Physical Sciences and Mathematics Commons^™

Validation Of Argon From Underground Sources For Use In The Darkside-50 Detector, Thomas R. Alexander

Masters Theses

Liquid argon is an attractive target for dark matter searches due to its low cost and exemplary event discrimination. However, atmospherically derived argon contains the beta-emitter 39Ar which confounds the growth of dual-phase time projection chamber (TPC) style detectors to the ton-scale. The DarkSide Collaboration seeks to bypass this limitation by extracting argon from deep underground, from a location known to contain significantly less 39Ar than atmospherically derived argon. This thesis will summarize the e orts taken to produce the first batch of underground argon, focusing on the first operation of the underground argon in a dual-phase TPC to validate …

Impacts Of Land Cover And Climate Change On Water Resources In Suasco River Watershed, Ammara Talib

Masters Theses

Hydrological balance and biogeochemical processes in watershed are significantly influenced by changes in land use land cover (LULC) and climate change. Those changes can influence interception, evapotranspiration (ET), infiltration, soil moisture, water balance and biogeochemical cycling of carbon, nitrogen and other elements at regional to global scales. The impacts of these hydrological disturbances are generally reflected in form of increasing runoff rate and volume, more intense and frequent floods, decreasing groundwater recharge and base flow, elevated levels of sediments and increase in concentration of nutrients in both streams and shallow groundwater. Water quality of Sudbury, Assabet and Concord (SuAsCo) watershed …

Using Digital Elevation Models Derived From Airborne Lidar And Other Remote Sensing Data To Model Channel Networks And Estimate Fluvial Geomorphological Metrics, Noah Slovin

Masters Theses

Recent advances in remote-sensing technologies and analysis methods, specifically airborne-LiDAR elevation data and corresponding geographical information system (GIS) tools, present new opportunities for automated and rapid fluvial geomorphic (FGM) assessments that can cover entire watersheds. In this thesis, semi-automated GIS tools are used to extract channel centerlines and bankfull width values from digital elevation models (DEM) for five New England watersheds. For each study site, four centerlines are mapped. LiDAR and NED lines are delineated using ArcGIS spatial analyst tools with high-resolution (1-m to 2-m) LiDAR DEMs or USGS National Elevation Dataset (NED) DEMs, respectively. Resampled LiDAR decreases LiDAR DEM …

Impacts Of Three-Dimensional Non-Uniform Groundwater Flows For Quantifying Groundwater-Surface Water Interactions Using Heat As A Tracer, Jonathan M. Reeves

Masters Theses

Heat-as-a-tracer has become a common method to quantify surface water-groundwater interactions (SW/GW). However, the method relies on a number of assumptions that are likely violated in natural systems. Numerical studies have explored the effects of violating these fundamental assumptions to various degrees, such as heterogeneous streambed properties, two-dimensional groundwater flow fields and uncertainty in thermal parameters for the 1-dimensional heat-as-a-tracer method. No work to date has addressed the impacts of non-uniform, three-dimensional groundwater flows on the use of heat-as-a-tracer to quantify SW/GW interactions. Synthetic temperature time series were generated using COMSOL Multiphysics for a three-dimensional cube designed to represent a …

A High-Resolution Paleoenvironmental And Paleoclimatic History Of Extreme Events On The Laminated Sediment Record From Basin Pond, Fayette, Maine, U.S.A., Daniel R. Miller

Masters Theses

Future impacts from climate change can be better understood by placing modern climate trends into perspective through extension of the short instrumental records of climate variability. This is especially true for extreme climatic events, such as extreme precipitation and wildfires, as the period of instrumental records provides only a few examples and these have likely have been influenced by anthropogenic warming. Multi-parameter records showing the past range of climate variability can be obtained from lakes. Lakes are particularly good recorders of climate variability because sediment from the surrounding environment accumulates in lakes, making them sensitive recorders of climate variability and …

Bayesian Model Selection And Parameter Estimation For Gravitational Wave Signals From Binary Black Hole Coalescences, Alexander L. Lombardi

Masters Theses

In his theory of General Relativity, Einstein describes gravity as a geometric property of spacetime, which deforms in the presence of mass and energy. The accelerated motion of masses produces deformations, which propagate outward from their source at the speed of light. We refer to these radiated deformations as gravitational waves. Over the past several decades, the goal of the Laser Interferometer Gravitational-wave Observatory (LIGO) has been the search for direct evidence of gravitational waves from astrophysical sources, using ground based laser interferometers. As LIGO moves into its Advanced era (aLIGO), the direct detection of gravitational waves is inevitable. With …

Studying Nanoparticle/Cell And Nanoparticle/Biosurface Interaction With Mass Spectrometry, Singyuk Hou

Masters Theses

Nanoparticles (NPs) have been used widely in various fields ranging from biomedical applications to life science due to their highly tunable properties. It is essential to understanding how NPs interact with biological systems of interest, therefore, analytical platforms to efficiently track NPs from cell to animal level are essential. In this thesis, laser desorption ionization mass spectrometry (LDI-MS) and inductively-coupled plasma mass spectrometry (ICP-MS) has been developed and applied to quantify NP/cell and NP/biological surface interactions. These two methods provide fast, label-free and quantitative analysis. New capability of LDI-MS to differentiate cell surface-bound and internalized NPs were established and ICP-MS …

Examining The Mid- Brunhes Event In The Terrestrial Arctic: An Organic Geochemical Record From Lake El’Gygytgyn, Russia, Mary Helen Habicht

Masters Theses

The characteristic glacial and interglacial cycles of the Pleistocene underwent a climatic transition at ~430 ka known as the Mid- Brunhes Event (MBE). Many studies, particularly from the Southern Hemisphere have noted that after this transition, the amplitude of the climatic cycles increased. Despite the indication of an MBE signal in many globally distributed paleoclimate records, the geographic extent of the climatic transition remains unknown and its presence in northern hemisphere and terrestrial records is debated. Lake El’gygytgyn is located in the far- east Russian Arctic and provides the longest, most continuous record of Arctic climate (3.6 Ma). This study …

Urban Agriculture And Ecosystem Services: A Typology And Toolkit For Planners, Kathleen Doherty

Masters Theses

This thesis makes the connection between urban agriculture and a specific suite of ecosystem services and lays out a typology and toolkit for planners to take advantage of these ecosystem services. The services investigated here are: food production, water management, soil health, biodiversity, climate mitigation, and community development benefits. Research from a variety of fields was aggregated and synthesized to prove that urban agriculture can be beneficial for human as well as environmental health.

A set of urban agriculture typologies was generated to illustrate best practices to maximize a particular set of ecosystem services. The typologies are: production farm, stormwater …

Molecular Interpretation Of A Trigger For Controlling An Amine Isocyanate Polyurethane Reaction, Katherine V. Carrasquillo

Masters Theses

The temperature profile needed to complete the reaction between the sodium-diamine complex and the isocyanate terminated prepolymer has been established. The sodium diamine complex has the advantage of blocking the nearly instantaneous reaction between the diamine and isocyanate from taking place until it is released at elevated temperatures. Because of its low melting temperature (~40 °C) and its low molecular weight (low viscosity), this chain extension reaction is not dependent on the participation of the prepolymer. Instead, the rate of reaction is dependent on the dissolution of the 4,4’-methylenedianiline (MDA) complex into the system. The dissolution of the MDA complex …

Niche-Based Modeling Of Japanese Stiltgrass (Microstegium Vimineum) Using Presence-Only Information, Nathan Bush

Masters Theses

The Connecticut River watershed is experiencing a rapid invasion of aggressive non-native plant species, which threaten watershed function and structure. Volunteer-based monitoring programs such as the University of Massachusetts’ OutSmart Invasives Species Project, Early Detection Distribution Mapping System (EDDMapS) and the Invasive Plant Atlas of New England (IPANE) have gathered valuable invasive plant data. These programs provide a unique opportunity for researchers to model invasive plant species utilizing citizen-sourced data. This study took advantage of these large data sources to model invasive plant distribution and to determine environmental and biophysical predictors that are most influential in dispersion, and to identify …

Sedimentological Records And Numerical Simulations Of The C.E. 1707 Hōei Tsunami In Southwestern Japan, Hannah Baranes

Masters Theses

A tsunami generated by the C.E. 1707 Hōei earthquake is largely thought to be the flood event of record for southwestern Japan, yet historical documentation of the event is scarce. This is particularly true in northwestern Shikoku within the Bungo Channel, where significant inconsistencies exist between historical records and model-derived tsunami heights. To independently assess flooding from the C.E. 1707 Hōei tsunami in the context of the region’s long-term flooding history, we present complementary reconstructions of extreme coastal inundation from three back-barrier lakes in the northern Bungo Channel: Lake Ryuuoo, Lake Amida, and Lake Kamega. At all sites, the most …

Automated Style Feedback For Advanced Beginner Java Programmers, Hannah Blau

Doctoral Dissertations

FrenchPress is an Eclipse plug-in that partially automates the task of giving students feedback on their Java programs. It is designed not for novices but for students taking their second or third Java course: students who know enough Java to write a working program but lack the judgment to recognize bad code when they see it. FrenchPress does not diagnose compile-time or run-time errors, or logical errors that produce incorrect output. It targets silent flaws, flaws the student is unable to identify for himself because nothing in the programming environment alerts him. FrenchPress diagnoses flaws characteristic of programmers who have …

Content Placement As A Key To A Content-Dominated, Highly Mobile Internet, Abhigyan Sharma

Doctoral Dissertations

Most of the Internet traffic is content, and most of the Internet connected hosts are mobile. Our work focuses on the design of infrastructure services needed to support such a content-dominated, highly mobile Internet. In the design of these services, three sets of decisions arise frequently: (1) Content placment for selecting the locations where a content is placed, (2) request redirection for selecting the location where a particular request is served from and (3) network routing for selecting the physical path between clients and the services they are accessing. Our central thesis is that content placement is a powerful factor, …

Informed Search For Learning Causal Structure, Brian J. Taylor

Doctoral Dissertations

Over the past twenty-five years, a large number of algorithms have been developed to learn the structure of causal graphical models. Many of these algorithms learn causal structures by analyzing the implications of observed conditional independence among variables that describe characteristics of the domain being analyzed. They do so by applying inference rules, data analysis operations such as the conditional independence tests, each of which can eliminate large parts of the space of possible causal structures. Results show that the sequence of inference rules used by PC, a widely applied algorithm for constraint-based learning of causal models, is effective but …

The Impact Of Terrestrial Noise On The Detectability And Reconstruction Of Gravitational Wave Signals From Core-Collapse Supernovae, Jessica Mciver

Doctoral Dissertations

Among of the wide range of potentially interesting astrophysical sources for gravitational wave detectors Advanced LIGO and Advanced Virgo are galactic core-collapse supernovae. Although detectable core-collapse supernovae have a low expected rate (a few per century, or less) these signals would yield a wealth of new physics. Of particular interest is the insight into the explosion mechanism driving core-collapse supernovae that can be gleaned from the reconstructed gravitational wave signal. A well-reconstructed waveform will allow us to assess the likelihood of different explosion models, perform model selection, and potentially map unexpected features to new physics. This dissertation presents a series …

Utilizing In Silico And/Or Native Esi Approaches To Provide New Insights On Haptoglobin/Globin And Haptoglobin/Receptor Interactions, Ololade Fatunmbi

Doctoral Dissertations

Haptoglobin (Hp), an acute phase protein, binds free hemoglobin (Hb) dimers in one of the strongest non-covalent interactions known in biology. This interaction protects Hb from causing potentially severe oxidative damage and limiting nitric oxide bioavailability. Once Hb/Hp complexes are formed, they proceed to bind CD163, a cell surface receptor on macrophages leading to complex internalization and catabolism. Myoglobin, (Mb) a monomeric protein, that is normally found in the muscle but can be released into the blood in high concentrations during myocardial injury, is homologous to Hb and shares many conserved Hb/Hp interface residues. Both monomeric Hb and Mb species …

An Empirical Approach To Understanding Of Star Formation In Dark Matter Halos, Zhankui Lu

Doctoral Dissertations

We present a data-driven approach to understand the star formation in dark matter halos over cosmic time. With a simple empirical model and advanced tools for Bayesian inference, we try to constrain how galaxies have assembled their stars across cosmic time using stellar mass functions (SMFs) and the luminosity function of cluster galaxies. The key ingredients of the empirical model include dark halo merger trees and a generic function that links star formation rate (SFR) to the host halos. We found a new characteristic redshift z_c ~ 2 above which the SFR in low mass halos < 10¹¹ solar mass …

Exploiting Social Media Sources For Search, Fusion And Evaluation, Chia-Jung Lee

Doctoral Dissertations

The web contains heterogeneous information that is generated with different characteristics and is presented via different media. Social media, as one of the largest content carriers, has generated information from millions of users worldwide, creating material rapidly in all types of forms such as comments, images, tags, videos and ratings, etc. In social applications, the formation of online communities contributes to conversations of substantially broader aspects, as well as unfiltered opinions about subjects that are rarely covered in public media. Information accrued on social platforms, therefore, presents a unique opportunity to augment web sources such as Wikipedia or news pages, …

Contact Angles And Contact Lines Around Particles At Isotropic And Anisotropic Liquid Interfaces, Nesrin Senbil

Doctoral Dissertations

Liquid interfaces, capillarity and self-assembly of particles at interfaces are important in nature and technology. When a particle is adsorbed to a liquid interface, the contact line of the particle with the liquid interface and the associated contact angle are the crucial parameters that drive assembly of the particles. We looked at how the shape of the liquid interface and the shape of the particle affect the contact angle and the shape of the contact line. We used millimeter-sized PDMS-coated glass spheres and measured the contact angles at isotropic (planar) and anisotropic interfaces (saddle and cylindrical in shape). Anisotropy of …

Inkjet Printing For Biosensing And Security Applications, Brian Creran

Doctoral Dissertations

The adaptation of inkjet printing technology has recently been used to create controlled high throughput micro- and nano-scaled structures. Coupling this technique with gold nanoparticles in our research has produced new platforms for biosensors, chemical patterning, and anti-counterfeiting applications. In this presentation, we will highlight promising fabrication strategies including the development of test strips for the determination of bacteria in drinking water as well as the use of patterned nanoparticles for security applications.

Impact Of Fabrication Parameters On The Internal Structure Of Poly(3-Hexylthiophene) Nanoparticles, Dana Desiree Algaier

Doctoral Dissertations

Morphological control of organic functional materials is central to understanding and improving upon current technologies. The ability to create hierarchical assemblies with purposeful design from nano to meso scale has remained largely unattainable. This body of work aims to provide a foundation for creating nanoscale domains of poly (3-hexylthiophene) (P3HT) that can be used as building blocks to larger scale assemblies. We present a method for the fabrication of P3HT nanoparticles on the ability to vary the particle size and more importantly, the internal structure. We have identified the oil phase and surfactant as parameters able to influence the nature …

Safe Reinforcement Learning, Philip S. Thomas

Doctoral Dissertations

This dissertation proposes and presents solutions to two new problems that fall within the broad scope of reinforcement learning (RL) research. The first problem, high confidence off-policy evaluation (HCOPE), requires an algorithm to use historical data from one or more behavior policies to compute a high confidence lower bound on the performance of an evaluation policy. This allows us to, for the first time, provide the user of any RL algorithm with confidence that a newly proposed policy (which has never actually been used) will perform well. The second problem is to construct what we call a safe reinforcement learning …

Estimation Problems In Complex Field Studies With Deep Interactions: Time-To-Event And Local Regression Models For Environmental Effects On Vital Rates, Krzysztof M. Sakrejda

Doctoral Dissertations

Field studies that measure vital rates in context over extended time periods are a cornerstone of our understanding of population processes. These studies inform us about the relationship between biological process and environmental noise in an irreplaceable way. These data sets bring ``big data'' and ``big model'' challenges, which limit the application of standard software (e.g., \textbf{BUGS}). The environmental sensitivity of vital rates is also expected to exhibit interactions and non-linearity, which typically result in difficult model selection questions in large data sets. Finally, long-term ecological data sets often contain complex temporal structure. In commonly applied discrete-time models complex temporal …

From Molecular Scale To Mesoscale: Establishing Structural Control Organic Photovoltaics Using Organic Nanoparticles, Timothy S. Gehan

Doctoral Dissertations

Organic photovoltaic devices use an active layer of organic materials that absorbs light and creates free charges to generate electricity. Such organic photovoltaics have many desirable properties as the final devices can be very lightweight, thin, flexible, have low manufacturing costs, and be semitransparent. These properties make them particularly advantageous for myriad of applications: e.g., use on non-planar surfaces, as tinted coatings on windows, any use for charging low power devices. One of the biggest problems preventing organic photovoltaics from being commercialized is controlling the packing of the organic materials within the active layer from the molecular scale through the …

Forensic And Management Challenges In Wireless And Mobile Network Environment, Sookhyun Yang

Doctoral Dissertations

The Internet recently passed an historic inflection point, with the number of broadband wireless/mobile devices surpassing the number of wired PCs and servers connected to the Internet. Smartphones, laptops, tablets, machine-to-machine (M2M) devices, and other portable devices have penetrated our daily lives. According to Cisco, by 2018, wired devices will account for only 39% of IP traffic, with the remaining traffic produced by wireless/mobile devices. This proliferation of wireless/mobile devices is profoundly changing many of the characteristics of network applications, protocols, and operation, and posing fundamental challenges to the Internet architecture. In light of this new trend, this thesis focuses …

Gravitational Wave Astrophysics: Instrumentation, Detector Characterization, And A Search For Gravitational Signals From Gamma-Ray Bursts, Daniel Hoak

Doctoral Dissertations

In the coming years, the second generation of interferometric gravitational wave detectors are widely expected to observe the gravitational radiation emitted by compact, energetic events in the nearby universe. The field of gravitational wave astrophysics has grown into a large international endeavor with a global network of kilometer-scale observatories. The work presented in this thesis spans the field, from optical metrology, to instrument commissioning, to detector characterization and data analysis. The principal results are a method for the precise characterization of optical cavities, the commissioning of the advanced LIGO Output Mode Cleaner at the Hanford observatory, and a search for …

Conjugated Polymers In Thermoelectric Composites And Small Molecules For High Light Absorptivity, Murat Tonga

Doctoral Dissertations

Over the past several decades with increasing of global energy demand, thermoelectric materials have gained considerable attention due to their unique ability to directly convert heat to electricity. In addition to inorganic semiconductors, polymers are potential candidates for high-performance thermoelectric applications due to their intrinsic advantages such as low thermal conductivity, solution processability, and roll-to-roll production, lightweight, and flexible thermoelectric modules. This thesis provides an insight into the emerging field of organic thermoelectrics, more specifically, thermoelectric power generation based on the composites of conducting polymers (MEH-PPV, P3HT and PEDOT:PSS) and carbon nanotubes (SWNT, SWNT-COOH, SWNT-OH and MWNT). A substantial portion …

Exact Solutions In Gravity: A Journey Through Spacetime With The Kerr-Schild Ansatz, Benjamin Ett

Doctoral Dissertations

The Kerr-Schild metric ansatz can be expressed in the form $g_{ab} = \gbar_{ab}+\lambda k_ak_b$, where $\gbar_{ab}$ is a background metric satisfying Einstein's equations, $k_a$ is a null-vector, and $\lambda$ is a free parameter. It was discovered in 1963 while searching for the elusive rotating black hole solutions to Einstein's equations, fifty years after the static solution was found and Einstein first formulated his theory of general relativity. While the ansatz has proved an excellent tool in the search for new exact solutions since then, its scope is limited, particularly with respect to higher dimensional theories. In this thesis, we present …

Design And Implementation Of An Economy Plane For The Internet, Xinming Chen

Doctoral Dissertations

The Internet has been very successful in supporting many network applications. As the diversity of uses for the Internet has increased, many protocols and services have been developed by the industry and the research community. However, many of them failed to get deployed in the Internet. One challenge of deploying these novel ideas in operational network is that the network providers need to be involved in the process. Many novel network protocols and services, like multicast and end-to-end QoS, need the support from network providers. However, since network providers are typically driven by business reasons, if they can not get …