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Full-Text Articles in Physical Sciences and Mathematics
Synthesis, Structural Variations And Trends In The Properties Of Unique Dinuclear And Polynuclear Complexes Of Bis(Pyrazolyl)Methane Ligands In Solid State And Solution, Andrea Eva Pascui
Synthesis, Structural Variations And Trends In The Properties Of Unique Dinuclear And Polynuclear Complexes Of Bis(Pyrazolyl)Methane Ligands In Solid State And Solution, Andrea Eva Pascui
Theses and Dissertations
The semi-rigid ligands, p-[CH(pz)2]2C6H4, Lp, m-[CH(pz)2]2C6H2, Lm, and m-[CH(3,5-Me2pz)2]2C6H4, Lm* (pz = pyrazolyl ring), link two bis(pyrazolyl)methane units into a single molecule by a rigid phenylene spacer and are used to study the structural variations and magnetic interactions in self-assembled first row, divalent transition metal complexes in polymeric, dinuclear and dinuclear metallacyclic settings. The formation of these architectures highly depend on the geometry of these ligands: anti, the …
Metallization Of Dna And Dna Origami Using A Pd Seeding Method, Yanli Geng
Metallization Of Dna And Dna Origami Using A Pd Seeding Method, Yanli Geng
Theses and Dissertations
In this dissertation, I developed a Pd seeding method in association with electroless plating, to successfully metallize both lambda DNA and DNA origami templates on different surfaces. On mica surfaces, this method offered a fast, simple process, and the ability to obtain a relatively high yield of metallized DNA nanostructures. When using lambda DNA as the templates, I studied the effect of Pd(II) activation time on the seed height and density, and an optimal activation time between 10 and 30 min was obtained. Based on the Pd seeds formed on DNA, as well as a Pd electroless plating solution, continuous …