Physical Sciences and Mathematics Commons^™

A Study On The Causes Of Variations In Transmissivity And Storativity During Pump Tests At Asylum Lake, Paul Joseph Pare

Masters Theses

Over a two year period, Western Michigan University ran a number of pump tests in the Asylum Lake Area in Kalamazoo, Michigan. The transmissivities and storativities calculated from these tests differed significantly from well to well in any particular test, and from pump test to pump test. Utilizing the computer programs AQTESOLV 3.0 and Aquifer Parameter Estimator, a number of T and S values were calculated. After analysis of the results, the following conclusion was drawn. The main reason for the deviations in the T and S values arose from the mixing of the results of numerous methods (some of …

Effects Of Insulin And Insulin Mimetics On Antioxidant Enzyme Levels: In Vivo And In Vitro, Shikha Varma

Masters Theses

Tissue antioxidation status is considered to be an important factor for elucidating the etiology of diabetes and its physiological complications. This study was aimed to determine the in vivo antioxidant enzyme levels in the altered antioxidant status of diabetic rat liver with the treatment of two potent insulin mimetics, vanadium and selenate. The direct effects of vanadate, selenate, and zinc (another insulin mimetic) on the antioxidant enzyme levels in primary rat hepatocytes in culture was also determined. Levels of superoxide dismutase (SOD), catalase (CAT) and gluthahione peroxidase (GPX) were determined in both model systems.

In the vivo model, insulin treatment …

The Effects Of Air Sparging On Aquifer Hydraulic Conductivity, Hans Neve

Masters Theses

Air sparging is a relatively new technology used to remove organic contaminants from aquifers. This remediation technique involves injecting into contaminated portions of water table aquifers. Theoretically air sparging will reduce aquifer hydraulic conductivity. Injected air fills some of the available sediment pores, thus restricting the flow of water to the remaining water-filled pore spaces.

The purpose of this study was to measure the reduction in hydraulic conductivity due to air sparging. This was assessed using both laboratory and field techniques. The hydraulic conductivities of several different sediments were determined in the laboratory using a large constant head permeameter modified …

Band Structure For Acoustic Waves Propagating In A Periodic Elastic Media And Impurity Modes Arising From Slab Substitutions, Abdur Rahman

Masters Theses

In this thesis I study the band structure for acoustic waves propagating in a one-dimensional elastic array which forms a periodic elastic system in which band gaps are opened in the frequency spectrum. Specifically, I study the single impurity problem in this system. An impurity is introduced in the system by replacing one of the acoustic slabs with a new slab of different acoustic medium or by changing the thickness of impurity slab. I study the very narrow (in frequency) impurity modes in the band gaps which are localized about the impurity sites. Then I study the frequency of impurity …

The Variability Of Carbon Dioxide In The Vadose Zone, John J. Ring

Masters Theses

The purpose of this thesis was to observe and attempt to explain the variations of carbon dioxide in the vadose zone of a nature area in southwestern Michigan. Well nests, consisting of discrete soil gas sampling points and temperature probes set at depths ranging from 3 to 53 feet, were constructed in a sandy, glacial outwash plain. Soil samples were collected for analysis of organic carbon content during installation. Soil gas samples were collected periodically from June, 1992 to March, 1993 and analyzed for CO₂ and O₂ concentrations. Occasionally, samples were collected and analyzed for isotopic C^{13 …}

Evaluation Of Bail-Down Test Methods For Characterizing Free Product Recoverability From An Aquifer, Laura L. Krol

Masters Theses

Determination of the occurrence and recoverability of free product impacting the subsurface environment has been an on-going challenge in the environmental industry. A simple and relatively inexpensive test to perform in the field is the free product bail-down test. Many authors have proposed various analysis methods using these data for the determination of different free product characteristics.

The purpose of this project was to determine the comparability and possible validity of bail-down test interpretation methods for predicting hydrocarbon hydraulic conductivity/transmissivity and true free product thickness. Bail-down test data collected from two sites were analyzed and interpreted using methods from the …

Regulation Of The Expression Of Lipogenic Enzymes By Insulin-Mimetics, Juiyu Wu

Masters Theses

Many researchers have shown that selenate (SeO₄^2-) and vanadate (VO₄^2-) have insulin-mimetic effects in certain biological processes. These mimetic effects include increasing glucose transport, regulating glycolytic enzymes, normalizing plasma glucose levels and activities of insulin regulated enzymes in diabetic rats. To clarify the functions and roles of these insulin-mimetics in different insulin-regulated metabolic pathways, the expression of the genes for glucose-6-phosphate dehydrogenase (G6PDH) and fatty acid synthase (FAS) were investigated. G6PDH is a key enzyme in the pentose phosphate pathway and is also involved in lipogenic metabolism by providing 55-70% of the NADPH utilization …

A Comparison Of Methods To Allocate Tasks On A Multiprocessor System, Kelly Cousineau

Masters Theses

The task scheduling problem is defined as a sequential algorithm, with individual tasks, t₁, t₂, t₃… having associated execution times to be ported to a multiprocessor system. To determine the fastest parallel implementation is known to be an NP-complete problem, therefore heuristic techniques are employed to arrive at the best solution.

Some of the traditional methods used to solve this problem, are the list scheduling algorithm and the simulated annealing algorithm. However, evolutionary techniques are now also a consideration with the increased computation power available.

Evolutionary techniques, based on the popular theory of evolution, …

Stratigraphy, Structure, And Environmental Site Assessment Of A Portion Of The Western Blue Ridge, Monroe County, Tennessee, Donald James Geddes

Masters Theses

The western Blue Ridge in southeastern Tennessee is underlain principally by metasedimentary rocks of the Walden Creek and Great Smoky Groups (Ocoee Supergroup). These rocks have traditionally been interpreted as turbiditic synrift sediments deposited along the Late Proterozoic to Early Cambrian southeastern Laurentian margin, which were subsequently metamorphosed and deformed during an early Paleozoic (Taconic) orogeny, then brittlely deformed and thrust westward during a late Paleozoic (Alleghanian) orogeny. More recent hypotheses suggest that at least part of the Walden Creek Group was deposited above the regional Middle Ordovician unconformity in post-Taconic successor basins, and deformed and metamorphosed only during a …

A Feasibility Study For Using Computerized Water Well Records To Delineate Areas Of Recharge-Discharge Potential, Lauren D. Hughes

Masters Theses

A method for delineating areas of recharge-discharge potential has been developed utilizing computerized water well records. The methodology is based on the vertical head differences found between wells with shallow depths of submergence and those with deeper depths of submergence. The residual values generated represent the magnitude of vertical potential and can be contoured to delineate areas of recharge-discharge potential. Well data were obtained from the Kalamazoo County Groundwater Database. Well selection was based on depth of submergence and total well depth.

The methodology was tested in Texas and Schoolcraft Townships, the Donnell Lake Study Area, and Kalamazoo County. Regularly …

A Unified Approach To Multilayer Routing, Sreekrishna Madhwapathy

Masters Theses

Several Over-the-Cell (OTC) routing algorithms have been proposed for two and three layer processes. All the existing OTC routers assume that the terminals are laid out in a specific predetermined fashion. These restrictions on the terminals complicate the task of cell design and increase the width of the cells.

In this thesis, we report two results. First, we present a new layout methodology, for obtaining minimum width cells, with arbitrarily located terminals. Next, we develop a multilayer routing approach, which is independent of the cell model used in the layout design. Freed from fixed terminal placement restrictions, cell designers can …

Structural Effects On Micellar Catalyzed Hydrolysis Of Hydroxamic Acids With Perfluorooctanoic Acid As Surfactant, Xing Zhang

Masters Theses

This thesis demonstrated the structural effects on micellar catalyzed hydrolysis of hydroxamic acids with prefluorooctanoic acid as the reactive counterion surfactant in aqueous acetonitrile solution.

For different hydroxamic acids, the observed pseudo-first order rate constant-surfactant concentration profiles were obtained and were used in the determination of critical micellar concentrations (cmc).

The micellar catalytic effect was satisfactorily explained by the pseudo-phase ion exchange (PPIE) model. The PPIE model was successfully applied in the determination of the reaction rate constants both in the water phase and in micellar pseudo-phase.

Further investigation into more appropriate hydroxamic acids is suggested in order to obtain …

Geophysical Investigation At The Mouth Of The St. Joseph River Valley And Adjacent Lake Michigan Shoreline In St. Joseph And Benton Harbor, Michigan, David L. Seng

Masters Theses

A combination of geophysical methods were employed in an attempt to characterize a small section of the shoreline of the St. Joseph, Michigan, region of the Lake Michigan shoreline. Electrical resistivity and Ground Penetrating Radar profiles conducted along the shoreline and within the nearshore environment reveal a buried valley of the ancestral St. Joseph river. This valley represents incision of the channel during lowered lake levels at the end of the Pleistocene.

Lakeward dipping radar reflectors are identified throughout the study site. Within the buried valley the reflectors are not glacial till as is the case outside the inferred valley …

Hydrogeochemical Delineation Of A Groundwater Flow System, Berrien County, Michigan, Patrick J. Bartnik

Masters Theses

The objective of this study was to examine the possibility of determining groundwater flow directions from natural variations in groundwater chemistry. Groundwater samples were analyzed for major cation and anion concentrations. These data were to have been contoured and then compared with groundwater flow maps generated by conventional methods. The purpose was to determine whether a correlation could be drawn between the two methods. However, the results of the study did not allow for this comparison.

The plotted major cation and anion data did not lend themselves to contouring, which suggests that greater control may be required during the selection …

An Experimental Apparatus For Studying Differential Scattering Of Multiply-Charged Ions From Neutral Targets Following Capture, John Edward Edens

Masters Theses

An experimental apparatus has been designed, enabling measurement of angular differential cross sections for single-electron capture (SEC). The design consists of a microchannel plate detector with a one-dimensional position sensitive anode. A bow-time shaped aperture was employed to convert a radially scattered distribution into an approximate linear one. An electrostatic retarding grid was used to separate SEC contributions from the reaction products. Measurements were made of the angular differential cross sections for SEC of Ar^q+ (q=4-6,8) ions scattering from He and Ar at impact energies of 600 to 3000 eV and angles between 0 and 23 mrad. The experimental …

Planar Over The Cell Routing, Srinivasa R. Danda

Masters Theses

Planar over the cell routing in standard cell layouts is an important problem and it has been studied quite extensively. In two layer standard cell design methodology, Ml layer is typically used for connections internal to the cell, and the M2 layer is available for routing over-the-cell. In this thesis, we consider the Two Row Maximum Planar Subset (TRMPS) problem in Over-The-Cell routing. The TRMPS problem requires selection of the maximum planar subset of nets, which can be routed between two rows of terminals in a cell row. This problem was first encountered by Cong, Liu, and Preas [3]. They …

The Synthesis And Characterization Of Novel 5,6-Disubstituted 1,10-Phenanthrolines, Liansheng Zeng

Masters Theses

Two new ligands, 5-amino-6-nitro-1,10-phenanthroline (5-NH₂-6-NO₂-phen), produced by amination of 5-NO₂-1,10-phenanthroline, and 5,6-diamino-1,10-phenanthroline (5,6-(NH₂) ₂-phen) ,produced by reduction of 5-NH₂-6-NO₂-phen, have been synthesized and characterized. The ligand 5-NH₂-6-NO₂-phen has been coordinated to a Ru(II) metal center to produce the Ru(II)-polypyridine complex [ (bpy) ₂Ru (5-NH₂-6-NO₂-phen)] (PF₆ ) ₂ (bpy= 2, 2' -bipyridine) . This complex has been characterized by IR, UV-Vis, ¹H-NMR, and cyclic voltammetry (CV) .

The Synthesis And Characterization Of [Ruii (Bpy) 2 (Biphen) ] (Pf6)2 And [ (Bpy) 2ruii (Biphen) Ruii (Bpy) 2] (Pf6)4, Mei-Yueh Chang

Masters Theses

A new bidentate polypyridine bridging ligand (biphen), produced by the condensation of 1,10-phenanthroline-5,6-dione with 5,6-diamino-phenanthroline has been synthesized and characterized. In addition the monometallic complex [(bpy)₂Ru^II(biphen)](PF₆)₂ and the bimetallic complex [(bpy)₂Ru^II(biphen)Ru^II(bpy)₂](PF₆)₄ have been prepared. The complexes were characterized by elemental analysis, by ¹H-NMR spectroscopy and by cyclic voltsmmetry(CV).

The results of these analyses seem to indicate that biphen acts like two independent units when attached to a - Ru^II(bpy)₂ fragment. a bipyridine portion and a phenazine portion. Moreover, …

Equilibrium And Kinetic Studies Of Isomerization Of (Oc)5m[Η1-Pph2ch2ch(Pph2)2] And (Oc)5m[Η1-Pph2ch(Pph2)Ch2pph2] (M=Cr, Mo, W), Weiying Lin

Masters Theses

It has been found that (OC)₅M[η¹-PPh₂CH₂CH(PPh₂)₂] and (OC)₅M[η¹-PPh₂CH(PPh₂)CH₂PPh₂] (M=Cr, Mo, W) exist in equilibrium in solution. This linkage isomerization is the first experimental evidence for the exchange of terminal and coordinated phosphorus groups in pentacarbonyl complexes of group 6 metals.

(OC)₅M[η¹-PPh₂CH₂CH(PPh₂)₂] ⇌ (OC)₅M[η¹-PPh₂CH(PPh₂)CH₂PPh₂]

(M = Cr, Mo, W)

In this work, equilibrium …

Novel Compounds (Including Transition-Metal Complexes) Based On 1,10-Phenanthroline-5,6-Dione, Hui Zhou

Masters Theses

This thesis describes the synthesis of the transition metal complex [(bpy) ₂Os^II (pptd)] (PF₆)₂^·2H₂O, an analog of [(bpy) ₂Ru^II (pptd)] (PF₆)₂^·2H₂O. Spectroscopic and electrochemical data on this complex are reported here. It was found that the electronic communication between the metal center and the pteridinedione portion of pptd did not appear to be enhanced in the Os(II) complex relative to its Ru(II) analog. The increased ability of Os(II) to undergo backbonding appeared to affect only the 1,10-phenanthroline portion of pptd.

A useful …

Reproductive Success Of Grassland Birds At East-Central Illinois Airports, Eric L. Kershner

Masters Theses

We determined the densities and reproductive success of birds on airport grasslands in east-central Illinois. Seven airports were sampled between 10 April and 15 August 1994 in Clark, Coles, Crawford, Douglas, Edgar, Macon and Richland counties. Nineteen species were detected on the airport grasslands and 147 nests were found representing six different species. Eastern meadowlarks (Sturnella magna) were the most abundant nesting species found; 105 out of the 147 nests (71%). Other nesting species included: grasshopper sparrow (Ammodramus savannarum), savannah sparrow (Passerculus sandwichensis), red-winged blackbird (Agelaius phoeniceus), song sparrow (Melospiza melodia) and horned lark (Eremophilia alpestris). Overall nest success was …

Isomerization And Chelation Studies Of Dangling Phosphine Complexes Of Group 6, Zhongjiang Jia

Masters Theses

Vinyl addition reactions, catalyzed by 2,2'-azobis(isobutyronitrile) (AIBN), have been used to prepare six pentacarbonyl complexes of group 6, each of which contains a dangling Ph₂PCH₂CH₂P(p-tol)₂ ligand.

Each of the six complexes undergoes slow isomerizationand chelation at 55 °C in perdeuterated toluene:

The reactions were monitored by ³¹P{¹H} NMR spectroscopy. The isomerization reactions are reversible in solution, while the chelated products form irreversibly with the loss of carbon monoxide. The rate constants, K₁ and K_-1, have been determined for the three pairs of linkage isomers. Equilibrium …

The Synthesis Of N-Chlorosulfonyl Β-Lactams And Their Rearrangements, Lihua Zhang

Masters Theses

The synthesis of several N-chlorosulfonyl-β-lactams and their rearrangements have been carried out via CSI (chlorosulfonylisocyanate) reaction. The mechanism of β-lactam synthesis as well as its rearrangements were also studied. The characterization of β-lactams was performed with IR, ¹H and ¹³C NMR, and HRMS. β-lactams 2-chlorosulfonyl-1-methyl-2-azabicyclo[4.2.0]octan-3-one (71), 1-chlorosulfonyl-4-methyl-4- (phenylmethyl)azetidin-2-one (74) and 1-chlorosulfonyl-4,4- (diphenylmethyl)azetidin-2-one (75) were synthesized for the first time. β-lactam 4-chlorosulfonyl-3, 9, 9-trimethyl-4-azatricyclo [6.1.0.0^3,6] nonan-5-one (73) was obtained as crystalline solid instead of liquid.

Different effects, such as temperature, solvents and catalysts, on the rearrangement of the …