Physical Sciences and Mathematics Commons^™

Biological, Clinical, And Forensic Analysis Using Comprehensive Two-Dimensional Gas Chromatography, Nicholas Snow

Nicholas A Snow

No abstract provided.

Controlling The Inhibition Of The Sarcoplasmic Ca2+-Atpase By Tuning Phospholamban Structural Dynamics, Kim Ha, Nathaniel J. Traaseth, Raffaello Verardi, Jamillah Zamoon, Alessandro Cembran, Christine B. Karim, Gianluigi Veglia

Kim N. Ha, Ph.D.

No abstract provided.

Structural Characterization Of Al10O6IBu16(Μ-H)2, A High Aluminum Content Cluster:  Further Studies Of Methylaluminoxane (Mao) And Related Aluminum Complexes, Feng-Jeng Wu, Larry S. Simeral, Anthony A. Mrse, Jan L. Eilertsen, Lacramioara Negureanu, Zhehong Gan, Frank R. Fronczek, Randall W. Hall, Leslie G. Butler

Randall W. Hall

Differences In Electrochemical Properties Of Contact Printed And Solution Adsorbed Alkanehtiol Self-Assembled Monolayers On Gold, Leslie Adamczyk, Mark Anderson

Mark R. Anderson

No abstract is currently available.

Effects Of Potential On Ionic Self-Assembly Of Carboxylic Acid Terminated Monolayers, Wesley Sanders, Mark Anderson

Mark R. Anderson

No abstract is currently available.

Functional Mechanisms Of Motor Skill Acquisition, Ashvin Shah, Andrew G. Barto

Andrew G. Barto

No abstract provided.

Characterization Of Metal-Reducing Enzymes Expressed By The Bacterium Shewanella Algae Under Anaerobic Conditions, Thomas Goyne, Deborah Steffen, Miriam Conces, Amanda Nosie

Thomas Goyne

No abstract provided.

High-Loading Nanosized Micelles Of Copoly(Styrene-Maleic Acid)-Zinc Protoporphyrin For Targeted Delivery Of A Potent Heme Oxygenase Inhibitor., Arun Iyer

Arun Iyer

Amphiphilic styrene-maleic acid (SMA) copolymer efficiently formed micelles with a potent heme oxygenase inhibitor-zinc protoporphyrin (ZnPP). The micelles were constructed by subtle pH adjustments to form non-covalent interaction between the hydrophobic ZnPP and amphiphilic SMA. The micelles (SMA-ZnPP) thus formed were nanoparticles with narrow size distribution in water (mean diameter 176.5nm), having tunable loading (from 15% to 60% w/w of ZnPP) with remarkable aqueous solubility. SMA-ZnPP had an average molecular size of 144kDa as determined by size-exclusion chromatography (SEC), this size is a marked increase from the molecular weight of free ZnPP (626.03Da), suggesting the formation of micellar structure. The …

Modification Of A Capillary For Electrophoresis By Electrostatic Self-Assembly Of An Enzyme For Selective Determination Of The Enzyme Substrate, Stephanie Hooper, Mark Anderson

Mark R. Anderson

The integration of a separation capillary for capillary electrophoresis (CE) with an on-column enzyme reaction for selective determination of the enzyme substrate is described. Enzyme immobilization is achieved by electrostatic assembly of poly(diallydimethylammonium chloride) (PDDA) followed by adsorption of a mixture of the negatively charged enzyme glucose oxidase (GOx) and anionic poly(styrenesulfonate) (PSS). The reaction of glucose with the GOx produces hydrogen peroxide which migrates the length of the capillary and is detected amperometrically at the capillary outlet. The enzyme reaction occurs during a capillary separation, allowing selective determination of the substrate in complex samples without the need for pre- …

Generation Of An On-Capillary Enzyme Reactor Coupled To Capillary Electrophoresis For The Selective Detection Of The Enzyme Substrate, Stephanie Hooper, Mark Anderson

Mark R. Anderson

No abstract is currently available.

Electrochemical Impedance Spectroscopy To Evalutate The Effects Of Ph Variations And Ionic Self-Assembly On Undecanoic Acid Monolayers Immobilized On Gold, Mark Anderson, Wesley Sanders

Mark R. Anderson

No abstract is currently available.

Tuning Nonlinear Optical Properties, T. Christopher Corkery, Marie P. Cifuentes, Marek Samok, Mark G. Humphrey

Chris Corkery

No abstract provided.

Thermochemistry Of 2- And 3-Acetylthiophenes: Calorimetric And Computational Study., María Victoria Roux, Manuel Temprado, And Pilar Jiménez, Rafael Notario, James S. Chickos, Ana Filipa L. O. M. Santos And, Manuel A. V. Ribeiro Da Silva

James Chickos

No abstract provided.

Calorimetric And Computational Study Of Indanones, M. Agostinha R. Matos, Margarida S. Miranda, Manuel J. S. Monte, Luis M. N. B. F. Santos, Victor M. F. Morais, James S. Chickos, Patamaporn Umnahanant, Joel F. Liebman

James Chickos

No abstract provided.

Experimental And Computational Thermochemical Study Of 2-And 3-Thiopheneacetic Acid Methyl Esters, Manuel Temprado, Rafael Notario, James S. Chickos, Ana Filipa, L. O. M. Santos, Manuel A. V. Ribeiro Da Silva

James Chickos

No abstract provided.

Crystal Structure Of A N-Butyllithium : 1,2-Dipiperidinoethane Dimer Complex, Michael Nichols, Rachel Sobinsky, Allen Hunter, Matthias Zeller

Michael A Nichols

No abstract provided.

Review Of Kitchen Chemistry., Chrystal Bruce

Chrystal D. Bruce

This book contains many modules emphasizing truly important concepts in chemistry: intermolecular forces, structure, reactivity, solubility. The experiments offered exemplify the recurring phrase, “familiar chemistry in an unfamiliar place.”

Crystal Structures O Hexameric And Dimeric Complexes Of Lithiosobutyrophenone., Michael Nichols, Christina Leposa, Allen Hunter, Matthias Zeller

Michael A Nichols

No abstract provided.

Analytical Chemistry: Theoretical And Metrological Fundamentals, Mark Anderson

Mark R. Anderson

Review of the book "Analytical Chemistry: Theoretical and Metrological Fundamentals," by K. Danzer. Springer: Berlin, Heidelberg, New York. 2007.

Well-Resolved Coherent Raman Spectra From Femtosecond Pulses, Sukhendu Nath, Diana Urbanek, Sean Kern, Mark Berg

Sean J. Kern

This paper demonstrates a method for measuring coherent anti-Stokes Raman spectra with a resolution limited only by the inherent linewidth of the sample, even when using pulses of a width (60 fs, 300 cm−1) that is between the widths needed for a pure frequency- or time-domain measurement. Data are collected as a function of both delay and frequency and used to recover a standard Raman spectrum. The resulting time/frequency detected experiment represents a bridge between standard time- and frequency-domain approaches to spectroscopy.

Simultaneous Time And Frequency Detection In Femtosecond Coherent Raman Spectroscopy, Sukhendu Nath, Diana Urbanek, Sean Kern, Mark Berg

Sean J. Kern

The preceding paper showed that, in principle, a high-resolution coherent Raman spectrum can be recovered using femtosecond probe pulses by combined detection in both time and frequency. This measurement is possible even when the pulses are too broad in frequency for conventional frequency-domain spectroscopy and too broad in time for conventional time-domain spectroscopy. In this paper, the method is tested on experimental coherent anti-stokes Raman spectroscopy data from acetonitrile. Compared to theoretical models, experimental data are complicated by noise and incomplete knowledge of the pulse structure. Despite these complications, most of the information in the Raman spectrum is recovered from …

Synthesis Of Homoallyl Ethers Via Allylation Of Acetals And Aldehydes In Ionic Liquids, Ram Mohan, Peter Anzalone

Ram S. Mohan

The TMS triflate catalyzed allylation of acetals to yield homoallyl ethers proceeds smoothly at room temperature in ionic liquids. A one-pot method for the conversion of aldehydes to homoallyl ethers in an ionic liquid has also been developed. This methodology is attractive because it allows allylations to be carried out at room temperature. Ionic liquids offer a convenient replacement for CH₂Cl₂, the commonly used solvent for such reactions.

Iron(Iii) P-Toluenesulfonate Catalyzed Synthesis Of Homoallyl Ethers From Acetals And Aldehydes, Ram S. Mohan, Matthew J. Spafford, Erin D. Anderson, Joshua R. Lacey, Ann C. Palma

Ram S. Mohan

Reactivity Of Ionic Liquids, Ram S. Mohan, Shahana Chowdhury, Janet L. Scott

Ram S. Mohan

An Empirical Study Of The Sources Affecting E-Business Value Creation In Jordanian Banking Services Sector, Philadelphia University

Philadelphia University, Jordan

No abstract provided.

Determination Of Labetalol Hydrochloride In Drug Formulations By Spectrophotometry, Habibur Rahman Dr.

Habibur Rahman

No abstract provided.

Synthesis, Physico-Chemical And Spectroscopic Investigations Of Sodium Dihydrobis(1,2,3-Benzotriazolyl)Borate Ligand And Its Transition Metal Complexes, Mohammad Mansoob Khan Dr, M. M. Rahman, Y. B. Hahn

Dr. Mohammad Mansoob Khan

The title ligand, sodium dihydrobis(1,2,3-benzotriazolyl) borate, Na[H2B(BTz)2],was synthesized by refluxing 1 mole of sodium borohydride with 2 moles of 1,2,3- benzotriazole in toluene. The ligand shows ample reactivity towards Cr(III), Mn(II), Fe(III), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) metal ions and forms stable complexes. The ligand and its metal complexes were characterized by physico-hemical and spectroscopic techniques. All the complexes of divalent metal ions are tetrahedral except for Cu(II), which has been proposed to have a square-planar geometry. The complexes of Cr(III) and Fe(III) appear to have an octahedralge ometry. The magnitude of molar conductance of 10−3 M …

The Translation Of Some Metaphorical Expressions In Shakespeare's Hamlet, Philadelphia University

Philadelphia University, Jordan

No abstract provided.