejian Liao, Feida Zhu
Research Collection School Of Computing and Information Systems
Intuitively, not only do ratings include abundant information for learning user preferences, but also reviews accompanied by ratings. However, most existing recommender systems take rating scores for granted and discard the wealth of information in accompanying reviews. In this paper, in order to exploit user profiles' information embedded in both ratings and reviews exhaustively, we propose a Bayesian model that links a traditional Collaborative Filtering (CF) technique with a topic model seamlessly. By employing a topic model with the review text and aligning user review topics with "user attitudes" (i.e., abstract rating patterns) over the same distribution, our method achieves …
Progressive Sequence Matching For Adl Plan Recommendation, Shan Gao, Di Wang, Ah-Hwee Tan, Chunyan Miao
Progressive Sequence Matching For Adl Plan Recommendation, Shan Gao, Di Wang, Ah-Hwee Tan, Chunyan Miao
Research Collection School Of Computing and Information Systems
Activities of Daily Living (ADLs) are indicatives of a person’s lifestyle. In particular, daily ADL routines closely relate to a person’s well-being. With the objective of promoting active lifestyles, this paper presents an agent system that provides recommendations of suitable ADL plans (i.e., selected ADL sequences) to individual users based on the more active lifestyles of the others. Specifically, we develop a set of quantitative measures, named wellness scores, spanning the evaluation across the physical, cognitive, emotion, and social aspects based on his or her ADL routines. Then we propose an ADL sequence learning model, named Recommendation ADL ART, or …
Modeling Social Media Content With Word Vectors For Recommendation, Ying Ding, Jing Jiang
Modeling Social Media Content With Word Vectors For Recommendation, Ying Ding, Jing Jiang
Research Collection School Of Computing and Information Systems
In social media, recommender systems are becoming more and more important. Different techniques have been designed for recommendations under various scenarios, but many of them do not use user-generated content, which potentially reflects users’ opinions and interests. Although a few studies have tried to combine user-generated content with rating or adoption data, they mostly reply on lexical similarity to calculate textual similarity. However, in social media, a diverse range of words is used. This renders the traditional ways of calculating textual similarity ineffective. In this work, we apply vector representation of words to measure the semantic similarity between text. We …
Active Crowdsourcing For Annotation, Shuji Hao, Chunyan Miao, Steven C. H. Hoi, Peilin Zhao
Active Crowdsourcing For Annotation, Shuji Hao, Chunyan Miao, Steven C. H. Hoi, Peilin Zhao
Research Collection School Of Computing and Information Systems
Crowdsourcing has shown great potential in obtaining large-scale and cheap labels for different tasks. However, obtaining reliable labels is challenging due to several reasons, such as noisy annotators, limited budget and so on. The state-of-the-art approaches, either suffer in some noisy scenarios, or rely on unlimited resources to acquire reliable labels. In this article, we adopt the learning with expert~(AKA worker in crowdsourcing) advice framework to robustly infer accurate labels by considering the reliability of each worker. However, in order to accurately predict the reliability of each worker, traditional learning with expert advice will consult with external oracles~(AKA domain experts) …
Time Distortion In Bierce's "One Of The Missing" And Uroshevic's "Ракописот Од Китаб-Ан" ("The Manuscript From Kitab-An"), Kalina Maleska
Time Distortion In Bierce's "One Of The Missing" And Uroshevic's "Ракописот Од Китаб-Ан" ("The Manuscript From Kitab-An"), Kalina Maleska
CLCWeb: Comparative Literature and Culture
In her article "Time Distortion in Bierce's 'One of the Missing' and Uroshevic's 'Ракописот од Китаб-Ан' ('The Manuscript from Kitab-An')" Kalina Maleska examines the relationship between literature and astronomy in the context of time. The two stories share several common elements: they explore the possible manipulations of time in unexpected and extraordinary ways and come close to certain scientific explorations of time. For "One of the Missing," Albert Einstein's theory of relativity provides an interesting foundation for understanding Bierce's treatment of time. For The Manuscript of Kitab-An, the speculations of time travel starting from the Einstein-Rosen concept of the black …
Lossy Projective Hashing And Its Applications, Haiyang Xue, Yamin Liu, Xianhui Lu, Bao Li
Lossy Projective Hashing And Its Applications, Haiyang Xue, Yamin Liu, Xianhui Lu, Bao Li
Research Collection School Of Computing and Information Systems
In this paper, we introduce a primitive called lossy projective hashing. It is unknown before whether smooth projective hashing (Cramer-Shoup, Eurocrypt’02) can be constructed from dual projective hashing (Wee, Eurocrypt’12). The lossy projective hashing builds a bridge between dual projective hashing and smooth projective hashing. We give instantiations of lossy projective hashing from DDH, DCR, QR and general subgroup membership assumptions (including 2k-th residue, p-subgroup and higher residue assumptions). We also show how to construct lossy encryption and fully IND secure deterministic public key encryption from lossy projective hashing. – We give a construction of lossy projective hashing via dual …
Aflatoxin Level In Selected Spices In Abu Dhabi Markets, Salma Ibrahim Al Hammadi
Aflatoxin Level In Selected Spices In Abu Dhabi Markets, Salma Ibrahim Al Hammadi
Theses
Aflatoxins (AF) are toxic secondary metabolites secreted by the fungi Aspergillus or Penicillium. Four aflatoxins (AFB1, AFB2, AFG1 and AFG2) are common in foods and feeds produced or stored under unfavorable conditions of humidity and temperature AFB1 is considered the most toxic.
Spices are significant ingredients in the UAE cuisine, used for the purpose of seasoning, coloring, and flavoring. In this research, 94 samples of spices (including pepper, chili, coriander, fennel seeds, paprika, turmeric, zataria, and mixed spices) purchased from different markets in the Emirate of Abu Dhabi, were analyzed for their contents of AF. Sample were analyzed using high-performance …
Assessment Of Current And Future Generated Selected E-Waste Quantities In Abu Dhabi, Khaleel Ibrahim Al Nasseri This
Assessment Of Current And Future Generated Selected E-Waste Quantities In Abu Dhabi, Khaleel Ibrahim Al Nasseri This
Theses
E-waste is a term used to describe electrical and electronic products that enter the waste stream. Currently, it is the fastest growing stream of municipal waste. Informal disposal of E-waste may cause serious health and pollution problems to humans as well as the environment. Although E-waste may represent less than 5% of the total waste discarded into landfills, yet it includes more than 70% of overall toxic waste. Not only the exact amount of E-waste generated in the UAE is unknown, but it is continuously increasing with the advent of new electronic products. Therefore, the main aim of this thesis …
An Integrated Drought Index (Idi) Incorporating Physical And Social Aspects, Rebecca L. Lanier
An Integrated Drought Index (Idi) Incorporating Physical And Social Aspects, Rebecca L. Lanier
Master's Theses
The purpose of this research was to determine significant bio-physical (physical and environmental) and social variables that can be integrated into a drought index to predict areas susceptible to drought. Severe drought events are capable of causing millions of dollars in damage. The 1988 drought caused the United States approximately $40 billion in damage. Drought forecasting, modeling, and detection have, therefore, become imperative to understand the social, economic and environmental impacts of droughts, and also to explore how these impacts play a role in the occurrence of a drought. A number of drought indices widely used in the U.S. rely …
Bombardment Simulations And Intercalation Studies Of Carbon Materials, Charles Lowe
Bombardment Simulations And Intercalation Studies Of Carbon Materials, Charles Lowe
All Dissertations
Molecular bombardment experiments have led to the possibility of altering materials with properties not normally associated with those materials. Molecular bombardment leads to defect formation in the material, potentially creating a pore, depending on the material and bombarding molecule. Carbon allotropes, specifically graphite and graphene, make excellent candidates for molecular bombardment experimentation. Depending on the bombarding molecule and the kinetic energy associated with that molecule, the defects induced will be sufficient to create a pore in the graphene. The AIREBO potential is used to simulate a graphene bilayer being bombarded with a single Ar atom, or a fullerene molecule, to …
Iterative Design And Testing Of A Mobile Application To Support Food Consumption Monitoring And Decision Making, Melva James
Iterative Design And Testing Of A Mobile Application To Support Food Consumption Monitoring And Decision Making, Melva James
All Dissertations
Food overconsumption is a major contributor to weight gain leading to obesity. Constant exposure to larger amounts of food and beverage has caused many individuals to experience “portion distortion,†the perception that bigger portion sizes are appropriate for consumption at a single sitting. Independently and accurately changing this perception can be very difficult even if one has a desire to do so. In response to these observations, we developed and tested Picture-Perfect Portions, a mobile application designed to combat overconsumption, at the individual level, by leveraging the power of simple visualizations to help adults understand and adjust their food consumption …
Multi-Factor Models To Resolve Growth Responses In Vitro And During Subsequent Greenhouse Growth For Turmeric (Curcuma Longa L.), Rabia El-Hawaz
Multi-Factor Models To Resolve Growth Responses In Vitro And During Subsequent Greenhouse Growth For Turmeric (Curcuma Longa L.), Rabia El-Hawaz
All Dissertations
Plant media has been developed over the last six decades, yet, there has not been medium optimized for microplant greenhouse growth, which may be important for producing chemical compounds and preparing transplants for success in the field. A series of multi-factor optimization experiments were conducted on turmeric (Curcuma longa L., genotype L 35-1) to identify the effects of mineral nutrition and plant density in vitro on laboratory and greenhouse production. The first experiment optimized PO43-, Ca2+, Mg2+, and KNO3 for five-months growth in bioreactors with periodic supplementation of sucrose solution +/- nutrients. Phosphorus (6.25 mM) increased sucrose supplement and rhizome …
Production And Characterization Of Cut Resistant Acrylic/Copolyaramid Fibers Via Bicomponent Wet Spinning, Stephen Hipp
Production And Characterization Of Cut Resistant Acrylic/Copolyaramid Fibers Via Bicomponent Wet Spinning, Stephen Hipp
All Dissertations
A composite fiber system consisting of a sheath core bicomponent polymer fiber loaded with hard ceramic particles was developed and characterized for use in cut protective clothing. The core component was comprised of a copolyaramid in order to provide high base cut resistance. An acrylic-copolyaramid polymer blend was used for the sheath component to improve processability and provide potential benefits such as dyeability. Lastly, aluminum oxide particles were incorporated into the fiber core to deflect and deform the cutting edge, further improving cut resistance. A series of designed experiments was used to explore the effects of the wet spinning and …
High Temperature Synthesis And Characterization Of Reduced Polyoxometalate Salt-Inclusion Solids, Dino Sulejmanovic
High Temperature Synthesis And Characterization Of Reduced Polyoxometalate Salt-Inclusion Solids, Dino Sulejmanovic
All Dissertations
Herein, several new salt-inclusion solids (SISs) featuring electronically reduced Keggin polyoxometalate (POM) clusters were isolated for the first time using molten-salt high temperature (> 500 oC) synthetic method. These POM-based SISs are novel all-inorganic materials featuring an integrated lattice of ionic halide salt and covalent metal oxide clusters. Due to the weak interactions at the interface between these two chemically dissimilar lattices, these POM SISs are soluble in aqueous and polar solvents. While POM compounds are well-studied and are routinely synthesized in solution, the synthetic method presented in this dissertation yielded several POM solids with interesting structures and infrequently observed, …