Physical Sciences and Mathematics Commons^™

Geochemical And Isotopic Characteristics Associated With High Conductivities In A Shallow Hydrocarbon-Contaminated Aquifier, Franklyn D. Legall

Dissertations

In-situ vertical resistivity probes (VRPs) deployed at a hydrocarboncontaminated site in SW Michigan showed high soil conductivities within the contaminated zone. Within this zone, different phases of hydrocarbon impact were recognized, namely, zones with residual and dissolved phase hydrocarbons (RDH) and zones where these phases coexist with free product (RDFH). Bulk soil conductivities were highest ( 12 to 30 mS/m) in the zone with RDFH compared to the RDH zone (10 to 25 mS/m). Groundwater chemistry and stable carbon isotope data from closely spaced vertical samples within the anomalous conductive zones were used to provide evidence for biodegradation and to …

Load Balancing And Congestion Avoidance Routing, Konstantinos N. Kokkinos

Dissertations

Today’s high speed backbone networks are expected to support a wide range of communication-intensive applications. One of the most important issues in Quality of Service (QoS) is efficient routing. Many QoS routing solutions have been published lately for different criteria of QoS requirements and resource constraints. In this dissertation we focus on the design of regular network topologies and suggest efficient routing schemes to reduce the probability of hot spot creation in the network. Furthermore, we provide a detection of congestion mechanism that reroutes traffic to maintain balancing with small communication cost. Several theoretical results relatively to network traffic balancing …

New Statitstical Methods For The Estimation Of The Mean And Standard Deviation From Normally Distributed Censored Samples, Abou El-Makarim Abd El-Alim Aboueissa

Dissertations

The main objective of this dissertation is to estimate the mean /x and standard deviation cr of a normal population from left-censored samples. We have developed new methods for calculating estimates for the mean and standard deviation of a normal population from left-censored samples. Some of these methods based on traditional estimating procedures. A new method of obtaining the Cohen maximum likelihood estimates for fx and cr without the aid of an auxiliary table will be introduced. This new method will be used to extend Cohen table of estimating the Cohen A-parameter that is required for calculating the maximum likelihood …

On Rank-Based Considerations For Generalized Linear Models And Generalized Estimating Equation Models, Diana R. Cucos

Dissertations

This study discusses rank-based robust methods for estimation of parameters and hypotheses testing in the generalized linear models (GLM) and generalized estimating equations (GEE) setting. The robust estimates are obtained by minimizing a Wilcoxon drop in dispersion function for linear or nonlinear regression models. In addition, diagnostic tools for outliers and influential observations are being developed. These models are generalizations of linear and nonlinear models. They allow for both nonlinear mean functions and heteroscedasticity of their random errors. This makes them quite useful in practice. Rank-based inference has been developed for linear models over the last thirty years. This inference …

Geoelectrical Response Of An Aged Lnapl Plume: Implications For Monitoring Natural Attenuation, Douglas D. Werkema Jr.

Dissertations

The geoelectric stratigraphy at a site impacted with light non-aqueous phase liquids (LNAPLs) is investigated for its link to natural biodegradation, its contribution to the conductive model for aged (i.e. mature) LNAPL contaminated sites, and the relationship to the natural hydrologic regime. The highest conductivities (lowest resistivities) were observed in portions o f soils where LNAPL was in residual and free phase. Corroborating evidence from bacteria enumeration from soil close to the vertical resistivity probe (VRP) installations show orders-of-magnitude increase in both heterotrophic and oil degrading microbes at the depths where the conductivity was at a maximum. The coincidence o …

Robust Residuals And Diagnostics In Autoregressive Time Series, Kirk W. Anderson

Dissertations

One of the goals of model diagnostics is outlier detection. In particular, we would like to use the residuals, appropriately standardized, to “flag” outliers. Hopefully, our (robust) procedure has yielded a fit that resists undue influence by outlying points, while simultaneously drawing attention to these interesting points via residual analysis. In this study we consider several different methods of standardizing the residuals resulting from autoregression. A large sample approximation for the variance of rank-based first order autoregressive time series residuals is developed. This provides studentized residuals, specific to the time series model and estimation procedure. Simulation studies are presented that …

Resolvability In Graphs, Varaporn Saenpholphat

Dissertations

The distance d (u, v ) between two vertices u and v in a connected graph G is the length of a shortest u - v path in G . For an ordered set W = { w1 , w2 , [Special characters omitted.] &cdots; , wk } of vertices in G and a vertex v of G , the code of v with respect to W is the k -vector cW (v ) = (d ( v, w1 ),d (v, w 2 ), [Special characters omitted.] &cdots; , d …

Resonances Of Periodic Metal-Dielectric Structures At The Infrared Wavelength Region, Oren Sternberg

Dissertations

Metal meshes have been used as reflectors in radar receivers for wavelength much longer than the periodic constant of the conducting wires and as optical reflectors in a FabryPerot in the far infrared. Cross shaped metal meshes can be used as band pass filters but the design theory and near field properties have not been known.

Transmittance of thin, single-layer and multiplayer metal meshes has been investigated using Micro-Strips, yielding numerical solutions of Maxwell's equations. The near field effect was studied for two alignment configurations of cross shaped metal meshes, both free standing and with dielectrics, and transmission line theory …

Knowledge Discovery And Modeling In Genomic Databases, Michael M. Yin

Dissertations

This dissertation research is targeted toward developing effective and accurate methods for identifying gene structures in the genomes of high eukaryotes, such as vertebrate organisms. Several effective hidden Markov models (HMMs) are developed to represent the consensus and degeneracy features of the functional sites including protein-translation start sites, mRNA splicing junction donor and acceptor sites in vertebrate genes. The HMM system based on the developed models is fully trained using an expectation maximization (EM) algorithm and the system performance is evaluated using a 10-way cross-validation method. Experimental results show that the proposed HMM system achieves high sensitivity and specificity in …

Thermal Treatment Of Organic Contaminated Solids And Waste : Experiment, Model And Mass Balance, Hsien-Tsung Chern

Dissertations

A number of processes can be used to remediate contaminated soils. The thermal technologies for remediation of contaminated soils are summarized in this study. Each of these treatment process along with their system components are identified and described. Waste applicability is included for each treatment technology. A detailed list of feasible treatment processes is presented with descriptions of site demonstration results to aid ill selection of a given process. Technology status is summarized to provide current information on the processes.

Energy components are discussed for cost requirement and safety considerations in thermal treatment applications. It is determined that the heat …

A Microfabricated Microconcentrator For Sensors And Chromatography, Minhee Kim

Dissertations

The detection and quantitative measurement of trace components is a challenging task. The key component in such an instrument is the concentration step where the analytes are accumulated before the analysis. In this research, simple and inexpensive processes for the microfabrication of microconcentrator that can be used with sensors and as an injector in GC were developed. Analytes are selectively concentrated in the microconcentrator. Rapid electrical heating of the microconcentrator releases the adsorbed species as a 66 concentration pulse", which serves as an injection for the detection system. The relatively small size of the microconcentrator allows it to be heated …

Development Of Membrane Extraction Techniques For Water Quality Analysis, Dawen Kou

Dissertations

This research involved the development of membrane-based analytical techniques as applied to various aspects of water quality analysis. Gas injection membrane extraction was developed for fast on-line analysis of volatile organic compounds in water. Gas injection of aqueous samples increased the speed of membrane extraction. The aqueous boundary layer effects encountered during water elution was reduced. Axial mixing of the sample with a gaseous eluent was minimal, and this eliminated the tailing in the permeation profiles. The overall effect was significantly faster penneation. The overall diffusion coefficient during gas injection was found to be seven times the value during aqueous …

Catalytic Reduction Of Nitric Oxide By Solid Carbonaceous Material Under Lean Condition, Shan Xiao

Dissertations

The reactions of O₂, NO_x and soot from Diesel exhaust over Cu containing catalysts can significantly reduce soot and NO_x emissions while producing N₂ and CO₂. The author has evaluated the performance of Cu ion exchanged ZSM-5 and Cu adsorbed on Granulated Activated Carbon (Cu-GAC) using GAC as a surrogate for soot in a packed bed reactor. CO, formed primarily by the oxidation of GAC with O₂, appears to be a stable intermediate in the reduction of NO. With experimental parameters chosen to simulate Diesel exhaust conditions, Cu-GAC is much more …

Visualization Methods: A Comparative Study Of New, Traditional And Robust Procedures, Kimberly Crimin

Dissertations

Two major goals in discriminant analysis are discrimination and classification. In discrimination, the goal is to describe graphically (visualization) different features of several known groups. In classification, the goal is to allocate unknown observations to one of several known groups. We have developed new visualization procedures based on traditional estimating procedures and also on robust estimating procedures. We have further developed robust classification procedures. We propose several robust classification procedures based on coordinatewise and affine equivariant, rank-based robust estimates. Empirical studies are performed over many different error distributions. These studies result in empirical efficiencies of the robust and traditional procedures. …

A New Type Of Particle Detector For Nuclear Scattering Experiments, Philip Ugorowski

Dissertations

A new detector was needed for counting recoil protons resulting from proton-proton (pp) elastic scattering during pion production experiments by the Polarized Internal Target Experiments (PINTEX) group at Indiana University Cyclotron Facility (IUCF). The previous silicon detectors were only usable forincoming protons up to 9 MeV, and a stopping power of at least 40 MeV was needed. In addition, the detector had to operate in nanotorr vacuum, and near strong varying magnetic fields, ruling out standard organic plastic scintillators and photomultiplier tubes. We needed to find the most suitable inorganic scintillator and another method of detecting the photons produced when …

Electron Correlation Leading To Double-K-Shell Vacancy Production In Li-Like Ions Colliding With Helium, Ali Sami Alnaser

Dissertations

Single and double K-shell vacancies in Li-like ions colliding with neutral helium target have been investigated using high-resolution Auger projectile spectroscopy. Be⁺, B²⁺, C³⁺, and O⁵⁺ Li-like ions were produced and accelerated to intermediate-to-high collision velocities where perturbative models are expected to be valid, using the Tandem Van de Graaff accelerator at Western Michigan University. Double-K-shell vacancies in atomic systems or so-called “ hollow ions” can be induced by different mechanism in ion-atom collisions. For intermediate-to-high velocity collisions where the collision time is small, the projectile ion can interact with only one of …

Separable Preference Orders, Jonathan K. Hodge

Dissertations

Whenever a decision-maker must express simultaneously his or her preferences on several possibly related issues, the existence of interdependence among these preferences can lead to collective decisions that are unsatisfactory or even paradoxical. Intuitively, an individual’s preferences are said to be separable on a subset of issues if they do not depend on the choice of alternatives for issues outside the subset. Here we explore from a mathematical standpoint the properties of separable and nonseparable preference orders. We begin by formulating a general model of multidimensional preferences and we formally introduce the notions of separability and noninfluentiality. We study the …

Nonlinear Regression Based On Ranks, Ashebar Abebe

Dissertations

This study presents robust methods for estimating parameters of nonlinear regression models. The proposed methods obtain estimates by minimizing rankbased dispersions instead of the Euclidean norm. We focus on the Wilcoxon and generalized signed-rank dispersion functions. Asymptotic properties of the estimators are established under mild regularity conditions similar to those used in least squares and least absolute deviations estimation. The study also shows that by considering the generalized signed-rank dispersion we obtain a class of estimators that encompasses most of the existing popular nonlinear regression estimators. As in linear models, these rank-based procedures provide estimators that are highly efficient. This …

Nonlinear Interfacial Stability Of Core-Annular Film Flows In The Presence Of Surfactants, Said A. Kas-Danouche

Dissertations

This work is an analytical and computational study of the nonlinear interfacial instabilities found in core-annular flows in the presence of surfactants. Core-annular flows arise when two immiscible fluids (for example water and oil) are caused to flow in a pipe under the action of ail axial pressure gradient. In one typical type of flow regime, the fluids arrange themselves so that the less viscous (e.g. water) lies in the region of high shear near the pipe wall, with the more viscous fluid occupying the core region. Tech nologically, this arrangement provides an advantage since the highly viscous fluid is …

Temporal Synchronization Of Ca1 Pyramidal Cells By High-Frequency, Depressing Inhibition, In The Presence Of Intracellular Noise, Stephen A. Kunec

Dissertations

The Sharp Wave-associated Ripple is a high-frequency, extracellular recording observed in the rat hippocampus during periods of immobility. During the ripple, pyramidal cells synchronize over a short period of time despite the fact that these cells have sparse recurrent connections. Additionally, the timing of synchronized pyramidal cell spiking may be critical for encoding information that is passed on to post-hippocampal targets. Both the synchronization and precision of pyramidal cells is believed to be coordinated by inhibition provided by a vast array of interneurons. This dissertation proposes a minimal model consisting of a single interneuron which synapses onto a network of …

Experimental And Theoretical Study Of An Integrated Silicon Mach-Zehnder Interferometer For Chemical Sensing Applications, Yew Fong Hor

Dissertations

This thesis involves the design, fabrication and characterization of an integrated optical waveguide sensor. Prior to fabrication, design parameters of the waveguide need to be determined and optimized. The waveguide parameters such as waveguide dimension and the refractive index of the core and cladding are obtained from the single-mode cutoff frequency calculated using either analytical or numerical methods. In this thesis, details of analytical calculations to determine the cutoff frequency in terms of the waveguide parameters will be presented. The method discussed here is Marcatili's approximation. The purpose is to solve the scalar wave equation derived from Maxwell's equations because …

Instability Of Electrified Viscous Films, Knograt Savettaseranee

Dissertations

We examine the stability of a thin two-dimensional liquid film with a regular electric field applied in a direction parallel to an initially flat bounding fluid interface. We study the distinct physical effects of surface tension, van der Waals and electrically induced forces for a viscous incompressible fluid. The film is assumed to be sufficiently thin, and the surface tension and electrically induced forces are large enough that gravity can be ignored to the leading order. Our target is to analyse the nonlinear stability of the flow. We attain this by deriving and numerically solving a set of nonlinear evolution …

Development And Characterization Of Methodology And Technology For The Alignment Of Fmri Time Series, Carlo Ciulla

Dissertations

This dissertation has developed, implemented and tested a novel computer based system (AUTOALIGN) that incorporates an algorithm for the alignment of functional Magnetic Resonance Image (fMRI) time series. The algorithm assumes the human brain to be a rigid body and computes a head coordinate system on the basis of three reference points that lie on the directions correspondent to two of the eigenvectors of inertia of the volume, at the intersections with the head boundary. The eigenvectors are found weighting the inertia components with the voxel's intensity values assumed as mass. The three reference points are found in the same …

Two-Dimensional Reflectivity Polarization Elastometry Imaging Techniques (Piet) Of Soft Tissue, Hee Chuan Lim

Dissertations

A non-invasive polarized light reflection measurement method to measure the stretch of soft tissue, such as skin, is described. The technique utilizes changes in the reflectivity of polarized light intensity as a monitor of skin stretch. Measurements on in-vitro pigskin and invivo human skin show that the reflectivity of polarized light intensity increases linearly with stretch over a range. The changes in diffusive reflectivity properties of skin result from the alterations that take place in the roughness across the thickness of the skin layers due to stretch. Conceptually, as the roughness of a layer decreases with stretch, a smoother reflecting …

An Analysis Of Field Data For Evidence Of Anaerobic Degradation Of Pah And Btex Plumes At Manufactured Gas Plant Sites, Georgene Mortimer

Dissertations

Field data (including geology, hydrogeology, soil chemistry, groundwater chemistry, and aquifer characteristics) were analyzed at eight MGP sites located in the New Jersey Coastal Plain. These data were used to calculate biodegradation rate constants, which were then compared with laboratory microcosm data and published values. Isopleths were drawn from the field data to indicate the dominant biodegradation mechanisms at each of the sites, and stoichiometric calculations were used to determine the total capacity of the electron acceptors present to degrade the plume contaminants. In examining these data, the protocol described by the Air Force Center for Environmental Excellence (AFCEE) was …

Collaborative Problem Solving And Program Development Model, Joanna Defranco-Tommarello

Dissertations

A model to enhance collaborative problem solving and program development is presented. The collaborative model is a detailed cognitive model that takes into consideration the cognitive and social activities that occur during collaborative problem solving and program development. The cognitive activities required for collaborative problem solving and program development are identified and integrated into a six-stage model. An extensive literature review in the associated fields is presented to show the need for the model described in this dissertation. In addition, a comprehensive study of tools to support collaboration during problem solving and program development was also performed as well as …

Chemical, Isotopic, And Hydrogeologic Investigations Of An Agriculturally Impacted Area, Nottawa Creek Watershed, Calhoun County, Michigan, Gerald A. Unterreiner

Dissertations

A 4 km2 agricultural area within the somewhat poorly drained Nottawa Creek Watershed, south central Michigan, was investigated to help understand transport and transformation processes of nutrients and herbicides to surface water. Geology o f the study area is comprised of a thin glacial drift cover overlying shale bedrock. A one layer, two-dimensional numerical triangular finite element groundwater flow model was developed to evaluate regional groundwater flow. Selected horizontal hydraulic conductivities ranged from 3 x 10‘3 m/day to 107 m/day. Field-scale infiltration modeling with the computer program GLEAMS, substantiated with water level measurements, suggest significant recharge events occur during summer, …

A New Theory Of Premixed Flames In Near-Stoichiometric Mixtures, Eliana S. Antoniou

Dissertations

In this dissertation, a new model of premixed flames in near-stoichiometric mixtures is derived. Unlike most previous theories, which are valid only for very lean or very rich, i.e. off-stoichiometric conditions, our model remains valid over the entire spectrum of mixture compositions, from lean to rich, including the near-stoichiometric regime. Since fuel-mixture composition is known to have a significant effect on flame behavior, such a model is expected to contribute new insights into classical problems in premixed combustion.

In the first part of this dissertation, we describe the derivation of a model for premixed flames in two-reactant mixtures in a …

Simultaneous Removal Of Ortho-Dichlorobenzene And Ethanol Vapors In A Biotrickling Filter : Experimental Results And Process Modeling, Suchismita Bhattacharya

Dissertations

This study investigated the possibility of simultaneous removal of vapors of dissimilar volatile organic compounds from air streams in a biotrickling filter (BTF). Using a rricrobial consortium known to utilize ortho-dichlorobenzene (o-DCB) as sole carbon and energy source, a culture was developed on o-DCB/ethanol mixtures and a BTF unit was developed and operated with air streams carrying o-DCB and ethanol vapors. Simultaneous removal of the two compounds was observed in experiments that span a period of over three years.

Experiments were performed at air residence times ranging from 4 to 6.5 min, liquid flow rates from 3.6 to 9 Lh …

Development Of Analytical Systems And Monitoring Of Vocs Emissions During Polymer Processing, Qin Xiang

Dissertations

A method using direct flame ionization detector (FID) measurement was developed to study total volatile organic compounds (VOCs) emissions during thermal degradation of polymers. This was used to estimate organic emissions from both virgin polymer resins and commingled plastics. The effects of process parameters, i. e., temperature, heating rate and residence time, were also studied. Significant VOCs emissions were observed at normal processing temperatures, particularly from recycled polymers. Each polymer showed a distinct evolution pattern during its thermal degradation. Kinetics of VOCs emissions were also studied using a non-isothermal technique. The kinetic parameters were in agreement with data from the …