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Full-Text Articles in Physical Sciences and Mathematics

Optimization Of Porous-Membranes Utilized In Chlor-Alkali Technology Via The Use Of Porosity And Electrochemical Impedance Spectroscopy, Jo Ann Jackson May 1996

Optimization Of Porous-Membranes Utilized In Chlor-Alkali Technology Via The Use Of Porosity And Electrochemical Impedance Spectroscopy, Jo Ann Jackson

Electronic Dissertations and Theses

A fundamental understanding of porous diaphragm membrane utilized by Dow Chemical Company in the production of chlorine gas and caustic soda, is integral to optimizing its performance. Several factors have been identified as integral components in this effort to optimize the chlorine cell diaphragm. Among these components are the diaphragm's porosity, pore size, thickness and tortuosity. Several methods have been utilized in an effort to determine not only the desired values of each of these variables but also to develop ways of achieving these desired values. Because not all of these variables can be measured directly, other methods of collecting …


A Coupled, Non-Linear, Steady State Model For Early Diagenetic Processes In Pelagic Sediments, Surya P. Dhakar, David J. Burdige Jan 1996

A Coupled, Non-Linear, Steady State Model For Early Diagenetic Processes In Pelagic Sediments, Surya P. Dhakar, David J. Burdige

OES Faculty Publications

A steady state, coupled, non-linear model has been developed for early diagenetic processes in pelagic and hemi-pelagic marine sediments. Model results show that the occurrence of oxic and sub-oxic diagenetic processes is significantly affected by variations in parameters such as the sedimentation rate, bioturbation coefficient, sediment porosity, and organic matter flux to the sediments. Increases in the sedimentation rate or the bioturbation coefficient increase organic matter oxidation by sub-oxic processes, whereas an increase in sediment porosity decreases organic matter oxidation by sub-oxic processes. Sediment data from three contrasting MANOP sites are fit reasonably well with the model. The resulting best-fit …