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Physical Sciences and Mathematics Commons

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2002

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Dissertations

Cu-ZSM-5

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Full-Text Articles in Physical Sciences and Mathematics

Catalytic Reduction Of Nitric Oxide By Solid Carbonaceous Material Under Lean Condition, Shan Xiao Aug 2002

Catalytic Reduction Of Nitric Oxide By Solid Carbonaceous Material Under Lean Condition, Shan Xiao

Dissertations

The reactions of O2, NOx and soot from Diesel exhaust over Cu containing catalysts can significantly reduce soot and NOx emissions while producing N2 and CO2. The author has evaluated the performance of Cu ion exchanged ZSM-5 and Cu adsorbed on Granulated Activated Carbon (Cu-GAC) using GAC as a surrogate for soot in a packed bed reactor. CO, formed primarily by the oxidation of GAC with O2, appears to be a stable intermediate in the reduction of NO. With experimental parameters chosen to simulate Diesel exhaust conditions, Cu-GAC is much more …