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Full-Text Articles in Physical Sciences and Mathematics

Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method, Guo-Qing Fang, Rui-Xue Zhang, Wei-Wei Liu, Bing-Bo Xia, Hong-Dan Sun, Hai-Bo Wang, Jing-Jing Wu, Shinko Kaneko, De-Cheng Li Dec 2013

Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method, Guo-Qing Fang, Rui-Xue Zhang, Wei-Wei Liu, Bing-Bo Xia, Hong-Dan Sun, Hai-Bo Wang, Jing-Jing Wu, Shinko Kaneko, De-Cheng Li

Journal of Electrochemistry

The amorphous ZnSnO3@C composite was synthesized via a simple glucose hydrothermal and subsequent carbonization approach. The structure, morphology and electrochemical property of the composite were characterized by XRD, TEM and electrochemical measurements. Compared to bare ZnSnO3, the ZnSnO3/C composite exhibited markedly enhanced lithium storage property and cycle performance, delivering a reversible capacity of 659 mAh·g-1 after 100 cycles at a current density of 100 mA·g-1.


Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia Dec 2013

Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia

Journal of Electrochemistry

We adopted an effective route to prepare the particle size controllable core-shell structure carbon-coated LiFePO4 from different sized FePO4 precursors, varying from 80 nm, 200 nm and 1 μm by an in situ polymerization method integrated with a surface modification technology. The discharge capacities of the three sized LiFePO4/C are, respectively, 162 mAh·g-1, 142 mAh·g-1 and 92 mAh·g-1 at 0.1C rate. The nano-sized LiFePO4-a/C (80 nm) delivers a discharge capacity as large as 100 mAh·g-1 even at 30C, while the macroscopic LiFePO4-c/C (1 μm) exhibits a much poorer discharge …


Design And Assembly Of Nanostructured Complex Metal Oxide Materials For The Construction Of Batteries And Thermoelectric Devices, Gautam Ganapati Yadav Oct 2013

Design And Assembly Of Nanostructured Complex Metal Oxide Materials For The Construction Of Batteries And Thermoelectric Devices, Gautam Ganapati Yadav

Open Access Dissertations

Thermoelectric devices and lithium-ion batteries are among the fastest growing energy technologies. Thermoelectric devices generate energy from waste heat, whereas lithium-ion batteries store energy for use in commercial applications. Two different topics are bound with a common thread in this thesis - nanotechnology! In fact, nanostructuring is a more preferred term for the approach I have taken herein. Another commonality between these two topics is the material system I have used to prove my hypotheses - complex metal oxides.

Complex metal oxides can be used for both energy generation and storage as they are stable at high temperatures, are benign …


Fluorous- Phase Synthesis Of Heparan Sulfate Disaccharides & Low-Molecular Weight Additives For Enhancing The Performance Of Lithium-Ion Batteries., Matthew Daniel Casselman Oct 2013

Fluorous- Phase Synthesis Of Heparan Sulfate Disaccharides & Low-Molecular Weight Additives For Enhancing The Performance Of Lithium-Ion Batteries., Matthew Daniel Casselman

Open Access Dissertations

Heparan sulfate is a complex cell-surface proteoglycan that serves many important roles in biology, such as growth and development, immune response and pathogenesis. Heparan sulfate is structurally heterogeneous due to the variable post- glycosylation modifications, particularly the generation of diverse sets of sulfate esters (sulfoforms) for any given disaccharide unit. In order to establish useful relationships between heparan sulfate structure and biological activity, a set of well-defined sulfoforms is necessary to support binding affinity screening. In this thesis, we describe the generation of diverse sulfoforms from heparan disaccharides using a fluorous tag to facilitate purification of highly charged intermediates, and …


Electrochemical Performance Of Lifepo4/C Synthesized Via Aqueous Solution-Evaporation Route, Ning-Yu Gu, Xing-Hua He, Yang Li Apr 2013

Electrochemical Performance Of Lifepo4/C Synthesized Via Aqueous Solution-Evaporation Route, Ning-Yu Gu, Xing-Hua He, Yang Li

Journal of Electrochemistry

The LiFePO4/C samples have been synthesized via an aqueous solution-evaporation route with LiH2PO4, FeC2O4.2H2O as raw materials and citric acid as a carbon source. X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were used to analyze structure and morphology of the samples. The electrochemical performances of the LiFePO4/C cathodes were characterized by charge/discharge cures and electrochemical impedance spectroscopy (EIS). The results show that the LiFePO4/C sample, calcined at 700 °C and contained 3.03% (by mass) carbon, exhibited a highly pure …


Lithium-Ion Batteries, Aaron Reed Jan 2013

Lithium-Ion Batteries, Aaron Reed

Natural Sciences Student Research Presentations

Summarizes the history of lithium-ion batteries, and their uses. This is a project for the Natural Sciences Poster Session at Parkland College.