Physical Sciences and Mathematics Commons^™

Enantioselective Synthesis Of The C11–C17 Segment Of Soraphen A1Α Via Organoiron Methodology, Yeyu Cao, Ahmad F Eweas, William A. Donaldson

Chemistry Faculty Research and Publications

The C11–C17 segment of the antifungal agent soraphen A_1α was prepared from glyceraldehyde acetonide in nine steps. The C12 stereocenter is derived from glyceraldehyde, while the C17 stereocenter as introduced by 1,6-asymmetric control via the coordinated Fe(CO)₃.

The C11–C17 segment of the antifungal agent soraphen A1α, with required inverted stereochemistry at C17, was prepared. The C12 stereocenter is derived from glyceraldehyde, while the C17 stereocenter is introduced by 1,6-asymmetric induction via a coordinated Fe(CO)₃.

Performance Evaluation Of Path Searching Heuristics For Multicast Qos Routing, Daniel Zappala, Dayi Zhou

Faculty Publications

Quality of Service routing for multicast enables a group member to find and install a branch of the multicast tree that can meet its QoS constraints. The most promising protocols in this area use receiver-oriented path searching heuristics to find feasible routes. In this paper, we examine the performance of the path searching heuristics used by these protocols, to determine which techniques are the most effective. We find that several low-overhead path searching heuristics are effective, and that generic path searching can work as well as targeted, QoS-specific searching.

Advanced Portfolio Theory: Why Understanding The Math Matters, Tom Arnold

Finance Faculty Publications

The goal of this paper is to motivate the use of efficient set mathematics for portfolio analysis [as seen in Roll, 1977] in the classroom. Many treatments stop at the two asset portfolio case (avoiding the use of matrix algebra) and an alarming number of treatments rely on illustration and templates to provide a heuristic sense of the material without really teaching how efficient portfolios are generated. This is problematic considering that the benefits of understanding efficient set mathematics go beyond portfolio analysis and into such topics as regression analysis (as demonstrated here).

Earth News, V26, Fall 2002, Department Of Earth Science, University Of Northern Iowa.

Earth News

Inside this issue:

--- Earth Science Staff Activities
--- STORM Curriculum Development Update
--- Earth Science Majors
--- Earth Science Student Assistants
--- Earth Science Seminar Series
--- Sigma Gamma Epsilon - Gamma Sigma Chapter
--- Summer 2002 Field Course "Paleontology in the Canadian Rockies"
--- Studies in the Geology of Iowa for Teachers
--- Workshop Teaches Educators the Value of Aggregates
--- Quarry Open House is a Smash Hit
--- 2002 Earth Science Graduates
--- Student Internships
--- Student Research Presentations
--- Gifts to the Department of Earth Science
--- 2002-2003 Scholarship and Award Recipients
--- President Bush Meets …

Object-Oriented Architecture For Concurrent Processes In A Port Simulation, Reejo Mathew

Electrical & Computer Engineering Theses & Dissertations

An architectural model to represent the resources and infrastructure within a cargo terminal, as well as to support the concurrent but opposite flow of cargo within the terminal, is presented in this thesis. The model supports the configuration of an individual cargo terminal according to its characteristics, as well as the processing involved in the simultaneous flow of cargo in opposite directions through the terminal. This is useful in the analysis of the flow of military cargo and aids the decision-making process to increase the efficiency and throughput of any military operation. This model has been developed with the aim …

A Comparison Of The Low Mode And Monte Carlo Conformational Search Methods, Carol A. Parish, Rosina Lombardi, Kent Sinclair, Emelyn Smith, Alla Goldberg, Melissa Rappleye, Myrianne Dure

Chemistry Faculty Publications

The Low Mode (LM) and Monte Carlo (MC) conformational search methods were compared on three diverse molecular systems; (4R, 5S, 6S, 7R)-hexahydro-5,6-dihydroxy-1,3,4,7-tetrakis(phenylmethyl)-2H-1,3-diazapin-2-one (1), 2-methoxy-2-phenyl-2-triflouromethyl-N-α-methyl benzyl propanamide (2) and a trimeric 39-membered polyazamacrolide (3). We find that either method, or a combination of the methods, is equally efficient at searching the conformational space of the smaller molecular systems while a 50:50 hybrid of Low Mode and Monte Carlo is most efficient at searching the space of the larger molecular system.

Cache Invalidation And Replacement Strategies For Location-Dependent Data In Mobile Environments, Baihua Zheng, Jianliang Xu, Dik Lun Lee

Research Collection School Of Computing and Information Systems

Mobile location-dependent information services (LDISs) have become increasingly popular in recent years. However, data caching strategies for LDISs have thus far received little attention. In this paper, we study the issues of cache invalidation and cache replacement for location-dependent data under a geometric location model. We introduce a new performance criterion, called caching efficiency, and propose a generic method for location-dependent cache invalidation strategies. In addition, two cache replacement policies, PA and PAID, are proposed. Unlike the conventional replacement policies, PA and PAID take into consideration the valid scope area of a data value. We conduct a series of simulation …

Compact Focusing Von Hamos Spectrometer For Quantitative X-Ray Spectroscopy, Larry V. Knight, A. P. Shevelko, Yu S. Kasyanov, O. F. Yakushev

Faculty Publications

A compact focusing crystal spectrometer based on the von Hamos scheme is described. Cylindrically curved mica and graphite crystals with a radius of curvature of R = 20 mm are used in the spectrometer. A front illuminated charge-coupled device (CCD) linear array detector makes this spectrometer useful for real-time spectroscopy of laser-produced plasma x-ray sources within the wavelength range of lambda= 1.8-10 Angstroms. Calibration of crystals and the CCD linear array makes it possible to measure absolute photon fluxes. X-ray spectra in an absolute intensity scale were obtained from Mg, Ti, and Fe laser-produced plasmas, with a spectral resolution lambda/delta …

Bluetooth: An Emerging Technology For Wireless Personal Area Networks, Eric S. Hall, Charles D. Knutson, David K. Vawdrey

Faculty Publications

Look under your desk or behind your computer. See that rat’s nest of wires and cables? Almost every cable or wire that tethers us to our devices (or our devices to one another) is unnecessary. Bluetooth wireless technology promises to reduce the cabling chaos that afflicts us all. Bluetooth is a recently developed technology that uses radio frequency (RF) transceivers to provide point-to-multipoint wireless connectivity within a personal space. Bluetooth was designed for both voice and data communication at low per-unit costs while consuming little power. To achieve the cost and power goals, Bluetooth limits connectivity to a sphere of …

Mobile Information Systems – Research Directions On The Conceptual And Logical Level, J. Krogstie, K. Lyytinen, A. Opdahl, B. Pernici, Keng Siau, K. Smolander

Research Collection School Of Computing and Information Systems

This paper discusses new challenges and possible approaches for developing and evolving mobile information systems, with focus on model-based approaches on the conceptual and logical level. We have experienced these new challenges through several research and industrial projects on mobile solutions, usability and model-based approaches over the last years. We summarize the main challenges on how model-based approaches can support the development of mobile information systems that are to be used together with other types of systems, primarily in a professional setting and indicate upcoming research issues in this very dynamic area. We argue that this research area is also …

Approaching High Fidelity Human Tracking And Representation In Interactive Virtual Environments, Taimur K. Khan

Electrical & Computer Engineering Theses & Dissertations

This thesis revolves around an Office of Naval Research (ONR) grant known as Virtual Environments for Training (VET). The primary goal is to determine the effectiveness of an immersive environment for training; the secondary goal is to compare the results of this study to a similar study conducted in an environment that is less immersive.

Effectiveness will be determined by the performance of trainees manning a virtual military checkpoint. A four-wall immersive environment employing cave technology will be compared to a three dimensional desktop version of the scenarios employed in the more immersive environment. In order to make this comparison, …

A Multilevel Neural Network Architecture For Digital Implementation Of A Face Recognition System Based On Eigenface Approach, Linda Rajan

Electrical & Computer Engineering Theses & Dissertations

The design and development of the digital implementation of a multilevel feed forward neural network architecture for face recognition based on statistical features representing Eigenfaces is presented in this thesis. The architecture is divided into three parts: feature extractor, classifier and identifier, The Eigenface extractor architecture is developed based on an efficient design strategy in which all the M weight values corresponding to the Eigenfaces are generated simultaneously from M images representing the Eigen vectors and the test input image. The multilayer neural network classifier is trained using error backpropagation algorithm. A novel multilevel digital architecture is developed for the …

Sustainability Issues For Agriculture In Western Australia, Anne Bennett, Ross Kingwell, Ross George

All other publications

Agriculture has been and will continue to be a major component of economic activity in several regions in Western Australia, and agricultural communities will remain an important part of the social fabric and landscape of the State. Promoting the sustainability of agriculture is likely to produce three main outcomes: vibrant rural communities; profitable agricultural systems; and conservation of the natural environment.

This paper describes briefly the main challenges to the sustainability of agriculture and outlines some means of responding to the challenges: market-based approaches; agricultural and environmental research and development; accelerated adjustment; and global and national policy initiatives.

A Novel Approach For The Analysis Of High Frequency Vibrations, G. W. Wei, Yibao Zhao, Y. Xiang

Research Collection Lee Kong Chian School Of Business

Despite much effort in the past few decades, the numerical prediction of high-frequency vibrations remains a challenging task to the engineering and scientific communities due to the numerical instability of existing computational methods. However, such prediction is of crucial importance to certain problems of pressing practical concern, as pointed out by Langley and Bardell (1998 The Aeronautical Journal102, 287-297). This paper introduces the discrete singular convolution (DSC) algorithm for the prediction and analysis of high-frequency vibration of structures. Both a beam and two-span plates are employed as test examples to demonstrate the capability of the DSC algorithm for high-frequency vibration …

The Kpss Test With Seasonal Dummies, Sainan Jin, Sainan Jin

Research Collection School Of Economics

It is shown that the KPSS test for stationarity may be applied without change to regressions with seasonal dummies. In particular, the limit distribution of the KPSS statistic is the same under both the null and alternative hypotheses whether or not seasonal dummies are used.

The Analysis Of Placement Values For Evaluating Discriminatory Measures, Margaret S. Pepe, Tianxi Cai

UW Biostatistics Working Paper Series

The idea of using measurements such as biomarkers, clinical data, or molecular biology assays for classification and prediction is popular in modern medicine. The scientific evaluation of such measures includes assessing the accuracy with which they predict the outcome of interest. Receiver operating characteristic curves are commonly used for evaluating the accuracy of diagnostic tests. They can be applied more broadly, indeed to any problem involving classification to two states or populations (D = 0 or D = 1). We show that the ROC curve can be interpreted as a cumulative distribution function for the discriminatory measure Y in the …

On-Site Sewage Disposal Systems & Septage Management For Individual Homes And Small Communities, James R. Hegarty

Watershed Management Plans and Reports

The purpose of this paper is two-fold:

To identify alternatives and/or improvements to conventional septic systems for residential sewage collection and treatment for small communities and residential developments.

To research existing ordinances that require on-going management of residential and community septic systems, disposal of septage, and develop a model septic system and septage management ordinance that can apply to Kent County communities.

It is hoped that this study’s recommendations will be adopted in Kent County. Eventually, Kent County’s model program can be used to effect statewide implementation of responsible environmental policies that will improve our environment and public health. The …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications: Annual Progress Report (September 2001 – August 2002), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. This alloy has been proven to be an excellent structural material to contain the lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. Very little data exist in the open literature on the tensile properties of this alloy. The test material will be thermally treated prior to the evaluation of its tensile properties at temperatures relevant to the transmutation applications. The deformation characteristics of tensile specimens, upon completion of testing, will be evaluated by surface …

Development Of A Systems Engineering Model Of The Chemical Separations Process, Yitung Chen, Randy Clarksean, Darrell Pepper

Separations Campaign (TRP)

The AAA program is developing technology for the transmutation of nuclear waste to address many of the long-term disposal issues. An integral part of this program is the proposed chemical separations scheme. This process, as envisioned by Argonne National Laboratory (ANL) researchers, will be outlined later in this report.

Nearly all issues related to risks to future generations arising from long-term disposal of such spent nuclear fuel is attributable to ~1% of its content. This 1% is made up primarily of plutonium, neptunium, americium, and curium (the transuranic elements) and long-lived isotopes of iodine and technetium created as products from …

Coupling Of Coamps And Wavetech With Improved Wave Physics, Shahrdad Sajjadi, Pat Fitzpatrick, Gueorgui Mostovoi, Yongzuo Li, Matt Bettencourt

Publications

The Model Coupling Executable Library (MCEL), developed at the University of Southern Mississippi's Center of Higher Learning, has been successfully used to couple the Coupled Ocean/Atmospheric Mesoscale Prediction System (COAMPS) and the ocean wave model WAVEWATCH. An example of its application is shown for Hurricane Gordon, showing that two-way coupling results affects boundary layer physics differently than one-way coupling --- in this case, resulting in larger o z and, consequently, larger surface fluxes and a more intense hurricane. However, since analyzing MCEL is difficult because the wave physics is inaccurate, improvements to the wave algorithms are also part of the …

Training Of The Exchange-Bias Effect In Nio-Fe Heterostructures, A. Hochstrat, Christian Binek, Wolfgang Kleemann

Christian Binek Publications

The training effect of a NiO(001)/Fe(110) heterostructure is studied from magnetic hysteresis loops measured by superconducting quantum interference device magnetometry. Consecutive hysteresis loops exhibit a decreasing exchange bias effect. This behavior is known as the training effect, which reflects the dependence of the exchange bias field on the antiferromagnetic interface magnetization. In order to evidence this dependence, we study the decrease of the total saturation magnetization of the heterostructure for an increasing number of hysteresis cycles. Assuming proportionality between the interface magnetization and the total saturation magnetization, the description of the data is consistent within the phenomenological Meiklejohn Bean approach.

Whole Mantle Shear Structure Beneath The East Pacific Rise, Timothy I. Melbourne, Donald V. Helmberger

All Faculty Scholarship for the College of the Sciences

We model broadband seismograms containing triplicated S, S², and S³ along with ScS to produce a pure path one‐dimensional model extending from the crust to the core‐mantle boundary beneath the East Pacific Rise. We simultaneously model all body wave shapes and amplitudes, thereby eliminating depth‐velocity ambiguities. The data consist of western North American broadband recordings of East Pacific Rise (EPR) affiliate transform events that form a continuous record section out to 82° and sample nearly the entire East Pacific Rise. The best fitting synthetics contain attenuation and small changes in lithospheric thickness needed to correct for …

Late Quaternary Slip Rates Across The Central Tien Shan, Kyrgyzstan, Central Asia, Stephen C. Thompson, Ray J. Weldon, Charles M. Rubin, Kanatbek Abdrakhmatov, Peter Molnar, Glenn W. Berger

All Faculty Scholarship for the College of the Sciences

Slip rates across active faults and folds show that late Quaternary faulting is distributed across the central Tien Shan, not concentrated at its margins. Nearly every intermontane basin contains Neogene and Quaternary syntectonic strata deformed by Holocene north‐south shortening on thrust or reverse faults. In a region that spans two thirds of the north‐south width of the central Tien Shan, slip rates on eight faults in five basins range from ∼0.1 to ∼3 mm/yr. Fault slip rates are derived from faulted and folded river terraces and from trenches. Radiocarbon, optically stimulated luminescence, and thermoluminescence ages limit ages of terraces and …

Accelerated Hazards Model: Method, Theory And Applications, Ying Qing Chen, Nicholas P. Jewell, Jingrong Yang

U.C. Berkeley Division of Biostatistics Working Paper Series

In an accelerated hazards model, the hazard functions of a failure time are related through the time scale-change, which is often a function of covariates and associated parameters. When the hazard functions have special properties, such as monotonicity in time, the parameters may be clinically meaningful in measuring a treatment effect. This paper reviews methodological and theoretical development of this model. Applications of the accelerated hazards model including sample size calculation in clinical trials, are also explored.

Using The Emulab Network Testbed To Evaluate The Armada I/O Framework For Computational Grids, Ron Oldfield, David Kotz

Computer Science Technical Reports

This short report describes our experiences using the Emulab network testbed at the University of Utah to test performance of the Armada framework for parallel I/O on computational grids.

Characterizing A Defect In A One-Dimensional Bar, Cynthia Gangi, Sameer Shah

Mathematical Sciences Technical Reports (MSTR)

We examine the inverse problem of locating and describing an internal point defect in a one­ dimensional rod W by controlling the heat inputs and measuring the subsequent temperatures at the boundary of W. We use a variation of the forward heat equation to model heat flow through W, then propose algorithms for locating an internal defect and quantifying the effect the defect has on the heat flow. We implement these algorithms, analyze the stability of the procedures, and provide several computational examples.

Caustics In Tachyon Matter And Other Born-Infeld Scalars, Gary Felder, Lev Kofman, Alexei Starobinsky

Physics: Faculty Publications

We consider scalar Born-Infeld type theories with arbitrary potentials V(T) of a scalar field T. We find that for models with runaway potentials V(T) the generic inhomogeneous solutions after a short transient stage can be very well approximated by the solutions of a Hamilton-Jacobi equation that describes free streaming wave front propagation. The analytic solution for this wave propagation shows the formation of caustics with multi-valued regions beyond them. We verified that these caustics appear in numerical solutions of the original scalar BI non-linear equations. Our results include the scalar BI model with …

Reconstruction Of Cracks With Unknown Transmission Condition From Boundary Data, F Ronald Ogborne Iii, Melissa E. Vellela

Mathematical Sciences Technical Reports (MSTR)

We examine the problem of Identifying both the location and constitutive law governing electrical current flow across a one-dimensional linear crack in a two dimensional region when the crack only partially blocks the flow of current. We develop a a constructive numerical procedure for solving the inverse problem and provide computational examples.

Locally Efficient Estimation Of Regression Parameters Using Current Status Data, Chris Andrews, Mark J. Van Der Laan, James M. Robins

U.C. Berkeley Division of Biostatistics Working Paper Series

In biostatistics applications interest often focuses on the estimation of the distribution of a time-variable T. If one only observes whether or not T exceeds an observed monitoring time C, then the data structure is called current status data, also known as interval censored data, case I. We consider this data structure extended to allow the presence of both time-independent covariates and time-dependent covariate processes that are observed until the monitoring time. We assume that the monitoring process satisfies coarsening at random.

Our goal is to estimate the regression parameter beta of the regression model T = Z*beta+epsilon where the …

Development And Implementation Of A Comprehensive Lake And Reservoir Strategy For Nebraska As A Model For Agricultural Dominated Ecosystems, John C. Holz, James W. Merchant, Anatoly A. Gitelson, Sherilyn C. Fritz, Kyle D. Hoagland, Istvan Bogardi, Donald C. Rundquist

Department of Earth and Atmospheric Sciences: Faculty Publications

In agriculturally dominated regions, land use practices have an unusually large impact on water bodies and, therefore, land use may reduce the utility of current ecoregion-based approaches to lake classification by dampening the signals that underlie the ecoregion framework. A team of water quality researchers has been assembled to develop a comprehensive classification scheme for agriculturally dominated ecosystems, using Nebraska as a highly representative model. Three objectives critical to achieving this goal are to establish: (1) a protocol for aggregating water bodies in agricultural ecosystems into classification strata and identifying reference conditions for these classes; (2) the role of remote …