Physical Sciences and Mathematics Commons^™

Thin Film Solar Cells Using Zno Nanowires, Organic Semiconductors And Quantum Dots, Kaitlyn Vansant

Dissertations and Theses

A thin film organic/ inorganic hybrid solar cell was fabricated by incorporating ZnO nanowires, n- and p-type organic semiconductors and inorganic quantum dots. The basic cell design involved the electrodeposition of ZnO nanowires grown on a substrate coated with a transparent conductive oxide. The ZnO nanowires were coated with a thin layer of an organic n-type material, followed by a deposition of inorganic quantum dots. A p-type polymer layer was subsequently deposited and the sample was then contacted with gold to form a quantum dot layer sandwiched between a p-n junction of organic conductive materials.

Various materials and processing methods …

Selective Growth Of Single-Crystalline Zno Nanowires On Doped Silicon, Rolf Könenkamp, Robert Campbell Word, M. Dosmailov, J. Meiss, Athavan Nadarajah

Physics Faculty Publications and Presentations

We report the growth of single-crystalline ZnO nanowires on n- and p-type Si wafers by electrodeposition. On strongly doped n-type Si high-quality nanowires can be grown under similar conditions as used for metallic substrates. For low electron concentrations occurring in weakly n-type or in p-type wafers, nanowire growth is inhibited. This difference allows selective growth in strongly n-type areas. The inhibited growth on weakly n-type and p-type wafers can be improved by applying stronger cathodic electrode potentials or by illuminating the growth area. The wires on n-Si show efficient electroluminescence covering the visible and extending into the ultraviolet spectral range.