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1999

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Articles 121 - 150 of 2333

Full-Text Articles in Physical Sciences and Mathematics

Implementing Sap R/3 At The University Of Nebraska, T. Sieber, Keng Siau, Fiona Fui-Hoon Nah, M. Sieber Dec 1999

Implementing Sap R/3 At The University Of Nebraska, T. Sieber, Keng Siau, Fiona Fui-Hoon Nah, M. Sieber

Research Collection School Of Computing and Information Systems

In April 1995, I asked four Nebraskans from the private sector and four senior people of the University to review the administrative processes of the University of Nebraska. In the appointment letter for this Task Force, I noted that many current administrative processes need to be examined to improve quality and productivity.


Measuring Information Quality Of Web Site: Development Of Instrument, P. Katerattanakul, Keng Siau Dec 1999

Measuring Information Quality Of Web Site: Development Of Instrument, P. Katerattanakul, Keng Siau

Research Collection School Of Computing and Information Systems

Web sites have been extensively used to provide information to consumers. While practitioners and researchers have proposed different criteria for effective Web site design based on common sense, intuition, and rules-ofthumb, effective Web site design focusing on the quality of the information it provides has rarely been studied. In this research, we propose a framework and develop an instrument to measure the information quality of individual or personal Web sites. The theoretical foundation of this research is the information quality framework. The proposed framework and instrument were tested in an individual or personal Web site context.


The Window Distribution Of Multiple Tcps With Random Loss Queues, Archan Misra, Teunis Ott, John Baras Dec 1999

The Window Distribution Of Multiple Tcps With Random Loss Queues, Archan Misra, Teunis Ott, John Baras

Research Collection School Of Computing and Information Systems

Two approximate techniques for analyzing the window size distribution of TCP flows sharing a RED-like bottleneck queue are presented. Both methods presented first use a fixed point algorithm to obtain the mean window sizes of the flows, and the mean queue length in the bottleneck buffer. The simpler of the two methods then uses the ‘square root formula’ for TCP; the other method is more complicated. More often than not, the simpler method is slightly more accurate; this is probably due to the fact that window sizes of the different flows are negatively correlated.


Mining Multiple-Level Association Rules In Large Databases, Jiawei Han, Yongjian Fu Dec 1999

Mining Multiple-Level Association Rules In Large Databases, Jiawei Han, Yongjian Fu

Computer Science Faculty Research & Creative Works

A top-down progressive deepening method is developed for efficient mining of multiple-level association rules from large transaction databases based on the Apriori principle. A group of variant algorithms is proposed based on the ways of sharing intermediate results, with the relative performance tested and analyzed. The enforcement of different interestingness measurements to find more interesting rules, and the relaxation of rule conditions for finding `level-crossing' association rules, are also investigated in the paper. Our study shows that efficient algorithms can be developed from large databases for the discovery of interesting and strong multiple-level association rules.


Application Of The Interaction Picture To Reactive Scattering In One Dimension, Michael J. Maclachlan Dec 1999

Application Of The Interaction Picture To Reactive Scattering In One Dimension, Michael J. Maclachlan

Theses and Dissertations

The interaction picture is used together with the channel-packet method in a new time-dependent approach to compute reactive scattering matrix elements. The channelpacket method enables the use of the interaction picture for computing reactive S-matrix elements by splitting the computational effort into two parts. First, asymptotic reactant and product wavepackets are individually propagated into the interaction region of the potential to form Moller states. The interaction picture, in contrast to the usual Schrödinger picture of quantum mechanics, is so constructed that a wavefunction that experiences no change in potential (that is, a free-particle wavefunction) remains always fixed, with no translation …


A Numerical Simulation Of A Carbon Black Suspension Cell Via A Time-Reversed, Double Layer Compute Algorithm, Gregg T. Anderson Dec 1999

A Numerical Simulation Of A Carbon Black Suspension Cell Via A Time-Reversed, Double Layer Compute Algorithm, Gregg T. Anderson

Theses and Dissertations

A numerical simulation of a carbon black suspension cell is explored which models a laser-induced plasma within a liquid ethanol medium of approximately 1 mm thickness. The simulation model assumes a laser pulse with a pulse width of approximately 9 nsecs propagating in the left-to-right direction striking the front surface of the medium and focusing to a spot within the liquid volume. When the energy density within a given irradiated volume is sufficiently high, it ignites the carbon particles and generates a large number of free electrons, i.e., a plasma. The plasma couples with the in-coming laser energy on a …


Network Security Versus Network Connectivity: A Framework For Addressing The Issues Facing The Air Force Medical Community, Franklin E. Cunningham Jr. Dec 1999

Network Security Versus Network Connectivity: A Framework For Addressing The Issues Facing The Air Force Medical Community, Franklin E. Cunningham Jr.

Theses and Dissertations

The Air Force has instituted Barrier Reef to protect its networks. The Air Force medical community operates network connections that are incompatible with Barrier Reef. To overcome this problem, OASD(HA) directed the Tri-Service Management Program Office (TIMPO) to develop an architecture that protects all military health systems and allows them to link with all three services and outside partners. This research studied the underlying networking issues and formed a framework based on data from network experts from the Air Force's medical centers and their base network organizations. The findings were compared TIMPO and a composite framework was developed that more …


Thermal Degradation Of Blends Of Polystyrene And Poly(Sodium 4-Styrenesulfonate) And The Copolymer, Poly(Styrene-Co-Sodium 4-Styrenesulfonate), Qiang Yao, Charles Wilkie Dec 1999

Thermal Degradation Of Blends Of Polystyrene And Poly(Sodium 4-Styrenesulfonate) And The Copolymer, Poly(Styrene-Co-Sodium 4-Styrenesulfonate), Qiang Yao, Charles Wilkie

Chemistry Faculty Research and Publications

The thermal degradation of blends and copolymers of styrene with styrenesulfonic acid has been studied using thermogravimetric analysis, TGA/FTIR, and cone calorimetry. The blends have enhanced thermal stability relative to virgin polystyrene but there is no enhancement in thermal stability for the copolymers. Apparently, it is necessary to have adjacent sulfonic acid groups in order to permit the formation of a graphite-like char which can provide thermal protection to the polymer. It is necessary to have a good match in degradation temperatures of the two components if one is to have significantly enhanced thermal stability.


Implementation Of Speech Recognition Software For Text Processing: An Exploratory Analysis, Sean P. Abell Dec 1999

Implementation Of Speech Recognition Software For Text Processing: An Exploratory Analysis, Sean P. Abell

Theses and Dissertations

The rationale behind implementing new information technologies is often to gain productivity improvements associated with the substitution of machinery for labor. However, the literature shows little direct evidence of a positive relationship between information technology investment and subsequent productivity benefits. This thesis reports on the examination into the productivity implications of implementing speech recognition software in a text processing environment. More specifically, research was conducted to compare text processing speeds and error rates using speech recognition software versus the keyboard and mouse. Of interest was the time required to input and proofread text processing tasks as well as the number …


Towards A Game Theory Model Of Information Warfare, David A. Burke Dec 1999

Towards A Game Theory Model Of Information Warfare, David A. Burke

Theses and Dissertations

The repeated game of incomplete information model, a subclass of game theory models, was modified to include aspects of information warfare. The repeated game of incomplete information model was first developed to analyze nuclear weapons disarmament negotiations. The central role of information in this model suggested its applicability to IW, which focuses on the defense and acquisition of information. A randomized experimental design was utilized to determine how people behave in a laboratory IW setting and to test the IW game model's basic predictions. The impact of experience and learning on IW performance was also assessed during the experiment. IW …


Power, Performance, And Perception (P3): Integrating Usability Metrics And Technology Acceptance Determinants To Validate A New Model For Predicting System Usage, Alan P. Fiorello Dec 1999

Power, Performance, And Perception (P3): Integrating Usability Metrics And Technology Acceptance Determinants To Validate A New Model For Predicting System Usage, Alan P. Fiorello

Theses and Dissertations

Currently, there are two distinct approaches to assist information technology managers in the successful implementation of office automation software. The first approach resides within the field of usability engineering, while the second approach is derived from the discipline of management information systems (MIS). However, neither approach has successfully produced conclusive evidence that explains what characteristics facilitate system use as well as influence user acceptance of the system. This study reports on the validity of a new model, entitled the Power, Performance, Perception (P3) model, that links the constructs of usability engineering to user acceptance. Additionally, speech recognition software (SRS) was …


Evaporation Of Jet Fuels, Charles Eric Hack Dec 1999

Evaporation Of Jet Fuels, Charles Eric Hack

Theses and Dissertations

Determining the fate and transport of JP-8 jet fuel is a complex and important problem. As part of the startup procedures for jet engines, fuel is passed through aircraft engines before combustion is initiated. Because of the extremely low temperatures at northern tier Air Force bases, the unburned fuel does not evaporate readily and may come into contact with ground crew. To determine the amount and duration of contaminant contact, the evaporation of the emitted fuel must be modeled. The amount and composition of the fuel upon reaching the ground crew may be determined by droplet evaporation models that have …


Information System Incidents: The Development Of A Damage Assessment Model, Mark D. Horony Dec 1999

Information System Incidents: The Development Of A Damage Assessment Model, Mark D. Horony

Theses and Dissertations

Information system (IS) incidents are on the rise. With low manning and undertrained information security specialists it is difficult for organizations to stop IS incidents from occurring. Once an incident has occurred it is the IS manager's responsibility to ensure that a full and accurate damage assessment has been accomplished. However, most IS managers lack the necessary tools to assess the damage from an incident. This exploratory thesis developed an IS incident damage assessment model (DAM) that can be part of the IS manager's tool kit. During the development of the model, it became apparent that the model was supported …


What Else Do We Forget To Tell Our Teachers?: A Response To Dancis, Stephen Sproule Nov 1999

What Else Do We Forget To Tell Our Teachers?: A Response To Dancis, Stephen Sproule

Humanistic Mathematics Network Journal

No abstract provided.


Interior-Point Methods And Modern Optimization Codes, Goran Lesaja Nov 1999

Interior-Point Methods And Modern Optimization Codes, Goran Lesaja

Mathematical Sciences: Faculty Publications

During the last fifteen years we have witnessed an explosive development in the area of optimization theory due to the introduction and development of interior-point methods. This development has quickly led to the development of new and more efficient optimization codes. In this paper, the basic elements of interior-point methods for linear programming will be discussed as well as extensions to convex programming, complementary problems, and semidefinite programming. Interior-point methods are polynomial and effective algorithms based on Newton 's method. Since they have been introduced, the classical distinction between linear programming methods, based on the simplex algorithm, and those methods …


Lattice-Stiffening Transition In Copolymer Films Of Vinylidene Fluoride (70%) With Trifluoroethylene (30%), C.N. Borca, Shireen Adenwalla, Jaewu Choi, P.T. Sprungerr, Stephen Ducharme, Lee Robertson, S.P. Palto, Jianglai Liu, Matt Poulsen, V.M. Fridkin, H. You, Peter A. Dowben Nov 1999

Lattice-Stiffening Transition In Copolymer Films Of Vinylidene Fluoride (70%) With Trifluoroethylene (30%), C.N. Borca, Shireen Adenwalla, Jaewu Choi, P.T. Sprungerr, Stephen Ducharme, Lee Robertson, S.P. Palto, Jianglai Liu, Matt Poulsen, V.M. Fridkin, H. You, Peter A. Dowben

Peter Dowben Publications

We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss …


Pushpush Is Np-Hard In 3d, Joseph O'Rourke, The Smith Problem Solving Group Nov 1999

Pushpush Is Np-Hard In 3d, Joseph O'Rourke, The Smith Problem Solving Group

Computer Science: Faculty Publications

We prove that a particular pushing-blocks puzzle is intractable in 3D. The puzzle, inspired by the game PushPush, consists of unit square blocks on an integer lattice. An agent may push blocks (but never pull them) in attempting to move between given start and goal positions. In the PushPush version, the agent can only push one block at a time, and moreover, each block, when pushed, slides the maximal extent of its free range. We prove this version is NP-hard in 3D by reduction from SAT. The corresponding problem in 2D remains open.


Studies On Methods Of Fuel Cells Electrodes Preparation, Jun Gu, Sheng Sui, Guang-Qiang Li, Zhitong Sui Nov 1999

Studies On Methods Of Fuel Cells Electrodes Preparation, Jun Gu, Sheng Sui, Guang-Qiang Li, Zhitong Sui

Journal of Electrochemistry

In fuel cells, the structure of electrodes is an important factor which effect the cell performance. To improve the structure and the performance of electrodes, a new method of providing fuel cell electrodes is proposed in this paper. PTFE (polytetrafluoroethylene) and ethyne black was ground for about half an hour in a high-speed grinder, then the catalyst was added into the grinder and milled for an hour. This milled catalyst was transferred into a mixer followed by the addition of surface-active agent. After a suspension was formed, it was filtered under vacuum condition.Then a thin uniform filter-cake of the catalyst …


A Novel Reaction Region Moving Electrode System For Electrochemical Power Sources, Jin-Kua You, Que Tu, Zheng-Jian Wang, Jie Sun, Zu-Geng Lin Nov 1999

A Novel Reaction Region Moving Electrode System For Electrochemical Power Sources, Jin-Kua You, Que Tu, Zheng-Jian Wang, Jie Sun, Zu-Geng Lin

Journal of Electrochemistry

In most of practical rechargeable batteries, charging/discharging process is always concerned with phase-transformation in the solid state. Due to the irreversibility of the phase-transformation, the cyclic performance of the rechargeable batteries are limited. In this paper, a novel reaction-region moving counter electrode system is constructed in our laboratory. The electrode system is operated at room temperature and cycled in solid-liquid phase during charging/discharging processes. With this electrode, the metal-complexes are firstly deposited (i.e. charging process) on the nearest working electrode and gradually extended to those another working electrodes several centimeters away from the counter electrode. The deposite is dissolved again …


Prparation Of Nanocrystaline Tio2(Anatase) With High Thermal And Textural Sability By Electrochemical Method, Dao-Bao Chu, Xing-Fu Zhou, Chang-Jian Lin, Jian-Guang Tang Nov 1999

Prparation Of Nanocrystaline Tio2(Anatase) With High Thermal And Textural Sability By Electrochemical Method, Dao-Bao Chu, Xing-Fu Zhou, Chang-Jian Lin, Jian-Guang Tang

Journal of Electrochemistry

Titanium alkoxides were prepared by anodic dissolution of metallic titanium in absolute ethanol in the presence of HN(C2H5)2·HCl (electro-conductive additives). The solution was directly hydrolyzed to prepare nanocrystalline of TiO2 (about 10nm)by a sol-gel process. The precursor gels was calcined at T =450 ℃ and 720 ℃ for 30 min, and nanocrystalline of TiO2 (anatase) with high textural and thermal stability was obtained. FTIR, XRD, TEM were used to characterize the structure of titanium alkoxides and nanocrystalline of TiO2. The characteristics of nanocrystalline of TiO2 was depended on the …


Surface Enhanced Raman Spectroscopic Study Of Scn- Adsorbed At The Copper And Gold Nanowire Arrays, Jian-Lin Yao, Guo-Ping Pan, Kuan-Hong Xue, Yong Xie, Jing Tang, Bin Ren, Dong-Mei Sun, Bing-Wei Mao, Zhong-Qun Tian Nov 1999

Surface Enhanced Raman Spectroscopic Study Of Scn- Adsorbed At The Copper And Gold Nanowire Arrays, Jian-Lin Yao, Guo-Ping Pan, Kuan-Hong Xue, Yong Xie, Jing Tang, Bin Ren, Dong-Mei Sun, Bing-Wei Mao, Zhong-Qun Tian

Journal of Electrochemistry

Two-dimensional arrays of Cu and Au nanowires have been fabricated by template synthesis method, using the anodic aluminum oxidation films as the template. The morphology of the nanowire array was monitored by atomic force microscope (AFM) in the dissolution processes of the alumina film. Based on the probe molecule strategy, the spectral feature of SCN- adsorbed at the Cu and Au nanowires with different diameters has been investigated by surface enhanced Raman spectroscopy (SERS). The results reveal that the intensity of the SERS bands depends on the length of the exposed nanowires. The C≡N stretching vibration frequency (νCN …


Aes Multi-Layer Structural Analysis Of Si Based Anodic Porous Alumina Films And Studies On Its Formation Mechanism, Jun-Hui Wu, Jian-Ping Zou, Qing Zhu, Xi-Mao Bao Nov 1999

Aes Multi-Layer Structural Analysis Of Si Based Anodic Porous Alumina Films And Studies On Its Formation Mechanism, Jun-Hui Wu, Jian-Ping Zou, Qing Zhu, Xi-Mao Bao

Journal of Electrochemistry

400 nm aluminum films were deposited onto a p-type, 0.5 Ω·cm,〈100〉oriented silicon wafers using electron beam evaporation technique. Then, the wafers was immersed in 15 wt% H2SO4 for porous-type over-anodization under a constant voltage of DC 60V. During the anodization,the temperature of the electrolyte was maintained at 0 ℃. The obtained samples were investigated by means of transmission electron microscopy, scanning electron microscopy, and AES depth profile for multi-layer structural information. In addition, the basic anodic formation mechanism of the Si-based aluminum films was brielfly discussed.


Study On Electrochemical Reduction Properties Of Nitrobenzene, Chu-Na Ma, Wen-Kui Zhang, Hui Huang, Yong-Ping Gan Nov 1999

Study On Electrochemical Reduction Properties Of Nitrobenzene, Chu-Na Ma, Wen-Kui Zhang, Hui Huang, Yong-Ping Gan

Journal of Electrochemistry

The electrochemical reduction characteristics of nitrobenzene was extensively investigated by using the techniques such as quasi-steady-state polarization, cyclic voltammetry, fast linear potential sweep method and chronoamperometry in this paper. The electroanalytic properties of Cu, Cu-Hg and Cu-Ni electrodes were evaluated. Based on the study of the transient steping behaviour of nitrobenzene to PAP, the reduction mechanism was discussed. The results showed that the transition steps existed on the electrochemical reduction of nitrobenzene in acidic solution, the reactant is also absorbed on electrodes surface. The control step in the reduction of nitrobenzene was ascribed to the diffusion of nitrobenzene and its …


High Performance Proton Exchange Membrane Fuel Cells, Jing-Rong Yu, Bao-Lian Yi, Ming Han, Xiao-Liang Cheng, Zhi-Gang Shao, Jing-Xin Zhang Nov 1999

High Performance Proton Exchange Membrane Fuel Cells, Jing-Rong Yu, Bao-Lian Yi, Ming Han, Xiao-Liang Cheng, Zhi-Gang Shao, Jing-Xin Zhang

Journal of Electrochemistry

Proton-exchange membrane fuel cells(PEMFC) using a perfluorosulfonic acid proton exchange membrane as an electrolyte can simplify water and electrolyte management. In this paper, the effects of thickness of PEM on the performance of PEMFC were studied. The Nafion-112 PEM and low platinum loading E-TEK electrode yielded very high power density, of the order of 0.95 W/cm2. The energy-conversion efficiency, the degree of platinum utilization and stability for PEMFC using Nafion 112 and E-TEK electrode were also investigated.


Photoelectrochemical Studies On The Tio2 Nanostructured Porous Film Sensitized By Cyanine Dye, Li Zhang, Mai-Zhi Yang, Xue-Bin Qiao, Yan-Zhong Hao, En-Qing Gao, Sheng-Min Cai Nov 1999

Photoelectrochemical Studies On The Tio2 Nanostructured Porous Film Sensitized By Cyanine Dye, Li Zhang, Mai-Zhi Yang, Xue-Bin Qiao, Yan-Zhong Hao, En-Qing Gao, Sheng-Min Cai

Journal of Electrochemistry

The photoelectrochemical behaviors of the TiOnanostructured porous film sensitized by cyanine dye were investigated in this paper. The results showed that the excitaed state level matched the conduction band edge of TiO2 nanoparticle. Therefore the sensitization of the dye can increase the photocurrent intensity of the TiOnanostructured electrode obviously and results in a red-shift of optical absorption from the ultra-violet region to the visible. As a result, the light-to-electricity conversion efficiency was improved evidently, the maximum value of IPCE has reached 12.1%.


Investigation Of Sodium Hypophosphite Anodic Oxidizing Behavior In The Process Of Acid Electroless Nickel Deposition, Mei-Yuan Wang, Ya-Fei Kuang, Yan Xu Nov 1999

Investigation Of Sodium Hypophosphite Anodic Oxidizing Behavior In The Process Of Acid Electroless Nickel Deposition, Mei-Yuan Wang, Ya-Fei Kuang, Yan Xu

Journal of Electrochemistry

The anodic oxidizing behavior of sodium hypophosphite in the process of electroless nickle deposition (pH=5.5) was investigated with the linear potential sweep method and alternating current impedance. The results indicated that, the oxidation of NaH2PO2 was a complicated electrochemical process and affected by the concentration of NaH2PO2, the temperature of the bath, the sweep rate and the existence of nickel ion. The NaH2PO2 electrooxidation reaction was very likely preceded by heterogeneous interface transformation process, which might be the control step of the whole anodic process.


The Preparation Of Flexible Polymeric Anode And The Measurement Of Its Protective Ability For Cathodic Protection, Ai-Ling Du, He-Ming Zhang, Ming-Zong Zhang, Shi-De Ma Nov 1999

The Preparation Of Flexible Polymeric Anode And The Measurement Of Its Protective Ability For Cathodic Protection, Ai-Ling Du, He-Ming Zhang, Ming-Zong Zhang, Shi-De Ma

Journal of Electrochemistry

The flexible electrode, whose shape can be changed freely, was made of ethenyl copolymer and conductive component and proper amount of additive for cathodic protection. The resistance of electrode was measured.In low concentration of H2SO4, the flexible electrode can be used as auxiliary anode to protect the carbon steel. The protection ability of the flexible auxiliary anode was measured too.


Studies Of The Electrode Preparation Of Electrode From Lead Carbonate For Lead Acid Batteryⅰ. The Activation Of The Pme, Zhong-Xu Dai, Di-Hua Wang, Jun-Wei Jiang, Yun-Hong Zhou, Jin-Yun Zou Nov 1999

Studies Of The Electrode Preparation Of Electrode From Lead Carbonate For Lead Acid Batteryⅰ. The Activation Of The Pme, Zhong-Xu Dai, Di-Hua Wang, Jun-Wei Jiang, Yun-Hong Zhou, Jin-Yun Zou

Journal of Electrochemistry

Lead carbonate which was an intermediate product in lead hydrometallurgy without pollution of lead vapor and sulfur dioxide was selected as electrode material of lead-acid batteries. In the present work, the performances of PbO2/PbSO4 or PbSO4/Pb electrode transformed from PbCO3 have been investigated by powder microelectrode technique combined with cyclic voltammetry. The results show that the CV characteristics of either negative or positive electrode prepared from PbCO3 is as good as that of both electrodes made from lead oxide produced by mill machine,when a powder microelectrode with PbCO3 transformed into PbSO 4 …


The Studies Of The (Photo) Electrochemical Character On The Electrodeposited Silver Indium Selenium Thin Films, Shao-Ai Xie, Xun-Nan Deng, You-Jin Kua Nov 1999

The Studies Of The (Photo) Electrochemical Character On The Electrodeposited Silver Indium Selenium Thin Films, Shao-Ai Xie, Xun-Nan Deng, You-Jin Kua

Journal of Electrochemistry

A photoelectrochemical cell (PEC) is constructed, using an AgInSe2 film photoanode made from electrodeposition and a platinium electrode in aqueous polyiodide or polysufide electrolyte. The Voc and Isc of PEC have been tested and measured, and the effect of chemical decoration on the photoanodes also studied.


The Electrochemical Behaviors Of Superoxide Dismutase At Promoter Modified Gold Electrode, Xia-Qin Wu, Xiao-Yun Meng, Zhe-Su Wang, Zong-Rang Zhang Nov 1999

The Electrochemical Behaviors Of Superoxide Dismutase At Promoter Modified Gold Electrode, Xia-Qin Wu, Xiao-Yun Meng, Zhe-Su Wang, Zong-Rang Zhang

Journal of Electrochemistry

The electron-transfer process of superoxide dismutase was investigated by cyclic voltammetry at the 4,4'-dithiodipyridine, L-cysteine, histidine and arginine modified gold wire electrodes repectively. The quasi-reversible behavior was observed at L-cysteine modified gold electrode. An irreversible electrochemical behavior has been observed at hisdinine modified gold wire electrode.