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2015

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University of Massachusetts Amherst

Doctoral Dissertations

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Full-Text Articles in Physical Sciences and Mathematics

Automated Style Feedback For Advanced Beginner Java Programmers, Hannah Blau Nov 2015

Automated Style Feedback For Advanced Beginner Java Programmers, Hannah Blau

Doctoral Dissertations

FrenchPress is an Eclipse plug-in that partially automates the task of giving students feedback on their Java programs. It is designed not for novices but for students taking their second or third Java course: students who know enough Java to write a working program but lack the judgment to recognize bad code when they see it. FrenchPress does not diagnose compile-time or run-time errors, or logical errors that produce incorrect output. It targets silent flaws, flaws the student is unable to identify for himself because nothing in the programming environment alerts him. FrenchPress diagnoses flaws characteristic of programmers who have …

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Content Placement As A Key To A Content-Dominated, Highly Mobile Internet, Abhigyan Sharma Nov 2015

Content Placement As A Key To A Content-Dominated, Highly Mobile Internet, Abhigyan Sharma

Doctoral Dissertations

Most of the Internet traffic is content, and most of the Internet connected hosts are mobile. Our work focuses on the design of infrastructure services needed to support such a content-dominated, highly mobile Internet. In the design of these services, three sets of decisions arise frequently: (1) Content placment for selecting the locations where a content is placed, (2) request redirection for selecting the location where a particular request is served from and (3) network routing for selecting the physical path between clients and the services they are accessing. Our central thesis is that content placement is a powerful factor, …

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Informed Search For Learning Causal Structure, Brian J. Taylor Nov 2015

Informed Search For Learning Causal Structure, Brian J. Taylor

Doctoral Dissertations

Over the past twenty-five years, a large number of algorithms have been developed to learn the structure of causal graphical models. Many of these algorithms learn causal structures by analyzing the implications of observed conditional independence among variables that describe characteristics of the domain being analyzed. They do so by applying inference rules, data analysis operations such as the conditional independence tests, each of which can eliminate large parts of the space of possible causal structures. Results show that the sequence of inference rules used by PC, a widely applied algorithm for constraint-based learning of causal models, is effective but …

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The Impact Of Terrestrial Noise On The Detectability And Reconstruction Of Gravitational Wave Signals From Core-Collapse Supernovae, Jessica Mciver Nov 2015

The Impact Of Terrestrial Noise On The Detectability And Reconstruction Of Gravitational Wave Signals From Core-Collapse Supernovae, Jessica Mciver

Doctoral Dissertations

Among of the wide range of potentially interesting astrophysical sources for gravitational wave detectors Advanced LIGO and Advanced Virgo are galactic core-collapse supernovae. Although detectable core-collapse supernovae have a low expected rate (a few per century, or less) these signals would yield a wealth of new physics. Of particular interest is the insight into the explosion mechanism driving core-collapse supernovae that can be gleaned from the reconstructed gravitational wave signal. A well-reconstructed waveform will allow us to assess the likelihood of different explosion models, perform model selection, and potentially map unexpected features to new physics. This dissertation presents a series …

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Utilizing In Silico And/Or Native Esi Approaches To Provide New Insights On Haptoglobin/Globin And Haptoglobin/Receptor Interactions, Ololade Fatunmbi Nov 2015

Utilizing In Silico And/Or Native Esi Approaches To Provide New Insights On Haptoglobin/Globin And Haptoglobin/Receptor Interactions, Ololade Fatunmbi

Doctoral Dissertations

Haptoglobin (Hp), an acute phase protein, binds free hemoglobin (Hb) dimers in one of the strongest non-covalent interactions known in biology. This interaction protects Hb from causing potentially severe oxidative damage and limiting nitric oxide bioavailability. Once Hb/Hp complexes are formed, they proceed to bind CD163, a cell surface receptor on macrophages leading to complex internalization and catabolism. Myoglobin, (Mb) a monomeric protein, that is normally found in the muscle but can be released into the blood in high concentrations during myocardial injury, is homologous to Hb and shares many conserved Hb/Hp interface residues. Both monomeric Hb and Mb species …

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An Empirical Approach To Understanding Of Star Formation In Dark Matter Halos, Zhankui Lu Nov 2015

An Empirical Approach To Understanding Of Star Formation In Dark Matter Halos, Zhankui Lu

Doctoral Dissertations

We present a data-driven approach to understand the star formation in dark matter halos over cosmic time. With a simple empirical model and advanced tools for Bayesian inference, we try to constrain how galaxies have assembled their stars across cosmic time using stellar mass functions (SMFs) and the luminosity function of cluster galaxies. The key ingredients of the empirical model include dark halo merger trees and a generic function that links star formation rate (SFR) to the host halos. We found a new characteristic redshift zc ~ 2 above which the SFR in low mass halos < 1011 solar mass …

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Exploiting Social Media Sources For Search, Fusion And Evaluation, Chia-Jung Lee Nov 2015

Exploiting Social Media Sources For Search, Fusion And Evaluation, Chia-Jung Lee

Doctoral Dissertations

The web contains heterogeneous information that is generated with different characteristics and is presented via different media. Social media, as one of the largest content carriers, has generated information from millions of users worldwide, creating material rapidly in all types of forms such as comments, images, tags, videos and ratings, etc. In social applications, the formation of online communities contributes to conversations of substantially broader aspects, as well as unfiltered opinions about subjects that are rarely covered in public media. Information accrued on social platforms, therefore, presents a unique opportunity to augment web sources such as Wikipedia or news pages, …

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Contact Angles And Contact Lines Around Particles At Isotropic And Anisotropic Liquid Interfaces, Nesrin Senbil Nov 2015

Contact Angles And Contact Lines Around Particles At Isotropic And Anisotropic Liquid Interfaces, Nesrin Senbil

Doctoral Dissertations

Liquid interfaces, capillarity and self-assembly of particles at interfaces are important in nature and technology. When a particle is adsorbed to a liquid interface, the contact line of the particle with the liquid interface and the associated contact angle are the crucial parameters that drive assembly of the particles. We looked at how the shape of the liquid interface and the shape of the particle affect the contact angle and the shape of the contact line. We used millimeter-sized PDMS-coated glass spheres and measured the contact angles at isotropic (planar) and anisotropic interfaces (saddle and cylindrical in shape). Anisotropy of …

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Inkjet Printing For Biosensing And Security Applications, Brian Creran Nov 2015

Inkjet Printing For Biosensing And Security Applications, Brian Creran

Doctoral Dissertations

The adaptation of inkjet printing technology has recently been used to create controlled high throughput micro- and nano-scaled structures. Coupling this technique with gold nanoparticles in our research has produced new platforms for biosensors, chemical patterning, and anti-counterfeiting applications. In this presentation, we will highlight promising fabrication strategies including the development of test strips for the determination of bacteria in drinking water as well as the use of patterned nanoparticles for security applications.

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Impact Of Fabrication Parameters On The Internal Structure Of Poly(3-Hexylthiophene) Nanoparticles, Dana Desiree Algaier Nov 2015

Impact Of Fabrication Parameters On The Internal Structure Of Poly(3-Hexylthiophene) Nanoparticles, Dana Desiree Algaier

Doctoral Dissertations

Morphological control of organic functional materials is central to understanding and improving upon current technologies. The ability to create hierarchical assemblies with purposeful design from nano to meso scale has remained largely unattainable. This body of work aims to provide a foundation for creating nanoscale domains of poly (3-hexylthiophene) (P3HT) that can be used as building blocks to larger scale assemblies. We present a method for the fabrication of P3HT nanoparticles on the ability to vary the particle size and more importantly, the internal structure. We have identified the oil phase and surfactant as parameters able to influence the nature …

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Safe Reinforcement Learning, Philip S. Thomas Nov 2015

Safe Reinforcement Learning, Philip S. Thomas

Doctoral Dissertations

This dissertation proposes and presents solutions to two new problems that fall within the broad scope of reinforcement learning (RL) research. The first problem, high confidence off-policy evaluation (HCOPE), requires an algorithm to use historical data from one or more behavior policies to compute a high confidence lower bound on the performance of an evaluation policy. This allows us to, for the first time, provide the user of any RL algorithm with confidence that a newly proposed policy (which has never actually been used) will perform well. The second problem is to construct what we call a safe reinforcement learning …

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Estimation Problems In Complex Field Studies With Deep Interactions: Time-To-Event And Local Regression Models For Environmental Effects On Vital Rates, Krzysztof M. Sakrejda Nov 2015

Estimation Problems In Complex Field Studies With Deep Interactions: Time-To-Event And Local Regression Models For Environmental Effects On Vital Rates, Krzysztof M. Sakrejda

Doctoral Dissertations

Field studies that measure vital rates in context over extended time periods are a cornerstone of our understanding of population processes. These studies inform us about the relationship between biological process and environmental noise in an irreplaceable way. These data sets bring ``big data'' and ``big model'' challenges, which limit the application of standard software (e.g., \textbf{BUGS}). The environmental sensitivity of vital rates is also expected to exhibit interactions and non-linearity, which typically result in difficult model selection questions in large data sets. Finally, long-term ecological data sets often contain complex temporal structure. In commonly applied discrete-time models complex temporal …

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From Molecular Scale To Mesoscale: Establishing Structural Control Organic Photovoltaics Using Organic Nanoparticles, Timothy S. Gehan Nov 2015

From Molecular Scale To Mesoscale: Establishing Structural Control Organic Photovoltaics Using Organic Nanoparticles, Timothy S. Gehan

Doctoral Dissertations

Organic photovoltaic devices use an active layer of organic materials that absorbs light and creates free charges to generate electricity. Such organic photovoltaics have many desirable properties as the final devices can be very lightweight, thin, flexible, have low manufacturing costs, and be semitransparent. These properties make them particularly advantageous for myriad of applications: e.g., use on non-planar surfaces, as tinted coatings on windows, any use for charging low power devices. One of the biggest problems preventing organic photovoltaics from being commercialized is controlling the packing of the organic materials within the active layer from the molecular scale through the …

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Forensic And Management Challenges In Wireless And Mobile Network Environment, Sookhyun Yang Nov 2015

Forensic And Management Challenges In Wireless And Mobile Network Environment, Sookhyun Yang

Doctoral Dissertations

The Internet recently passed an historic inflection point, with the number of broadband wireless/mobile devices surpassing the number of wired PCs and servers connected to the Internet. Smartphones, laptops, tablets, machine-to-machine (M2M) devices, and other portable devices have penetrated our daily lives. According to Cisco, by 2018, wired devices will account for only 39% of IP traffic, with the remaining traffic produced by wireless/mobile devices. This proliferation of wireless/mobile devices is profoundly changing many of the characteristics of network applications, protocols, and operation, and posing fundamental challenges to the Internet architecture. In light of this new trend, this thesis focuses …

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Gravitational Wave Astrophysics: Instrumentation, Detector Characterization, And A Search For Gravitational Signals From Gamma-Ray Bursts, Daniel Hoak Nov 2015

Gravitational Wave Astrophysics: Instrumentation, Detector Characterization, And A Search For Gravitational Signals From Gamma-Ray Bursts, Daniel Hoak

Doctoral Dissertations

In the coming years, the second generation of interferometric gravitational wave detectors are widely expected to observe the gravitational radiation emitted by compact, energetic events in the nearby universe. The field of gravitational wave astrophysics has grown into a large international endeavor with a global network of kilometer-scale observatories. The work presented in this thesis spans the field, from optical metrology, to instrument commissioning, to detector characterization and data analysis. The principal results are a method for the precise characterization of optical cavities, the commissioning of the advanced LIGO Output Mode Cleaner at the Hanford observatory, and a search for …

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Conjugated Polymers In Thermoelectric Composites And Small Molecules For High Light Absorptivity, Murat Tonga Nov 2015

Conjugated Polymers In Thermoelectric Composites And Small Molecules For High Light Absorptivity, Murat Tonga

Doctoral Dissertations

Over the past several decades with increasing of global energy demand, thermoelectric materials have gained considerable attention due to their unique ability to directly convert heat to electricity. In addition to inorganic semiconductors, polymers are potential candidates for high-performance thermoelectric applications due to their intrinsic advantages such as low thermal conductivity, solution processability, and roll-to-roll production, lightweight, and flexible thermoelectric modules. This thesis provides an insight into the emerging field of organic thermoelectrics, more specifically, thermoelectric power generation based on the composites of conducting polymers (MEH-PPV, P3HT and PEDOT:PSS) and carbon nanotubes (SWNT, SWNT-COOH, SWNT-OH and MWNT). A substantial portion …

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Exact Solutions In Gravity: A Journey Through Spacetime With The Kerr-Schild Ansatz, Benjamin Ett Nov 2015

Exact Solutions In Gravity: A Journey Through Spacetime With The Kerr-Schild Ansatz, Benjamin Ett

Doctoral Dissertations

The Kerr-Schild metric ansatz can be expressed in the form $g_{ab} = \gbar_{ab}+\lambda k_ak_b$, where $\gbar_{ab}$ is a background metric satisfying Einstein's equations, $k_a$ is a null-vector, and $\lambda$ is a free parameter. It was discovered in 1963 while searching for the elusive rotating black hole solutions to Einstein's equations, fifty years after the static solution was found and Einstein first formulated his theory of general relativity. While the ansatz has proved an excellent tool in the search for new exact solutions since then, its scope is limited, particularly with respect to higher dimensional theories. In this thesis, we present …

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Design And Implementation Of An Economy Plane For The Internet, Xinming Chen Nov 2015

Design And Implementation Of An Economy Plane For The Internet, Xinming Chen

Doctoral Dissertations

The Internet has been very successful in supporting many network applications. As the diversity of uses for the Internet has increased, many protocols and services have been developed by the industry and the research community. However, many of them failed to get deployed in the Internet. One challenge of deploying these novel ideas in operational network is that the network providers need to be involved in the process. Many novel network protocols and services, like multicast and end-to-end QoS, need the support from network providers. However, since network providers are typically driven by business reasons, if they can not get …

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Assessing Kiln-Produced Hardwood Biochar For Improving Soil Health In A Temperate Climate Agricultural Soil, Emily J. Cole Nov 2015

Assessing Kiln-Produced Hardwood Biochar For Improving Soil Health In A Temperate Climate Agricultural Soil, Emily J. Cole

Doctoral Dissertations

Soil quality has become a major factor used in assessing sustainable land management and the overall environmental quality, food security, and economic viability of agricultural lands. Recently, biochar has been touted as having many potential uses as a soil amendment for improving soil quality, specifically improving cation exchange capacity, pH and nutrient availability. However, soil biology also plays a significant role in biogeochemical processes that influence soil health and should be included in a more comprehensive study of soil health. This dissertation describes 4 projects within the same 3-year field study with the cumulative purpose of better understanding the effect …

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Population Annealing Monte Carlo Studies Of Ising Spin Glasses, Wenlong Wang Nov 2015

Population Annealing Monte Carlo Studies Of Ising Spin Glasses, Wenlong Wang

Doctoral Dissertations

Spin glasses are spin-lattice models with quenched disorder and frustration. The mean field long-range Sherrington-Kirkpatrick (SK) model was solved by Parisi and displays replica symmetry breaking (RSB), but the more realistic short-range Edwards-Anderson (EA) model is still not solved. Whether the EA spin glass phase has many pairs of pure states as described by the RSB scenario or a single pair of pure states as described by two-state scenarios such as the droplet/scaling picture is not known yet. Rigorous analytical calculations of the EA model are not available at present and efficient numerical simulations of spin glasses are crucial in …

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Elasticity And Geometry In Curved-Filament Assemblies, Luis Cajamarca Ospina Nov 2015

Elasticity And Geometry In Curved-Filament Assemblies, Luis Cajamarca Ospina

Doctoral Dissertations

In this dissertation we explore the effect of shape, mechanics and geometry in assemblies of tubular filaments by introducing the notion of cohesive contact. We first study the optimal geometry of cohesive interactions in straight flexible tubes by considering two interaction potentials. We find filaments adopt a locally skewed configuration, associated with a twist angle. The interaction energy decreases with the twist angle and ground states are found to be twisted. For pair-wise interactions, we find a generic behavior in the profile of the cohesive energy where the geometry of close-packed double helices dictates the shape of the assembly. By …

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Energy-Efficient Content Delivery Networks, Vimal Mathew Nov 2015

Energy-Efficient Content Delivery Networks, Vimal Mathew

Doctoral Dissertations

Internet-scale distributed systems such as content delivery networks (CDNs) operate hundreds of thousands of servers deployed in thousands of data center locations around the globe. Since the energy costs of operating such a large IT infrastructure are a significant fraction of the total operating costs, we argue for redesigning them to incorporate energy optimization as a first-order principle. We focus on CDNs and demonstrate techniques to save energy while meeting client-perceived service level agreements (SLAs) and minimizing impact on hardware reliability. Servers deployed at individual data centers can be switched off at low load to save energy. We show that …

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Skeleton Structures And Origami Design, John C. Bowers Nov 2015

Skeleton Structures And Origami Design, John C. Bowers

Doctoral Dissertations

In this dissertation we study problems related to polygonal skeleton structures that have applications to computational origami. The two main structures studied are the straight skeleton of a simple polygon (and its generalizations to planar straight line graphs) and the universal molecule of a Lang polygon. This work builds on results completed jointly with my advisor Ileana Streinu. Skeleton structures are used in many computational geometry algorithms. Examples include the medial axis, which has applications including shape analysis, optical character recognition, and surface reconstruction; and the Voronoi diagram, which has a wide array of applications including geographic information systems …

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Analysis Of The Impact Of Technological Change On The Cost Of Achieving Climate Change Mitigation Targets, Robert W. Barron Nov 2015

Analysis Of The Impact Of Technological Change On The Cost Of Achieving Climate Change Mitigation Targets, Robert W. Barron

Doctoral Dissertations

There is widespread consensus that low carbon energy technologies will play a key role in the future global energy system. Many of the low-carbon technologies under consideration are not yet commercially available, and their ultimate value depends on a host of deeply uncertain socioeconomic, environmental, and technological considerations. While it is clear that significant investment in the energy system is needed, the optimal allocation of these investments is unclear. This dissertation develops a methodology for (1) analyzing the impact of low carbon energy technologies on the cost of meeting emission reduction targets (policy cost) and (2) using this information to …

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Wind Power Capacity Value Metrics And Variability: A Study In New England, Frederick W. Letson Nov 2015

Wind Power Capacity Value Metrics And Variability: A Study In New England, Frederick W. Letson

Doctoral Dissertations

Capacity value is the contribution of a power plant to the ability of the power system to meet high demand. As wind power penetration in New England, and worldwide, increases so does the importance of identifying the capacity contribution made by wind power plants. It is critical to accurately characterize the capacity value of these wind power plants and the variability of the capacity value over the long term. This is important in order to avoid the cost of keeping extra power plants operational while still being able to cover the demand for power reliably. This capacity value calculation is …

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Quantum Calculations Of Aldol Condensation In Acidic Zeolites, Angela N. Migues Nov 2015

Quantum Calculations Of Aldol Condensation In Acidic Zeolites, Angela N. Migues

Doctoral Dissertations

We have used Density Functional Theory to model the mixed aldol condensation reaction catalyzed by acidic zeolites. We have studied the convergence of barriers for the keto-enol tautomerization of acetone in cluster models of HZSM-5 and HY ranging in size from 3-37T. A key finding was that activation barriers for keto-enol tautomerization of acetone in both zeolites (~20 kcal/mol) are significantly higher than those for the condensation reaction between the acetone enol and formaldehyde in 11T cluster models of HZSM-5 and HY. Moreover we found that three zeolite clusters of HZSM-5, similarly sized but including different structural features of the …

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General Program Synthesis From Examples Using Genetic Programming With Parent Selection Based On Random Lexicographic Orderings Of Test Cases, Thomas Helmuth Nov 2015

General Program Synthesis From Examples Using Genetic Programming With Parent Selection Based On Random Lexicographic Orderings Of Test Cases, Thomas Helmuth

Doctoral Dissertations

Software developers routinely create tests before writing code, to ensure that their programs fulfill their requirements. Instead of having human programmers write the code to meet these tests, automatic program synthesis systems can create programs to meet specifications without human intervention, only requiring examples of desired behavior. In the long-term, we envision using genetic programming to synthesize large pieces of software. This dissertation takes steps toward this goal by investigating the ability of genetic programming to solve introductory computer science programming problems. We present a suite of 29 benchmark problems intended to test general program synthesis systems, which we systematically …

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Photochemical Tools For Fluorescent Labeling Of Endogenous Proteins, Stephen T. Mccarron Nov 2015

Photochemical Tools For Fluorescent Labeling Of Endogenous Proteins, Stephen T. Mccarron

Doctoral Dissertations

The study of the dynamic movements of membrane bound proteins is typically achieved through an exogenously applied fluorescent tag or genetic modification of a receptor of interest to spatiotemporally monitor protein location. Techniques often used for labeling proteins include overexpression of a fluorescent protein such as GFP fused to a target protein or the application of antibodies. These methods benefit from superb specificity towards a receptor of interest, but may impose unforeseen consequences when studying natural protein movements. Thus, it is advantageous to development small, modular probes that would allow for visualization of endogenous membrane bound receptors in a minimally …

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Exploiting Concepts In Videos For Video Event Detection, Ethem Can Nov 2015

Exploiting Concepts In Videos For Video Event Detection, Ethem Can

Doctoral Dissertations

Video event detection is the task of searching videos for events of interest to a user where an event is a complex activity which is localized in time and space. The video event detection problem has gained more importance as the amount of online video is increasing by more than 300 hours every minute on Youtube alone. In this thesis, we tackle three major video event detection problems: video event detection with exemplars (VED-ex), where a large number of example videos are associated with queries; video event detection with few exemplars (VED-ex_few), in which only a small number of example …

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Morphology Evolution Mechanisms Of Low Band Gap Polymer-Based Photovoltaics, Sunzida Ferdous Nov 2015

Morphology Evolution Mechanisms Of Low Band Gap Polymer-Based Photovoltaics, Sunzida Ferdous

Doctoral Dissertations

An optimal nanoscale phase separation between the donor (generally, a conjugated polymer) and the acceptor (generally, a fullerene derivative) materials is one of the major requirements for obtaining high efficiency organic photovoltaic (OPV) device. Recent methods of controlling such nanostructure morphology in a bulkheterojunction (BHJ) OPV device involve addition of a small amount of solvent additive to the donor and acceptor solutions. The idea is to retain the acceptor materials into the solution for a longer period of time during the film solidification process, thus allowing the donor material to crystallize earlier. The ultimate morphology resulting from the solvent casting …

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