Physical Sciences and Mathematics Commons^™

Studies On The Methylation Of 5-Nitro-Benzimidazoles, Mashooda Hasan, Farzana Shaheen, Uzma Yunus

Turkish Journal of Chemistry

Methylation of 2H, 5-nitro- (1) and 2-ethyl, 5-nitro- (2) benzimidazoles separately with methyl iodide in acetone in the presence of potassium carbonate yielded 2H, 5/6-nitro-(3A and 3B) and 2-ethyl, 5/6-nitro- (4A and 4B) methylbenzimidazoles respectively. Methylation of 1 and 2 in dimethylformamide in place of acetone yielded not only 3A, 3B and 4A, 4B respectively, but in addition 1,3-dimethyl-5-nitro-benzimidazol-2-one (5) was also obtained in each case. The structure of the synthesized compounds was determined with the help of mass and ^1H NMR spectroscopic analysis.

Biochemical Composition Of Particles And Dissolved Organic Matter Slong An Estuarine Gradient: Sources And Implications For Dom Reactivity, Antonio Mannino, H. Rodger Harvey

OES Faculty Publications

The chemical composition of high molecular weight dissolved organic matter (DOM) and particulate organic matter (POM) was examined along the salinity gradient of the Delaware Estuary. DOM was collected and fractionated by tangential-flow ultrafiltration into 1-30 kDa (HDOM; high molecular weight) and 30 kDa to 0.2 μm (VHDOM; very high molecular weight) and compared to particles collected in parallel. Polysaccharides comprised 12-43% of particulate organic carbon (POC), 30-56% of VHDOM carbon, and 7.5-19% of HDOM carbon. Hydrolyzable amino acids comprised 17-38% of POC, 5.4-12% of VHDOM carbon, and 1.5-4.2% of HDOM carbon. Only 7-43% of dissolved organic nitrogen in VHDOM …

A System For Analysing Patient History (Az-Phis), Kemalatha Krishnasamy

Student Works (2000-2009)

The improvement of health care service has a great effect on patient satisfaction. In order to improve the health care service, effective processing of patient history and analysis on the respondent is necessary. The results of the statistical analysis performed on patient history eases the decision making of physicians and other related medical staff. Therefore, this dissertation mainly investigates information pertaining to patient history, statistical analysis, and development of a system for analyzing patient history. The study employs the questionnaire survey method to gather data and make analyses using the Spreadsheet; Microsoft® Excel 97. The survey was done in government …

Thickness Variation Of Self-Processing Acrylamide-Based Photopolymer And Reflection Holography, F. O'Neill, Justin Lawrence, J. Sheridan

Articles

There are many types of holographic recording material. The acrylamide-based recording material examined here has one significant advantage: it is self-processing. This simplifies the recording process and enables holographic interferometry to be carried out without the need for complex realignment procedures. However, the effect that the polymerization process has on the grating thickness must be examined. This question is fundamental to the material's use in holographic optical elements, as thickness variations affect the replay conditions of the produced elements. This paper presents a study of this thickness variation and reports for the first time the production of reflection holographic gratings …

Production Of A Signal By Irradiated Cells Which Leads To A Response In Unirradiated Cells Characteristic Of Initiation Of Apoptosis, Fiona Lyng, C. Seymour, C. Mothersill

Articles

This study investigated the ability of medium from irradiated cells to induce early events in the apoptotic cascade, such as mobilization of intracellular calcium, loss of mitochondrial membrane potential and increase in reactive oxygen species, in cells which were never exposed to radiation. Medium from irradiated human keratinocytes was harvested and transferred to unirradiated keratinocytes. Endpoints characteristic of the initiation of apoptosis were monitored for a period of 24 h following medium transfer. Clonogenic survival was also measured. Rapid calcium fluxes (within 30 s), loss of mitochondrial membrane potential, increases in reactive oxygen species (from 6 h after medium transfer), …

Dynamics Of Interfacial Polymers In Composites, Frank D. Blum, Wuu-Yung Lin

Chemistry Faculty Research & Creative Works

Much experimental and theoretical work has been done on the behavior of adsorbed polymers. However, not much work has focused on the dynamics, especially segmental dynamics, of the adsorbed polymers. This is especially true of filled polymer or composite systems as the interfacial layers in these systems are difficult to study with most techniques. NMR is not restricted to use in optically clear samples and its use in the characterization in the surface polymers has been reviewed. In our laboratory, we have found that deuterium NMR could be used to probe the segmental dynamics of adsorbed polymers. The position of …

Renormalons As Dilation Modes In The Functional Space, A. Babansky, I. Balitsky

Physics Faculty Publications

There are two possible sources of the factorial large-order behavior of a typical perturbative series. First, the number of different Feynman diagrams may be large; second, there may be abnormally large diagrams known as renormalons. It is well known that the large combinatorial number of diagrams is described by instanton-type solutions of the classical equations. We demonstrate that, from the functional-integral viewpoint, the renormalons do not correspond to a particular configuration but manifest themselves as dilatation modes in the functional space.

Deeply Virtual Compton Scattering At Small X, Ian Balitsky, Elena Kuchina

Physics Faculty Publications

We calculate the cross section of deeply virtual Compton scattering at large energies and intermediate momentum transfers.

High Energy Effective Action From Scattering Of Shock Waves In Qcd, Ian Balitsky

Physics Faculty Publications

The author demonstrates that the amplitude for high-energy scattering can be factorized as a convolution of the contributions due to fast and slow fields. The fast and slow fields interact by means of Wilson-line operators -- infinite gauge factors ordered along the straight line. The resulting factorization formula gives a starting point for a new approach to the effective action for high-energy scattering in QCD.

Search For Resonances Decaying To E+-Jet In E+P Interactions At Hera, J. Breitweg, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Stanek, R. Yoshida, Margarita C. K. Mattingly, G. Abbiendi, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, N. Coppola, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Laurenti

Faculty Publications

The e+-jet invariant mass spectrum produced in the reaction e+p → e+ X has been studied at a center-of-mass energy of 300 GeV. The data were collected using the ZEUS detector operating at the HERA collider, and correspond to an integrated luminosity of 47.7 pb-1. The observed mass spectrum is in good agreement with Standard Model expectations up to an e+-jet mass of 210 GeV. Above this mass, some excess is seen. The angular distribution of these events is typical of high-Q2 neutral current events and does not give convincing evidence for the presence of a narrow scalar or vector …

Search For Contact Interactions In Deep Inelastic E+P → E+X Scattering At Hera, J. Breitweg, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Stanek, R. Yoshida, Margarita C. K. Mattingly, G. Abbiendi, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, N. Coppola, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Laurenti

Faculty Publications

In a search for signatures of physics processes beyond the Standard Model, various eeqq vector contact-interaction hypotheses have been tested using the high-Q2 deep inelastic neutral-current e+p scattering data collected with the ZEUS detector at HERA. The data correspond to an integrated luminosity of 47.7pb-1 of e+p interactions at 300 GeV center-of-mass energy. No significant evidence of a contact-interaction signal has been found. Limits at the 95% confidence level are set on the contact-interaction amplitudes. The effective mass scales Λ corresponding to these limits range from 1.7 TeV to 5 TeV for the contact-interaction scenarios considered.

Measurement Of D*± Production And The Charm Contribution To F2 In Deep Inelastic Scattering At Hera, J. Breitweg, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Stanek, R. Yoshida, Margarita C. K. Mattingly, G. Abbiendi, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, N. Coppola, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Laurenti

Faculty Publications

The production of D*± (2010) mesons in deep inelastic scattering has been measured in the ZEUS detector at HERA using an integrated luminosity of 37 pb-1. The decay channels D*+ → D0π+ (+c.c.), with D0 → K-π+ or D0 → K-π-π+π+, have been used to identify the D mesons. The e+p cross section for inclusive D*± production with 1 < Q2 < 600 GeV2 and 0.02 < y < 0.7 is 8.31±0.31(stat.)+0.30-0.50 (syst.) nb in the kinematic region 1.5 < pT(D*±) < 15 GeV and \η(D*±)\ < 1.5. Differential cross sections are consistent with a next-to-leading-order perturbative-QCD calculation when using charm-fragmentation models which take into account the interaction of the charm quark with the proton remnant. The observed cross section is extrapolated to the full kinematic region in pT(D*±) and η(D*±) in order to determine the charm contribution, Fcc̄2 (x, Q2), to the proton structure function. The ratio Fcc̄2/F2 rises from ≃10% at Q2 ≃ 1.8GeV2 to ≃30% at Q2 ≃130GeV2 for x values in the range 10-4 to 10-3.

Angular And Current-Target Correlations In Deep Inelastic Scattering At Hera, J. Breitweg, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Stanek, R. Yoshida, Margarita C. K. Mattingly, G. Abbiendi, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, N. Coppola, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Laurenti

Faculty Publications

Correlations between charged particles in deep inelastic e+ p scattering have been studied in the Breit frame with the ZEUS detector at HERA using an integrated luminosity of 6.4pb-1. Short-range correlations are analysed in terms of the angular separation between current-region particles within a cone centred around the virtual photon axis. Long-range correlations between the current and target regions have also been measured. The data support predictions for the scaling behaviour of the angular correlations at high Q2 and for anti-correlations between the current and target regions over a large range in Q2 and in the Bjorken scaling variable x. …

Software Design Recovery Of Object Oriented Systems Developed In C++, Mohamed Reffat El Harras

Archived Theses and Dissertations

No abstract provided.

Bismuth(Iii) Oxide Perchlorate Promoted Rearrangement Of Epoxides To Aldehydes And Ketones, Ram Mohan, Andrew Anderson, Jesse Blazek, Parie Garg, Brian Payne

Scholarship

Aryl-substituted epoxides and aliphatic epoxides with a tertiary epoxide carbon undergo smooth rearrangement in the presence of 10–50 mol% bismuth(III) oxide perchlorate, BiOClO₄•xH₂O, to give carbonyl compounds. The rearrangement is regioselective with aryl substituted epoxides and a single carbonyl compound arising from cleavage of benzylic C―O bond is formed. BiOClO_4•xH₂O is relatively non-toxic, insensitive to air and inexpensive, making this catalyst an attractive alternative to more corrosive and toxic Lewis acids such as BF₃•Et₂O or InCl₃ currently used to effect epoxide rearrangements.

Isolation Of Curcumin From Tumeric, Ram Mohan, Andrew Anderson, Matthew Mitchell

Scholarship

No abstract provided.

The Discovery-Oriented Approach To Organic Chemistry. 3. Boron-Trifluoride Catalyzed Rearrangement Of Cis- And Trans-Stilbene Oxides. An Exercise In 1H Nmr Spectroscopy For Sophomore Organic Laboratories, Ram Mohan, Erik Sgariglia, Regina Schopp, Kostas Gavardinas

Scholarship

Epoxides, or oxiranes, are among the most versatile intermediates in organic synthesis. Yet very few examples of laboratory experiments involving reactions of epoxides are to be found in lab texts. We have developed a discovery-oriented laboratory experiment that involves the rearrangement of both cis- and trans-stilbene oxides with boron trifluoride etherate. The identity of the product can be easily determined by ¹H NMR spectroscopy and, in case of the trans isomer, by preparation of the semicarbazone derivative as well. In spite of the simplicity of the experiment, the element of discovery ensures that student interest and enthusiasm are retained.

Analysis Of Remote Sensing Data For Development Of I/M Program Evaluation Protocols, Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.

A Brief Biography Of Professor L.C. Hsu (Lizhi Xu), Tian-Xiao He

Scholarship

No abstract provided.

Rsd Versus Im240 Fleet Average Correlations, Sajal S. Pokharel, Donald H. Stedman, Gary A. Bishop

Fuel Efficiency Automobile Test Publications

No abstract provided.

Development Of A Quality Control Procedure For Force Platforms, Jacinta Browne, Neil O'Hare

Articles

A force platform is a technical method of quantitatively assessing balance indirectly. The use of force platforms in physiotherapy departments has become more prominent over the last few years. However, the main drawback in the use of force platforms is the lack of comprehensive calibration procedures, which casts doubt on the results obtained with these systems. Existing calibration tests are limited to testing the spatial accuracy of the force platform. This paper describes a comprehensive quality control test procedure which was developed. It is proposed that the developed quality control test procedure could be used to test all types of …

Development Of A Novel Method For Assessing Balance: The Quantitative Posturography System, Jacinta Browne, Neil O'Hare

Articles

Balance is the ability to maintain equilibrium while sitting or standing. There are a number of different methods, which are used to assess balance: technical methods such as Sway Magnetometry, Ataxia Meter and Force Platforms and clinical methods such as Functional Reach Test, Berg Balance Test and Fall Risk Index. The most frequently used technical method is the force platform. There are two types of Force Platform a static and a dynamic Force Platform of which the dynamic Force Platform has been found to be more sensitive at detecting impaired balance. The Quantitative Posturography System (QPS) described in this paper …

A Scene Similarity Metric For Matching Configurations Of Image Objects, James Carswell

Articles

This paper proposes a novel solution to querying image databases by matching raster features to imagery completely in the raster/spatial domain using the shape of single features together with their spatial relations as the matching primitives. The core feature-based matching module combines a revised least-squares matching algorithm, to accomplish the matching process on binary images, with a unique implementation of a feature library that organizes and links query objects with their images in the database, thus enabling fast and efficient real-time retrieval of relevant imagery. The purpose is to extend this previous work of ours, which matches on the shape …

Civilian Conservation Corps Rubble And Masonry Dams And Gully Morphology In Northeastern Iowa, Timothy Robert Beerman

Dissertations and Theses @ UNI

The Civilian Conservation Corps (CCC) was created in 1933 in an effort to help solve the problems associated with the lack of jobs for young men, the nations dwindling natural resources, and problems associated with soil erosion. The CCC's work in Iowa was primarily in the areas of reforestation and erosion control. Company 1749 of Cresco, Iowa stands out as an example of how the CCC worked to halt erosion. As a part of their erosion-control strategy, Company 1749 built a large number of rubble and masonry dams on gullies. These dams were designed to trap sediments and prevent further …

Mcnair Scholars Journal

Georgia Southern University McNair Scholars Journal (Archived)

• Director's Message
• Relationship Between a Precipitate Found in Ethanol Preserved Crustaceans and The Molt Cycle Lacrissa Cook
• Main Influences of Perceived Gender Differences in Middle and High School Students: Unveiling the Curtain of Silence Ebonique Thomas
• The Sagittal Suture in Homo Sapiens: Is It Fractal? Ron Wright
• The Black Elite in Atlanta, Georgia: Perpetuating and Idealistic Society Phyllis M. Hill
• The Quarterman Incident: The Albany Movement Pushed Back to Strength Kameelah L. Martin
• The Effects of Various Materials for the Purpose of Sound Reduction Christopher Johnson
• Maintaining Doctrinal Integrity and Continuity in The Absence of Organizational Structure Among Primitive Baptists …

On Some Length Biased Inequalities For Reliability Measures, Broderick O. Oluyede

Mathematical Sciences: Faculty Publications

In this note, inequalities for length biased and the original residual life function and equilibrium distribution function with monotone hazard rate and mean residual life functions are derived. We also obtain estimates of the length biased probability density function and hazard function under random censoring. Finally, the Bayesian exponential reliability estimate under length biased sampling using a conjugate prior for the scale parameter is given.

Local Environment Of Iron And Uranium Ions In Vitrified Iron Phosphate Glasses Studied By Fe K And Uliii-Edge X-Ray Absorption Fine Structure Spectroscopy, Mevlüt Karabulut, G. K. Marasinghe, C. S. Ray, D. E. Day, George Daniel Waddill, P. G. Allen, C. H. Booth, J. J. Bucher, D. L. Caulder, D. K. Shuh, M. Grimsditch, M.-L. Saboungi

Materials Science and Engineering Faculty Research & Creative Works

The local structure of iron and uranium ions in a series of iron phosphate glasses with the general composition (40 - x)Fe₂O₃-xUO₂-60P₂O₅ and (1-x-y)(40Fe₂O₃-60P₂O₅)-xUO_2-y(Na₂O or CaO) was investigated using Fe K-edge and U L_III-edge x-ray absorption fine structure spectroscopy. Replacing Fe₂O₃ by UO₂ in the glass caused more distortion in the coordination environment of Fe(III) ions. Extended x-ray absorption fine structure fits revealed that the Fe-P bonds observed in the base glass also …

Crystal And Magnetic Structures Of Lani₅₋ₓmnₓ, Chiu-Ying Tai, G. K. Marasinghe, Oran Allan Pringle, William Joseph James, Muguo Chen, William B. Yelon, I. Dubenko, Naushad Ali, Ph. I'Héritier

Physics Faculty Research & Creative Works

The crystallographic and magnetic properties of LaN_5-xMn_x with x = 1, 1.5, and 2, have been investigated using x-ray and neutron diffraction, vibrating sample magnetometer and superconducting quantum interference device measurements. All the samples crystallize in the hexagonal CaCu₅-type (P6/mmm) structure. Manganese atoms preferentially occupy the 3 g site in the LaNi₅ structure. The bulk magnetization of the LaNi_5-xMn_x powder samples decreases rapidly as nickel is replaced by manganese. A ferrimagnetic model is applied to describe the magnetic structure of the LaNi_5-xMn_x samples for x = 1.5 and …

The Effects Of Substituting Iron For Manganese In Smmn₆Ge₆: Magnetic And Crystallographic Properties, J. Han, William B. Yelon, Naushad Ali, I. Dubenko, G. K. Marasinghe, Ph. I'Héritier, William Joseph James

Physics Faculty Research & Creative Works

No abstract provided.

X-Ray Emission Following Low-Energy Charge Exchange Collisions Of Highly Charged Ions, P. Beiersdorfer, Ronald E. Olson, G. V. Brown, H. Chen, C. L. Harris, P. A. Neill, L. Schweikhard, S. B. Utter, K. Widmann

Physics Faculty Research & Creative Works

K-shell x-ray emission following low-energy charge exchange collisions (≤11 eV/amu) has been measured for ten bare and hydrogenic ions up to U⁹¹⁺. The data resolve capture into angular momentum states with ℓ=1 and provide a stringent test of theory. The assumption of Stark mixing of angular momentum states is inappropriate at such energies. Results from detailed calculations give a better description of the data, but significant discrepancies are noted. The measurements show that the hardness ratio of charge-exchange induced K-shell x-ray emission represents a diagnostic of the dynamics of ion-atom interactions in situations where the energy is below …