Physical Sciences and Mathematics Commons^™

Effect Of Quench Rate On Nanostructure And Magnetic Properties Of Prco5, Wenyong Zhang, Ralph Skomski, Xingzhong Li, Shah R. Valloppilly, Jeffrey E. Shield, David J. Sellmyer

David Sellmyer Publications

The effect of quench rate on nanostructure and magnetic properties of PrCo₅ alloy has been investigated. The increase of quench rate through wheel speed in melt spinning suppresses the formation of the secondary Pr₂Co₁₇ and Pr₅Co₁₉ phases with low magnetocrystalline anisotropy field and refines the nanostructure. This significantly improves the coercivity, remanence, and energy product. For example, increasing the wheel speed from 30 m/s to 70 m/s increases the coercivity and energy product from 3.2 kOe and 4.0 MGOe to 10.3 kOe and 13.7 MGOe, respectively. The magnetic hardening mechanism appears to be …

Kondorski Reversal In Magnetic Nanowires, Ralph A. Skomski, Eva Schubert, Axel Enders, David J. Sellmyer

David Sellmyer Publications

Magnetization reversal in nanowire systems, such as alnico-type permanent magnets, slanted columns produced by glancing-angle deposition, and nanowires embedded in alumina templates, is investigated by model calculations. The angular dependence of the domain-wall propagation is Kondorski-like, reminiscent of Kondorski pinning in bulk materials but with a somewhat different physics and consistent with Kerr hysteresis-loop measurements. Criss-cross patterning of alnicos improves the coercivity but reduces the remanence, with virtually zero net effect on energy product. Finally, we briefly discuss the wire-radius dependence of the coercivity in the context of "shape anisotropy" and the occurrence of interaction domains in alnico.

Phase Composition And Nanostructure Of Zr2Co11-Based Alloys, Y.L. Jin, Wenyong Zhang, Ralph A. Skomski, Shah R. Valloppilly, Jeffrey E. Shield, David J. Sellmyer

David Sellmyer Publications

The effect of Mo addition on phase composition and nanostructure of nanocrystalline Zr₁₆Co_84-xMo_x (x=0–2.0) melt spun at 55 m/s has been investigated. All the ribbons consist mainly of a hard magnetic Zr₂Co₁₁ phase with rhombohedral crystal structure but also contain minor amounts of soft-magnetic phases. The increase in cell volume on alloying suggests that Mo mainly enters the rhombohedral Zr₂Co₁₁ structure and occupies the Co site. Mo addition promotes the formation of the hard magnetic phase and increases its volume fraction. The mean grain size of the hard magnetic …

Structural, Magnetic, And Electron Transport Properties Of Mn3-XPtXSn (X = 0, 0.5, 1) Nanomaterials, A Nelson, Yung Huh, Parashu Kharel, Shah R. Valloppilly, Ralph A. Skomski, David J. Sellmyer

David Sellmyer Publications

The structural, magnetic, and electron-transport properties of Mn_3-xPt_xSn (x=0, 0.5, 1) nanomaterials prepared by arc-melting, melt-spinning, and annealing were investigated. It was found that the hexagonal structure is the most stable structure for Mn³Sn and the samples show an antiferromagnetic spin order at room temperature. The Pt-containing samples are mainly tetragonal but contain a small amount of other impurity phases, including hexagonal Mn³Sn and Mn₂Sn. At room temperature, the Pt-containing samples show ferri- or ferromagnetic spin order with a Curie temperature of about 370 K. The measured high-field magnetization and …

Exploring The Structural Complexity Of Intermetallic Compounds By An Adaptive Genetic Algorithm, X Zhao, M C. Nguyen, Wenyong Zhang, C Z. Wang, Matthew J. Kramer, David J. Sellmyer, Xingzhong Li, F Zhang, Liqin Ke, Vladimir P. Antropov, K M. Ho

David Sellmyer Publications

Solving the crystal structures of novel phases with nanoscale dimensions resulting from rapid quenching is difficult due to disorder and competing polymorphic phases. Advances in computer speed and algorithm sophistication have now made it feasible to predict the crystal structure of an unknown phase without any assumptions on the Bravais lattice type, atom basis, or unit cell dimensions, providing a novel approach to aid experiments in exploring complex materials with nanoscale grains. This approach is demonstrated by solving a long-standing puzzle in the complex crystal structures of the orthorhombic, rhombohedral, and hexagonal polymorphs close to the Zr₂Co_{11 …}

Magnetic Nanostructuring And Overcoming Brown’S Paradox To Realize Extraordinary High-Temperature Energy Products, Balamurugan Balasubramanian, Pinaki Mukherjee, Ralph A. Skomski, Priyanka Manchanda, Bhaskar Das, David J. Sellmyer

David Sellmyer Publications

Nanoscience has been one of the outstanding driving forces in technology recently, arguably more so in magnetism than in any other branch of science and technology. Due to nanoscale bit size, a single computer hard disk is now able to store the text of 3,000,000 average-size books, and today’s high-performance permanent magnets—found in hybrid cars, wind turbines, and disk drives—are nanostructured to a large degree. The nanostructures ideally are designed from Co- and Fe-rich building blocks without critical rare-earth elements, and often are required to exhibit high coercivity and magnetization at elevated temperatures of typically up to 180 °C for …

Size-Induced Chemical And Magnetic Ordering In Individual Fe–Au Nanoparticles, Pinaki Mukherjee, Priyanka Manchanda, Pankaj Kumar, Lin Zhou, Matthew J. Kramer, Arti Kashyap, Ralph Skomski, David J. Sellmyer, Jeffrey E. Shield

David Sellmyer Publications

Formation of chemically ordered compounds of Fe and Au is inhibited in bulk materials due to their limited mutual solubility. However, here we report the formation of chemically ordered L12-type Fe₃Au and FeAu₃ compounds in Fe–Au sub-10 nm nanoparticles, suggesting that they are equilib-rium structures in size-constrained systems. The stability of these L12-ordered Fe₃Au and FeAu₃ com-pounds along with a previously discovered L10-ordered FeAu has been explained by a size-dependent equilibrium thermodynamic model. Furthermore, the spin ordering of these three com-pounds has been computed using ab initio first-principle calculations. All ordered compounds exhibit a …

Direct Chemical Synthesis Of L10-Feptau Nanoparticles With High Coercivity, Yongsheng Yu, Pinaki Mukherjee, Yuan Tian, Xingzhong Li, David J. Sellmyer

David Sellmyer Publications

We report a facile synthesis of hard magnetic L1₀-FePtAu nanoparticles by coreduction of Fe(acac)₃, Pt(acac)₂ (acac = acetylacetonate), and gold acetate in oleylamine. In the current reaction condition, NP sizes are controlled to be 5.5 to 11.0 nm by changing the amount of Au doping. When the Au composition in the NPs is higher than 14%, the hard magnetic NPs are directly obtained without any annealing. The highest coercivity of 12.15 kOe at room temperature could be achieved for the NPs with 32% Au doping, which is much higher than the coercivities reported by the …

Positive Exchange Bias In Epitaxial Permalloy/Mgo Integrated With Si (100), S. S. Rao, J. T. Prater, Fan Wu, S. Nori, D. Kumar, Lanping Yue, Sy_Hwang Liou, Jagdish Narayan

Sy-Hwang Liou Publications

In magnetic random access memory (MRAM) devices, soft magnetic thin film elements such as permalloy (Py) are used as unit cells of information. The epitaxial integration of these elements with the technologically important substrate Si (100) and a thorough understanding of their magnetic properties are critical for CMOS-based magnetic devices. We report on the epitaxial growth of Ni_82.5Fe_17.5 (permalloy, Py) on Si (100) using a TiN/MgO buffer layer. Initial stages of growth are characterized by the formation of discrete islands that gradually merge into a continuous film as deposition times are extended. Interestingly, we find that the …

Systematic Government Access To Private-Sector Data Redux, Fred H. Cate, Christopher Kuner, Christopher Millard, Dan Jerker B. Svantesson

Articles by Maurer Faculty

No abstract provided.

Taking Stock After Four Years, Fred H. Cate, Christopher Kuner, Christopher Millard, Dan Jerker B. Svantesson

Articles by Maurer Faculty

No abstract provided.

Skyrmionic Spin Seebeck Effect Via Dissipative Thermomagnonic Torques, Alexey Kovalev

Department of Physics and Astronomy: Faculty Publications

We derive thermomagnonic torque and its “β-type” dissipative correction from the stochastic Landau-Lifshitz-Gilbert equation. The β-type dissipative correction describes viscous coupling between magnetic dynamics and magnonic current and it stems from spin mistracking of the magnetic order. We show that thermomagnonic torque is important for describing temperature gradient induced motion of skyrmions in helical magnets while dissipative correction plays an essential role in generating transverse Magnus force. We propose to detect such skyrmionic motion by employing the transverse spin Seebeck effect geometry.

Parafermion Stabilizer Codes, Utkan Güngördü, Rabindra Nepal, Alexey Kovalev

Department of Physics and Astronomy: Faculty Publications

We define and study parafermion stabilizer codes, which can be viewed as generalizations of Kitaev’s onedimensional (1D) model of unpaired Majorana fermions. Parafermion stabilizer codes can protect against lowweight errors acting on a small subset of parafermion modes in analogy to qudit stabilizer codes. Examples of several smallest parafermion stabilizer codes are given. A locality-preserving embedding of qudit operators into parafermion operators is established that allows one to map known qudit stabilizer codes to parafermion codes. We also present a local 2D parafermion construction that combines topological protection of Kitaev’s toric code with additional protection relying on parity conservation.

Demonstrating Entanglement By Testing Bell's Theorem In Majorana Wires, David E. Drummond, Alexey Kovalev, Chang-Yu Hou, Kirill Shtengel, Leonid P. Pryadko

Department of Physics and Astronomy: Faculty Publications

We propose an experiment that would establish the entanglement of Majorana zero modes in semiconductor nanowires by testing the Bell and Clauser-Horne-Shimony-Holt inequalities. Our proposal is viable with realistic system parameters, simple “keyboard” gating, and projective measurement. Theoretical models and simulation results indicate entanglement can be demonstrated with moderately accurate gate operations. In addition to providing further evidence for the existence of the Majorana bound states, our proposal could be used as an experimental stepping stone to more complicated braiding experiments.

Numerical Techniques For Finding The Distances Of Quantum Codes, Ilya Dumer, Alexey Kovalev, Leonid P. Pryadko

Department of Physics and Astronomy: Faculty Publications

We survey the existing techniques for calculating code distances of classical codes and apply these techniques to generic quantum codes. For classical and quantum LDPC codes, we also present a new linked-cluster technique. It reduces complexity exponent of all existing deterministic techniques designed for codes with small relative distances (which include all known families of quantum LDPC codes), and also surpasses the probabilistic technique for sufficiently high code rates.

Wavefront-Correction For Nearly Diffraction Limited Focusing Of Dual-Color Laser Beams To High Intensities, Baozhen Zhao, Jun Zhang, Shouyuan Chen, Cheng Liu, Grigory V. Golovin, Sudeep Banerjee, Kevin J. Brown, Jared Mills, Chad Petersen, Donald Umstadter

Donald Umstadter Publications

We demonstrate wavefront correction of terawatt-peak-power laser beams at two distinct and well-separated wavelengths. Simultaneous near diffraction-limited focusability is achieved for both the fundamental (800 nm) and second harmonic (400 nm) of Ti:sapphire-amplified laser light. By comparing the relative effectiveness of various correction loops, the optimal ones are found. Simultaneous correction of both beams of different color relies on the linear proportionality between their wavefront aberrations. This method can enable two-color experiments at relativistic intensities.

Generation Of 9 Mev Γ-Rays By All-Laser-Driven Compton Scattering With Second-Harmonic Laser Light, Cheng Liu, Grigory V. Golovin, Shouyuan Chen, Jun Zhang, Baozhen Zhao, Daniel Haden, Sudeep Banerjee, Jack Silano, Hugon Karwowski, Donald Umstadter

Donald Umstadter Publications

Gamma-ray photons with energy >9 MeV were produced when second-harmonic-generated laser light (3 eV) inverse-Compton-scattered from a counterpropagating relativistic (∼450 MeV) laser-wakefield-accelerated electron beam. Two laser pulses from the same laser system were used: one to accelerate electrons and one to scatter. Since the two pulses play very different roles in the γ-ray generation process, and thus have different requirements, a novel laser system was developed. It separately and independently optimized the optical properties of the two pulses. This approach also mitigated the deleterious effects on beam focusing that generally accompany nonlinear optics at high peak-power levels.

Parametric And Nonparametric Statistical Methods For Genomic Selection Of Traits With Additive And Epistatic Genetic Architectures, Reka Howard, Alicia L. Carriquiry, William D. Beavis

Department of Statistics: Faculty Publications

Parametric and nonparametric methods have been developed for purposes of predicting phenotypes. These methods are based on retrospective analyses of empirical data consisting of genotypic and phenotypic scores. Recent reports have indicated that parametric methods are unable to predict phenotypes of traits with known epistatic genetic architectures. Herein, we review parametric methods including least squares regression, ridge regression, Bayesian ridge regression, least absolute shrinkage and selection operator (LASSO), Bayesian LASSO, best linear unbiased prediction (BLUP), Bayes A, Bayes B, Bayes C, and Bayes Cπ. We also review nonparametric methods including Nadaraya-Watson estimator, reproducing kernel Hilbert space, support vector machine regression, …

Information In Biological Systems And The Fluctuation Theorem, Yaşar Demirel

Department of Chemical and Biomolecular Engineering: Faculty Publications

Some critical trends in information theory, its role in living systems and utilization in fluctuation theory are discussed. The mutual information of thermodynamic coupling is incorporated into the generalized fluctuation theorem by using information theory and nonequilibrium thermodynamics. Thermodynamically coupled dissipative structures in living systems are capable of degrading more energy, and processing complex information through developmental and environmental constraints. The generalized fluctuation theorem can quantify the hysteresis observed in the amount of the irreversible work in nonequilibrium regimes in the presence of information and thermodynamic coupling.

Structure And Function Of Preq1 Riboswitches, Catherine D. Eichhorn, Mijeong Kang, Juli Feigon

Department of Chemistry: Faculty Publications

PreQ₁ riboswitches help regulate the biosynthesis and transport of PreQ₁ (7-aminomethyl-7- deazaguanine), a precursor of the hypermodified guanine nucleotide queuosine (Q), in a number of Firmicutes, Proteobacteria, and Fusobacteria. Queuosine is almost universally found at the wobble position of the anticodon in asparaginyl, tyrosyl, histidyl and aspartyl tRNAs, where it contributes to translational fidelity. Two classes of PreQ₁ riboswitches have been identified (PreQ₁-I and PreQ₁-II), and structures of examples from both classes have been determined. Both classes form H-type pseudoknots upon PreQ₁ binding, each of which has distinct unusual features and modes …

Advances In Chemical And Structural Characterization Of Concretion With Implications For Modeling Marine Corrosion, Donald L. Johnson, Robert J. Deangelis, Dana J. Medlin, James D. Carr, David L. Conlin

Department of Chemistry: Faculty Publications

The Weinsnumber model and concretion equivalent corrosion rate methodology were developed as potential minimum-impact, cost-effective techniques to determine corrosion damage on submerged steel structures. To apply the full potential of these technologies, a detailed chemical and structural characterization of the concretion (hard biofouling) that transforms into iron bearing minerals is required. The fractions of existing compounds and the quantitative chemistries are difficult to determine from x-ray diffraction. Environmental scanning electron microscopy was used to present chemical compositions by means of energy-dispersive spectroscopy (EDS). EDS demonstrates the chemical data in mapping format or in point or selected area chemistries. Selectedarea EDS …

Analogues Of (-)-Picropodophyllin, Synthesis And Uses Thereof, David B. Berkowitz, Sylvain Broussy

Department of Chemistry: Faculty Publications

Analogs of (-)-Picropodophyllin, synthesis thereof, and uses in pharmaceuticals as inhibitors of IGF1RK.

Iterative Assembly Of Two Separate Polyketide Chains By The Same Single-Module Bacterial Polyketide Synthase In The Biosynthesis Of Hsaf, Yaoyao Li, Haotong Chen, Yanjiao Ding, Yunxuan Xie, Haoxin Wang, Ronald Cerny, Yuemao Shen, Liangcheng Du

Ronald Cerny Publications

HSAF (1) was isolated from the biocontrol agent Lysobacter enzymogenes (Figure 1).^[1-4]

This bacterial metabolite belongs to polycyclic tetramate macrolactams (PTM) that are

emerging as a new class of natural products with distinct structural features. ^{[5, 6]} HSAF

exhibits a potent antifungal activity and shows a novel mode of action.^[1-4] The HSAF

biosynthetic gene cluster contains only a single-module hybrid polyketide synthasenonribosomal

peptide synthetase (PKS-NRPS), although the PTM scaffold is apparently

derived from two separate hexaketide chains and an ornithine residue.^[1-4] This suggests that

the same PKS module would act not only iteratively, but also …

Photocatalytic Hydrogen Production From A Noble Metal Free System Based On A Water Soluble Porphyrin Derivative And A Cobaloxime Catalyst, Theodore Lazarides, Milan Delor, Igor V. Sazanovich, Theresa M. Mccormick, Irene Georgakaki, Georgios Charalambidis, Julia A. Weinstein, Athanassios G. Coutsolelos

Chemistry Faculty Publications and Presentations

A combination of noble-metal free components, a water soluble porphyrin photosensitizer zincmeso-tetrakis(1-methylpyridinium-4-yl)porphyrin chloride [ZnTMPyP⁴⁺]Cl₄ (1) with cobaloxime complex [Co^III(dmgH)₂(py)Cl] (2) as a catalyst, creates an efficient system for photochemical hydrogen production acting under visible light with 280 TONs. This is the first example of a water soluble porphyrin acting as a photosensitizer for cobaloxime catalysed H₂ production.

Loess Records, Daniel R. Muhs, Stephen R. Cattle, Onn Crouvi, Denis-Didier Rousseau, Jimin Sun, Marcelo A. Zárate

United States Geological Survey: Staff Publications

Loess is aeolian sediment, dominated by silt-sized particles, that is identifiable in the field as a distinct sedimentary body. It covers a significant portion of the land surface of the Earth and as such constitutes one of the most important archives of long-term dust deposition. Large tracts of loess cover Europe, Asia, South America, and North America, and smaller loess bodies are found covering parts of Africa, the Middle East, New Zealand, and Australia. Loess thickness, particle size, and carbonate content decrease downwind from sources, trends that are powerful tools for reconstructing paleowinds. Many loess sections consist of relatively thick …

Evidence Of Repeated Wildfires Prior To Human Occupation On San Nicolas Island, California, Jeffrey S. Pigati, John P. Mcgeehin, Gary L. Skipp, Daniel R. Muhs

United States Geological Survey: Staff Publications

Understanding how early humans on the California Channel Islands might have changed local fire regimes requires a baseline knowledge of the frequency of natural wildfires on the islands prior to human occupation. A sedimentary sequence that was recently discovered in a small canyon on San Nicolas Island contains evidence of at least 24 burn events that date to between ~37 and 25 ka (thousands of calibrated ¹⁴C years before present), well before humans entered North America. The evidence includes abundant macroscopic charcoal, blackened sediments, and discrete packages of oxidized, reddish-brown sediments that are similar in appearance to sedimentary features …

Nongeocentric Axial Dipole Field Behavior During The Mono Lake Excursion, Robert M. Negrini, Daniel T. Mccuan, Robert A. Horton, James D. Lopez, William S. Cassata, James E. T. Channell, Kenneth L. Verosub, Jeffrey R. Knott, Robert S. Coe, Joseph C. Liddicoat, Steven P. Lund, Larry Benson, Andrei M. Sarna-Wojcicki

United States Geological Survey: Staff Publications

A new record of the Mono Lake excursion (MLE) is reported from the Summer Lake Basin of Oregon, USA. Sediment magnetic properties indicate magnetite as the magnetization carrier and imply suitability of the sediments as accurate recorders of the magnetic field including relative paleointensity (RPI) variations. The magnitudes and phases of the declination, inclination, and RPI components of the new record correlate well with other coeval but lower resolution records from western North America including records from the Wilson Creek Formation exposed around Mono Lake. The virtual geomagnetic pole (VGP) path of the new record is similar to that from …

Wetland Reserve Program Enhances Site Occupancy And Species Richness In Assemblages Of Anuran Amphibians In The Mississippi Alluvial Valley, Usa, Susan C. Walls, J. Hardin Waddle, Stephen P. Faulkner

United States Geological Survey: Staff Publications

We measured amphibian habitat use to quantify the effectiveness of conservation practices implemented under the Wetland Reserve Program (WRP), an initiative of the U.S. Department of Agriculture’s Natural Resources Conservation Service. From February to June 2007, we quantified calling male anurans in cultivated cropland, former cultivated cropland restored through the WRP, and mature bottomland hardwood forest. Sites were located in two watersheds within the Mississippi Alluvial Valley of Arkansas and Louisiana, USA. We estimated detection probability and site occupancy within each land use category using a Bayesian hierarchical model of community species occurrence, and derived an estimate of species richness …

Mapping Irrigated Areas In Afghanistan Over The Past Decade Using Modis Ndvi, Md. Shahriar Pervez, Michael Budde, James Rowland

United States Geological Survey: Staff Publications

Agricultural production capacity contributes to food security in Afghanistan and is largely dependent on irrigated farming, mostly utilizing surface water fed by snowmelt. Because of the high contribution of irrigated crops (> 80%) to total agricultural production, knowing the spatial distribution and year-to-year variability in irrigated areas is imperative to monitoring food security for the country. We used 16-day composites of the Normalized Difference Vegetation Index (NDVI) from the Moderate Resolution Imaging Spectroradiometer (MODIS) sensor to create 23-point time series for each year from 2000 through 2013. Seasonal peak values and time series were used in a threshold-dependent decision tree …

Maintaining Resilience In The Face Of Climate Change, Alejandro E. Camacho, T. Douglas Beard

United States Geological Survey: Staff Publications

Climate change, when combined with more conventional stress from human exploitation, calls into question the capacity of both existing ecological communities and resource management institutions to experience disturbances while substantially retaining their same functions and identities (Zellmer and Gunderson 2009; Ruhl 2011). In other words, the physical and biological effects of climate change raise fundamental challenges to the resilience of natural ecosystems (Gunderson and Holling 2002). Perhaps more importantly, the projected scope of ecological shifts from global climate change-and uncertainty about such changes-significantly stresses the capacity of legal institutions to manage ecosystem change (Camacho 2009). Existing governmental institutions lack the …